Answer:
A) Decreasing solubility with increasing lattice energy.
B) Ionic compounds are more soluble in a polar solvent.
C) Increasing solubility with increasing enthalpy of hydration.
Explanation:
A) Lattice energy is the energy contained in the crystal lattice of a compound (mostly ionic). It is also the energy that would be released if the component ions were brought together from infinity to form the compound.
For a compound to dissolve, the solvation energy that the fluid would use to work on its ions must exceed the compound's lattice energy. Hence, the higher the lattice energy, the less soluble the compound would be.
B) The 'like dissolves like' law in dissolution is very true and applicable. The law explains that polar compounds will dissolve in polar solvents and not dissolve in non-polar solvents. Only non-polar compounds will dissolve in non-polar solvents.
Ionic compounds contain positive and negative ions, making them one of the most polar sets of compounds. So, they will easily dissolve in polar solvents.
C) Enthalpies of hydration of the cations and anions represent the total enthalpy of dissolution. This is the energy released when a compound undergoes hydration. A form of salvation of the ions, the enthalpy of hydration need to match or exceed the lattice energybof the compound For the compound to be soluble. Hence, the larger the enthalpies of hydration, the more likely the compound will be soluble.
Hope this Helps!!!
If one contraction cycle in muscle requires 55 kJ55 kJ , and the energy from the combustion of glucose is converted with an efficiency of 35%35% to contraction, how many contraction cycles could theoretically be fueled by the complete combustion of one mole of glucose? Round your answer to the nearest whole number.
Answer:
18 moles
Explanation:
Here the combustion of one mole of glucose ----> carbon dioxide + water, releases 2870 kilojoules / moles.
_______________________________________________________
With one contraction cycle requiring 55 kilojoules,
2870 / 55 ≈ 52.18
And with the efficiency being 35 percent,
52.1818..... * 0.35 = ( About ) 18 moles
Hope that helps!
475 grams of solid calcium oxide reacts with water vapor to form solid calcium hydroxide.Calculate the heat of reaction.
(A) - 221.1 kcal
(B) + 290.8 kcal
C) - 290.8 kcal
(D) + 324.6 kcal
(E) + 221.1 kcal
Answer:
(A) - 221.1 kcal
Explanation:
Based in the reaction:
CaO(s) + H₂O(g) → Ca(OH)₂ ΔH = -109kJ/mol
When 1 mole of CaO reacts per mole of water vapor producing calcium hydroxide there are released -109kJ
475g of CaO (Molar mass CaO: 56.08g/mol) are:
475g CaO × (1mol / 56.08g) = 8.47 moles of CaO
As 1 mole of CaO in reaction release -109kJ, 8.47 moles release:
8.47 mol CaO × (-109 kJ / 1 mol CaO) = -923.2kJ are released
As 1 kCal = 4.184kJ:
-923.2kJ × (1kCal / 4.184kJ) =
-220.7kCal ≈ (A) - 221.1 kcalHow does the number of valence electrons in an atom relate to the element's
placement on the periodic table?
O A. Elements in the same group have the same number of valence
electrons.
B. The number of valence electrons increases as the atomic number
increases
C. The number of valence electrons is the same for all elements on
the periodic table.
D. Elements in the same period have the same number of valence
electrons.
Answer:
A
Explanation:
On a hot summer day, the density of air at atmospheric pressure at 35.5°C is 1.1970 kg/m3. (a) What is the number of moles contained in 1.00 m3 of an ideal gas at this temperature and
Complete question:
On a hot summer day, the density of air at atmospheric pressure at 35.5°C is 1.1970 kg/m3. (a) What is the number of moles contained in 1.00 m3 of an ideal gas at this temperature and pressure.
Answer:
The number of moles contained by an ideal gas at this temperature and pressure is 41.32 moles.
Explanation:
Given;
density of dry air, ρ = 1.1970 kg/m³
temperature of the air, T = 35.5°C = 273 + 35.5 = 308.5 K
air volume, V = 1 m³
Apply ideal gas law for dry to calculate the air pressure;
[tex]P = \rho R_dT[/tex]
where;
P is the air pressure
ρ is the air density
Rd is gas constant for dry air = 287 J/kg/K
P = 1.197 x 287 x 308.5 = 105,981.78 Pa
(a) Now, determine the number of moles contained by an ideal gas at this temperature and pressure, by applying ideal gas law;
PV = nRT
where;
P is the pressure of the gas (Pa)
V is the volume of the gas (m³)
n is number of gas moles
R is gas constant = 8.314 m³.Pa / mol.K
T is temperature (K)
n = (PV) / (RT)
n = (105,981.78 x 1) / (8.314 x 308.5)
n = 41.32 moles
Therefore, the number of moles contained by an ideal gas at this temperature and pressure is 41.32 moles.
