Answer:
204.7 g
Explanation:
(taking the atomic mass of C, H, O as 12, 1 and 16 respectively).
no. of moles of C3H8 burnt = 56.3 / (12x3 + 1x8)
= 1.27955 mol
From the equation, the mole ratio of C3H8 : O2 = 1:5
Hence,
the no. of moles of O2 required will be
=1.27955 x 5
= 6.397727 mol
Mass of O2 required = 6.397727 x (16x2)
= 204.7 g
The reaction rate is k[Ce4+][Mn2+] for the following reaction: 2Ce4+(aq) + Tl+(aq) + Mn2+(aq) → 2Ce3+(aq) + Tl3+(aq) + Mn2+(aq What is the catalyst?
Answer:
Manganese (II) ion, Mn²⁺
Explanation:
Hello,
In this case, given the overall reaction:
[tex]2Ce^{4+}(aq) + Tl^+(aq) + Mn^{2+}(aq) \rightarrow 2Ce^{3+}(aq) + Tl^{3+}(aq) + Mn^{2+}(aq)[/tex]
Thus, since manganese (II) ion, Mn²⁺ is both at the reactant and products, we infer it is catalyst, since catalysts are firstly consumed but finally regenerated once the reaction has gone to completion. Moreover, since inner steps are needed to obtain it, we can infer that the given rate law corresponds to the slowest step that is related with the initial collisions between Ce⁴⁺ and Mn²⁺
Best regards.
which element will have higher electronegativity
Calculate Ecell at 80 ºC for a voltaic cell based on the following redox reaction: H2(g, 1.25 atm) + 2AgCl(s) → 2Ag(s) + 2H+(aq, 0.10 M) + 2Cl–(aq, 1.5 M) The standard cell potential Eºcell = +0.18 V at this temperature.
Answer:
Ecell = +0.25V
Explanation:
the half-cell reactions for a voltanic cell
cathode(reduction): 2H⁺(aq) + 2e⁻ ------- H₂(g)
anode(oxidation): 2AgCl(s) ------- 2Ag⁺(aq) + 2Cl⁻ + 2e⁻
we have the standard cell potential E⁺cell = 0.18V at 80C respectively
Q = [H⁺]/[Cl⁻]
sub for [H+] = 0.10M and [Cl-] = 1.5M
Q= 0.1M/1.5M
Q = 0.067
Ecell = E⁺cell - [tex]\frac{0.059}{n}[/tex] logQ
= 0.18 - [tex]\frac{0.056}{1}[/tex] log 0.067
0.18- 0.059(-1.174)
Ecell = +0.25V
Given the information below, which is more favorable energetically, the oxidation of succinate to fumarate by NAD+ or by FAD? Fumarate + 2H+ + 2e- → Succinate E°´ = 0.031 V NAD+ + 2H+ + 2e- → NADH + H+ E°´ = -0.320 FAD + 2H+ + 2e- → FADH2 E°´ = -0.219
Answer:
Oxidation by FAD
Explanation:
1. Oxidation by NAD⁺
Succinate ⇌ Fumarate + 2H⁺ + 2e⁻; E°´ = -0.031 V
NAD⁺ + 2H⁺ + 2e⁻ ⇌ NADH + H⁺; E°´ = -0.320 V
Succinate + NAD⁺ ⇌ Fumarate + NADH + H⁺; E°' = -0.351 V
2. Oxidation by FAD
Succinate ⇌ Fumarate + 2H⁺ + 2e⁻; E°´ = -0.031 V
FAD + 2H⁺ + 2e⁻ ⇌ FADH₂; E°´ = -0.219 V
Succinate + FADH₂ ⇌ Fumarate + FAD; E°' = -0.250 V
Neither reaction is energetically favourable, but FAD has a more positive half-cell potential.
FAD is the stronger oxidizing agent.
The oxidation by FAD has a more positive cell potential, so it is more favourable energetically.
The gas evolved in the metal carbonate reaction with acid turns limewater milky The milky substance formed is
Answer:
The gas evolved because of reaction of acid with metal carbonate or metal hydrogen carbonate turns lime water milky. This shows that the gas is carbon dioxide gas. This happens because of formation of white precipitate of calcium carbonate.
Hope it helps you!
