A solution contains 0.0440 M Ca2 and 0.0940 M Ag. If solid Na3PO4 is added to this mixture, which of the phosphate species would precipitate out of solution first?
A. Na3PO4.
B. Ag3PO4.
C. Ca3(PO4)2
When the second cation just starts to precipitate, what percentage of the first cation remains in solution?

Answers

Answer 1

Answer:

C. [tex]Ca_3(PO_4)_2[/tex]  will precipitate out first

the percentage of [tex]Ca^{2+}[/tex]remaining =  12.86%

Explanation:

Given that:

A solution contains:

[tex][Ca^{2+}] = 0.0440 \ M[/tex]

[tex][Ag^+] = 0.0940 \ M[/tex]

From the list of options , Let find the dissociation of [tex]Ag_3PO_4[/tex]

[tex]Ag_3PO_4 \to Ag^{3+} + PO_4^{3-}[/tex]

where;

Solubility product constant Ksp of [tex]Ag_3PO_4[/tex] is [tex]8.89 \times 10^{-17}[/tex]

Thus;

[tex]Ksp = [Ag^+]^3[PO_4^{3-}][/tex]

replacing the known values in order to determine the unknown ; we have :

[tex]8.89 \times 10 ^{-17} = (0.0940)^3[PO_4^{3-}][/tex]

[tex]\dfrac{8.89 \times 10 ^{-17}}{(0.0940)^3} = [PO_4^{3-}][/tex]

[tex][PO_4^{3-}] =\dfrac{8.89 \times 10 ^{-17}}{(0.0940)^3}[/tex]

[tex][PO_4^{3-}] =1.07 \times 10^{-13}[/tex]

The dissociation  of [tex]Ca_3(PO_4)_2[/tex]

The solubility product constant of [tex]Ca_3(PO_4)_2[/tex]  is [tex]2.07 \times 10^{-32}[/tex]

The dissociation of [tex]Ca_3(PO_4)_2[/tex]   is :

[tex]Ca_3(PO_4)_2 \to 3Ca^{2+} + 2 PO_{4}^{3-}[/tex]

Thus;

[tex]Ksp = [Ca^{2+}]^3 [PO_4^{3-}]^2[/tex]

[tex]2.07 \times 10^{-33} = (0.0440)^3 [PO_4^{3-}]^2[/tex]

[tex]\dfrac{2.07 \times 10^{-33} }{(0.0440)^3}= [PO_4^{3-}]^2[/tex]

[tex][PO_4^{3-}]^2 = \dfrac{2.07 \times 10^{-33} }{(0.0440)^3}[/tex]

[tex][PO_4^{3-}]^2 = 2.43 \times 10^{-29}[/tex]

[tex][PO_4^{3-}] = \sqrt{2.43 \times 10^{-29}[/tex]

[tex][PO_4^{3-}] =4.93 \times 10^{-15}[/tex]

Thus; the phosphate anion needed for precipitation is smaller i.e [tex]4.93 \times 10^{-15}[/tex] in [tex]Ca_3(PO_4)_2[/tex] than  in  [tex]Ag_3PO_4[/tex]  [tex]1.07 \times 10^{-13}[/tex]

Therefore:

[tex]Ca_3(PO_4)_2[/tex]  will precipitate out first

To determine the concentration of [tex][Ca^+][/tex] when  the second cation starts to precipitate ; we have :

[tex]Ksp = [Ca^{2+}]^3 [PO_4^{3-}]^2[/tex]

[tex]2.07 \times 10^{-33} = [Ca^{2+}]^3 (1.07 \times 10^{-13})^2[/tex]

[tex][Ca^{2+}]^3 = \dfrac{2.07 \times 10^{-33} }{(1.07 \times 10^{-13})^2}[/tex]

[tex][Ca^{2+}]^3 =1.808 \times 10^{-7}[/tex]

[tex][Ca^{2+}] =\sqrt[3]{1.808 \times 10^{-7}}[/tex]

[tex][Ca^{2+}] =0.00566[/tex]

This implies that when the second  cation starts to precipitate ; the  concentration of [tex][Ca^{2+}][/tex] in the solution is  0.00566

Therefore;

the percentage of [tex]Ca^{2+}[/tex]  remaining = concentration remaining/initial concentration × 100%

the percentage of [tex]Ca^{2+}[/tex] remaining = 0.00566/0.0440  × 100%

the percentage of [tex]Ca^{2+}[/tex] remaining = 0.1286 × 100%

the percentage of [tex]Ca^{2+}[/tex]remaining =  12.86%


Related Questions

It was calculated that 4.3mL of 0.417 M HCl is required to titrate 11.9 mL of 0.151 M Mg(OH)2. Show evidence 2 HCl(aq) + Mg(OH)2(aq) → + MgCl2(aq) + 2 H2O(l)

Answers

Answer:

See explanation.