The number of moles of an ideal gas at this temperature and pressure is 41.5 moles.
Given that;
Density of dry air = 1.1970 kg/m3
Pressure of dry air = ?
Temperature of dry air = 35.5°C + 273 = 308.5 K
Hence;
P = Density × gas constant of dry air × Temperature
P = 1.1970 kg/m3 × 287.1 J/Kg/K × 308.5 K
P = 106019 Pa or 1.05 atm
Using the ideal gas equation;
PV = nRT
n = PV/RT
n = 1.05 atm × 1000 L/0.082 atmL/K.mol × 308.5 K
n = 41.5 moles
Learn more: https://brainly.com/question/11897796
Harvey kept a balloon with a volume of 348 milliliters at 25.0˚C inside a freezer for a night. When he took it out, its new volume was 322 milliliters, but its pressure was the same. If the final temperature of the balloon is the same as the freezer’s, what is the temperature of the freezer?
Answer:
[tex]T2=276K[/tex]
Explanation:
Given:
Initial volume of the balloon V1 = 348 mL
Initial temperature of the balloon T1 = 255C
Final volume of the balloon V2 = 322 mL
Final temperature of the balloon T2 =
To calculate T1 in kelvin
T1= 25+273=298K
Based on Charles law, which states that the volume of a given mass of a ideal gas is directly proportional to the temperature provided that the pressure is constant. It can be applied using the below formula
[tex](V1/T1)=(V2/T2)[/tex]
T2=( V2*T1)/V1
T2=(322*298)/348
[tex]T2=276K[/tex]
Hence, the temperature of the freezer is 276 K
Answer: 276 kelvins
Explanation:
State the effect of anion hydrolysis on the pH of water
Answer:
Depending on the anions and cations present within a hydrolysis reaction, the solution can be more... ... This lesson will explain how this occurs. ... that could react with water and create products that affect the characteristics of the solution.
Answer:
Salts of weak bases and strong acids do hydrolyze, which gives it a pH less than 7. This is due to the fact that the anion will become a spectator ion and fail to attract the H+, while the cation from the weak base will donate a proton to the water forming a hydronium ion.
Explanation:
I hope this is the answer your looking for
describe how would you use chromatography to show whether blue ink contains a single purple dye or a mixture of dyes
Explanation:
if the solution placed on the chromatography is pure there will be formation of one spot from the baseline and will go farthest to the front line unlike the impure one
With ink chromatography, a small amount of ink is added to the paper, one end is submerged in water, and the different colors of the ink are revealed as the water moves up the paper. All of this is made possible by the water base and variety of salabilities or densities that make up ink.
What is chromatography ?Separating mixture's constituent parts by chromatography is a method. The mixture is dissolved in a material known as the mobile phase to start the process, which then transports it through a material known as the stationary phase.
A little dot of the ink to be separated is placed at one end of a strip of filter paper to perform ink chromatography. The paper strip's opposite end is submerged in a solvent. The solvent moves up the paper strip, dissolving the chemical combination as it goes and pulling it up the paper.
Throughout the experiment, the dyes are pulled along by the mobile phase (water) as it gently advances up the stationary phase (paper).
Thus, With ink chromatography, a small amount of ink is added to the paper, one end is submerged in water.
To learn more about chromatography, follow the link;
https://brainly.com/question/11960023
#SPJ5
An electron in a 3s3s orbital penetrates into the region occupied by core electrons more than electrons in a 3p3p orbital. An electron in a orbital penetrates into the region occupied by core electrons more than electrons in a orbital. true false
Answer:
True
Explanation:
The penetrating ability of electrons in the orbitals is in the order s > p > d > f
An electron in a 3s orbital is closer to the nucleus than the one in a 3p orbital and as a result, there will be lesser shielding effect on it. This low shielding effect experienced by the 3s electron gives it a high penetration ability and hence will be able to easily penetrate regions occupied by core electrons. Conversely, the 3p orbital is farther away from the nucleus, electrons revolving around it are highly shielded which limits their ability to penetrate regions of core electrons.
Note that the maximum electrons that the s orbital can accommodate is 2 while p orbital can accommodate a maximum of 8.
s the following nuclear equation balanced? yes no
Answer:
Yes.
