An unknown acid was titrated two times with 0.10 M NaOH. The first titration was done using an indicator to determine the equivalence point volume. A second titration was carried out where the pH was determined throughout the entire titration. The data is given below.
Titration 1: mL unknown acid = 25.0, mL of NaOH needed to reach equivalence point = 30.00
Titration 2: mL unknown acid = 25.0
mL 0.1M pH
NaOH Added
0.0 3.72
5.0 5.82
10.0 6.22
15.0 6.52
20.0 6.82
25.0 7.22
30.0 9.63
35.0 11.92
a. What is the concentration of the unknown acid?
b. What is the Ka of the unknown acid?
c. Which of the indicators given below would be a good choice to use in the titration of this acid with the NaOH?

Answers

Answer 1

Answer:

hello your question is incomplete attached below is the complete question

a) 0.12 M

b) Ka = 3.0 * 10^-7

c) Alizarin Yellow R

Explanation:

A) Determine the concentration of the unknown acid

The PH of the unknown acid before addition of NaOH is ; 3.72 ( weak acid )

First determine the moles of of NaOH

= molarity * volume

= 0.10 M * 30.0 ML = 0.0030 mol

at equivalence point

moles of NaOH = moles of unknown acid = 0.0030 mol

volume of unknown acid = 25.0 mL

Next calculate the concentration of the Acid ( HA )

= moles / volume

= 0.0030 mol / 25.0 mL

= 0.12 M

b) Determine the Ka of the unknown acid

attached below is the detailed solution

Ka = 3.0 * 10^-7

c) The indicator that would be a good choice to use in the titration of this acid with NaOH is ; Alizarin Yellow R . this is because the titration is between a strong base and a weak acid.

An Unknown Acid Was Titrated Two Times With 0.10 M NaOH. The First Titration Was Done Using An Indicator
An Unknown Acid Was Titrated Two Times With 0.10 M NaOH. The First Titration Was Done Using An Indicator

Related Questions

If you have a gas sample with a pressure of 2 atm, a volume of 40 L and a temperature of 300 K, what will be the number of moles of gas in that sample?

Answers

Answer:

n = 3.25 mol

Explanation:

Given data:

Pressure of sample = 2 atm

Volume of sample = 40 L

Temperature = 300 K

Number of moles = ?

Solution:

PV = nRT

R = general gas constant = 0.0821 atm.L/mol.K

2 atm ×40 L = n × 0.0821 atm.L/mol.K × 300 K

80 atm.L = n  × 24.63 atm.L/mol

n = 80 atm.L  /24.63 atm.L/mol

n = 3.25 mol

what is the molarity of a solutoin which contains 38.5 g of sodium chloride disolved in 325 ml solution ?

Answers

Answer:

Molarity =  2.02 M

Explanation:

Given data:

Molarity of solution = ?

Mass of sodium chloride = 38.5 g

Volume of solution = 325 mL (0.325 L)

Solution:

Number of moles = mass/molar mass

Number of moles = 38.5 g/ 58.44 g/mol

Number of moles = 0.658 mol

Molarity:

Molarity = number of moles / volume of solution in L

Molarity = 0.658 mol /0.325 L

Molarity =  2.02 M

11. A 4.175 gram sample of a certain hydrate of copper (II) sulfate, CuSO,• xH,O, is heated until all
the water is driven off. The resulting anhydrous compound weighs 3.120 grams. What is the
formula of the hydrate?

Answers

The  formula of the hydrate = CuSO₄• 3H₂O

Further explanation

Given

4.175 grams sample CuSO₄• xH₂O

3.120 grams anhydrous compound CuSO₄

Required

The formula

Solution

mass of H₂O driven off :

= 4.175 - 3.12

= 1.055 g

MW CuSO₄ = 159.5 g/mol

MW H₂O = 18 g/mol

mol ratio of CuSO₄ : H₂O :

= 3.12/159.5 : 1.055/18

= 0.01956 : 0.05861

= 1 : 3

Based on the data provided, the formula of the hydrated salt is CuSO4.3H20

What is the formula of the hydrate?

The formula of the hydrate is determined from the mole ratio of the anhydrous saltand water.

