Identify the acid, base, conjugate acid and conjugate base in the following reactions:
a. NH_3(aq) + CH_3COOH(aq) NH_4^+ (aq) + CH_3COO^-(aq)
b. HClO_4(aq) + NH_4(aq) ClO_4^- (aq) + NH_4^+ (aq)

Answers

Answer 1

Answer:

a. NH₃ : base

CH₃COOH (acetic acid) : acid

NH₄⁺ : conjugate acid

CH₃COO⁻ : conjugate base

b. HClO₄ (perchloric acid) : acid

NH₃ : base

ClO₄⁻ : conjugate base

NH₄⁺ : conjugate acid

Hope this helps.


Related Questions

How does the carbon calculator estimate the amount of CO2 that each individual releases into the atmosphere?

Answers

Answer:

The calculator add the CO2 released from the use of electricity, released from driving and the CO2 from the waste that we disposed.

Explanation:

The carbon dioxide, CO2 is what the human body does not need, therefore, we breathe it out, hence taking in oxygen(respiration process). The plants need oxygen for the production of their own food.

The carbon calculator estimate the amount of CO2 that each individual releases into the atmosphere through the consideration of several factors such as the kind of food that we eat.

Therefore, if we are to use the carbon calculator to determine the amount of CO2 that each individual releases into the atmosphere we will have:

The amount of CO2 that each individual releases into the atmosphere =( CO2 released from the use of electricity) + (CO2 released from driving) + (the CO2 from the waste that we disposed).

Which element has 4 valence electrons in the 3p sublevel?
The Periodic Table
A. Ga
B. Si
C. N
D. S

Answers

Answer:

D . Sulphur

Explanation:

the element with a 3p4 valence configuration, look in period 3 and group XVI, and that is ...

S, sulfur.

It’s definitely D: sulpher

The element nitrogen forms a(n) _______ with the charge . The symbol for this ion is , and the name is . The number of electrons in this ion is .

Answers

Answer:

The element nitrogen forms an anion with the charge -3. The symbol for this ion is N³⁻, and the name is nitride. The number of electrons in this ion is 10.

Explanation:

The element nitrogen is in the Group 15 in the Periodic Table, so it tends to gain 3 electrons (3 negative charges) to fill its valance shell with 8 electrons.

The element nitrogen forms an anion with the charge -3. The symbol for this ion is N³⁻, and the name is nitride. The number of electrons in this ion is 10 (the original 7 plus the 3 gained). It is isoelectronic with the gas Neon, which accounts for its stability.

What is the core charge of helium and why?

Answers

Answer:

Formula for effective nuclear charge is as follows. So, for He atom value of S = 0.30 because the electrons are present in 1s orbital. Therefore, calculate the effective nuclear charge for helium as follows. Thus, we can conclude that the effective nuclear charge for helium is 1.7

Explanation:

The effective nuclear charge experienced by a 1s electron in helium is +1.70.

When 75.5 grams of phosphorus pentachloride react with an excess of water, as shown in the unbalanced chemical equation below, how many moles of hydrochloric acid will be produced? Please show all your work for the calculations for full credit. PCl5 + H2O --> H3PO4 + HC

Answers

Answer:

Explanation: M(PCL5)= 31 + 5(35.5)

=208.5g/mol

M(H20)= 18g/mol

n(PCL5) = 75.5÷208.5

= 0.362mol

n(HCl)/n(PCL5)= 5/1

n(HCl)= 5×0.362

=1.81mol of HCl

Homolysis, or homolytic bond dissociation, produces a very specific type of product under certain reaction conditions. In Part 1, select all the products (in formulae and general chemical terms) that could result from homolysis. In Part 2, select the reaction conditions that are most likely to promote homolysis.
Part 1. Choose all that may occur as possible products of a homolysis reaction.
Choose one or more:_______.
a. hydride ion
b. R3CO
c. Br2
d. H
e. a carbocation
f. H3C
g. H3CO-
h. hydrogen ion
i. a carbon free radical
Part 2. Choose the conditions under which homolysis is likely to occur.
Choose one or more:_______.
a. strong base
b. ultraviolet irradiation
c. high temperature
d. strong acid
e. infrared irradiation
f. low temperature

Answers

Answer:

1) R₃CO , H, H₃C, a carbon free radical

2) high temperature, ultraviolet irradiation

Explanation:

1) Homolysis leads to the formation of free radicals (species having a free electron). Thus, answer is :

R₃CO

H

H₃C

a carbon free radical

2) Homolysis require high temperature, ultraviolet irradiation.