Explanation:
The nuclear equation {226/88 Ra → 222/26 Rn + 4/2 He} is balanced. As we know that an alpha particle is identical to a helium atom. This implies that if an alpha particle is eliminated from an atom's nucleus, an atomic number of 2 and a mass number of 4 is lost.
Therefore, the equation will be reduced to:
226 - 4 = 222
88 - 2 = 86
Hence, the equation is balanced.
Be sure to answer all parts. Three 8−L flasks, fixed with pressure gauges and small valves, each contain 4 g of gas at 276 K. Flask A contains He, flask B contains CH4, and flask C contains H2. Rank the flask contents in terms of:
Here is the complete question.
Be sure to answer all parts. Three 8−L flasks, fixed with pressure gauges and small valves, each contain 4 g of gas at 276 K. Flask A contains He, flask B contains CH4, and flask C contains H2. Rank the flask contents in terms of: the following properties. (Use the notation >, <, or =, for example B=C>A.)
(a) pressure
(b) average molecular kinetic energy
(c) diffusion rate after the valve is opened
(d) total kinetic energy of the molecules
Answer:
Explanation:
Given that:
Three flask A,B, C:
contains a volume of 8-L
mass m = 4g &;
Temperature = 276 K
Flask A = He
Flask B = H₂
Flask C = CH₄
a) From the ideal gas equation:
PV = nRT
where;
n = number of moles = mass (m)/molar mass (mm)
Then:
PV = m/mm RT
If T ,m and V are constant for the three flasks ; then
P ∝ 1/mm
As such ; the smaller the molar mass the larger the pressure.
Now; since the molecular weight of CH₄ is greater than He and H₂ and also between He and H₂, He has an higher molecular weight .
Then the order of pressure in the flask is :
[tex]\mathbf{P_B >P_A>P_C}[/tex]
where :
[tex]P_A[/tex] = pressure in the flask A
[tex]P_B[/tex] = pressure in the flask B
[tex]P_C[/tex]= Pressure in the flask C
b)
average molecular kinetic energy
We all know that the average molecular kinetic energy varies directly proportional to the temperature.
Thus; the given temperature = 276 K
∴ The order of the average molecular kinetic energy is [tex]\mathbf{K.E_A =K.E_B =K.E_C}[/tex]
c)
The rate of diffusion of gas is inversely proportional to the square root of it density . Here the density is given in relation to their molar mass.
So;
rate of diffusion ∝ [tex]\dfrac{1}{\sqrt{mm} }[/tex]
where;
[tex]D_A[/tex] = rate of diffusion in flask A
[tex]D_B[/tex] = rate of diffusion in flask B
[tex]D_C[/tex] = rate of diffusion in flask C
Thus; the order of the rate of diffusion = [tex]D_B[/tex] > [tex]D_A[/tex] > [tex]D_C[/tex]
d) total kinetic energy of the molecules .
The kinetic energy deals with how the speed of particles of a substance determines how fast the substances will diffuse in a given set of condition.
The the order of the total kinetic energy depends on the molecular speed
Thus; the order of the total kinetic energy for the three flask is as follows:
[tex]\mathbf{ K.E_B>K.E_A>K.E_C}[/tex]
Which describes an effect that ocean currents have on short-term climate change? Ocean currents increase the strength of prevailing winds, which can cool the air and land. Ocean currents can carry cold water, which can cool the air and land. Ocean currents increase hurricane activity, which can raise the temperature of the air and land. Ocean currents can carry warm water, which causes hurricane activity and raises the temperature of the air and land.
Answer: B
Ocean currents can carry cold water, which can cool the air and land.
Explanation:
eet ees wat eet ees
plz mark brainliest
Answer:
B is right
Explanation:
Which diagram represents the bonding pattern of metals?
Answer:
there's no image can't help without it sorry
Duncan knows that it takes 36400 cal of energy to heat a pint of water from room temperature to boiling. However, Duncan has prepared ramen noodles so many times he does not need to measure the water carefully. If he happens to heat 0.800 pint of room-temperature water, how many kilojoules of heat energy will have been absorbed by the water at the moment it begins to boil?
Answer:
[tex]\large \boxed{\text{122 000 J}}[/tex]
Explanation:
1. Calculate the energy needed
[tex]\text{Energy} = \text{0.800 pt} \times \dfrac{\text{36 400 cal}}{\text{1 pt}} = \text{ 29 120 cal}[/tex]
2. Convert calories to joules
[tex]\text{Energy} = \text{29 120 cal} \times \dfrac{\text{4.184 J}}{\text{1 cal}} = \textbf{122 000 J}\\\\\text{The water will have absorbed $\large \boxed{\textbf{122 000 J}}$}[/tex]
Draw structural formulas for all the alkene(s) formed by treatment of each haloalkane or halocycloalkane with sodium ethoxide in ethanol. Assume that elimination occurs by an E2 mechanism.