Mass of water = 4.175 - 3.120

mass of water = 1.055 g

Mole ratio= mass/molar mass

molar mass of CuSO4 = 160 g/mol

molar mass of H2O = 18 g/mol

CuSO4 = 3.120/160 = 0.0195

H2O = 1.055/18 = 0.0586

CuSO4 = 0.0195/0.0195 = 1

H2O = 0.0586/0.0195 = 3

Therefore, the formula of the hydrated salt is CuSO4.3H20

Learn more about hydrated salts at: https://brainly.com/question/24920157

WHICH ONE IS TRUE WHICH ONE IS FALSE?
The number of valence electrons decreases from left to right across each period.
The number of valence electrons increases from top to bottom within each group.
All of the elements in group 9 have nine valence electrons.
Elements with the most valence electrons are in group 18.

Answers

Answer:

The number of valence electrons increases from top to bottom within each group.

Explanation:

The valence electrons are the outermost shell electrons.

Therefore, the number of valence electrons does not increase from top to bottom within each of the group.

Down a group, the number of valence electrons remains the same.

For group I elements, the number of electrons is 1.

 The group is the vertical arrangement of elements.

From left to right across a period, the number of valence electrons increases because you move from group to group.

Decide whether the compound is ionic or molecular, if you can.

Compound is a soft waxy white solid that can be easily shaped and molded by hand. When the flame of an ordinary laboratory burner is held about away from the solid, it rapidly and extensively melts into a clear liquid.

Answers

Answer:

Molecular solid

Explanation:

Molecular solids have a very low melting point. This is because, they are composed of weak intermolecular forces hence the layers of the solid easily fall apart as the solid melts.

We can see here that the solid being considered melts easily. Hence we can conclude that it is actually a molecular solid.

For the reaction of hydrogen with iodine
H2(g) + I2(g) rightarrow 2HI(g)
relate the rate of disappearance of hydrogen gas to the rate of formation of hydrogen iodide.

Answers

Answer:

[tex]r_{H_2} = \frac{-1}{2} r_{HI}[/tex]

Explanation:

Hello!

In this case, considering the given chemical reaction:

[tex]H_2(g) + I_2(g) \rightarrow 2HI(g)[/tex]

Thus, by applying the law of rate proportions, we can write:

[tex]\frac{1}{-1} r_{H_2} = \frac{1}{-1}r_{i_2} = \frac{1}{2} r_{HI}[/tex]

Whereas the stoichiometric coefficients of reactants are negative due their disappearance and that of the product is positive due to its appearance. In such a way, when we relate the rate of disappearance of hydrogen gas to the rate of formation of hydrogen iodide, we obtain:

[tex]r_{H_2} = \frac{-1}{2} r_{HI}[/tex]

Best regards!

HELP PLEASE
Instantaneous speed is the rate of motion at an instant in time. Based on this statement, a reasonable conclusion is that if and object's instantaneous speed does not chang over time then,________.

•the object is quickly speeding up
•the object is very gradually slowing down
•the object is moving at a constant speed
•the object has returned to its beginning position ​

Answers

Answer:

The object is moving at a constant speed.

Can anybody answer this question of chemistry?

Answers

Answer:

Answer:A

Answer:AExplanation:

Answer:AExplanation:Molar Mass of glucose = (6×12)+(1×12)+(16×6)= 180g/mol

= 180g/molNumber of moles of Glucose = Mass/Molar Mass

= 180g/molNumber of moles of Glucose = Mass/Molar Mass= 5000/180

= 180g/molNumber of moles of Glucose = Mass/Molar Mass= 5000/180= 27.7778moles

= 180g/molNumber of moles of Glucose = Mass/Molar Mass= 5000/180= 27.7778molesIn the balanced equation of fermentation, the ratio of glucose to ethanol is 2:1

= 180g/molNumber of moles of Glucose = Mass/Molar Mass= 5000/180= 27.7778molesIn the balanced equation of fermentation, the ratio of glucose to ethanol is 2:1Therefore the number of moles of ethanol is 2×27.7778

= 180g/molNumber of moles of Glucose = Mass/Molar Mass= 5000/180= 27.7778molesIn the balanced equation of fermentation, the ratio of glucose to ethanol is 2:1Therefore the number of moles of ethanol is 2×27.7778=55.5556moles