Which of the following is NOT one of the types of bonds? A. Ionic B. Metallic C. Covalent D. Valence

Answers

Considering the definition of bond and the different type of bonds, valence is not one of  the types of bonds.

What is a chemical bond

A chemical bond is defined as the force by which the atoms of a compound are held together. These are electromagnetic forces that give rise to different types of chemical bonds.

In other words, a chemical bond is the force that joins atoms to form chemical compounds and confers stability to the resulting compound.

Covalent bond

The covalent bond is the chemical bond between atoms where electrons are shared, forming a molecule. Covalent bonds are established between non-metallic elements, such as hydrogen H, oxygen O and chlorine Cl. These elements have many electrons in their outermost level (valence electrons) and have a tendency to gain electrons to acquire the stability of the electronic structure of noble gas. The shared electron pair is common to the two atoms and holds them together.

Ionic bond

An ionic bond is produced between metallic and non-metallic atoms, where electrons are completely transferred from one atom to another. During this process, one atom loses electrons and another one gains them, forming ions.

Metallic bond

Metallic bonds are a type of chemical bond that occurs only between atoms of the same metallic element. In this way, metals achieve extremely compact, solid and resistant molecular structures, since the atoms that share their valence electrons.

Summary

In summary, valence is not one of  the types of bonds. The types of bonds are covalent, ionic and metallic.

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If you combine 24.2 g of a solute that has a molar mass of 24.2 g/mol with 100.0 g of a solvent, what is the molality of the resulting solution

Answers

Answer: 10 moles/kg.

Explanation:

Given, Mass of solute = 24.2 g

Molar mass of solute = 24.2 g/mol

[tex]\text{Moles of solute =}\dfrac{\text{Mass of solute}}{\text{Molar mass of solute}}\\\\=\dfrac{24.2}{24.2}=1[/tex]

Mass of solvent = 100.0g = 0.1 kg  [1 g=0.001 kg]

[tex]\text{Molality}=\dfrac{\text{Moles of solute}}{\text{kilograms of Solvent}}\\\\=\dfrac{1}{0.1}\\\\=10\ moles/kg[/tex]

Hence, the molality of the resulting solution is 10 moles/kg.

How many valence electrons are in the electron dot structures for the elements in group 3A(13)?

Answers

Answer:

here, as we have known the elements of group 3A(13) such as aluminium , boron has three valance electron and in perodic table the elements are kept with similar proterties in same place so, their valance electron is 3.

hope it helps...

The number of valence electrons are in the electron dot structures for the elements in group 3A(13) is three.

What are Groups in the Periodic Table?

The periodic table is organized into groups (vertical columns), periods (horizontal rows), and families (groups of elements that are similar). Elements in the same group have the same number of valence electrons.

Groups are the columns of the periodic table, and periods are the rows. There are 18 groups, and there are 7 periods plus the lanthanides and actinides.

There are two different numbering systems that are commonly used to designate groups, and you should be familiar with both.

The traditional system used in the United States involves the use of the letters A and B. The first two groups are 1A and 2A, while the last six groups are 3A through 8A. The middle groups use B in their titles.

Therefore, The number of valence electrons are in the electron dot structures for the elements in group 3A(13) is three.

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Identify the following substances:
(1) An acidic gas which gives dense white fumes with NH3
(11 An alkane which can also be called a green house gas.
(iii) A solid which when kept in the open, forms a solution after som
(iv) An alloy used in electrical fittings.
(v) A metal which gives hydrogen gas on reacting with both dilute a
Write equations for the following reactions:
Aluminium oxide and Sodium hydroxide.
(ii) Zine and dilute sulphuric acid.
(
11​

Answers

Answer:

1) HCl (Hydrochloric acid reacts with NH3 and forms dense fumes)

2) Methane (It is from the group of alkanes and is a green house gas)

3) Deliquescent substance (It is a solid which when kept in open forms a solution after sometime)