Answer:
Explanation:
Kindly note that I have attached the complete question as an attachment.
Here, we are told that elimination occurs by an E2 mechanism. What this means is that the hydrogen and the halogen must be above and below for the reaction to proceed.
The possible products are as follows;
Please check attachment for complete equations and diagrams of compounds too.
The acetic acid/acetate buffer system is a common buffer used in the laboratory. Write the equilibrium equation for the acetic acid/acetate buffer system. The formula of acetic acid is CH3CO2H .
Answer:
CH₃CO₂H + H₂O ⇄ CH₃CO₂⁻ + H₃O⁺
Explanation:
A buffer is defined as the mixture of a weak acid and its conjugate base or vice versa.
For the acetic acid buffer, CH₃CO₂H is the weak acid and its conjugate base is the ion without H⁺, that is CH₃CO₂⁻. The equilibrium equation in water knowing this is:
CH₃CO₂H + H₂O ⇄ CH₃CO₂⁻ + H₃O⁺In the equilibrium, the acid is dissociated in the conjugate base and the hydronium ion.
The acetic acid/acetate buffer system is a common buffer used in the laboratory, the equilibrium equation for the acetic acid/acetate buffer system. The formula of acetic acid is CH3CO2H -
CH₃CO₂H + H₂O ⇄ CH₃CO₂⁻ + H₃O⁺
An acid buffer is a solution that contains roughly the same concentrations of a weak acid and its conjugate base.
an acetate buffer contains roughly equal concentrations of acetic acid and acetate ion.Both are in chemical equilibrium with each other.The equation is:
CH₃CO₂H + H₂O ⇄ CH₃CO₂⁻ + H₃O⁺
where CH₃CO₂H - acetic acid
and, CH₃CO₂⁻ acetate ion
Thus, CH₃CO₂H + H₂O ⇄ CH₃CO₂⁻ + H₃O⁺ is the equilibrium equation for the acetic acid/acetate buffer system.
Learn more:
https://brainly.com/question/3435382
which proess is part of the carbon cycle
Answer:
The key processes in the carbon cycle are: carbon dioxide from the atmosphere is converted into plant material in the biosphere by photosynthesis.
Explanation:
organisms in the biosphere obtain energy by respiration and so release carbon dioxide that was originally trapped by photosynthesis. ... The carbon becomes part of the .
Air is compressed from an inlet condition of 100 kPa, 300 K to an exit pressure of 1000 kPa by an internally reversible compressor. Determine the compressor power per unit mass flow rate if the device is (a) isentropic, (b) polytropic with n =1.3, (c) isothermal
Answer:
(a) [tex]W_{isoentropic}=8.125\frac{kJ}{mol}[/tex]
(b) [tex]W_{polytropic}=7.579\frac{kJ}{mol}[/tex]
(c) [tex]W_{isothermal}=5.743\frac{kJ}{mol}[/tex]
Explanation:
Hello,
(a) In this case, since entropy remains unchanged, the constant [tex]k[/tex] should be computed for air as an ideal gas by:
[tex]\frac{R}{Cp_{air}}=1-\frac{1}{k} \\\\\frac{8.314}{29.11} =1-\frac{1}{k}\\[/tex]
[tex]0.2856=1-\frac{1}{k}\\\\k=1.4[/tex]
Next, we compute the final temperature:
[tex]T_2=T_1(\frac{p_2}{p_1} )^{1-1/k}=300K(\frac{1000kPa}{100kPa} )^{1-1/1.4}=579.21K[/tex]
Thus, the work is computed by:
[tex]W_{isoentropic}=\frac{kR(T_2-T_1)}{k-1} =\frac{1.4*8.314\frac{J}{mol*K}(579.21K-300K)}{1.4-1}\\\\W_{isoentropic}=8.125\frac{kJ}{mol}[/tex]
(b) In this case, since [tex]n[/tex] is given, we compute the final temperature as well:
[tex]T_2=T_1(\frac{p_2}{p_1} )^{1-1/n}=300K(\frac{1000kPa}{100kPa} )^{1-1/1.3}=510.38K[/tex]
And the isentropic work:
[tex]W_{polytropic}=\frac{nR(T_2-T_1)}{n-1} =\frac{1.3*8.314\frac{J}{mol*K}(510.38-300K)}{1.3-1}\\\\W_{polytropic}=7.579\frac{kJ}{mol}[/tex]
(c) Finally, for isothermal, final temperature is not required as it could be computed as:
[tex]W_{isothermal}=RTln(\frac{p_2}{p_1} )=8.314\frac{J}{mol*K}*300K*ln(\frac{1000kPa}{100kPa} ) \\\\W_{isothermal}=5.743\frac{kJ}{mol}[/tex]
Regards.
