What would have happened to your % Transmittance reading and to your calculations of Keq if the spectrophotometer had been set at 520 nm rather than 447nm

Answers

Answer 1

Answer:

On the off chance that the wavelength(λ) maximum worth has been changed to 520 nm from 470 nm on the spectrophotometer, less light would be absorbed and in this way %T would be higher than the one found at 470 nm. The wavelength utilized at 520 nm isn't adequate for the excitation and consequently lesser light is absorbed by the arrangement.

Explanation:

A spectrophotometer is an analytical equipment used to quantitatively gauge the transmission(passage) or impression of visible light, UV light or infrared light through a medium.

Transmittance (τ) is the ratio of the brilliant or luminous flux at a given wavelength that is transmitted to that of the incident radiation.

where, Keq is the equilibrium constant.

Answer 2

On the off chance that the wavelength(λ) has been changed to 520 nm from 470 nm on the spectrophotometer, less light would be absorbed and in this way %T would be higher than the one found at 470 nm.

What happens to Transmittance?

A spectrophotometer is an analytical equipment used to quantitatively gauge the transmission(passage) or impression of visible light, UV light or infrared light through a medium. Transmittance (τ) is the ratio of the brilliant or luminous flux at a given wavelength that is transmitted to that of the incident radiation. The wavelength utilized at 520 nm isn't adequate for the excitation and consequently lesser light is absorbed by the arrangement. As the concentration goes up, more radiation is absorbed and the absorbance goes up. Therefore, the absorbance is directly proportional to the concentration.

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Related Questions

The mathematics of combining quantum theory with wave motion of atomic particles is known as _____.


Answers

Combining quantum theory with wave motion of atomic particles is: Wave Mechanics

Write the empirical formula

Answers

Answer:

[tex]1) NH_{4}IO_{3}\\2) Pb(IO_{3})_{4} \\3) NH_{4}(C_{2}H_{3}O_{2})\\4) Pb(C_{2}H_{3}O_{2})_{4}[/tex]

Explanation:

[tex]1) NH_{4}^{+}IO_{3}^{-} ---> NH_{4}IO_{3}\\2) Pb^{4+}(IO_{3}^{-})_{4} --->Pb(IO_{3})_{4} \\3) NH_{4}^{+}(C_{2}H_{3}O_{2})^{-} ---> NH_{4}(C_{2}H_{3}O_{2})\\4) Pb^{4+}(C_{2}H_{3}O_{2})^{-} _{4} --->Pb(C_{2}H_{3}O_{2})_{4}[/tex]

A silver cube with an edge length of 2.42 cm and a gold cube with an edge length of 2.75 cm are both heated to 85.4 ∘C and placed in 112.0 mL of water at 20.5 ∘C . What is the final temperature of the water when thermal equilibrium is reached?

Answers

Answer:

Explanation:

Volume of silver cube = 2.42³ = 14.17 cm³

mass of silver cube = volume x density

= 14.17 x 10.49 = 148.64 gm

Volume of gold cube = 2.75³ = 20.8  cm³

mass of gold cube =  20.8 x 19.3 = 401.44 gm

specific heat of silver and gold are .24 and .129 J /g°C

mass of 112 mL water = 112 g

Heat absorbed = heat lost = mass x specific heat x temperature fall or rise

Heat lost by metals

= 148.64 x .24 x ( 85.4 -T) + 401.44 x .129 x ( 85.4 - T )

= (35.67 + 51.78 ) x ( 85.4 - T )

87.45 x ( 85.4 - T )

= 7468.23 - 87.45 T

Heat gained by water

= 112 x 1 x ( T - 20.5 )

= 112 T - 2296

Heat lost = heat gained

7468.23 - 87.45 T = 112 T - 2296

199.45 T = 9764.23

T = 48.95° C

Draw the structure 2 butylbutane

Answers

Answer:

please look at the picture below.