The milky substance formed is CO₂ gas.
What leads to the formation of white precipitate of calcium carbonate ?The gas evolved because of reaction of acid with metal carbonate or metal hydrogen carbonate turns lime water milky. This shows that the gas is carbon dioxide gas.
This happens because of formation of white precipitate of calcium carbonate.
Lime water turns milky when the gas liberated from an acidified carbonate solution is passed into it.
The liberated CO₂ reacts with lime water to give calcium bicarbonate as the precipitate.
Hence, the milky substance formed is CO₂ gas.
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An adult rhino xan have a mass of 1400 kg the mass of a small egret is about 0.76kg. what is the radio of these two masses? how does this ratio compare to the ratio of the mass of a proton ti the mass of an electron?
Answer:
The ratio of the mass of an adult rhino to the mass of a small egret is
(1400 kg)/(0.76 kg) = 1842.11
The ratio of the mass of a proton to the mass of an electron is
1836.15
The two ratios are very similar, the ratio of the masses of the proton to the electron being slightly smaller.
Rank the following in terms of increasing atomic radius Mg, Sc, Ca
Answer:
Mg, Sc, Ca
Explanation:
To figure out increasing atomic radii, we use Periodic Trends applied to the Elements of the Periodic Table to help us out. We know that the trend for atomic radii is increasing left and down. Since Ca is the furthest down and left of the 3, it has the largest atomic radius. Since Sc is next element to Ca, it would be the 2nd largest atomic radius of the 3. Since Mg is above Ca, it has the smallest atomic radius of the 3.
Write a balanced equation depicting the formation of one mole of NaBr(s) from its elements in their standard states.
Express your answer as a chemical equation. Identify all of the phases in your answer.
Write a balanced equation depicting the formation of one mole of SO3(g) from its elements in their standard states.
Express your answer as a chemical equation. Identify all of the phases in your answer.
For SO3(g) find the value of ΔH∘f. (Use Appendix C in the textbook.)
Express your answer using four significant figures.
For NaBr(s) find the value of ΔH∘f. (Use Appendix C in the textbook.)
Express your answer using four significant figures.
Write a balanced equation depicting the formation of one mole of Pb(NO3)2(s) from its elements in their standard states.
Express your answer as a chemical equation. Identify all of the phases in your answer.
For Pb(NO3)2(s) find the value of ΔH∘f. (Use Appendix C in the textbook.)
Express your answer using four significant figures.
Answer:
Check Explanation.
Explanation:
Formation reactions are chemical reactions where one mole of a compound is produced from its constituent elements in their standard states.
NaBr (s)
The Standard formation reaction is
Na (s) + (1/2)Br₂ (g) → NaBr (s)
Using appendix C, the standard heat of formation of NaBr(s) is
ΔH∘f = -359.8 kJ/mol.
SO₃ (g)
The Standard formation reaction is
S (s) + (3/2) O₂ (g) → SO₃ (g)
Using appendix C, the standard heat of formation of SO₃(g) is
ΔH∘f = -395.2 kJ/mol.
Pb(NO₃)₂ (s)
The Standard formation reaction is
Pb (s) + N₂ (g) + 3O₂ (g) → Pb(NO₃)₂ (s)
Using appendix C, the standard heat of formation of Pb(NO₃)₂(s) is
ΔH∘f = -451.9 kJ/mol.
Hope this Helps!!!
Answer:
Explanation:
Formation reactions are chemical reactions where one mole of a compound is produced from its constituent elements in their standard states.
Name the compound Ga S3
Answer:
Gallium(III) sulfide1.60 mL of a suspension of 320.0 mg/5.00 mL aluminum hydroxide is
added to 2.80 mL of hydrochloric acid. What is the molarity of the
hydrochloric acid?
Answer:
1.41 M
Explanation:
First we must use the information provided to determine the concentration of the aluminum hydroxide.