A scientist wants to make a solution of tribasic sodium phosphate, Na3PO4, for a laboratory experiment. How many grams of Na3PO4 will be needed to produce 525 mL of a solution that has a concentration of Na ions of 1.10 M
Answer:
31.652g of Na3PO4
Explanation:
We'll begin by calculating the molarity of Na3PO4 solution. This can be achieved as shown below:
Na3PO4 will dessicate in solution as follow:
Na3PO4(aq) —> 3Na+(aq) + PO4³¯(aq)
From the balanced equation above,
1 mole of Na3PO4 produce 3 moles of sodium ion, Na+.
Therefore, xM Na3PO4 will produce 1.10M sodium ion, Na+ i.e
xM Na3PO4 = (1.10 x 1)/3
xM Na3PO4 = 0.367M
Therefore, the molarity of Na3PO4 is 0.367M.
Next, we shall determine the number of mole of Na3PO4 in the solution. This is illustrated below:
Molarity of Na3PO4 = 0.367M
Volume = 525mL = 525/1000 = 0.525L
Mole of Na3PO4 =..?
Molarity = mole /Volume
0.367 = mole /0.525
Cross multiply
Mole of Na3PO4 = 0.367 x 0.525
Mole of Na3PO4 = 0.193 mole.
Finally, we shall convert 0.193 mole of Na3PO4 to grams. This is illustrated below:
Molar mass of Na3PO4 = (23x3) + 31 + (16x4) = 164g/mol
Mole of Na3PO4 = 0.193 mole
Mass of Na3PO4 =.?
Mass = mole x molar mass
Mass of Na3PO4 = 0.193 x 164
Mass of Na3PO4 = 31.652g
Therefore, 31.652g of Na3PO4 is needed to prepare the solution.
The cytochromes are heme‑containing proteins that function as electron carriers in the mitochondria. Calculate the difference in the reduction potential (ΔE∘′) and the change in the standard free energy (ΔG∘′) when the electron flow is from the carrier with the lower reduction potential to the higher. cytochrome c1 (Fe3+)+e−↽−−⇀cytochrome c1 (Fe2+)E∘′=0.22 V cytochrome c (Fe3+)+e−↽−−⇀cytochrome c (Fe2+)E∘′=0.254 V Calculate ΔE∘′ and ΔG∘′ .
Complete Question
The complete question is shown on the first uploaded image
Answer:
The change in reduction potential is [tex]\Delta E^o=E^o_{cell} = 0.034 V[/tex]
The change in standard free energy is [tex]\Delta G^o = -3.2805 \ KJ/mol[/tex]
Explanation:
From the question we are told that
At the anode
[tex]cytochrome \ c_1 \ (Fe^{3+}) + e^-[/tex]⇔[tex]cytochrome \ c_1 \ (Fe^{2+}) \ \ E^o = 0.22 \ V[/tex]
At the cathode
[tex]cytochrome \ c \ (Fe^{3+}) + e^-[/tex]⇔[tex]cytochrome \ c \ (Fe^{2+}) \ \ E^o = 0.254 \ V[/tex]
The difference in the reduction potential is mathematically represented as
[tex]\Delta E^o = E^o_{cathode} - E^o_{anode}[/tex]
substituting values
[tex]\Delta E^o = 0.254 - 0.220[/tex]
[tex]\Delta E^o=E^o_{cell} = 0.034 V[/tex]
The change in the standard free energy is mathematically represented as
[tex]\Delta G^o = -n * F * E^o_{cell}[/tex]
Where F is the Faraday constant with value F = 96485 C
and n i the number of the number of electron = 1
So
[tex]\Delta G^o = -(1) * 96485 * 0.034[/tex]
[tex]\Delta G^o = -3.2805 \ KJ/mol[/tex]
A scientist measures the standard enthalpy change for the following reaction to be -115.5 kJ: CO(g) + Cl2(g)___COCl2(g) Based on this value and the standard enthalpies of formation for the other substances, the standard enthalpy of formation of COCl2(g) is ________ kJ/mol.
Answer:
-226.0kJ = ΔH°f COCl₂(g)
Explanation:
Using Hess' law, it is possible to obtain the enthalpy of formation of a substance from the enthalpy change of a reaction and the other enthalpies of formation involved in the reaction.