= 180g/molNumber of moles of Glucose = Mass/Molar Mass= 5000/180= 27.7778molesIn the balanced equation of fermentation, the ratio of glucose to ethanol is 2:1Therefore the number of moles of ethanol is 2×27.7778=55.5556molesMass of ethanol= Molar Mass of ethanol × Number of moles

= 180g/molNumber of moles of Glucose = Mass/Molar Mass= 5000/180= 27.7778molesIn the balanced equation of fermentation, the ratio of glucose to ethanol is 2:1Therefore the number of moles of ethanol is 2×27.7778=55.5556molesMass of ethanol= Molar Mass of ethanol × Number of moles={(12×2)+(1×6)+16} × 55.5556

= 180g/molNumber of moles of Glucose = Mass/Molar Mass= 5000/180= 27.7778molesIn the balanced equation of fermentation, the ratio of glucose to ethanol is 2:1Therefore the number of moles of ethanol is 2×27.7778=55.5556molesMass of ethanol= Molar Mass of ethanol × Number of moles={(12×2)+(1×6)+16} × 55.5556= 46.5×55.5556

= 180g/molNumber of moles of Glucose = Mass/Molar Mass= 5000/180= 27.7778molesIn the balanced equation of fermentation, the ratio of glucose to ethanol is 2:1Therefore the number of moles of ethanol is 2×27.7778=55.5556molesMass of ethanol= Molar Mass of ethanol × Number of moles={(12×2)+(1×6)+16} × 55.5556= 46.5×55.5556= 2555.55

Answer:

Answer:A

Answer:AExplanation:

Answer:AExplanation:Molar Mass of glucose = (6×12)+(1×12)+(16×6)= 180g/mol

= 180g/molNumber of moles of Glucose = Mass/Molar Mass

= 180g/molNumber of moles of Glucose = Mass/Molar Mass= 5000/180

= 180g/molNumber of moles of Glucose = Mass/Molar Mass= 5000/180= 27.7778moles

= 180g/molNumber of moles of Glucose = Mass/Molar Mass= 5000/180= 27.7778molesIn the balanced equation of fermentation, the ratio of glucose to ethanol is 2:1

= 180g/molNumber of moles of Glucose = Mass/Molar Mass= 5000/180= 27.7778molesIn the balanced equation of fermentation, the ratio of glucose to ethanol is 2:1Therefore the number of moles of ethanol is 2×27.7778

= 180g/molNumber of moles of Glucose = Mass/Molar Mass= 5000/180= 27.7778molesIn the balanced equation of fermentation, the ratio of glucose to ethanol is 2:1Therefore the number of moles of ethanol is 2×27.7778=55.5556moles

= 180g/molNumber of moles of Glucose = Mass/Molar Mass= 5000/180= 27.7778molesIn the balanced equation of fermentation, the ratio of glucose to ethanol is 2:1Therefore the number of moles of ethanol is 2×27.7778=55.5556molesMass of ethanol= Molar Mass of ethanol × Number of moles

= 180g/molNumber of moles of Glucose = Mass/Molar Mass= 5000/180= 27.7778molesIn the balanced equation of fermentation, the ratio of glucose to ethanol is 2:1Therefore the number of moles of ethanol is 2×27.7778=55.5556molesMass of ethanol= Molar Mass of ethanol × Number of moles={(12×2)+(1×6)+16} × 55.5556

= 180g/molNumber of moles of Glucose = Mass/Molar Mass= 5000/180= 27.7778molesIn the balanced equation of fermentation, the ratio of glucose to ethanol is 2:1Therefore the number of moles of ethanol is 2×27.7778=55.5556molesMass of ethanol= Molar Mass of ethanol × Number of moles={(12×2)+(1×6)+16} × 55.5556= 46.5×55.5556

= 180g/molNumber of moles of Glucose = Mass/Molar Mass= 5000/180= 27.7778molesIn the balanced equation of fermentation, the ratio of glucose to ethanol is 2:1Therefore the number of moles of ethanol is 2×27.7778=55.5556molesMass of ethanol= Molar Mass of ethanol × Number of moles={(12×2)+(1×6)+16} × 55.5556= 46.5×55.5556= 2555.55

the number that go before symbols and formulas in a chemicql equation are

A.SuperScripts
B.Subscripts
C.Catalysts
D.Coefficients​

Answers

Answer: D. Coefficients

Which constants would most likely be filled in the first row of the table?
O temperature and moles of gas
O volume and temperature
O
pressure and volume
pressure and moles of gas

Answers

Answer:

A

Explanation:

Correct on edge

The temperature and moles of gas constants would most likely be filled in the first row of the table. Therefore, option A is correct.