Explanation:

Cual es la diferencia entre agua pesada y agua ligera a) el agua pesada contiene mas minerales que el agua ligera b) el agua ligera es liquida mientras el agua pesada es solida c) el agua ligera es agua purificada y el agua pesada es agua contaminada d) el agua pesada contiene mas elementos estearato de sodio

Answers

Answer:

d) El agua pesada contiene mas elementos

Explanation:

La diferencia fundamental entre el agua pesada y el agua ligera es que la primera tiene una proporción mayor de deuterio que la segunda. El deuterio es un ión del hidrógeno que tiene un peso atómico mayor que el hidrógeno común y corriente. Por ende, la opción D ofrece la mejor aproximación.

Answer:

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Explanation:ki

Description (with words) of water just above melting temperature. What intermolecular forces do you expect to find in water in liquid state

Answers

Answer:

intermolecular dipole-dipole hydrogen bonds

Explanation:

Water is a polar molecule. Recall that the central atom in water is oxygen. The molecule is bent, hence it has an overall dipole moment directed towards the oxygen atom. Since it has a permanent dipole moment, we expect that it will show dipole-dipole interactions in the liquid state.

Similarly, water contains hydrogen and oxygen. Recall that hydrogen bonds are formed when hydrogen is covalently bonded to highly electronegative elements. Hence, water in the liquid state exhibits strong hydrogen bonding. The unique type of dipole-dipole interaction in liquid water is actually hydrogen bonding, hence the answer.

(-)-Cholesterol has a specific rotation of -32o. A mixture of ( )- and (-)-cholesterol was analyzed by polarimetry, and the observed rotation was 14o. What is the percent composition of the ( ) isomer in this mixture

Answers

Answer:

(+)-cholesterol = 71.88%

(-)-cholesterol = 28.12%

Explanation:

Asuming 1 gram of sample is dissolved in 1mL of water and the sample cell was 1dm long.

Enantiomeric excess is defined as the amount of pure enantiomer in a sample. The formula is:

ee = [α]mixture / [α]pure enantiomer.

Replacing:

ee = 14° / 32°×100 = 43.75%

As the sample is 14°, There is an excess of (+)-cholesterol and 56.25% is a 1:1 mixture of enantiomers.

That means percent composition of enantiomers is:

(+)-cholesterol = 43.75% + 56.25%/2 = 71.88%(-)-cholesterol =  56.25%/2 = 28.12%

what is the molarity of a solution that contains 49.8 grams of nai and is dissolved in enough water to make 1.50 liters

Answers

Answer: The molarity of solution is 0.221 M

Explanation:

Molarity of a solution is defined as the number of moles of solute dissolved per liter of the solution.

[tex]Molarity=\frac{n}{V_s}[/tex]

where,

n = moles of solute

[tex]V_s[/tex] = volume of solution in L

moles of [tex]NaI[/tex] = [tex]\frac{\text {given mass}}{\text {Molar mass}}=\frac{49.8g}{149.89g/mol}=0.332mol[/tex]

Now put all the given values in the formula of molality, we get

[tex]Molarity=\frac{0.332mol}{1.50L}[/tex]

[tex]Molarity=0.221mol/L[/tex]

Therefore, the molarity of solution is 0.221 M

which factor is most responsible for the fact that water is a liquid rather than a gas at room temperature

Answers

The answer is Hydrogyn bonding. It keeps the water molocules bonded together and in a liquid state, without it it'd be in a gashious state.

Answer:Hydrogen bonds keep them together in room temperature, hope this helps!

Explanation:

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Which correctly lists three characteristics of minerals?
solid, crystal structure, definite chemical composition
organic, crystal structure, definite chemical composition
human-made, solid, organic
crystal structure, definite chemical composition, human-made

Answers

Answer:a

Explanation:

The three characteristics of minerals are that they are solid, have definite crystal structure and definite chemical composition.

What are minerals?

Minerals are defined as a chemical compound  which has a well -defined composition and possesses a specific crystal structure.It occurs naturally in the pure form.

If a compound occurs naturally in different crystal structure then each structure is considered as a different mineral.The chemical composition of a mineral varies  depending on the presence of small impurities which are present in small quantities.

Some minerals  can have variable proportions of two or more chemical elements  which occupy equivalent position in the crystal structure.It may also have variable composition which is split into separate species.

Physical properties of minerals include color,streak, luster,specific gravity  and cleavage.