For the reaction:
CO(g) + Cl₂(g) → COCl₂(g)
Hess's law is:
ΔHr = -115.5kJ = ΔH°f COCl₂(g) - (ΔH°f CO(g) + ΔH°f Cl₂(g))
ΔH°f CO(g) is -110.5kJ/mol
ΔH°f Cl₂(g) is 0 kJ/mol
Replacing in Hess's law:
-115.5kJ = ΔH°f COCl₂(g) - (-110.5kJ/mol + 0kJ/mol)
-115.5kJ = ΔH°f COCl₂(g) + 110.5kJ
-226.0kJ = ΔH°f COCl₂(g)Consider the insoluble compound zinc carbonate , ZnCO3 . The zinc ion also forms a complex with hydroxide ions . Write a balanced net ionic equation to show why the solubility of ZnCO3 (s) increases in the presence of hydroxide ions and calculate the equilibrium constant for this reaction. For Zn(OH)42- , Kf = 2.9×1015 . Use the pull-down boxes to specify states such as (aq) or (s).
Answer:
The net ionic equation is [tex]ZnCO_3 _{(s)} + 4 OH^{-}_{(aq)} \to [Zn(OH)_4]^{2-} _{(aq)} + CO_3^{2-} _{(aq)}[/tex]
The equilibrium constant is [tex]K = 4.06 *10^{4}[/tex]
Explanation:
From the question we are that
The [tex]K_f = 2.9 *10^{15 }[/tex]
The ionic equation is chemical represented as
Step 1
[tex]ZnCO_3 _{(s)}[/tex] ⇔ [tex]Zn^{2+} _{aq} + CO_3^{2-} _{aq}[/tex] The solubility product constant for stage is [tex]K_{sp} = 1.4*10^{-11}[/tex]
Step 2
[tex]Zn^{2+} _{(aq)} + 4 0H^{-} _{(aq)}[/tex] ⇔ [tex][Zn(OH_4)]^{2-} _{(aq)}[/tex] The formation constant for this step is given as [tex]K_f = 2.9 *10^{15 }[/tex]
The net reaction is
[tex]ZnCO_3 _{(s)} + 4 OH^{-}_{(aq)} \to [Zn(OH)_4]^{2-} _{(aq)} + CO_3^{2-} _{(aq)}[/tex]
The equilibrium constant is mathematically evaluated as
[tex]K = K_{sp} * K_f[/tex]
substituting values
[tex]K = 1.4*10^{-11} * 2.9 *10^{15}[/tex]
[tex]K = 4.06 *10^{4}[/tex]
An experimenter studying the oxidation of fatty acids in extracts of liver found that when palmitate (16:0) was provided as substrate, it was completely oxidized to CO2. However, when undecanoic acid (11:0) was added as substrate, incomplete oxidation occurred unless he bubbled CO2 through the reaction mixture. The addition of the protein avidin, which binds tightly to biotin, prevented the complete oxidation of undecanoic acid even in the presence of CO2, although it had no effect on palmitate oxidation. Explain these observations in light of what you know of fatty acid oxidation reactions.
Answer:
Even-number fatty acids such as palmitate undergoes complete β-oxidation in the liver motochondria to CO₂ because the product, acetyl-CoA can enter the TCA cycle.
Oxidation of odd-number fatty acids such as undecanoic acid yields acetyl-CoA + propionyl-CoA in their last pass. Propionyl-CoA requires additional reactions including carboxylation in order to be able to enter the TCA cycle.
The reaction CO2 + propionyl-CoA ----> methylmalonyl-CoA is catalyzed by propionyl-CoA carboxylase, a biotin-containing enzyme, which is inhibited by avidin. Palmitate oxidation however, does not involve carboxylation.
Explanation:
Even-number fatty acids such as palmitate undergoes complete β-oxidation in the liver motochondria to CO₂ because their oxidation product, acetyl-CoA, can enter the TCA cycle where it is oxidized to CO₂.
Undecanoic acid is an odd-number fatty acid having 11 carbon atoms. Oxidation of odd-number fatty acids such as undecanoic acid yields a five -carbon fatty acyl substrate for their last pass through β-oxidation which is oxidized and cleaved into acetyl-CoA + propionyl-CoA. Propionyl-CoA requires additional reactions including carboxylation in order to be able to enter the TCA cycle. Since oxidation is occuring in a liver extract, CO₂ has to be externally sourced in order for the carboxylation of propionyl-CoA to proceed and thus resulting in comlete oxidation of undecanoic acid.