What is gas constant ?

The gas constant, denoted by R, is a physical constant that is expressed in terms of units of energy per temperature increment per mole. It's also referred to as the ideal gas constant, the molar gas constant, or the universal gas constant.

A general constant in the equation of state of gases that is equal to the product of the pressure and volume of one mole divided by the absolute temperature in the case of an ideal gas see gas law sense c.

All gases adapt an equation of state known as the ideal gas law: PV = nRT, where n is the number of moles of the gas and R is the universal gas constant.

Thus, option A is correct.

To learn more about the gas constant, follow the link;

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Your question is incomplete, most probably your question was

The incomplete table below shows selected characteristics of gas laws.

Name

Variables

Constants

Equation

?

?

?

PV = k

Charles's law

?

?

V = kT

?

Temperature, pressure

?

P = kT

Combined gas law

Pressure, temperature, volume

?

?

Which constants would most likely be filled in the first row of the table?

temperature and moles of gas

volume and temperature

pressure and volume

pressure and moles of gas

Assign oxidation numbers to the element in each of the following compounds. Remember an oxidation number is for one atom of the element.

a. HgO
b. Al4C3
c. CrF2
d. Fe2S3

Answers

Answer:

a.  x = + 2

b.  x = + 3

c.  x = + 2

d.  x = + 3

Explanation:

The oxidation number is a formal charge assigned to an atom present in a molecule or formula unit or ion based on some arbitrary rules.

a.

HgO

The oxidation number of Hg in HgO is:

x + (-2) = 0

x = +2

b.

Al₄C₃

The oxidation number of Al in Al₄C₃ is:

4x +(3 × -4) = 0

4x - 12 = 0

4x = +12

x = 12/4

x = +3

c. CrF₂

x + ( 2 × - 1) = 0

x - 2 = 0

x = + 2

d. Fe₂S₃

2x + ( 3 × - 2) = 0

2x + (-6) = 0

2x = 6

x = 6/2

x = +3

Which two elements have similar characteristics?

Answers

Answer:

The two elements are FLUORINE AND CHLORINE. These two elements have similar characteristics because they belong to the same group in the periodic table. On the periodic table, elements with similar properties are grouped together in the same group. Both chlorine and fluorine belongs to the halogen group.

Explanation:

Hope it helps, some how.

When titanium (II) nitride forms an ionic compound, what is the chemical formula of the compound?

Answers

Answer:

When titanium (II) nitride forms an ionic compound, TiN is the chemical formula of the compound.

if you know an object's distance from the sun in kilometers,how can you find the distance in AU?​

Answers

Answer:

We divide our value by 1.5×10⁸

Explanation:

AU is a unit to determine distance in the space.

We know that AU means astronomic unit.

The value for conversion is 1.5×10⁸ Km

1 AU = 1.5×10⁸ Km

Let's see the example:

One star is located from the sun, around 3.35×10¹⁰ Km away. To determine the distance in AU we use the conversion factor:

3.35×10¹⁰ Km . 1 AU / 1.5×10⁸ Km = 223.3 AU

all organisms begins life as a ________ cell.

Answers

Answer:

All organisms begin life as a single cell

Explanation:

Single cell also did you know 15 minutes can save you 15% more on car insurance

Conclusion
In this activity, thermal energy was transferred ( into / out of the hand warmer while it changed from
liquid to solid.

Answers

whats the question?

How to change 5 % W/V of NaCl to ppm , M ? molar mass = 58.5
please clear explain​

Answers

Answer:

50000ppm and 0.855M.

Explanation:

ppm is an unit of chemistry defined as the ratio between mg of solute (NaCl) and Liters of solution. Molarity, M, is the ratio between moles of NaCl and liters

A 5% (w/v) NaCl contains 5g of NaCl in 100mL of solution.

To solve the ppm of this solution we need to find the mg of NaCl and the L of solution:

mg NaCl:

5g * (1000mg / 1g) = 5000mg

L Solution:

100mL * (1L / 1000mL) = 0.100L

ppm:

5000mg / 0.100L = 50000ppm

To find molarity we need to obtain the moles of NaCl in 5g using its molar mass:

5g * (1mol / 58.5g) = 0.0855moles NaCl

Molarity:

0.0855mol NaCl / 0.100L = 0.855M

Suppose 7.17g of barium acetate is dissolved in 350mL of a 79.0mM aqueous solution of sodium chromate. Calculate the final molarity of barium cation in the solution. You can assume the volume of the solution doesn't change when the barium acetate is dissolved in it. Round your answer to 1 significant digit.

Answers

Answer:

0.0802 M.

Explanation:

Hello!

In this case, since the barium acetate has the following formula:

[tex]Ba(CH_3COO)_2[/tex]

So its molar mass is 255.43 g/mol, in order to compute the molarity of the barium cation, we first need the moles in 7.17 g:

[tex]n_{Ba(CH_3COO)_2} = 7.17g*\frac{1molBa(CH_3COO)_2}{255.43g} =0.0281molBa(CH_3COO)_2[/tex]

Now, since one mole of barium acetate contains one mole of barium cations, we infer there are 0.0281 moles of barium cations. Moreover, since the molarity is computed by dividing the moles of those ones by the volume of the solution in liters, 350 mL (0.350 L) as it does not change, it turns out:

[tex]M=\frac{0.0281molBa^{2+}}{0.350L}\\\\M=0.0802M[/tex]

Best regards!

Insulin is a protein that is used by the body to regulate both carbohydrate and fat metabolism. A bottle contains 225 mL of insulin at a concentration of 20.0 mg/mL . What is the total mass of insulin in the bottle?

Answers

The total mass of insulin in the bottle : m = 4500 mg

Further explanation

Given

225 ml of insulin

The concentration 20 mg/ml

Required

The total mass of insulin

Solution

Density is the ratio of mass per unit volume

Can be formulated

ρ = m / V

m = ρ x V

Input the value :

m = 20 mg/ml x 225 ml

m = 4500 mg

The Question A 1.80 x 10-2 kg block of metal has the following dimensions: 0.4981 inches by 0.531 inches, by 0.5839 inches. Determine the density of the block in g/mL. Using the provided list of metals and their respective densities, what is the metal's identity

Answers

Answer:

Zinc

Explanation:

m = Mass of block [tex]1.8\times 10^{-2}\ \text{kg}=18\ \text{g}[/tex]

Dimension of block is 0.4981 inches by 0.531 inches, by 0.5839 inches

[tex]1\ \text{inch}^3=16.3871\ \text{mL}[/tex]

Volume of block

[tex]V=0.4981\times 0.531\times 0.5839\times 16.3871\ \text{mL}[/tex]

Density is given by

[tex]\rho=\dfrac{m}{V}\\\Rightarrow \rho=\dfrac{18}{0.4981\times 0.531\times 0.5839\times 16.3871}\\\Rightarrow \rho=7.112\ \text{g/mL}[/tex]

The density of the metal is [tex]7.112\ \text{g/mL}[/tex]. The metal here is zinc.

12. Which gas has the greatest kinetic energy at STP?

a. He

b. Ne

c. Ar

d. none of the above (all have the same kinetic energy)

Answers

Answer:

d. none of the above (all have the same kinetic energy)

Explanation:

The kinetic theory of gases states that the molecules of an ideal gas experience a constant random motion.

At standard temperature and pressure (STP), the kinetic energy of an ideal gas such as hydrogen, argon, neon, sodium, oxygen, helium, magnesium, beryllium, nitrogen, carbon, fluorine, chlorine etc are all the same.

The standard temperature and pressure (STP) of an ideal gas is 273K and 100 kPa.

Hence, all of the gases have the same kinetic energy at standard temperature and pressure (STP).

Kinetic energy can be defined as an energy possessed by an object or body due to its motion.

Mathematically, kinetic energy is given by the formula;

[tex] K.E = \frac{1}{2}MV^{2}[/tex]

Where, K.E represents kinetic energy measured in Joules.

M represents mass measured in kilograms.

V represents velocity measured in metres per seconds square.