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How many oxygen molecules are needed to make 10 carbon dioxide molecules according to the following balanced chemical equation? 2 CO + O2 → 2 CO2

Answers

answer.

five oxygen molecules

step by step explanation.

according to the equation,one molecule of oxygen is enough to react with two carbon molecules thus 10 carbon molecules need 5oxygen molecules

Lewis structure of methyl metcaptain

Answers

Answer:

The lewis structure of the compounds can be drawn by making the skeleton of the molecule first. Then the different atoms are arranged and the electrons are arranged in their bonding pattern. The lone pair of the atoms, which are not involved in the bonding are represented by the dots.

So the lewis structures of both the compound methyl mercaptan has been in the attached image:

Spelling of methyl metcaptain is wrong, the correct spelling is methyl mercaptan.

Answer:

Methyl mercaptan is also known as Methanethiol with the chemical formula  CH3SH and it is an organosulfur compound.

For lewis structure of methyl mercaptan (CH3SH), there are total 14 valence electrons. Four hydrogen atoms has one valence electron each, carbon has four valence electrons and sulfur has six valence electrons. Carbon form one bond with three hydrogen atoms by sharing one electron with each, carbon form one single bond with sulfur atom by sharing one electron with it and sulfur form one single bond with hydrogen. Sulfur left with four unpair electrons.

What is the specific heat of a 85.01 g piece of an unknown metal that exhibits a 45.2°C temperature change upon absorbing 1870 J of heat?

Answers

Answer:

[tex]0.48~\frac{J}{g~^{\circ}C}[/tex]

Explanation:

In this question, we have to remember the relationship between Q (heat) and the specific heat (Cp) the change in temperature (ΔT), and the mass (m).

[tex]Q=m*Cp*ΔT[/tex]

The next step is to identify what values we have:

[tex]Q~=~1870~J[/tex]

[tex]m~=~85.01~g[/tex]

[tex]ΔT~=~45.2~^{\circ}C[/tex]

[tex]Cp~=~X[/tex]

Now, we can plug the values and solve for "Cp":

[tex]1870~J=~85.01~g~*Cp*45.2~^{\circ}C[/tex]

[tex]Cp=\frac{1870~J}{85.01~g~*45.2~^{\circ}C}[/tex]

[tex]Cp=0.48~\frac{J}{g~^{\circ}C}[/tex]

The unknow metal it has a specific value of [tex]0.48~\frac{J}{g~^{\circ}C}[/tex]

I hope it helps!

when dissolved in water, an acid or a base breaks down into a. a proton and an electron b. two negative ions c. a positive and a negative ion d. a positive ion and a proton

Answers

Answer:

C. A positive and a negative ion

Explanation:

Acids and bases are made up of charged particles known as ions. The ions present in acids are oppositely charged and are held together by strong electrostatic forces. When acids or bases are dissolved in water, the electrostatic forces holding their individual molecules together are weakened and these ions are free to move apart in a process known as dissociation. Dissociation occurs because of the attraction between the positive and negative ions in the acid and bases and the negative and positive polarity of water.

For example, when an acid like hydrochloric acid is dissolved in water it dissociates into positive and negative ions as follows:

HCl(aq) -----> H+ + Cl-

When a base like sodium hydroxide is dissolved in water, it dissociates into positive and negative ions as follows:

NaOH(aq) ----> Na+ + OH-

Answer:

yeah C is correct

Explanation:

What is the mass of 3.45 moles
NO2?
(N = 14.01 g/mol, O = 16.00 g/mol)

Answers

Answer:

158.7 g

Its the right answer

which process is used to produce gases from solutions of salts dissolved in water or another liquid?

A.Electrolysis
B.Metallic bonding
C.Ionic bonding
D. Polar covalent bonding

Answers

Answer:

A.Electrolysis

Explanation:

A.Electrolysis

For example,  electrolysis of solution of NaCl in water gives H2 and O2.