Explanation:

Hello,

In this case, for the described chemical reaction:

2 HCl(aq) + Mg(OH)2(aq) → MgCl2(aq) + 2 H2O(l)

We can notice there is a 2:1 molar ratio between the moles of hydrochloric acid and magnesium hydroxide, therefore, at the equivalence point:

[tex]n_{HCl}=2*n_{Mg(OH)_2}[/tex]

And in terms of volumes and concentrations we verify:

[tex]V_{HCl}M_{HCl}=2*V_{Mg(OH)_2}M_{Mg(OH)_2}[/tex]

So we use the given data to proof it:

[tex]4.3mL*0.417M=2*11.9mL*0.151M\\1.793=3.594[/tex]

Therefore, we can conclude the data is wrong by means of the 2:1 mole ratio that for sure was not taken into account. This is also supported by the fact that normalities are actually the same, but the nomality of magnesium hydroxide is the half of the hydrochloric acid normality since the acid is monoprotic and the base has two hydroxyl ions.

Best regards.

Why does a new period start on the periodic table, instead of the row continuing? A. A new period starts when a new energy shell starts. B. A new period starts when a new neutron cycle starts. C. None of these D. It is based on how many protons it has.

Answers

Answer:

B

Explanation:

All the elements in a period have valence electrons in the same shell. The number of valence electrons increases from left to right in the period. When the shell is full, a new row is started and the process repeats.

A new period starts when a new neutron cycle starts. Hence, option B is correct.

What is the period in the periodic table?

A period in the periodic table is a row of chemical elements. All elements in a row have the same number of electron shells.

All the elements in a period have valence electrons in the same shell.

The number of valence electrons increases from left to right in the period.

When the shell is full, a new row is started and the process repeats.

Hence, option B is correct.

Learn more about the period in the periodic table here:

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When a hydrochloric acid solution is combined with a potassium hydroxide solution, an acid-base reaction occurs Write a balanced molecular equation for this reaction. Express your answer as a chemical equation. Identify all of the phases in your answer..

Answers

Answer:

HCl(aq) + KOH(aq) ⇒ KCl(aq) + H₂O(l)

Explanation:

Hydrochloric acid is an acid because it releases H⁺ in an aqueous solution.

Potassium hydroxide is a base because it releases OH⁻ in an aqueous solution.

When an acid reacts with a base they form a salt and water. This is a neutralization reaction. The neutralization reaction between hydrochloric acid and potassium hydroxide is:

HCl(aq) + KOH(aq) ⇒ KCl(aq) + H₂O(l)

4. What is the molar concentration and grams/Liter of a NaOH solution if 86 ml are titrated to an
endpoint by 375 ml of a solution of HCl that is .0175 M?
g/L: ________
Molarity: ____

Answers

Answer:

0.76 M

30 g/L

Explanation:

Step 1: Given data

Molarity of the acid (Ma): 0.175 MVolume of the acid (Va): 375 mLMolarity of the base (Mb): ?Volume of the base (Vb): 86 mL

Step 2: Calculate the molarity of the base

We will use the following expression.

[tex]Ma \times Va = Mb \times Vb\\Mb = \frac{Ma \times Va}{Vb} = \frac{0.175M \times 375mL}{86mL} = 0.76 M[/tex]

Step 3: Calculate the concentration of the base in g/L

The molar mass of NaOH is 40.00 g/mol.

[tex]\frac{0.76mol}{L} \times \frac{40.00g}{mol} = 30 g/L[/tex]

Each energy sub level contains __________ number of electrons. For example, sub level D can hold up to _______ electrons. A. the same, 10 B. the same, 14 C. a different, 6 D. a different, 10

Answers

Answer:

the same and 14

Explanation:

ed tell chem

Answer: the same 10

Explanation:

Which of the following aqueous solutions are good buffer systems? . a. 0.12 M calcium hydroxide + 0.29 M calcium bromide . b. 0.25 M perchloric acid + 0.16 M sodium perchlorate . c. 0.34 M hydrocyanic acid + 0.27 M sodium cyanide .

Answers

Answer:

c. 0.34 M hydrocyanic acid + 0.27 M sodium cyanide .