4) Brass (It is a solid-in-solid solution used to make electrical fittings)

5) Aluminium

Question 2:

1)    Al₂O₃ + 2NaOH    ⇒   2NaAlO₂  (Sodium Aluminate) + H₂O

2)   Zn +  H₂SO₄   (dilute)  =>  ZnSO₄  (Zinc Sulphate) + H₂

Answer:

HCl is the gasmethanedeliquescent substances (they absorbs water out of the air until they dissolve themselves into liquid solutions. )brass

equations

Aluminium oxide and Sodium hydroxide react to form water and sodium aluminate

Al2O3 + 2NaOH → 2NaAlO2 + H2O

Zinc reacts with dilute sulphuric acid to form zinc sulphate and hydrogen gas

Zn + H2SO4 → ZnSO4 +H2

List the following compounds in order from strongest acid to weakest acid. Rank the acids from strongest to weakest.
CH2CHCH2COOH CH2CH2CH2COOH CH3CHCH2COOH CH3CH2CH2COOH
Strongest Weakest

Answers

Answer:

CH3CH2CH2COOH<CH2(F)CH2CH2COOH<CH3CH(F)CH2COOH<CH2(F)CH(F)CH2COOH

Explanation:

We know that the presence of highly electronegative elements in carboxylic acid molecules lead to -I inductive effect. This implies that electrons are withdrawn along the chain towards the electronegative element. As electrons are withdrawn towards the electronegative element, the electron cloud of the carbonyl- hydrogen bond in the acid weakens and the hydrogen can now be easily lost as a proton, that is , the molecule becomes more acidic.

The -I inductive effect increases with increase in the number of electronegative elements present in the molecule and the proximity of the electronegative element to the carbonyl group. The closer the electronegative element is to the carbonyl group, the greater the acidity of the molecule since the -I inductive effect dies out with increasing distance from the carbonyl group. Also, the more the number of electronegative elements in the molecule, the greater the - I inductive effect and the greater the acidity of the molecule, hence the answer.

An electrode has a negative electrode potential. Which statement is correct regarding the potential energy of an electron at this electrode?

A. An electron at this electrode has the same potential energy as it has at a standard hydrogen electrode.
B. An electron at this electrode has a lower potential energy than it has at a standard hydrogen electrode.
C. An electron at this electrode has a higher potential energy than it has at a standard hydrogen electrode.

Answers

Answer:

C. An electron at this electrode has a higher potential energy than it has at a standard hydrogen electrode.

Explanation:

The standard hydrogen electrode (SHE) is used to measure the electrode potential of substances. The standard hydrogen electrode is arbitrarily assigned an electrode potential of zero. Recall that electrode potentials are always measured as reduction potentials in electrochemical systems.

For an electrode that has a negative electrode potential, electrons at this electrode have a higher potential energy compared to electrons at the standard hydrogen electrode. Electrons flow from this electrode to the hydrogen electrode.

On the other hand, a positive electrode potential implies that an electron at this electrode has a lower potential energy than it has at a standard hydrogen electrode. Hence electrons will flow from the standard hydrogen electrode to this electrode.

neeeeed helpppppppppp

Answers

Answer:

Option C. Will always.

Explanation:

A spontaneous reaction is a reaction that occurs without an external supply of heat.

This implies that spontaneous reaction will always occur as no external supply of heat is needed.

Erbium metal (Er) can be prepared by reacting erbium(III) fluoride with magnesium; the other product is magnesium fluoride. Write and balance the equation.

Answers

Answer:

2ErF3 + 3Mg → 2Er + 3MgF2

Explanation:

Erbium metal is a member of the lanthaniod series. It reacts with halogens directly to yield erbium III halides such as erbium III chloride, Erbium III fluoride etc.