Pb(OH)Cl, one of the lead compounds used in ancient Egyptian cosmetics, was prepared from PbO according to the following recipe: PbO(s) NaCl(aq) H2O(l) --> Pb(OH)Cl(s) NaOH(aq) How many grams of PbO and how many grams of NaCl would be required to produce 10.0 g of Pb(OH)Cl

Answers

Answer:

8.59 g

2.25 g

Explanation:

According to the given situation the calculation of grams of PbO and grams of NaCL is shown below:-

Moles of Pb(OH)CL is

[tex]= \frac{Mass}{Molar\ mass}[/tex]

[tex]= \frac{10.0 g}{259.65g / mol}[/tex]

= 0.0385 mol

Mass of PbO needed is

[tex]= 0.385mol Pb(OH) Cl\times \frac{1 mol PbO}{1molpb (OH) cl} \times \frac{223.2g PbO}{1mol PbO}[/tex]

After solving the above equation we will get

= 8.59 g

Mass of NaCL needed is

[tex]= \frac{1mol\ NaCl}{1molPb\ (OH)Cl} \times \frac{58.45NaCl}{1mol NaCl}[/tex]

After solving the above equation we will get

= 2.25 g

Therefore we have applied the above formula.

What is the half-life for the first order decay of 14C according to the reaction, 146C — 147N +e- ?
The rate constant for the decay is 1.21 x10-4 year-1

Answers

Answer:

5727 years or 5730 (rounded to match 3 sig figs) whichever one your teacher prefers

Explanation:

First Order decay has a half life formula of Half Life = Ln (2) / k = 0.693/K

Half-life = 0.693/k = 0.693/1.21 x10-4 =  5727 years or 5730 (rounded to match 3 sig figs)

This should be correct because if you google the half-life of 14 C it is ~ 5700 years

Hypochlorous acid is formed in situ by reaction of aq. sodium hypochlorite solution with acetic acid. Draw balanced chemical equations to show the formation of hypochlorous acid and protonated hypochlorous acid.

Answers

Answer:

NaClO + CH₃COOH ----> HClO + CH3CO- + Na

Explanation:

This reaction occurs between the combination of a salt and an acid, that is, an oxide-reduction reaction

g Which statement is incorrect regarding oxidation? Oxidation is a "gain" of electrons. Oxidation is the combination with O atoms. Oxidation is an increase in oxidation state. Oxidation is always accompanied by reduction. none of these

Answers

Answer:

The incorrect statement from the options is OXIDATION IS A "GAIN" OF ELECTRONS

Explanation:

Oxidation in a redox reaction is the loss of electrons. It is also the increase in the oxidation states of an atom or ion or atoms in a molecule. A redox reaction is a type of chemical reaction in which there is a transfer of electrons from an atom or ion to another resulting in a change in oxidation states of the substances involved. The reducing agent in the reaction is undergoes oxidation by losing electrons while the oxidating agent is reduced that is it gains electrons at the end of the reaction. The atom or ion from which electron is lost is said to be oxidized while the other atom or ion involved in the reaction is reduced.

Oxidation is also the combination with O atoms and it is always accompanied by reduction because oxidation forms a half of the whole redox reaction. A substance cannot be oxidized except it has reduced another substance by losing electrons to it.

A 25.0-mL sample of 0.150 M hydrazoic acid, HN3, is titrated with a 0.150 M NaOH solution. What is the pH after 13.3 mL of base is added? The Ka of hydrazoic acid = 1.9 x 10-5.

Answers

Answer:

pH ≅ 4.80

Explanation:

Given that:

the volume of HN₃ = 25 mL = 0.025 L

Molarity of HN₃ = 0.150 M

number of moles of HN₃ = 0.025 × 0.150

number of moles of HN₃ =  0.00375  mol

Molarity of NaOH = 0.150 M

the volume of NaOH = 13.3 mL = 0.0133

number of moles of NaOH = 0.0133× 0.150

number of moles of NaOH = 0.001995 mol

The chemical equation for the reaction of this process can be written as:

[tex]HN_3 + OH- ---> N^-_{3} + H_2O[/tex]

1 mole of hydrazoic acid react with 1 mole of hydroxide to give nitride ion and water

thus the new number of moles of HN₃ = 0.00375 - 0.001995 = 0.001755 mol

Total volume used in the reaction =  0.025 +  0.0133 = 0.0383  L

Concentration of [tex]HN_3[/tex] = [tex]\dfrac{0.001755}{0.0383}[/tex] = 0.0458 M