The reaction CO2 + propionyl-CoA ----> methylmalonyl-CoA is catalyzed by propionyl-CoA carboxylase, a biotin-containing enzyme. The role of biotin is to activate the CO₂ before its tranfer to the propionate moiety. The addition of the protein avidin prevents the complete oxidation of undecanoic acid by binding tightly to biotin, hence inhibiting the activation and transfer of CO₂ to propionate.
Palmitate oxidation however, does not involve carboxylation, hence addition of avidin has no effect on its oxidation.
Which of the following aqueous solutions are good buffer systems?
0.31 M ammonium bromide + 0.39 M ammonia
0.31 M nitrous acid + 0.25 M potassium nitrite
0.21 M perchloric acid + 0.21 M potassium perchlorate
0.16 M potassium cyanide + 0.21 M hydrocyanic acid
0.14 M hypochlorous acid + 0.21 M sodium hypochlorite
0.13 M nitrous acid + 0.12 M potassium nitrite
0.15 M potassium hydroxide + 0.22 M potassium bromide
0.23 M hydrobromic acid + 0.20 M potassium bromide
0.34 M calcium iodide + 0.29 M potassium iodide
0.33 M ammonia + 0.30 M sodium hydroxide
0.20 M nitrous acid + 0.18 M potassium nitrite
0.30 M ammonia + 0.34 M ammonium bromide
0.29 M hydrobromic acid + 0.22 M sodium bromide
0.17 M calcium hydroxide + 0.28 M calcium bromide
0.34 M potassium iodide + 0.27 M potassium bromide
Answer:
Answers are in the explanation.
Explanation:
A buffer is defined as the aqueous mixture of a weak acid and its conjugate base or vice versa. Having this in mind:
0.31 M ammonium bromide + 0.39 M ammonia . Is a good buffer system because ammonia is a weak base and its conjugate base, ammonium ion is in the solution.
0.31 M nitrous acid + 0.25 M potassium nitrite . Is a good buffer system because nitrous acid is the weak acid and nitrite ion its conjugate base.
0.21 M perchloric acid + 0.21 M potassium perchlorate . Perchloric acid is a strong acid. Thus, Is not a good buffer system.
0.16 M potassium cyanide + 0.21 M hydrocyanic acid . Hydrocyanic acid is a weak acid and cyanide ion is its conjugate base. Is a good buffer system.
0.14 M hypochlorous acid + 0.21 M sodium hypochlorite . Hypochlorous acid is a weak acid and hypochlorite ion its conjugate base. Is a good buffer system.
0.13 M nitrous acid + 0.12 M potassium nitrite . Is a good buffer system as I explained yet.
0.15 M potassium hydroxide + 0.22 M potassium bromide . Potassium hydroxide is a strong base. Is not a good buffer system.
0.23 M hydrobromic acid + 0.20 M potassium bromide . HBr is a strong acid. Is not a good buffer system.
0.34 M calcium iodide + 0.29 M potassium iodide . CaI and KI are both salts, Is not a good buffer system.
0.33 M ammonia + 0.30 M sodium hydroxide . Ammonia is a weak base but its conjugate base ammonium ion is not in solution. Is not a good buffer system.
0.20 M nitrous acid + 0.18 M potassium nitrite . Is a good buffer system.
0.30 M ammonia + 0.34 M ammonium bromide . Ammonia and ammonium in solution, Good buffer system.
0.29 M hydrobromic acid + 0.22 M sodium bromide . HBr is a strong acid, is not a good buffer system.
0.17 M calcium hydroxide + 0.28 M calcium bromide . CaOH is a strong base, is not a good buffer system.
0.34 M potassium iodide + 0.27 M potassium bromide. KI and KBr are both salts, is not a good buffer system.
When comparing the two chair conformations for a monosubstituted cyclohexane ring, which type of substituent shows the greatest preference for occupying an equatorial position rather than an axial position
Answer:
See the explanation
Explanation:
In this case, we have to keep in mind that in the monosubstituted product we only have to replace 1 hydrogen with another group. In this case, we are going to use the methyl group [tex]CH_3[/tex].
In the axial position, we have a more steric hindrance because we have two hydrogens near to the [tex]CH_3[/tex] group. If we have more steric hindrance the molecule would be more unstable. In the equatorial positions, we don't any interactions because the [tex]CH_3[/tex] group is pointing out. If we don't have any steric hindrance the molecule will be more stable, that's why the molecule will the equatorial position.
See figure 1
I hope it helps!
Look at the picture and observations below.