Erbium metal (Er) can be prepared by reacting erbium(III) fluoride with magnesium; the products are erbium metal and magnesium fluoride. This is a normal redox process in which the Erbium metal is reduced while the magnesium is oxidized. The balanced reaction equation of this process is; 2ErF3 + 3Mg → 2Er + 3MgF2

Which of the following atoms would have the longest de Broglie wavelength, if all have the same velocity?
A) Li
B) Na
C) Fe
D) Pb
E) Not possible to tell with given information

Answers

Answer:

Li

Explanation:

The phenomenon of wave particle duality was well established by Louis deBroglie. The wavelength associated with matter waves was related to its mass and velocity as shown below;

λ= h/mv

Where;

λ= wavelength of matter waves

m= mass of the particle

v= velocity of the particle

This implies that if the velocities of all particles are the same, the wavelength of matter waves will now depend on the mass of the particle. Hence; the wavelength of a matter wave associated with a particle is inversely proportional to the magnitude of the particle's linear momentum. The longest wavelength will then be obtained from the smallest mass of matter. Hence lithium which has the smallest mass will exhibit the longest DeBroglie wavelength

The atom that have the longest de Broglie wavelength is ; ( A ) Li

Wave particle duality is a phenomenon by de Broglie. that shows that The wavelength associated with matter waves is related to its mass and velocity .

Wave particle duality is represented as ;  λ = h / mv

λ= wavelength of matter waves

m= mass of the particle

v= velocity of the particle

Given that the elements have the same velocity the atom that would have the longest de Broglie wavelength is Li

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How fast are the atoms moving if the temperature of a gas is cold?

A. very, very slowly

B. they are stagnant

C. very, very quickly

Answers

Answer:

i think option a is correct answer because when there is low temperature then the kinetic enegry will be very less and the atoms moves very slowly.

Answer:

A. very, very slowly

Explanation:

A is the answer because atoms will move faster in hot gas than in cold gas.

A 0.4647-g sample of a compound known to contain only carbon, hydrogen, and oxygen was burned in oxygen to yield 0.01962 mol of CO2 and 0.01961 mol of H2O. The empirical formula of the compound was found to be C3H6O2. Show how this was calculated.

What does the empirical formula tell you about the compound?

The molar mass of the actual compound was found to be 222.27g/mol. Find the molecular formula of this compound. What does the molecular formula tell you about the compound?

Can you see what type of functional group this compound could have?

Answers

Answer:

See explanation.

Explanation:

Hello,

In this case, we can show how the empirical formula is found by following the shown below procedure:

1. Compute the moles of carbon in carbon dioxide as the only source of carbon at the products:

[tex]n_C=0.01962molCO_2*\frac{1molC}{1molCO_2} =0.01962molC[/tex]

2. Compute the moles of hydrogen in water as the only source of hydrogen at the products:

[tex]n_H=0.01961molH_2O*\frac{2molH}{1molH_2O}=0.03922molH[/tex]

3. Compute the mass of oxygen by subtracting the mass of both carbon and hydrogen from the 0.4647-g sample:

[tex]m_O=0.4647g-0.01962molC*\frac{12gC}{1molC}-0.03922molH*\frac{1gH}{1molH} =0.1900gO[/tex]

4. Compute the moles of oxygen by using its molar mass:

[tex]n_O=0.1900gO*\frac{1molO}{16gO}=0.01188molO[/tex]

5. Divide the moles of carbon, hydrogen and oxygen by the moles of oxygen (smallest one) to find the subscripts in the empirical formula:

[tex]C=\frac{0.01962}{0.01188}=1.65\\ \\H=\frac{0.03922}{0.01188} =3.3\\\\O=\frac{0.01188}{0.01188} =1[/tex]

6. Search for the closest whole number (in this case multiply by 2):

[tex]C_3H_6O_2[/tex]

Moreover, the empirical formula suggests this compound could be carboxylic acid since it has two oxygen atoms, nevertheless, this is not true since the molar mass is 222.27 g/mol, therefore, we should compute the molar mass of the empirical formula, that is:

[tex]M=12*3+1*6+16*2=74g/mol[/tex]

Which is about three times in the molecular formula, for that reason, the actual formula is:

[tex]C_9H_{18}O_6[/tex]

It suggest that the compound has a highly oxidizing character due to the presence of oxygen, therefore, we cannot predict the distribution of the functional groups as it could contain, carboxyl, carbonyl, hydroxyl or even peroxi.

Best regards.