Concentration of [tex]N^{-}_3[/tex] = [tex]\dfrac{ 0.001995 }{0.0383}[/tex] = 0.0521 M

GIven that :

Ka = [tex]1.9 x 10^{-5}[/tex]

Thus; it's pKa = 4.72

[tex]pH =4.72 + log(\dfrac{ \ 0.0521}{0.0458})[/tex]

[tex]pH =4.72 + log(1.1376)[/tex]

[tex]pH =4.72 + 0.05598[/tex]

[tex]pH =4.77598[/tex]

pH ≅ 4.80

The pH of the solution 0.150 M hydrazoic acid after 13.3 mL of NaOH base is added is 4.80.

How we calculate the pH?

pH of the given solution will be used by using the following equation:

pH = pKa + log[conjugate base] / [weak acid]

Given chemical reaction will be represented as:

HN₃ + OH⁻ → N₃⁻ + H₂O

Moles will be calculated as:

n = M×V, where

M = molarity

V = volume

Moles of 0.150 M hydrazoic acid = (0.150M)(0.025L) = 0.00375  mol

Moles of 0.150 M NaOH = (0.0133)(0.150) = 0.001995 mol

From the above calculation it is clear that moles of hydrazoic acid is present in excess and it will be:

0.00375 - 0.001995 = 0.001755 mol

And 0.001995 mol of N₃⁻ is preduced by the reaction.

Total volume of the solution = 0.025 +  0.0133 = 0.0383  L

To calculate the pH after titration, first we have to calculate the concentration in terms of molarity of N₃⁻ and HN₃ as:

[N₃⁻] = 0.001995 mol / 0.0383  L = 0.0521 M

[HN₃] = 0.001755 mol / 0.0383  L = 0.0458 M

Ka for HN₃ = 1.9 × 10⁻⁵

pKa = -log( 1.9 × 10⁻⁵ ) = 4.72

On putting all these values on the above equation, we get

pH = 4.72 + log (0.0521) / (0.0458)

pH = 4.80

Hence, pH of the solution is 4.80.

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A solid white substance A is heated strongly in the absence of air. It decomposes to form a new white substance B and a gas C. The gas has exactly the same properties as the product obtained when carbon is burned in an excess of oxygen. Based on these observations, can we determine whether solids A and B and the gas C are elements or compounds?

Answers

Answer:

A, B and C are compounds

Explanation:

First of all, I need to establish that when carbon is burnt in excess oxygen, carbon dioxide is obtained as shown by this equation; C(s) + O2(g) ----> CO2(g).

Looking at the presentation in the question, A was said to be heated strongly and it decomposed to B and C. Only a compound can decompose when heated. Elements can not decompose on heating. Secondly, compounds usually decompose to give the same compounds that combined to form them. Compounds hardly decompose into their constituent elements.

Again from the information provided, the compound A is a white solid. This is likely to be CaCO3. It decomposes to give another white solid. This may be CaO and the gas was identified as CO2.

Hence;

CaCO3(s)--------> CaO(s) + CO2(g)

Which element has the largest atomic radius

Answers

Answer:

Francium

Explanation:

The atomic radius increases from top to bottom in a group, and decreases from left to right across a period.

so francium (Fr) is the largest atom or has highest radii.

Hope this helps & please mark as brainiest!

Answer:

Francium has the largest atomic radius.

The general trend for atomic radii is increasing from top to bottom and decreasing from left to right so the one with the largest atomic radius will be in the bottom left of the periodic table.

Write the empirical formula

Answers

Answer:

[tex]Pb(CO_{3})_{2} \\Pb(NO_{3})_{4} \\FeCO_{3}\\Fe(NO_{3})_{2}[/tex]

Explanation:

[tex]Pb^{4+}(CO_{3}^{2-})_{2} --->Pb(CO_{3})_{2} \\Pb^{4+} (NO_{3}^{-})_{4} --->Pb(NO_{3})_{4} \\Fe^{2+} CO_{3}^{2-} --->FeCO_{3}\\Fe^{2+} (NO_{3}^{-})_{2}--->Fe(NO_{3})_{2}[/tex]

(a) How many stereoisomers are possible for 4-methyl-1,2-cyclohexanediol? ___ (b) Name the stereoisomers formed by oxidation of (S)-4-methylcyclohexene with osmium tetroxide. If there is only one stereoisomer formed, leave the second space blank. Isomer #1: Isomer #2: (c) Is the product formed in step (b) optically active? _____

Answers

Answer:

See explanation

Explanation:

For the first part of the question, we have to check the chiral carbons in 4-methyl-1,2-cyclohexanediol. In this case carbons, 1 and 2 are chiral, if we have 2 chiral carbons we will have 4 isomers. We have to remember that formula 2^n in which "n" is the number of chiral carbons, so:

2^n = 2^2 = 4 isomers

And the isomers that we can have are:

1) (1R,2S)-4-methylcyclohexane-1,2-diol

2) (1S,2S)-4-methylcyclohexane-1,2-diol

3) (1S,2S)-4-methylcyclohexane-1,2-diol

4) (1S,2R)-4-methylcyclohexane-1,2-diol

See figure 1

For the second part of the question, we have to remember that the oxidation with [tex]OsO_4[/tex] is a syn addition. In other words, the "OHs" are added in the same plane. In this case, we have the methyl group with a wedge bond, so the "OH" groups will have a dashed bond due to the steric hindrance. Due to this we only can have 1 isomer ((1S,2R,4S)-4-methylcyclohexane-1,2-diol). Finally, on this molecule, we dont have any symmetry planes (this characteristic will cancel out the optical activity), so the product of this reaction has optical activity.

See figure 2

I hope it helps!

What volume of 6.00 M hydrochloric acid is needed to prepare 500 mL of 0.100 M solution?

Answers

Answer:

8.33mL or .0083L

Explanation:

Use m1 * V1 = m2 * V2

6.00M(x) = 0.100M(500mL)

solve for x

x= (.1 * 500) / 6

x=8.333 mL

g A laboratory analysis of an unknown compound found the following composition: C 75.68% ; H 8.80% ; O 15.52%. What is the empirical formula of the compound?

Answers

Answer:

THE EMPIRICAL FORMULA FOR THE UNKNOWN COMPOUND IS C7H9O

Explanation:

The empirical formula for the unknown compound can be obtained by following the processes below:

1 . Write out the percentage composition of the individual elements in the compound

C = 75.68 %

H = 8.80 %

O = 15.52 %

2. Divide the percentage composition by the atomic masses of the elements

C = 75 .68 / 12 = 6.3066

H = 8.80 / 1 = 8.8000

O = 15.52 / 16 = 0.9700

3. Divide the individual results by the lowest values

C = 6.3066 / 0.9700 = 6.5016

H = 8.8000 / 0.9700 = 9.0722

O = 0.9700 / 0.9700 = 1

4. Round up the values to the whole number

C = 7

H = 9

O = 1

5 Write out the empirical formula for the compound

C7H90

In conclusion, the empirical formula for the unknown compound is therefore C7H9O

A 3.00-g sample of an alloy (containing only Pb and Sn) was dissolved in nitric acid (HNO3). Sulfuric acid was added to this solution, which precipitated 2.93 g of PbSO4. Assuming that all of the lead was precipitated, what is the percentage of Sn in the sample? (molar mass of PbSO4 = 303.3 g/mol)

Answers

Answer:

33.3% of Sn in the sample

Explanation:

The addition of SO₄⁻ ions produce the selective precipitation of Pb²⁺ to produce PbSO₄.

Moles of PbSO₄ (molar mass 303.26g/mol) in 2.93g are:

2.93g ₓ (1mol / 303.26) = 9.66x10⁻³ moles PbSO₄ = Moles Pb²⁺.

As molar mass of Pb is 207.2g/mol, mass in 9.66x10⁻³ moles of Pb²⁺ is:

9.66x10⁻³ moles of Pb²⁺ ₓ (207.2g / mol) = 2.00g of Pb²⁺

As mass of the sample is 3.00g, mass of Sn²⁺ is 3.00g - 2.00g = 1.00g

And the percentage of Sn in the sample is:

1.00g / 3.00g ₓ 100 =

33.3% of Sn in the sample
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