Explanation:

A buffer is defined as the aqueous mixture of a weak acid with its conjugate base or vice versa. Based on the systems:

a. 0.12 M calcium hydroxide + 0.29 M calcium bromide. IS NOT A GOOD BUFFER SYSTEM because Ca(OH)₂ is a strong base.

b. 0.25 M perchloric acid + 0.16 M sodium perchlorate. IS NOT A GOOD BUFFER SYSTEM because perchloric acid is a strong acid

c. 0.34 M hydrocyanic acid + 0.27 M sodium cyanide. IS A GOOD BUFFER SYSTEM because HCN is a weak acid, and its conjugate base, CN⁻, is obtained in the dissolution of NaCN as Na⁺ and CN⁻ ions.

A 32.3-gram sample of gas is found to have a volume of 1.9 liters at 301 K and 1.21 atm. What is the molar mass of this gas? Show all of the work used to solve this problem.

Answers

Answer:

351.1g/mol

Explanation:

you can find the answer using The ideal gas equation

n= PV/RT

n=(1.21*1.9/0.082*301)mol

n=0.092 mol

molar mass=Mass/mole

m=32.3g/0.092mol

m=351.1g/mol

solution solution solution​

Answers

Answer:

Oxygen present in food items makes then rancid due to the presence of oils and fats. If the food is flushed with nitrogen, it prevents it from being oxidised (the nitrogen acts as an antioxidant).

Hope it helps ! :)

Describe what happens when two substances at different temperatures cine into contact. Describe how the law of conservation of energy applies to this system

Answers

Answer:

The substance with the highest heat gives heat to the lowest temperature, equating both temperatures,

In this situation there is talk of giving up heat but not matter, it is here that the law of conservation of energy comes into play.

Explanation:

The law of conservation of energy talks about that energy is transformed and never lost between two substances or two bodies that interact with each other, these interactions can be heat exchanges, as in this example.

By what mechanism does cyclohexanol react when treated in sulfuric acid and what compound results?A) E 1; methoxycyclohexane B) E2: methoxycyclohexane C) SN 1; methoxycycloheXafle D) E2; cyclohexene E) E 1: cyclohexene

Answers

Answer:

E 1: cyclohexene

Explanation:

This reaction is an example of the dehydration of cyclic alcohols. The reaction proceeds in the following steps;

1) The first step of the process is the protonation of the cyclohexanol by the acid. This now yields H2O^+ attached to the cyclohexane ring.

2) the water molecule, which a good leaving group now leaves yielding a carbocation. This now leaves a cyclohexane carbocation which is highly reactive.

3) A water molecule now abstracts a proton from the carbon adjacent to the carbocation leading to the formation of cyclohexene and the regeneration of the acid catalyst. This is an E1 mechanism because it proceeds via a carbocation intermediate and not a concerted transition state, hence the answer.

A mixture with H2 and He exerts a total pressure of 0.48 atm. If there is 1.0 g of H2 and 1.0 g of He in the mixture, what is the partial pressure (in atmospheres) of hydrogen?

Answers

Answer:

Partial pressure of hydrogen H₂ = 0.32 atm

Explanation:

Given:

Total pressure = 0.48 atm

Find:

Partial pressure of hydrogen

Computation:

Number of mole of H₂ = 1 / 2 = 0.5 moles

Number of mole of He  = 1 / 4 = 0.25 moles

Total moles = 0.5 + 0.25 = 0.75

Partial pressure of hydrogen H₂ = [moles / total moles] Total pressure

Partial pressure of hydrogen H₂ = [0.50 / 0.75]0.48 atm

Partial pressure of hydrogen H₂ = 0.32 atm

Answer: 0.32 atm

Explanation:

First convert the mass of H2 to moles using the molar mass.

(1.0 gram H2 ⋅ (1.0 mol H2 / 2.016 g H2)) ≈ 0.50 mol H2

Next, convert the mass of helium He to moles using the atomic mass.

(1.0 gram He ⋅ (1.0 mol He / 4.003 g He)) ≈ 0.25mol He

The total number of moles is about 0.75 moles . The partial pressure of a component of a gas mixture can be found by multiplying the mole fraction by the total pressure.

PH2 = XH2 × Ptotal

PH2 = (0.50 mol / 0.75 mol)(0.48 atm) = 0.32 atm

If Kb = 1.6 x 10−6, calculate the pH of solution of 0.0015 M morphine. Justify any approximations you make

Answers

Answer:

4.3

Explanation:

Data provided in the question as per the question is as follows

[tex]k_b = 1.6 \times 10^{-6}[/tex]

Now we use the log in both the sides

So,

[tex]Pk_b = -log\ k_b = -log (1.6 \times 10^{-6})[/tex]

[tex]Pk_b[/tex] = 5.795

And, C = 0.0015

log c = -2.823

Now pH is

[tex]= \frac{1}{2} (Pk_b - log\ c)[/tex]

[tex]= \frac{1}{2} (5.795 - (-2.823))[/tex]

= 4.3

Hence, the pH of the solution of 0.0015 M morphine is 4.3 and the same is to be considered by applying the above formulas and the calculations part

A mixture of krypton and nitrogen gases, at a total pressure of 711 mm Hg, contains 11.7 grams of krypton and 4.10 grams of nitrogen. What is the partial pressure of each gas in the mixture

Answers

Answer:

A. Partial pressure of krypton, Kr is 346.97 mmHg

B. Partial pressure of nitrogen, N2 is 364.03 mmHg.

Explanation:

Step 1:

Data obtained from the question. This include the following:

Total pressure (Pt) = 711 mmHg

Mass of Kr = 11.7 g

Mass of N2 = 4.10 g

Partial pressure of Kr =..?

Partial pressure of N2 =...?

Step 2:

Determination of the number of mole of krypton, Kr and nitrogen, N2. This is illustrated below:

Molar mass of Kr = 84g/mol

Mass of Kr = 11.7g

Mole of Kr =?

Mole = mass /Molar mass

Mole of Kr = 11.7/84 = 0.139 mole

Molar mass of N2 = 2x14 = 28g/mol

Mass of N2 = 4.10g

Mole of N2 =?

Mole = mass /Molar mass

Mole of N2 = 4.1/28 = 0.146 mole

Step 3:

Determination of the mole fraction for each gas. This is illustrated below:

Mole of Kr = 0.139 mole

Mole of N2 = 0.146 mole

Total mole = 0.139 + 0.146 = 0.285 mole

Mole fraction of Kr = mol of Kr/total mol

Mole fraction of Kr = 0.139/0.285

Mole fraction of Kr = 0.488

Mole fraction of N2 = mol of N2/total mol

Mole fraction of N2 = 0.146/0.285

Mole fraction of N2 = 0.512

A. Determination of the partial pressure of krypton, Kr.

This is illustrated below:

Total pressure (Pt) = 711 mmHg

Mole fraction of Kr = 0.488

Partial pressure of Kr =..?

Partial pressure = mole fraction x total pressure

Partial pressure of Kr = 0.488 x 711

Partial pressure of Kr = 346.97 mmHg

B. Determination of the partial pressure of nitrogen, N2

This is illustrated below:

Total pressure (Pt) = 711 mmHg

Mole fraction of N2 = 0.512

Partial pressure of N2 =?

Partial pressure = mole fraction x total pressure

Partial pressure of N2 = 0.512 x 711

Partial pressure of N2 = 364.03 mmHg

Average Molarity for HCl is .391
Average Molarity for NaOH is .0962

Volume for HCl is:
Trial 1 Your Answer: 14mL
Trial 2 Your Answer: 14mL
Trial 3 Your Answer: 14mL

Volume for NaOH is:
Trial 1: 34.26mL
Trial 2: 33.48mL
Trial 3: 33.84mL

Entry # mass tablet(g) mass antacid(g) Vol HCl(mL) Vol NaOH(mL)
#1: 1.515 0.9010 14.00 34.26
#2: 1.452 0.8370 14.00 33.48
#3: 1.443 0.8280 14.00 33.84

I need help finding the mmoles HCl/mg please.

Answers

Answer:

#1: 0.00144 mmolHCl/mg Sample

#2: 0.00155 mmolHCl/mg Sample

#3: 0.00153 mmolHCl/mg Sample

Explanation:

A antiacid (weak base) will react with the HCl thus:

Antiacid + HCl → Water + Salt.

In the titration of antiacid, the strong acid (HCl)  is added in excess, and you're titrating with NaOH moles of HCl that doesn't react.

Moles that react are the difference between mmoles of HCl - mmoles NaOH added (mmoles are Molarity×mL added). Thus:

Trial 1: 0.391M×14.00mL - 0.0962M×34.26mL = 2.178 mmoles HCl

Trial 2: 0.391M×14.00mL - 0.0962M×33.48mL = 2.253 mmoles HCl

Trial 3: 0.391M×14.00mL - 0.0962M×33.84mL = 2.219 mmoles HCl

The mass of tablet in mg in the 3 experiments is 1515mg, 1452mg and 1443mg.

Thus, mmoles HCl /mg OF SAMPLE for each trial is:

#1: 2.178mmol / 1515mg

#2: 2.253mmol / 1452mg

#3: 2.219mmol / 1443mg

#1: 0.00144 mmolHCl/mg Sample#2: 0.00155 mmolHCl/mg Sample#3: 0.00153 mmolHCl/mg Sample

A 25.0 mL sample of a solution of an unknown compound is titrated with a 0.115 M NaOH solution. A buffer region was found around a pH of 3.5. The unknown compound is

Answers

Answer:

The unknown compound is a weak acid.

Explanation:

Given that :

a 25 mL sample of a solution of an unknown compound is titrated with a 0.115 M NaOH solution.

A buffer region was found around a pH of 3.5. We know that a pH of 3.5 is a weak acid. So, it is likely to be an organic acid

Let assume the solution of the unknown sample to be CH₃COOH

Now :

25 mL of CH₃COOH reacted with 0.115 M of NaOH

The equation for the reaction will be :

CH₃COOH    +    NaOH -----> CH₃COONa + H₂O

at x mole of      0.115y M of

CH₃COOH       NaOH is present

If NaOH was added in excess;

CH₃COOH    +    NaOH -----> CH₃COONa , NaOH will be lost then CH₃COOH    and CH₃COONa will be present

Therefore;

At equilibrium : Only CH₃COONa will be present but if it is above equilibrium NaOH will be present   because the pH will increase due to the presence of the strong base

A metal, M , of atomic mass 56 amu reacts with chlorine to form a salt that can be represented as MClx. A boiling point elevation experiment is performed to determine the subscript x , and therefore, the formula of the salt. A 22.9 g sample of the salt is dissolved in 100.0 g of water and the boiling point of the solution is found to be 375.93 K. Find the formula of the salt. Assume complete dissociation of the salt in solution g

Answers

Answer:

Formula for the salt: MCl₃

Explanation:

MClₓ → M⁺  +  xCl⁻

We apply the colligative property of boiliing point elevation.

We convert the boiling T° to °C

375.93 K - 273K = 102.93°C

ΔT = Kb . m . i

where ΔT means the difference of temperature, Keb, the ebulloscopic constant for water, m the molality of solution (mol of solute/kg of solvent) and i, the Van't Hoff factor (numbers of ions dissolved)

ΔT = 102.93°C - 100°C = 2.93°C

Kb = 0.512 °C/m

We replace data: 2.93°C = 0.512 °C/m . m . i

i = x + 1 (according to the equation)

22.9 g / (56g/m + 35.45x) = moles of salt / 0.1kg = molality

We have calculated the moles of salt in order to determine the molar mass, cause we do not have the data. We replace

2.93°C = 0.512 °C/m . [22.9 g / (56g/m + 35.45x)] / 0.1kg . (x+1)

2.93°C / 0.512 m/°C = [22.9 g / (56g/m + 35.45x)] / 0.1kg . (x+1)

5.72 m = [22.9 g / (56g/m + 35.45x)]/ 0.1 (x+1)

5.72 . 0.1 / [22.9 g / (56g/m + 35.45x)] = x+1

0.572 / (22.9 g / (56g/m + 35.45x) = x+1

0.572 (56 + 35.45x) / 22.9 = x+1

0.572 (56 + 35.45x) = 22.9x + 22.9

32.03 + 20.27x = 22.9x + 22.9

9.13 = 2.62x

x = 3.48 ≅ 3

can somebody please help me asap !!!

Answers

Answer:

Option A. 1191.49 K

Explanation:

Data obtained from the question include:

The equation for the reaction is given below:

4HCl + O2 —> 2Cl2 + 2H2O

Enthalpy (H) = +280 KJ/mol = +280000 J/mol

Entropy (S) = +235 J/Kmol

Temperature (T) =..?

The temperature at which the reaction will be feasible can be obtained as follow:

Change in entropy (ΔS) = change in enthalphy (ΔH)/T

(ΔS) = (ΔH)/T

235 = 280000/T

Cross multiply

235 x T = 280000

Divide both side by 235

T = 280000/235

T = 1191.49 K

Therefore, the temperature at which the reaction will be feasible is 1191.49 K

What is the mass of 7.68 x 1024 molecules of phosphorus trichloride?

Answers

Answer:

THE MASS OF 7.68 *10^24 MOLECULES OF PHOSPHORUS TRICHLORIDE IS 1746.25 g.

Explanation:

Molar mass of PCl3 = ( 31 + 35.5 *3) = 137.5 g/mol

At 7.68 * 10^24 molecules, how many number of mole is present?

6.03 * 10^23 molecules = 1 mole

7.68*10^24 molecules = x mole

x mole = 7.68 *10^24 molecules/ 6.03 *10^23

x mole = 1.27 *10 moles

x mole = 12.7 moles

Using mole = mass / molar mass

mass = mole * molar mass

mass = 12.7 moles * 137.5 g/mol

mass = 1746.25 g

Hence, the mass of 7.68 *10^24 molecules is 1746.25 g

The graph below shows the half life values of parent isotopes


Based on the graph, it can be concluded that the isotope which is most likely to be found with 12.5% of its original amount in 42 billion years is

Answers

Answer:

Thorium-235

Explanation:

Half-life is defined as the time taken for a radioactive material to reduce to half of its original amount. If the original amount of a radioactive substance N is 100%, then;

1st half-life- 50% of N is left

2nd half life - 25% of N is left

3rd half-life- 12.5% of N is left

The half-life of Thorium-235 is 15 billion years, hence three half lives will take place in 45 billion years. Hence 12.5% of the original amount of Thorium-235 present will remain after about 42 billion years.

Suppose you are working with a NaOH stock solution but you need a solution with a lower concentration for your experiment. Calculate the volume (in milliliters) of the 1.436 M stock NaOH solution needed to prepare 250.0 mL of 0.1342 M dilute NaOH solution.

Answers

Answer:

23.36mL of the stock solution are required.

Explanation:

A dilution consist in the addition of solvent to decreases the concentration of a stock solution (The solution more concentrated).

As you want to prepare 250.0mL = 0.2500L of a 0.1342M NaOH, moles of NaOH you require to make this concentration in this volume are:

0.2500L × (0.1342mol / L) = 0.03355 moles of NaOH you require in the diluted solution.

These moles comes from the 1.436M stock solution. The volume of the stock solution you need to add is:

0.03355moles NaOH × (1L / 1.436mol) = 0.02336L of the 1.436M solution =

23.36mL of the stock solution are required.

A 2.0 g sample of hydrocarbon was burned in the calorimeter. The temperature rose from 29°c to 32°c and heat and combustion is 11. Kj/g. Thr heat capacity of the calorimeter is

Answers

Answer:

THE HEAT CAPACITY OF THE CALORIMETER IS 3666.67 J/C

Explanation:

Mass = 2 g

Temperature difference = 32 C - 29 C = 3 C

Heat of combustion = 11 kJ/g

Heat capacity of the calorimeter = unknown

It is important to note that the heat of combustion of the reaction is the heat absorbed by the calorimeter in raising the mixture by 3 C

So therefore,

Heat = heat capacity * temperature difference

Heat capacity = Heat / temperature difference

Heat capacoty = 11 000 J / 3 C

Heat capacity = 3666.67 J/ C

If the reaction consumes methane gas ( CH4 ) at a rate of 2.08 M/s, what is the rate of formation of H2 ? the balanced equation is CH4 + N2Cl4 = CCl4 + N2 + 2 H2

Answers

Answer:

4.16M/s

Explanation:

Based on the reaction:

CH₄ + N₂Cl₄ ⇄ CCl₄ + N₂ + 2H₂

1 mole of methane, CH₄, produce 2 moles of H₂.

That means whereas 1 mole of methane is consumed, 2 moles of H₂ are formed

Having this in mind, if you are consuming methane at a rate of 2.08M/s, the rate of formation of hydrogen must be twice this rate, because there are produced twice moles of H₂.

Thus, rate of formation of H₂ is:

2.08M/s ₓ 2 =

4.16M/s

The rate of formation of H2 is 4.16M/s

The calculation is as follows:

Based on the reaction:

CH₄ + N₂Cl₄ ⇄ CCl₄ + N₂ + 2H₂

here

1 mole of methane, CH₄, produce 2 moles of H₂.

In the case when you are consuming methane at a rate of 2.08M/s, the rate of formation of hydrogen must be twice this rate, because there are produced twice moles of H₂.

Thus, rate of formation of H₂ is:

2.08M/s ( 2) = 4.16M/s

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According to valence bond theory, which orbitals overlap in the formation of the bond in HCl?
a) 1s on H and 3p on Cl
b) 1s on H and 4s on Cl
c) 1s on H and 2p on Cl
d) 2s on H and 3p on Cl
e) 2s on H and 2p on Cl

Answers

a) 1s on H and 3p on Cl

In HCl, the H atom has only one valance electron. Each share an electron an therefore a single covalent bond is formed between the two. The bond in HCl is therefore a result of an overlap between 1s orbital and ONLY ONE of the lobes of the 3p orbital of Chlorine.

Determine the enthalpy change when 19.399999999999999 g of carbon is reacted with oxygen according to the reaction

Answers

Answer:

The enthalpy change is −636.9798 kJ

Explanation:

The equation of the reaction between Carbon and Oxygen can be represented as :

[tex]C_{(s)} + O_{2(g)} \to CO_{2_(g)} \ \ \ \ \ \ \Delta H = -394 \ \ kJ/mol[/tex]

molar mass of Carbon = 12 mole

when mass of  19.399999999999999 g of carbon reacted with oxygen;

the number of moles = mass/molar mass

the number of moles = 19.399999999999999/12

the number of moles = 1.6167 mol

Thus the enthalpy change when  1 mole of carbon react with oxygen = -394 kJ/mol

Therefore when 1.6167 moles react with oxygen; we have:

= 1.6167 mol ×  -394 kJ/mol

= −636.9798 kJ

Select the correct classification for the reaction.
4NH3(g) + 502(g) – 4NO(g) + 6H20(9)

Answers

ΔGrxn = 958 kJ

(answer on Edge)

To solve such this we must know the concept of redox reaction. Redox reaction is the one in which oxidation and reduction takes place simultaneously. The classification for the given reaction is redox reaction.

What is chemical reaction?

Chemical reaction is a process in which two or more than two molecules collide in right orientation and energy to form a new chemical compound. The mass of the overall reaction should be conserved. There are so many types of chemical reaction reaction like combination reaction, double displacement reaction.

The balanced equation is

4NH[tex]_3[/tex](g) + 50[tex]_2[/tex](g) – 4NO(g) + 6H[tex]_2[/tex]0(9)

In the given reaction, Nitrogen in NH[tex]_3[/tex] is getting reduced, Oxygen in 0[tex]_2[/tex] is getting oxidized.

Therefore, the classification for the given reaction is redox reaction.

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If the NaOH is added to 35.0 mL of 0.167 M Cu(NO3)2 and the precipitate isolated by filtration, what is the theoretical yield of the reaction?

Answers

Answer:

The correct answer is - 0.570 grams

Explanation:

The balanced chemical reaction is given by

Cu(NO3)2(aq)     + 2NaOH(aq)    -------->    Cu(OH)2(s)      + 2NaNO3(aq)

        1.0 mole            2.0 mole                 1.0 mole          2.0 mole

number of mol of Cu(OH)2,

n = Molarity * Volume

= [tex]35.0*0.167 = 5.845[/tex] millimoles

As clear in the equation, 1 mole of Cu(NO3)2 gives 1 mole of Cu(OH)2 , So, 5.845 millimoles of Cu(NO3)2 will produce 5.845 millimoles of Cu(OH)2

Mass of Cu(OH)2 = number of mol * molar mass

= [tex]97.5*5.845*10^-3[/tex]

= 0.570 grams

Thus, the correct answer is - 0.570 grams

Calculate the amount of heat required to convert 10.0 grams of ice at –20.°C to steam at 120.°C. (Sp. heat of H2O(s) = 2.09 J/g•°C, Sp. heat of H2O(l) = 4.18 J/g•°C, Sp. heat of H2O(gas) = 2.03 J/g•°C; heat of fusion of H2O(solid) = 333 J/g, heat of vaporization of H2O(liquid) = 2260 J/g).

Answers

Answer:

THE AMOUNT OF HEAT REQUIRED TO CONVERT ICE FROM -20 C TO STEAM AT 120 C IS 30 946 J OR 30.946 KJ OF HEAT.

Explanation:

Mass = 10 g

To convert 10 g of ice at -20°C to steam at 120°C, the heat involved is:

1. Heat involved in converting the ice from -20 °c to ice at 0 °C:

Heat = mass * specific heat of water solid * change in temperature

heat = 10g * 2.09 J/g°C * ( 0- (-20))

Heat = 10 * 2.09 * 20

heat = 418 J

2. Heat required to convert the ice from 0°C to water at 0°C:

Heat = mass * specific heat of fusion of water solid

Heat = 10 * 333

Heat = 3330 J

3. Heat required to convert water at 0 C to water at 100 C:

Heat = mass * specific heat of water * change in teperature

Heat = 10 * 4.18 * (100 -0)

Heat = 4180 J

4. Heat required to convert water at 100 C to steam at 100 C:

Heat = mass * specific heat of vaporization

Heat = 10 * 2260

Heat = 22600 J

5. Heat required to convert steam from 100 C to steam at 120 C:

Heat = mass * specific heat of water * change in temperature

Heat = 10 * 2.09 * (120 -100)

Heat = 10 * 2.09 * 20

Heat = 418 J

T

he heat required to convert 10 g of ice at -20 C to steam at 120 C is therefore the total of the individual heat of reactions

Total amount of heat = ( 418 J + 3330 J + 4180 J + 22600 J + 418 J)

Total heat =  30946 J

The substance used by homeowners and municipal workers to melt ice on sidewalks and roadways is usually calcium chloride rather than sodium chloride. Discuss two possible rea-sons for this preference.

Answers

Answer:

1. It dissolves much more ice faster than sodium chloride

2. Calcium chloride is more effective in melting ice at lower temperatures.

Explanation:

Salts are used to melt ice on roadways and sidewalks because they help to lower the freezing point of water.

Sodium chloride and calcium chloride are both salts used for this purpose but calcium chloride is usually preferred for the following two reasons:

1. It dissolves much more ice faster than sodium chloride: Calcium chloride dissolves much more ice faster than sodium chloride because when it dissociates, it produces three ions instead of the two produced when sodium chloride. Therefore, the heat of hydration of its ions is greater than that of sodium chloride.

2. Calcium chloride is more effective in melting ice at lower temperatures. It lowers the freezing point of water more than sodium chloride. Calcium chloride is able to lower the freezing point of water to about -52°C while sodium chloride only lowers it to about -6°C.

Al(NO3)3+H2SO4=HNO3+Al2(SO4)3

Answers

Hey there!:

2 Al(NO)₃+ 3 H₂SO₄ → 1 Al₂O₁₂S₃+ 6 HNO₃

Reagents : Al(NO₃)₃ and H₂SO₄

Products : Al₂O₁₂S₃ and HNO₃

Coefficients  : 2 , 3 , 1  and 6

Hope this helps!

Which aqueous solution will have the highest boiling point temperature? A. 0.100 molal NiBr2(aq) B. 0.250 molal CH3OH(aq) C. 0.100 molal MgSO4(aq) D. 0.150 molal Na2SO4(aq) E. 0.150 molal NH4NO3(aq)

Answers

Answer: 0.150 m [tex]Na_2SO_4(aq)[/tex] will have highest boiling point.

Explanation:

Formula used for Elevation in boiling point :

[tex]\Delta T_b=i\times k_b\times m[/tex]

where

[tex]\Delta T_b=T_b-T^o_b[/tex]= elevation in boiling point

[tex[k_b[/tex]  = boiling point constant  

m = molality

i = Van't Hoff factor

A) 0.100 m [tex]NiBr_2[/tex]

i = 3 as [tex]NiBr_2\rightarrrow Ni^{2+}+2Br^-[/tex]

concentration will be [tex]3\times 0.100=0.300[/tex]

B) 0.250 m [tex]CH_3OH[/tex]

i = 1 as [tex]CH_3OH[/tex] is a non electrolyte

concentration will be [tex]1\times 0.250=0.250[/tex]

C) 0.100 molal [tex]MgSO_4(aq)[/tex]

i = 2 as [tex]MgSO_4\rightarrrow Mg^{2+}+SO_4^{2-}[/tex]

concentration will be [tex]2\times 0.100=0.200[/tex]

D. 0.150 molal [tex]Na_2SO_4(aq)[/tex]

i = 3 as [tex]Na_2SO_4\rightarrrow 2Na^{+}+SO_4^{2-}[/tex]

concentration will be [tex]3\times 0.150=0.450[/tex]

E. 0.150 molal [tex]NH_4NO_3(aq)[/tex]

i = 2 as [tex]NH_4NO_3\rightarrrow NH_4^{+}+NO_3^{-}[/tex]

concentration will be [tex]2\times 0.150=0.300[/tex]

The solution having the highest concentration of ions will have the highest boiling point and thus 0.150 m [tex]Na_2SO_4(aq)[/tex] will have highest boiling point.

The aqueous solution that would have the highest temperature at boiling point would be:

D). 0.150 molal Na2SO4(aq)

What is a boiling point?

The boiling point is described as the temperature at which the solution starts boiling or the vapor pressure becomes equivalent to the provided external/outer pressure.

To determine the elevation in boiling point, we will use:

Δ[tex]T_{b}[/tex] [tex]= i[/tex] × [tex]k_{b}[/tex] × [tex]m[/tex]

with

[tex]T_{b}[/tex] [tex]= T_{b} - T^{0}_{b}[/tex]

[tex]k_b[/tex] [tex]=[/tex] constant of boiling point

Using this formula,

0.150 molal Na2SO4(aq)

Given,

[tex]i = 3[/tex]

[tex]Na2So4[/tex] will have

[tex]2Na^{+}[/tex] [tex]+[/tex] [tex]SO^{2-}_{4}[/tex]

So,

Concentration [tex]= 3[/tex] × [tex]0.15[/tex][tex]0[/tex]

[tex]= 0.45[/tex][tex]0[/tex]

∵ 0.150 molal [tex]Na2SO4[/tex]Na2SO4(aq) has the maximum concentration.

Thus, option D is the correct answer.

Learn more about "Aqueous solution" here:

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