Identify the types of information that are necessary to communicate with emergency responders. Select one or more: Any chemicals involved in an incident Any other hazards present in the lab The history of safety incidents in the lab How the incident happened

Answers

Answer:

How the incident happened

Any chemicals involved in an incident

Any other hazards present in the lab

Explanation:

Above are the types of information that are necessary to communicate with emergency responders. The emergency responders ask the first question that how the incident happened. After that they ask that is there any harmful chemicals are present in the laboratory or what types of chemicals present in the laboratory. These questions were asked by the emergency responders in order to give the patient a suitable treatment.

The emergency responders are persons that helps in the case of emergency to deal with hazardous conditions. The information provided to the emergency responders helps in dealing with the condition.

The information that has to be provided to the emergency responder in case of a laboratory incident helps them to handle the situation. The questions about how the incident occurs, the presence of hazardous chemicals in the laboratory will help in avoiding the further hazard. The involvement of the chemical in the hazard will help to deal with the situation.

For more information about emergency responders, refer to the link:

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A 2.54 g piece of zinc (density = 7.14 g/mL) is added to a graduated cylinder that contains 12.13 mL h2o. What will be the final volume reading on the graduated cylinder, in mL?

Answers

Answer: If I'm correct it's 12.54 mL but don't rely on this because I'm not sure

Explanation:

Answer:

12.49 ml

Explanation:

Density = mass / volume

Volume = mass / density

Volume of zinc = 2.54/7.14

Volume of zinc = 0.3557

Initial volume = 12.13 ml

Total volume = initial volume+ volume of zinc

Total volume = 12.13 + 0.3557

Total volume = 12.4857 = 12.49 ml

is water vapor only found in hot water?

Answers

i think so, you have to have a heat source to produce water vapor
No, if you really think, there are so many things that are

< Progress: 19/21 groups Due Jan 15 at 11:55 PM Use the References to access important values if needed for this question. The compound cobalt (II) sulfate forms a hydrate with seven water molecules per formula unit. What are the name and formula of the hydrate

Answers

Answer:

CoSO4.7H2O

Cobalt II tetraoxosulphate VI heptahydrate

Explanation:

According to IUPAC nomenclature, compounds are named systematically.

We were told that there are seven water molecules in each formula unit Hence the correct formula of the compound is CoSO4.7H2O

According to IUPAC system, the metal is first named, followed by its oxidation state in Roman numerals. Then the name of the anion is mentioned as well as the number of water molecules. We have to take into account the correct prefix signifying the number of molecules of water of crystallization.

Chromuate found inside which of the following structures of a eukaryotic cell?

Answers

Answer:

Chromuates are found in the chromosomes of the eukaryotic cells!!!!

Explanation:

I learned this in 7th grade!!!!

Mark Me Brainliest plzz

What is the mass of 1.0 × 10^9 molecules of aspartame?

Answers

Answer:

294.3 g/mol b.

The mass of 1.0*10^9 molecules of aspartame is 2.943*10^11 g/mol

ASPARTAME

Aspartame is  used as an artificial non-saccharide sweetener 200 times sweeter than sucrose, and is commonly used as a sugar substitute in foods and beverages.

CALCULATION

mass  of one molecule of aspartame = 294.3g/mol

mass of 1.0*10^9 molecules of aspartame =294.3*(1.0*10^9) g/mol

                                                                     =2.943*10^11 g/mol

refer https://brainly.com/question/25225559

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PLSSS HELP!! In the demonstration, Iron reacted with the oxygen in the air. Which one ran out
first? How do you know?

Answers

it has to be iron because oxygen doesn’t run out unless being used by something like sticking it in a bubble.

Which of the following represents a compound made of five molecules
OCOS
OC205
Осо
5002

Answers

I think B I’m not sure

Classify each of the compounds as an ionic compound, a covalent compound or an acid.a. BaCl2______________________d. CH4______________________b. MnO2______________________e. H2S*______________________c. H3AsO4______________________f. CH3OH

Answers

Answer:

a. BaCl2 is ionic compound.

b. CH4 is covalent compound.

b. MnO2 is ionic compound.

e. H2S is covalent compound.

c. H3AsO4 is ionic compound.

f. CH3OH is covalent compound.

Explanation:

BaCl2, MnO2 and H3AsO4 are ionic compounds due to the presence of ionic bond between the atoms while on the other hand, CH4, H2S and CH3OH are covalent compounds due to the presence of covalent bond between their atoms. In covalent bonds, sharing of electrons occur whereas in ionic bonds, complete transfer of electrons occur from one atom to another atom.

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