Observations: The bee's wings are moving very fast.
The bee's wings are much smaller than its body.
what’s the answer ?
Answer:
How are bees able to fly?
Explanation:
What are the concentrations of Cu2+, NH3, and Cu(NH3)42+ at equilibrium when 18.8 g of Cu(NO3)2 is added to 1.0 L of a 0.800 M solution of aqueous ammonia? Assume that there is no volume change upon the addition of the solid, and that the reaction goes to completion and forms Cu(NH3)42+.
Answer:
Explanation:
Cu(NO₃)₂ + 4NH₃ = Cu(NH₃)₄²⁺ + 2 NO₃⁻
187.5 gm 4M 1 M
187.5 gm reacts with 4 M ammonia
18.8 g reacts with .4 M ammonia
ammonia remaining left after reaction
= .8 M - .4 M = .4 M .
187.5 gm reacts with 4 M ammonia to form 1 M Cu(NH₃)₄²⁺
18.8 g reacts with .4 M ammonia to form 0.1 M Cu(NH₃)₄²⁺
At equilibrium , the concentration of Cu²⁺ will be zero .
concentration of ammonia will be .4 M
concentration of Cu(NH₃)₄²⁺ formed will be 0.1 M
Why need to add NaAlF6 to Al2O3?
How many grams of POCl3 are produced when 225.0 grams of P4O10 and 675.0 grams of PCl5 react? This is the balance equation P4O10 + 6PCl5 → 10POCl3
Answer:
900g of POCl₃
Explanation:
Hello,
To solve this question, we'll require the equation of reaction.
P₄O₁₀ + 6PCl₅ → 10POCl₃
Molar mass of P₄O₁₀ = 283.886 g/mol
Molar mass of PCl₅ = 208.24 g/mol
Molar mass of POCl₃ = 153.33 g/mol
But Number of moles = mass / molar mass
Mass = molar mass × number of moles
Mass of POCl₃ = 153.33 × 10 = 1533.3g
Mass of PCl₅ = 208.24 × 6 = 1249.44g
Mass of P₄O₁₀ = 283.886 × 1 = 283.886g
From the equation of reaction,
283.886g of P₄O₁₀ + 1249.44g of PCl₅ produces 1533.33g of POCl₃
I.e 1533.33g of reactants produces 1533.33g of product (law of conservation of mass)
Therefore, (225g of P₄O₁₀ + 675g of PCl₅) = 900g will give x g of POCl₃.
1533.33g of reactants = 1533.33g of products
900g of reactants = x g of products
x = (900 × 1533.33) / 1533.33
x = 900g of POCl₃
When ethanol, C2H5OH (a component in some gasoline mixtures) is burned in air, one molecule of ethanol combines with three oxygen molecules to form two CO2 molecules and three H2O molecules.
A) Write the balanced chemical equation for the reaction described.
B) How many molecules of CO2 and H2O would be produced when 2 molecules ethanol are consumed? Equation?
C) How many H2O molecules are formed, then 9 O2 molecules are consumed? What conversion factor did you use? Explain!
D) If 15 ethanol molecules react, how many molecules O2 must also react? What conversion factor did you use? Explain!
Answer:
1) C2H5OH(l)+3O2(g)⟶2CO2(g)+3H2O(l)
2) four molecules of CO2 will be produced and six molecules of water
3)9 molecules of water are formed when 9 molecules of oxygen are consumed.
4) 45 molecules of oxygen
Explanation:
The balanced chemical reaction equation is shown here and must guide our work. When ethanol is burned in air, it reacts as shown;
C2H5OH(l)+3O2(g)⟶2CO2(g)+3H2O(l)
Hence, if we use 2 molecules of ethanol, the balanced reaction equation will look like this;
2C2H5OH(l)+6O2(g)⟶4CO2(g)+6H2O(l)
Hence four molecules of CO2 are formed and six molecules of water are formed
From the balanced stoichiometric equation;
3 molecules of oxygen yields 3 molecules of water
Therefore, 9 molecules of oxygen will yield 9 × 3/3 = 9 molecules of water
Therefore, 9 molecules of water are formed when 9 molecules of oxygen are consumed.
From the reaction equation;
1 molecule of ethanol reacts with 3 molecules of oxygen
Therefore 15 molecules of ethanol will react with 15 × 3/1 = 45 molecules of oxygen
Why does a chemical change occur when copper is heated?
Answer:
When copper is heated, it decomposes to form copper oxide and carbon dioxide. It is an endothermic reaction, which means that it absorbs heat. When heated, copper is easily bent or molded into shapes.
Explanation: