Explanation:
At 593K a particular decomposition’s rate constant had a value of 5.21×10−4 and at 673K the same reaction’s rate constant was 7.42×10−3. It was noticed that when the reactant’s initial concentration was 0.2264 M (with a 593K reaction temperature), the initial reaction rate was identical to the initial rate when the decomposition was run at 673K with an initial reactant concentration of 0.05999 M. Recall that rate laws have the form rate = k [A]x and, showing work, determine the order of the decomposition reaction.
Which of the following metals has a low melting point?
2 A. Rubidium
B. Potassium
C. Calcium
D. Sodium
Answer:
Rubidium
Explanation:
Which functional group does the molecule below have?
A. Ether
B. Ester
C. Hydroxyl
D. Amino
Answer:
Hydroxyl
Explanation:
A hydroxyl group is a functional group that attaches to some molecules containing an oxygen and hydrogen atom, bonded together. Also spelled hydroxy, this functional group provides important functions to both alcohols and carboxylic acids.
The functional groups are the part of the organic chemistry that confers the characteristic feature of a molecule. The molecule has a hydroxyl group in its structure. Thus, option C is correct.
What are hydroxyl functional groups?Hydroxyl functional groups are the atoms or molecules that provide a distinctive property to a compound. It has a chemical formula of -OH that has oxygen covalently bonded to the hydrogen atom.
The hydroxyl group is called the alcohol group that is seen in methanol, ethanol, propanol, etc. The presence of hydrogen allows the compound to form a water bond with other molecules and makes them soluble and polar.
Therefore, option C. the molecule has a hydroxyl or alcoholic functional group attached to its carbon atom.
Learn more about the hydroxyl functional group here:
https://brainly.com/question/4682253
#SPJ5
Use your periodic table and calculator as needed for the following question.
How much stock solution is needed to make 250 mL of a 6.0M solution. The molarity of the stock solution is 18M.
Selections may be rounded so choose the best answer.
56 mL
83 mL
2.3 mL
4.7 ml
In movies about space, there is frequently a space battle scene where ships
explode in big fireballs. Why are these scenes unscientific?
O
A. The explosion would not be a fireball, but would point towards the closest gravity
source, a planet or star. They are only fireballs on Earth because we are already on a
gravity source.
B. None of these
C. There is no oxygen in space, so there can be no combustion.
OD. Space is very cold, there would not be enough heat energy for an explosion to occur.
-
The correct answer is C. There is no oxygen in space, so there can be no combustion.
Explanation:
Fire and flames are the result of a chemical process known as combustion. Moreover, for combustion to occur there are two essential elements. The first one is a fuel or a substance that releases energy and ignites, and the second one is an oxidant, which accepts electrons. This mix and reaction causes high temperatures and release of heat in the form of fire and flames.
This implies, that for fireballs or any other form of fire to exist there must be oxygen or any substance that replaces it. This does not occur in space because the levels of oxygen are extremely low, this means, at least oxygen is added fireballs are not possible in this context as there is no oxygen, and therefore no combustion (Option C).
Answer:
C.) There is no oxygen in space, so there can be no combustion.
Explanation:
I got it correct on founders edtell
What was Ernest Rutherford experiment
The rate law for the reaction 2NO2 + O3 → N2O5 + O2 is rate = K[NO2][O3].
Which one of the following mechanisms Is consistent with this rate law?
A. NO2 + NO2 → N2O2 (fast)
N2O4 + O3 → N2O5 + O2 (slow)
B. NO2 + O3 → NO5 (fast)
NO5 + NO5 → N2O5 + (5/2)O2 (slow)
C. NO2 + O3 → NO3 + O2 (slow)
NO3 + NO2 → N2O5 (fast)
D. NO2 + NO2 → N2O2 + O2 (slow)
N2O2 + O3 → N2O5 (fast)
Answer:
C. NO2 + O3 → NO3 + O2 (slow)
NO3 + NO2 → N2O5 (fast)
Explanation:
A reaction mechanism represents an amount of elementary steps that explain how a reaction proceeds. The mechanism must explain the experimental rate law. Also, the slow step is the rate determining step.
This rate law is obtained from the multiplication of the reactants in the slow step, thus:
A. NO2 + NO2 → N2O2 (fast)
N2O4 + O3 → N2O5 + O2 (slow)
Rate law:
rate = k [N2O4] [O3]
This mechanism is not consistent with rate law.
B. NO2 + O3 → NO5 (fast)
NO5 + NO5 → N2O5 + (5/2)O2 (slow)
Rate law:
rate = k [NO5]²
This mechanism is not consistent with rate law.
C. NO2 + O3 → NO3 + O2 (slow)
NO3 + NO2 → N2O5 (fast)
Rate law:
rate = k [NO2] [O3]
This mechanism is consistent with rate law.D. NO2 + NO2 → N2O2 + O2 (slow)
N2O2 + O3 → N2O5 (fast)
Rate law:
rate = k [NO2]²
This mechanism is not consistent with rate law.
Thus, right solution is:
C. NO2 + O3 → NO3 + O2 (slow)
NO3 + NO2 → N2O5 (fast)
bleaching powder reaction, mechanism, use
Answer:
Bleaching Powder's chemical formula is CaOCl2 and is called Calcium Oxychloride. It is prepared on dry slaked lime by chlorine gas. 2. ... It gives calcium chloride, chlorine and water when bleaching powder reacts with hydrochloric acid.
Explanation:
Consider the following reaction: Br2(g) + 3 F2(g) LaTeX: \rightarrow→ 2 BrF3(g) LaTeX: \Delta H_{rxn}Δ H r x n= ‒836 kJ/mol Bond Bond Energy (kJ/mol) Br–Br 193 F–F 155 Using the above bond dissociation energies, calculate the energy, in kJ/mol, of a Br–F bond.
Answer: The energy of a Br–F bond is 110 kJ/mol
Explanation:
The balanced chemical reaction is,
[tex]Br_2(g)+3F_2(g)\rightarrow 2BrF_3(g)[/tex]
The expression for enthalpy change is,
[tex]\Delta H=\sum [n\times B.E(reactant)]-\sum [n\times B.E(product)][/tex]
[tex]\Delta H=[(n_{Br_2}\times B.E_{Br_2})+(n_{F_2}\times B.E_{F_2}) ]-[(n_{BrF_3}\times B.E_{BrF_3})][/tex]
[tex]\Delta H=[(n_{Br_2}\times B.E_{Br-Br})+(n_{F_2}\times B.E_{F_F}) ]-[(n_{BrF_3}\times 3\times B.E_{Br-F})][/tex]
where,
n = number of moles
Now put all the given values in this expression, we get
[tex]\Delta H=[(1\times 193)+(3\times 155)]-[(2\times 3\times B.E_{Br-F})][/tex]
[tex]B.E_{Br-F}=110kJ/mol[/tex]
Thus the energy, in kJ/mol, of a Br–F bond is 110
A 45.0 mL sample of 0.020 M acetic acid (HC2H3O2) is titrated with 0.020 M NaOH.? Determine the pH of the solution after adding 35.0 mL of any NaOH. (Ka of acetic acid is 1.8 x 10-5) HC2H3O2 (aq) + NaOH (aq) D NaC2H3O2(aq) + H2O (l) (Hint: Calculate new concentration and ICE table)
Answer:
Explanation:
CH₃COOH + NaOH = CH₃COONa + H₂O .
.02M
CH₃COOH = CH₃COO⁻ + H⁺
C xC xC
Ka = xC . xC / C = x² C
1.8 x 10⁻⁵ = x² . .02
x² = 9 x 10⁻⁴
x = 3 x 10⁻²
= .03
concentration of H⁺ = xC = .03 . .02
= 6 x 10⁻⁴ M , volume = 45 x 10⁻³ L
moles of H⁺ = 6 X 10⁻⁴ x 45 x 10⁻³
= 270 x 10⁻⁷ moles
= 2.7 x 10⁻⁵ moles
concentration of NaOH = .0200 M , volume = 35 x 10⁻³ L
moles of Na OH = 2 X 10⁻² x 35 x 10⁻³
= 70 x 10⁻⁵ moles
=
NaOH is a strong base so it will dissociate fully .
there will be neutralisation reaction between the two .
Net NaOH remaining = (70 - 2.7 ) x 10⁻⁵ moles
= 67.3 x 10⁻⁵ moles of NaOH
Total volume = 45 + 35 = 80 x 10⁻³
concentration of NaOH after neutralisation.= 67.3 x 10⁻⁵ / 80 x 10⁻³ moles / L
= 8.4125 x 10⁻³ moles / L
OH⁻ = 8.4125 x 10⁻³
H⁺ = 10⁻¹⁴ / 8.4125 x 10⁻³
= 1.1887 x 10⁻¹²
pH = - log ( 1.1887 x 10⁻¹² )
= 12 - log 1.1887
= 12 - .075
= 11.925 .
Which Group is in the second column of the periodic table?
A. Noble gases
B. Halogens
C. Alkali metals
D. Alkaline earth metals
Answer:
Hey there!
That would be the alkaline earth metals.
Hope this helps :)
Answer: alkaline earth metals
Explanation:
The Lucas test has _______ results based on the type of alcohol present because the reaction involves a _________, which is ________ stable for tertiary alcohols compared to primary alcohols. Therefore, tertiary alcohols react ________ primary alcohols.
Answer:
1) positive
2) carbocation
3) most stable
4) faster
Explanation:
A common test for the presence of alcohols can be achieved using the Lucas reagent. Lucas reagent is a mixture of concentrated hydrochloric acid and zinc chloride.
The reaction of Lucas reagent reacts with alcohols leading to the formation of an alkyl chloride. Since the reaction proceeds via a carbocation mechanism, tertiary alcohols give an immediate reaction. Once a tertiary alcohol is mixed with Lucas reagent, the solution turns cloudy almost immediately indicating an instant positive reaction.
Secondary alcohols may turn cloudy within five minutes of mixing the solutions. Primary alcohols do not significantly react with Lucas reagent obviously because they do not form stable carbocations.
Therefore we can use the Lucas reagent to distinguish between primary, secondary and tertiary alcohols.
Medical implants and high-quality jewelry items for body piercings are frequently made of a material known as G23Ti or surgical-grade titanium. The percent composition of the material is 64.39% titanium, 24.19% aluminum, and 11.42% vanadium. What is the empirical formula for surgical-grade titanium
Answer:
The Empirical Formular is given as; Ti₆Al₄V
Explanation:
The percent composition of the material is 64.39% titanium, 24.19% aluminum, and 11.42% vanadium.
Elements Titanium Aluminium Vanadium
Percentage 64.39 24.19 11.42
Divide all through by their molar mass
64.39 / 47.87 24.19 / 27 11.42 / 50.94
= 1.345 = 0.896 = 0.224
Divide all though by the smallest number (0.224)
1.345 / 0.224 0.896 / 0.224 0.224 / 0.224
= 6 = 4 = 1
The Empirical Formular is given as; Ti₆Al₄V
Using the stepwise procedure for obtaining the empirical formula of a compound, the empirical formula is [tex] T_{6}Al_{4}V[/tex]
Titanium :
Percentage composition = 64.39%Molar mass = 47.87Divide by Molar mass : = 64.39/47.87 = 1.345
Aluminum :
Percentage composition = 24.19%Molar mass = 27Divide by Molar mass : = 24.19/27 = 0.896
Vanadium :
Percentage composition = 11.42%Molar mass = 50.94%Divide by Molar mass : = 11.42/50.94 = 0.224
Divide by the smallest :
Titanium = 1.345 / 0.224 = 6.00
Aluminum = 0.896 / 0.224 = 4
Vanadium = 0.224 / 0.224 = 1
Hence, the empirical formula is [tex] T_{6}Al_{4}V[/tex]
Learn more : https://brainly.com/question/17091379
Name the physical properties used in seperating kerosene and petrol
simple distillation can be used when the temperature difference between the boiling points of two miscible liquid is at least 25°c. the temperature difference between the boiling points of kerosene and petrol is 25c. hence, this mixture can separated using simple distillation.
answer:simple distillation
Which phase change is an example of an exothermic process?
A.
solid to liquid
B.
solid to gas
C.
liquid to solid
D.
liquid to gas
E.
solid to plasma
Reset
Answer:
C
Explanation:
Turning liquid to a solid is like freezing water to ice and requires the water to LOSE (release) heat causing an exothermic reaction.
Write a balanced equation for the double-replacement precipitation reaction described, using the smallest possible integer coefficients. A precipitate forms when aqueous solutions of ammonium bromide and silver(I) nitrate are combined. (Use the lowest possible coefficients. Omit states of matter.)
Answer:
NH4Br + AgNO3 —> AgBr + NH4NO3
Explanation:
When ammonium bromide and silver(I) nitrate react, the following are obtained as shown below:
NH4Br(aq) + AgNO3(aq) —>
In solution, NH4Br(aq) and AgNO3(aq) will dissociate as follow:
NH4Br(aq) —> NH4+(aq) + Br-(aq)
AgNO3(aq) —> Ag+(aq) + NO3-(aq)
The double displacement reaction will occur as follow:
NH4+(aq) + Br-(aq) + Ag+(aq) + NO3-(aq) —> Ag+(aq) + Br-(aq) + NH4+(aq) + NO3-(aq)
NH4Br(aq) + AgNO3(aq) —> AgBr(s) + NH4NO3(aq)
Eugenol is a molecule that contains the phenolic functional group. Which option properly identifies the phenol in eugenol
Answer:
Explanation:
Hello,
Among the options given on the attached document, since phenolic functional group is characterized by a benzene ring bonded with a hydroxyl group (C₆H₅OH) we can see that the first option correctly points out such description. Thus, answer is on the second attached picture. Other options are related with other sections found in eugenol that are not phenolic.
Best regards.
The first option identified the phenol in eugenol.
Phenolic functional groupAccording to the attached image, since the phenolic functional group should be characterized by a benzene ring bonded along with a hydroxyl group (C₆H₅OH) so here we can see that the first option correctly points out such description. However, other options are related to other sections found in eugenol that are not phenolic.
learn more about molecule here: https://brainly.com/question/13127022
Ag+(aq)+2NH3(aq)⇌Ag(NH3)2+(aq) : A g + ( a q ) + 2 N H 3 ( a q ) ⇌ A g ( N H 3 ) 2 + ( a q ) : blank is the Lewis acid and blank is the Lewis base. is the Lewis acid and A g + ( a q ) + 2 N H 3 ( a q ) ⇌ A g ( N H 3 ) 2 + ( a q ) : blank is the Lewis acid and blank is the Lewis base. is the Lewis base.
Answer:
Silver ion - Lewis acid, Ammonia - Lewis base
Explanation:
The reaction is given as;
Ag+(aq) + 2NH3(aq) ⇌ [Ag(NH3)]2+(aq)
A lewis acid is an electron pair acceptor. While a lewis base is any substance that that can donate a pair of nonbonding electrons.
This reaction however is a complexation reaction, where ammonia is reacting with the silver ion.
Silver ion accepts electrons in this reaction, hence it is the lewis acid. The ammonia on the other hand donates the electrons used in bonding so it is the lewis base.
Modern atomic theory states that atoms are neutral. How is this neutrality achieved in atoms? (2 points)
15. Ammonium nitrate, NH4NO3, and aluminum powder react explosively producing nitrogen gas, water vapor and aluminum oxide. Write the balanced equation and calculate the enthalpy change for this reaction.
Answer:
[tex]2Al_(_S_) ~+~3NH_4NO_3_(_a_q_) ->3N_2_(_g_) ~+~6H_2O_(_g_) ~+~Al_2O_3_(_S_)[/tex]
[tex]Entalpy=-2861.9~KJ[/tex]
Explanation:
In this case, we have to start with the reagents:
[tex]Al~+~NH_4NO_3[/tex]
The compounds given by the problem are:
-) Nitrogen gas = [tex]N_2[/tex]
-) Water vapor = [tex]H_2O[/tex]
-) Aluminum oxide = [tex]Al_2O_3[/tex]
Now, we can put the products in the reaction:
[tex]Al_(_S_) ~+~NH_4NO_3_(_aq_) ->N_2_(_g_) ~+~H_2O_(_g_) ~+~Al_2O_3_(_S_) [/tex]
When we balance the reaction we will obtain:
[tex]2Al_(_S_) ~+~3NH_4NO_3_(_a_q_) ->3N_2_(_g_) ~+~6H_2O_(_g_) ~+~Al_2O_3_(_S_)[/tex]
Now, for the enthalpy change, we have to find the standard enthalpy values:
[tex]Al_(_S_)=0~KJ/mol[/tex]
[tex]NH_4NO_3_(_a_q_)=-132.0~KJ/mol[/tex]
[tex]N_2_(_g_)=0~KJ/mol[/tex]
[tex]H_2O_(_g_)=~-~241.8~KJ/mol[/tex]
[tex]Al_2O_3_(_S_)=~-~1675.7~KJ/mol[/tex]
With this in mind, if we multiply the number of moles (in the balanced reaction) by the standard enthalpy value, we can calculate the energy of the reagents:
[tex](0*2)~+~(-132*3)=~-396~KJ[/tex]
And the products:
[tex](0*3)~+~(-241.8*6)~+~(-1675.7*1)=-3125.9~KJ[/tex]
Finally, for the total enthalpy we have to subtract products by reagents :
[tex](-3125.9~KJ)-(-396~KJ)=-2729.9~KJ[/tex]
I hope it helps!
At what pressure would 11.1 moles of a gas occupy 44.8 L at 300 K?
Answer:
[tex]P=6.10atm[/tex]
Explanation:
Hello,
In this case, we can study the ideal gas equation that relates temperature, volume, pressure and moles as shown below:
[tex]PV=nRT[/tex]
Thus, since we are asked to compute the pressure y simply solve for it as follows:
[tex]P=\frac{nRT}{V}=\frac{11.1mol*0.082\frac{atm*L}{mol*K}*300K}{44.8L}\\ \\P=6.10atm[/tex]
Best regards.
Question 5 options: The cell potential for an electrochemical cell with a Zn, Zn2 half-cell and an Al, Al3 half-cell is _____ V. Enter your answer to the hundredths place and do not leave out a leading zero, if it is needed.
Answer:
The voltage is [tex]E_{cell} = 0.944 \ V[/tex]
Explanation:
Generally the half reaction for Zn, Zn2 half-cell is mathematically represented as
[tex]Zn_{(s)}[/tex] ⇔ [tex]Zn^{2+}_{ (aq)} + 2e^-[/tex] (reference study academy)
and the electric potential for this is a constant value
[tex]E_{zn } = -0.7618 \ V[/tex]
Generally the half reaction for Al, Al3 half-cell is mathematically represented as
[tex]Al^{3+} _{(aq)} + 3e^-[/tex] ⇔ [tex]Al_{(s)}[/tex]
and the electric potential for this is constant value
[tex]E_{Al } = -1.662 \ V[/tex]
Therefore the cell potential for an electrochemical cell is mathematically represented as
[tex]E_{cell} = E_{zn } - E_{Al }[/tex]
substituting values
[tex]E_{cell} = -0.718 - (-1.662)[/tex]
[tex]E_{cell} = 0.944 \ V[/tex]
Q1) How much heat is released when 6.38 grams of Ag(s) (m.m = 107.9 g/mol) reacts by the equation shown below at
standard state conditions?
4A9 (s) + 2H,Sq) + O2(g)
2Ag $(s) + 2H200)
Substance
AHof (kJ/mol)
-20.6
H259)
Ag2S (5)
H200
-32.6
-285.8
a)
8.80 KI
b) 69.9 kJ
C) 22.1 kJ
d) 90.8 kJ
e) 40.5 kJ
Answer:
The correct answer is -8.80 kJ.
Explanation:
The ΔH° can be determined by using the formula,
ΔH°rxn = ΔH°f (products) - ΔH°f(reactants)
Based on the given information, the ΔH°f of H2S(g) is -20.6, for Ag2S (s) is -32.6 and for H2O (l) is -285.8 kJ/mole.
Now putting the values we get,
= [2 molΔH°f (Ag2S) + 2 molΔH°f (H2O)] - [4 molΔH°f(Ag) + 2 molΔH°f(H2S) + 1 molΔH°f(O2)]
=[2 mol (-32.6 kJ/mol) + 2 mol(-285.8 kJ/mol)] - [4 mol(0.00 kJ/mol) + 2 mol (-20.6 kJ/mol) + 1 mol (0.00 kJ/mol)
= [(-65.2 kJ) + (-571.6 kJ)] - [(-41.2 kJ)]
= -595.6 kJ
Thus, the enthalpy change of -595.6 kJ takes place when 4 mol of Ag reacts by the equation mentioned.
The mass of Ag given is 6.38 grams, the molecular mass of Ag is 107.9 g/mol. The formula for calculating moles is,
Moles = mass/molar mass
= 6.38 g / 107.9 g/mol
= 0.0591 mol
Now the change in enthalpy when 0.0591 mol of Ag reacts by the given reaction is (-595.6 kJ/4 mol) × 0.0591 mol = -8.80 kJ
The negative sign indicates that the heat is released in the process. Therefore, the -8.80 kJ of heat is released by 6.38 grams of Ag in the given case.
8.670 mL + 9.87 mL=
Answer:18.4 ML
Explanation:
easy add
Convert the following measurement
Answer:
6.9 Kg/mol•dL
Explanation:
To convert 6.9×10⁴ g/mol•L to kg/mol•dL,
First, we shall convert to kg/mol•L.
This can be achieved by doing the following:
Recall: 1 g = 1×10¯³ Kg
1 g/mol•L = 1×10¯³ Kg/mol•L.
Therefore,
6.9×10⁴ g/mol•L = 6.9×10⁴× 1×10¯³
6.9×10⁴ g/mol•L = 69 Kg/mol•L
Finally, we shall convert 69 Kg/mol•L to Kg/mol•dL.
This is illustrated below:
Recall: 1 L = 10 dL
1 Kg/mol•L = 1×10¯¹ Kg/mol•dL
Therefore,
69 Kg/mol•L = 69 × 1×10¯¹
69 Kg/mol•L = 6.9 Kg/mol•dL
Therefore, 6.9×10⁴ g/mol•L is equivalent to 6.9 Kg/mol•dL.
What is an example of a molecular compound
Answer:
Molecular compounds are inorganic compounds that take the form of discrete (covalent) molecules. Examples include such familiar substances as water (H2O) and carbon dioxide (CO2).
Calculate the maximum volume in mL of 0.18 M HCl that a tablet containing 340 mg Al(OH)3 and 516 mg Mg(OH)2 would be expected to neutralize. Assume complete neutralization.
Answer:
171 mL of HCl
Explanation:
The first thing we want to do is consider the reaction between Al(OH)3 and water - as that is the expected reaction that is taking place,
Al(OH)3 + 3HCl → AlCl3 + 3H2O
Knowing this, let's identify the mass of Al(OH)3. Aluminum = 27 g / mol, Oxygen( 3 ) = 16 [tex]*[/tex] 3 = 48, Hydrogen ( 3 ) = 1 [tex]*[/tex] 3 = 3 - 27 + 48 + 3 = 78 g / mol. This value is approximated however ( 78 g / mol ), as the molar mass of each substance is rounded as well. Another key thing we need to do here is to convert 340 mg → grams, considering that that unit is a necessity with respect to moles, as you might know - 340 mg = 0.340 g.
Now we can calculate how much moles of HCl will be present in solution, provided we have sufficient information for that,
(0.340 g Al(OH)3) / (78.0036 g / mol Al(OH)3) [tex]*[/tex] (3 mol HCl / 1 mol Al(OH)3)
⇒ (.004358773185 g^2 / mol Al(OH)3) [tex]*[/tex] (3 HCl / Al(OH)3 )
⇒ .01307632 mol HCl
We can apply this same concept on the reaction of Mg(OH)2 and water, receiving the number of moles of HCl when that takes place. Then we can add the two ( moles of HCl ) and divide by the value " 0.18 mol / L " given to us.
" Mg(OH)2 + 2HCl → MgCl2 + 2H2O "
Molar mass of Mg(OH)2 = 58.3197 g / mol,
516 mg = 0.516 g
(0.516 g Mg(OH)2) / (58.3197 g / mol Mg(OH)2) [tex]*[/tex] (2 mol HCl / 1 mol Mg(OH)2)
= .017695564 mol HCL
___________
( .01307632 + .017695564 ) / ( 0.18 M HCl )
= 0.170954911 L
= 171 mL of HCl
In each of the three reactions between NaOH and HCl, the sign of q for the water was positive. This means the the sign of q for the reaction was ______ and the reaction was ______.
Answer:
This means the the sign of q for the reaction was _NEGATIVE _____ and the reaction was _EXOTHERMIC_____.
Explanation:
In calorimetry, when heat is absorbed by the solution, the q-value of the solution will have a positive value. This means that the reaction will produce heat for the solution to absorb and thus the q-value for the reaction will be negative. This is an exothermic reaction.
Whereas, when heat is absorbed from the solution, the q-value for the solution will have a negative value. This means that the reaction will absorb heat from the solution and so the reaction is endothermic, and q value for the reaction is positive.
So, from the question, since the q-value of water is positive, it means that heat is absorbed by the solution and the reaction will produce a negative value of q and it's an exothermic reaction because the reaction produces heat for the solution.
For each of the following, classify the substance as a strong acid, strong base, weak acid, or weak base (or perhaps not acidic or basic). Then determine the pH of the solution and calculate the concentrations of all aqueous species present in the solution.a. 2.0 × 10 ^–2 M HBrb. 1.0 × 10^–4 M NaOHc. 0.0015 M Ba(OH)2 d. 0.25 M HCN e. 2.0 × 10 ^–10 M KOH f. 0.050 M NH3 g. 0.100 M NH4Cl h. 0.200 M CaF2 i. 0.0500 M Ba(NO3)2 j. 0.100 M Al(NO3)3
Answer:
a. Strong acid, pH = 1.69
b. Strong base, pH = 10
c. Strong base, pH = 11
d. Weak acid, pH = 4.90
e. Strong base, pH ≅ 7 (pH should be higher than 7, but the base is so diluted)
f. Weak base, pH = 10.96
g. Acidic salt, pH = 5.12
h. Basic salt, pH = 8.38
i. Neutral salt, pH = 7
j. Acidic salt, pH < 7
Explanation:
a. HBr → H⁺ + Br⁻
Hydrobromic acid is a strong acid.
pH = - log [H⁺]
- log 0.02 = 1.69
b. NaOH → Na⁺ + OH⁻
Sodium hydroxide is a strong base.
pH = 14 - pOH
pOH = - log [OH⁻]
pH = 14 - (-log 0.0001) = 10
c. Ba(OH)₂ → Ba²⁺ + 2OH⁻
Barium hydroxide is a strong base
[OH⁻] = 2 . 0.0015 = 0.003M
pH = 14 - (-log 0.003) = 11
d. HCN + H₂O ⇄ H₃O⁺ + CN⁻
This is a weak acid, it reacts in water to make an equilibrium between the given protons and cyanide anion.
To calculate the [H₃O⁺] we must apply, the Ka
Ka = [H₃O⁺] . [CN⁻] / [HCN]
6.2×10⁻¹⁰ = x² / 0.25-x
As Ka is really small, we can not consider the x in the divisor, so we avoid the quadratic formula.
[H₃O⁺] = √(6.2×10⁻¹⁰ . 0.25) = 1.24×10⁻⁵
-log 1.24×10⁻⁵ = 4.90 → pH
e. KOH → K⁺ + OH⁻
2×10⁻¹⁰ M → It is a very diluted concentration, so we must consider the OH⁻ which are given, by water.
In this case, we propose the mass and charges balances equations.
Analytic concentration of base = 2×10⁻¹⁰ M = K⁺
[OH⁻] = K⁺ + H⁺ → Charges balance
The solution's hydroxides are given by water and the strong base.
Remember that Kw = H⁺ . OH⁻, so H⁺ = Kw/OH⁻
[OH⁻] = K⁺ + Kw/OH⁻. Let's solve the quadratic equation.
[OH⁻] = 2×10⁻¹⁰ + 1×10⁻¹⁴ /OH⁻
OH⁻² = 2×10⁻¹⁰. OH⁻ + 1×10⁻¹⁴
2×10⁻¹⁰. OH⁻ + 1×10⁻¹⁴ - OH⁻²
We finally arrived at the answer [OH⁻] = 1.001ₓ10⁻⁷
pH = 14 - (- log1.001ₓ10⁻⁷) = 7
The strong base is soo diluted, that water makes the pH be a neutral value.
Be careful, if you determine the [OH⁻] as - log 2×10⁻¹⁰, because you will obtain as pOH 9.69, so the pH would be 4.31. It is not possible, KOH is a strong base and 4.30 is an acid pH.
f. Ammonia is a weak base.
NH₃ + H₂O ⇄ NH₄⁺ + OH⁻
Kb = OH⁻ . NH₄⁺ / NH₃
1.74×10⁻⁵ = x² / 0.05 - x
We can avoid the x from the divisor, so:
[OH⁻] = √(1.74×10⁻⁵ . 0.05) = 9.32×10⁻⁴
pH = 14 - (-log 9.32×10⁻⁴ ) = 10.96
g. NH₄Cl, an acid salt. We dissociate the compound:
NH₄Cl → NH₄⁺ + Cl⁻. We analyse the ions:
Cl⁻ does not make hydrolisis to water. In the opposide, the ammonium can react given OH⁻ to medium, that's why the salt is acid, and pH sould be lower than 7
NH₄⁺ + H₂O ⇄ NH₃ + H₃O⁺ Ka
Ka = NH₃ . H₃O⁺ / NH₄⁺
5.70×10⁻¹⁰ = x² / 0.1 -x
[H₃O⁺] = √ (5.70×10⁻¹⁰ . 0.1) = 7.55×10⁻⁶
pH = - log 7.55×10⁻⁶ = 5.12
As Ka is so small, we avoid the x from the divisor.
h. CaF₂ → Ca²⁺ + 2F⁻
This is a basic salt.
The Ca²⁺ does not react to water. F⁻ can make hydrolisis because, the anion is the strong conjugate base, of a weak acid.
F⁻ + H₂O ⇄ HF + OH⁻ Kb
Kb = x² / 2 . 0.2 - x
Remember that, in the original salt we have an stoichiometry of 1:2, so 1 mol of calcium flouride may have 2 moles of flourides.
As Kb is small, we avoid the x, so:
[OH⁻] = √(1.47×10⁻¹¹ . 2 . 0.2) = 2.42×10⁻⁵
14 - (-log 2.42×10⁻⁵) = pH → 8.38
i . Neutral salt
BaNO₃₂ → Ba²⁺ + 2NO₃⁻
Ba²⁺ comes from a strong base, so it is the conjugate weak acid and it does not react to water. The same situation to the nitrate anion. (The conjugate weak base, from a strong acid, HNO₃)
pH = 7
j. Al(NO₃)₃, this is an acid salt.
Al(NO₃)₃ → Al³⁺ + 3NO₃⁻
The nitrate anion is the conjugate weak base, from a strong acid, HNO₃ so it does not make hydrolisis. The Al³⁺ comes from the Al(OH)₃ which is an amphoterous compound (it can react as an acid or a base) but the cation has an acidic power.
Al·(H₂O)₆³⁺ + H₂O ⇄ Al·(H₂O)₅(OH)²⁺ + H₃O⁺
How many moles of HNO3 will be produced 3 NO2+H2O=2HNO3+ NO
Answer:
2 moles of HNO3
Explanation:
The equation seems to be balanced correctly. The problem is we done know what you started with. We will assume it is 3 moles of NO2.
If that is the case then 2 moles of HNO3 will be produced.
A compound containing only C, H, and O, was extracted from the bark of the sassafras tree. The combustion of 32.3 mg produced 87.7 mg of CO2 and 18.0 mg of H2O. The molar mass of the compound was 162 g/mol. Determine its empirical and molecular formulas.
Answer:
Empirical formula: C₅H₅O
Molecular formula: C₁₀H₁₀O₂
Explanation:
When a compound containing C, H and O elements is combusted, the general reaction is:
CₐHₓOₙ + O₂ → a CO₂ + X/2 H₂O
Thus, you can find moles of carbon and hydrogen knowing moles of CO₂ and H₂O that are produced.
Moles CO₂ = Moles C = 0.0877g × (1mol / 44g) =
2.0x10⁻³ moles of CO₂ = moles C
Moles H₂O = 1/2 Moles H = 0.018g × (1mol / 18g) =
1x10⁻³ moles of H₂O; 2.0x10⁻³ moles H
The mass of the moles of C and H are:
2x10⁻³ moles C ₓ (12g / mol) = 0.024g C
2x10⁻³ moles H ₓ (1g / mol) = 0.002g H
Thus, mass of Oxygen is 32.3mg - 24mg C - 2mg O = 6.3mg O
Moles are:
0.0063g O ₓ (1mol / 16g) = 4x10⁻⁴ moles O
Empirical formula is the simplest ratio of atoms in a compound. Dividing each amount of moles for each atom in the 4x10⁻⁴ moles of oxygen (The lower moles), you will obtain:
C: 2.0x10⁻³ / 4x10⁻⁴ = 5
H: 2.0x10⁻³ / 4x10⁻⁴ = 5
O: 4x10⁻⁴ / 4x10⁻⁴ = 1
Thus, empirical formula is:
C₅H₅OThe molar mass of the empirical formula is:
12×5 + 1×5 + 16×1 = 81g/mol
As molar mass of the compound is 162g/mol, molecular formula is twice empirical formula:
C₁₀H₁₀O₂