What volume of CH4(g), measured at 25oC and 745 Torr, must be burned in excess oxygen to release 1.00 x 106 kJ of heat to the surroundings

Answers

Answer:

[tex]V=27992L=28.00m^3[/tex]

Explanation:

Hello,

In this case, the combustion of methane is shown below:

[tex]CH_4+2O_2\rightarrow CO_2+2H_2O[/tex]

And has a heat of combustion of −890.8 kJ/mol, for which the burnt moles are:

[tex]n_{CH_4}=\frac{-1.00x10^6kJ}{-890.8kJ/mol}= 1122.6molCH_4[/tex]

Whereas is consider the total released heat to the surroundings (negative as it is exiting heat) and the aforementioned heat of combustion. Then, by using the ideal gas equation, we are able to compute the volume at 25 °C (298K) and 745 torr (0.98 atm) that must be measured:

[tex]PV=nRT\\\\V=\frac{nRT}{P}=\frac{1122.6mol*0.082\frac{atm*L}{mol*K}*298K}{0.98atm}\\\\V=27992L=28.00m^3[/tex]

Best regards.

Chemistry question. Image attached.

Answers

Answer:

The answer to your question is given below

Explanation:

The balanced equation for the reaction is given below:

CaO(s) + CH4(g) + 2H2O(g) <=> CaCO3(s) + 4H2(g)

1. Writing an expression for the equilibrium constant, K.

The equilibrium constant, K for a reaction is simply the ratio of the concentration of the products raised to their coefficient to the concentration of the reactants raised to their coefficient.

Thus, we can write the equilibrium constant, K for the reaction as follow:

CaO(s) + CH4(g) + 2H2O(g) <=> CaCO3(s) + 4H2(g)

K = [CaCO3] [H2]⁴ / [CaO] [CH4] [H2O]²

2. Based on the value of K, more products will be in the equilibrium mixture since the value of K is a positive large number.

The rate at which two methyl radicals couple to form ethane is significantly faster than the rate at which two tert-butyl radicals couple. Offer two explanations for this observation.

Answers

Answer:

1. stability factor

2. steric hindrance factor

Explanation:

stability of ethane is lesser to that of two tert-butyl, so ethane will be more reactive and faster.

ethane is less hindered and more reactive, while two tert-butyl is more hindered and less reactive

A sample of gas is observed to effuse through a pourous barrier in 4.98 minutes. Under the same conditions, the same number of moles of an unknown gas requires 6.34 minutes to effuse through the same barrier. The molar mass of the unknown gas is:________.
g/mol.

Answers

Answer:

The molar mass of the unknown gas is [tex]\mathbf{ 51.865 \ g/mol}[/tex]

Explanation:

Let assume that  the gas is  O2 gas

O2 gas is to effuse through a porous barrier in time t₁ = 4.98 minutes.

Under the same conditions;

the same number of moles of an unknown gas requires  time t₂  =  6.34 minutes to effuse through the same barrier.

From Graham's Law of Diffusion;

Graham's Law of Diffusion states that, at a constant temperature and pressure; the rate of diffusion of a gas is inversely proportional to the square root of its density.

i.e

[tex]R \ \alpha \ \dfrac{1}{\sqrt{d}}[/tex]

[tex]R = \dfrac{k}{d}[/tex]  where K = constant

If we compare the rate o diffusion of two gases;

[tex]\dfrac{R_1}{R_2}= {\sqrt{\dfrac{d_2}{d_1}}[/tex]

Since the density of a gas d is proportional to its relative molecular mass M. Then;

[tex]\dfrac{R_1}{R_2}= {\sqrt{\dfrac{M_2}{M_1}}[/tex]

Rate is the reciprocal of time ; i.e

[tex]R = \dfrac{1}{t}[/tex]

Thus; replacing the value of R into the above previous equation;we have:

[tex]\dfrac{R_1}{R_2}={\dfrac{t_2}{t_1}}[/tex]

We can equally say:

[tex]{\dfrac{t_2}{t_1}}= {\sqrt{\dfrac{M_2}{M_1}}[/tex]

[tex]{\dfrac{6.34}{4.98}}= {\sqrt{\dfrac{M_2}{32}}[/tex]

[tex]M_2 = 32 \times ( \dfrac{6.34}{4.98})^2[/tex]

[tex]M_2 = 32 \times ( 1.273092369)^2[/tex]

[tex]M_2 = 32 \times 1.62076418[/tex]

[tex]\mathbf{M_2 = 51.865 \ g/mol}[/tex]

If the vinegar were measured volumetrically (e.g., a pipet), what additional piece of data would be needed to complete the calculations for the experiment?

Answers

Answer:

the density if vinegar will also be needed

Explanation:

Because this is an experiment of volumetric analysis

The thermochemical equation is for the reaction of hydrogen bromide gas to form hydrogen gas and bromine liquid. 2HBr(g) = H 2 (g)+ Br 2 (l) 72.6 kJ How many grams of HBr (g) would be made to react if 11.4 energy were provided?

Answers

Answer:

the mass of HBr that would react is 25.41 g of HBr

Explanation:

attached is the calculations.

Which physical method can be used for obtaining a sample of salt from a small beaker of salt water?
boiling
freezing
chromatography
sorting

Answers

Answer:

a. boiling

Explanation:

What is the absolute magnitude of the rate of change for [NH3] if the
rate of change for [Hz] is 9.00 M/s in the reaction 2 NH3(g) → N2(g) +
3 H2(g)?

Answers

Answer:

[tex]r_{NH_3,abs} =6.00\frac{M}{s}[/tex]

Explanation:

Hello,

In this case, we can write the law of mass action for the undergoing chemical reaction, based on the rates and the stoichiometric coefficients:

[tex]\frac{1}{-2}r_{NH_3} =\frac{1}{1} r_{N_2}=\frac{1}{3}r_{H_2}[/tex]

In such a way, knowing the rate of formation hydrogen (H₂), we can know the  rate of change of ammonia, that must be negative for consumption:

[tex]r_{NH_3} =\frac{-2}{3}r_{H_2}=\frac{-2}{3}*9.00\frac{M}{s} \\\\r_{NH_3} =-6.00\frac{M}{s}[/tex]

Nevertheless, the absolute magnitude will be positive:

[tex]r_{NH_3,abs} =6.00\frac{M}{s}[/tex]

Best regards.

what is the electron configuration of the iodide ion?
A. 1s²2s²2p⁶3s²3p⁶3d¹⁰4s²4p⁶4d¹⁰5s²
B. 1s²2s²2p⁶3s²3p⁶3d¹⁰4s²4p⁶
C. 1s²2s²2p⁶3s²3p⁶3d¹⁰4s²4p⁶4d¹⁰5s²5p⁶
D. 1s²2s²2p⁶3s²3p⁶3d¹⁰4s²4p⁶4d¹⁰

Answers

Answer:

the answer to this question is C

The electron configuration of the iodide ion is 1s²2s²2p⁶3s²3p⁶3d¹⁰4s²4p⁶4d¹⁰5s²5p⁶. The correct option is option C.

What is electron configuration ?

The arrangement of an atom's or molecule's electrons in their respective atomic or molecular orbitals is known as its electron configuration; for instance, the electron configuration of the neon atom is 1s2 2s2 2p6.

According to electronic configurations, electrons move individually within each orbital while interacting with the average field produced by all other orbitals. The corrosion potential and reactivity of an atom may be calculated from its electron configuration. The electron configuration of the iodide ion is  1s²2s²2p⁶3s²3p⁶3d¹⁰4s²4p⁶4d¹⁰5s²5p⁶.

Therefore, the correct option is option C.

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A constant volume and mass of helium gas at 77°C is heated so that the pressure of the gas doubles. What is the new temperature of the gas in Celsius degrees?

Answers

Answer:

427°C .

Explanation:

Step 1:

Data obtained from the question. This include the following:

Initial temperature (T1) = 77°C

Initial pressure (P1) = P

Final pressure (P2) = 2P

Final temperature (T2) =?

Step 2:

Conversion of celsius temperature to Kelvin temperature.

This is illustrated below:

T(K) = T (°C) + 273

Initial temperature (T1) = 77°C

Initial temperature (T1) = 77°C+ 273 = 350K

Step 3:

Determination of the new temperature. The new temperature can be obtained as follow:

P1/T1 = P2/T2

P/350 = 2P/T2

Cross multiply

P x T2 = 350 x 2P

Divide both side by P

T2 = (350 x 2P ) / P

T2 = 700K

Step 4:

Conversion of Kelvin temperature to celsius temperature.

This can be obtained as follow:

T(°C) = T(K) – 273

T(K) = 700K

T(°C) = 700 – 273

T(°C) = 427°C

Therefore, the new temperature of the gas is 427°C

How many minutes would be required to electroplate 25.0 grams of chromium by passing a constant current of 4.80 amperes through a solution containing CrCl3

Answers

Answer:

483.27 minutes

Explanation:

using second faradays law of electrolysis

A 1.00 liter solution contains 0.31 M sodium acetate and 0.40 M acetic acid. If 0.100 moles of barium hydroxide are added to this system, indicate whether the following statements are TRUE or FALSE . (Assume that the volume does not change upon the addition of barium hydroxide.)

a. The number of moles of CH3COOH will remain the same.
b. The number of moles of CH3COO- will increase.
c. The equilibrium concentration of H3O+ will decrease.
d. The pH will decrease.
e. The ratio of [CH3COOH] / [CH3COO-] will remain the same.

Answers

Answer and Explanation:

The buffer solution is composed by sodium acetate (CH₃COONa) and acetic acid (CH₃COOH). Thus, CH₃COOH is the weak acid and CH₃COO⁻ is the conjugate base, derived from the salt CH₃COONa.

If we add a strong base, such as barium hydroxide, Ba(OH)₂, the base will dissociate completely to give OH⁻ ions, as follows:

Ba(OH)₂ ⇒ Ba²⁺ + 2 OH⁻

The OH⁻ ions will react with the acid (CH₃COOH) to form the conjugate base CH₃COO⁻.

Initial number of moles of CH₃COOH = 0.40 mol/L x 1 L = 0.40 mol

Initial number of moles of CHCOO⁻= 0.31 mol/L x 1 L = 0.31 mol

moles of OH- added: 2 OH-/mol x 0.100 mol/L x 1 L = 0.200 OH-

According to this, the following are the answers to the sentences:

a. The number of moles of CH₃COOH will remain the same ⇒ FALSE

The number of moles of CH₃COOH will decrease, because they will react with OH⁻ ions

b. The number of moles of CH₃COO⁻ will increase ⇒ TRUE

Moles of CH₃COO⁻ will be formed from the reaction of the acid (CH₃COOH) with the base (OH⁻ ions)

c. The equilibrium concentration of H₃O⁺ will decrease ⇒ FALSE

The equilibrium concentration of OH⁻ is increased

d. The pH will decrease⇒ FALSE

pKa for acetic acid is 4.75. We add the moles of base to the acid concentration and we remove the same number of moles from the conjugate base in the Henderson-Hasselbach equation to calculate pH:

[tex]pH= pKa + log \frac{[conjugate base + base]}{[acid - base]}[/tex]

pH = 4.75 + log (0.31 mol + 0.20 mol)/(0.40 mol - 0.20 mol) = 5.15

Thus, the pH will increase.

You use 10.0 mL of solution A, 10.0 mL of solution B, and 70.0 mL of water for your first mixture. What is the initial concentration of KIO3

Answers

Complete Question

The complete question is shown on the first uploaded image

Answer:

The  initial concentration is  [tex]C_f = 0.0022 \ M[/tex]

Explanation:

From the question we are told that

    The volume of solution A is  [tex]V_i = 10.0 mL[/tex]

    The concentration of A is [tex]C_i = 0.0200 \ M[/tex]

    The volume of solution B  is  [tex]V_B = 10.0mL[/tex]

    The volume of water is  [tex]V_{w } = 70.0 mL[/tex]

Generally the law of dilution is mathematically represented as

             [tex]C_i * V_i = C_f * V_f[/tex]

Where  [tex]C_f[/tex] is the concentration of  the mixture

            [tex]V_f[/tex] is the volume of the mixture which is mathematically evaluated as

            [tex]V_f = 10 + 10 + 70[/tex]

           [tex]V_f = 90mL[/tex]

So  

      [tex]C_f = \frac{C_i * V_i}{ V_f}[/tex]

substituting values

       [tex]C_f = \frac{0.0200 * 10 }{90}[/tex]

       [tex]C_f = 0.0022 \ M[/tex]

Note the mixture obtained is  [tex]KIO_3[/tex]

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