Mass of aluminum hydroxide= 320mg = 0.32 g
Molar mass of aluminum hydroxide= 78 g/mol
Volume of the solution= 5.00 ml
From;
m/M= CV
Where;
m= mass of aluminum hydroxide= 0.32 g
M= molar mass of aluminum hydroxide = 78 g/mol
C= concentration of aluminum hydroxide solution = the unknown
V= volume of aluminum hydroxide solution = 5.0 ml
0.32 g/78 g/mol = C × 5/1000
C = 4.1×10^-3/5×10^-3
C= 0.82 M
Reaction equation;
Al(OH)3(aq) + 3HCl(aq) -----> AlCl3(aq) + 3H2O(l)
Concentration of base CB= 0.82 M
Volume of base VB= 1.60 ml
Concentration of acid CA= the unknown
Volume of acid VA= 2.80 ml
Number of moles of acid NA = 3
Number of moles of base NB= 1
Using;
CA VA/CB VB = NA/NB
CAVANB = CBVBNA
CA= CB VB NA/VA NB
CA= 0.82 × 1.60 × 3/ 2.80 ×1
CA= 1.41 M
Therefore the concentration of HCl is 1.41 M
A 0.1-L unbuffered solution needs the pH adjusted from 3.5 to 1. How many microliters of a 6 molar HCl solution need to be added to adjust the pH
Answer:
1661μL of a 6M HCl you need to add
Explanation:
pH is defined as -log[H⁺] ([H⁺] =10^{-pH}), the initial and final concentrations of [H⁺] you need are:
Initial [H⁺] = 10^{-3.5} = 3.16x10⁻⁴M H⁺
Final [H⁺] = 10^{-1} = 0.1M H⁺
In moles, knowing volume of the solution is 0.1L:
Initial [H⁺] = 0.1L ₓ (3.16x10⁻⁴mol H⁺ / L) = 3.16x10⁻⁵moles H⁺
Final [H⁺] = 0.1L ₓ (0.1mol H⁺ / L) = 0.01 moles H⁺.
That means, moles of H⁺ you need to add to the solution is:
0.01mol - 3.16x10⁻⁵moles = 9.9684x10⁻³ moles of H⁺.
A solution of HCl dissociates in H⁺ and Cl⁻ ions, that means moles of HCl added are equal to moles of H⁺. As you need to add 9.9684x10⁻³ moles of H⁺ = 9.9684x10⁻³ moles of HCl:
9.9684x10⁻³ moles of HCl ₓ (1L / 6mol) = 1.6614x10⁻³L
In μL:
1.661x10⁻³L × (1x10⁶μL / 1L) =
1661μL of a 6M HCl you need to addMary smith obtained a density of 2.226g/ml for a metal sample. Using a different method, Joseph Henry obtained a value of 2.335g/mL for the same metal sample. Which student’s value is more accurate? Use the definition of accuracy to explain your answer. the true value is 2.300g/ml.
Answer:
Joseph Henry.
Explanation:
Hello,
In this case, we define the accuracy based on the degree of deviation a measure has regarding the the true or expected value. In this case, the lower the difference, the more accurate the procedure. In such a way, for the two students, we compute the difference between the expected value and the obtained value:
[tex]Mary=2.300g/mL-2.226g/mL=0.074g/mL[/tex][tex]Joseph=2.335g/mL-2.300mL=0.035g/mL[/tex]
In such a way, since the difference is lower in Joseph's measure, we can say he is the most accurate.
Best regards.
What is the density of a gas with a molar mass of 28.26g/mol at 3.510atm and 237k?
Answer:
density = 5.1g/m³
Explanation:
use ideal gas equation
Pv=nRT
28.26 x 3.51 = m/v x 0.08206 x 237
m/v = (28.26 x3.51)/(237 x 0.08206) = 5.1g/m³
Ethylene glycol, C2H6O2, is infinitely miscible (soluble) in water. It is a nonelectrolyte that is used as antifreeze. What is the lowest possible melting point for engine coolant that is 26.1% ethylene glycol
Answer: The lowest possible melting point for engine coolant that is 26.1% ethylene glycol is [tex]-7.83^0C[/tex]
Explanation:
Depression in freezing point or melting point is given by:
[tex]\Delta T_f=i\times K_f\times m[/tex]
[tex]\Delta T_f=T_f^0-T_f=(0-T_f)^0C[/tex] = Depression in freezing point
i= vant hoff factor = ( 1 for non electrolyte)
[tex]K_f[/tex] = freezing point constant for water= [tex]1.86^0C/m[/tex]
m= molality
[tex]\Delta T_f=i\times K_f\times \frac{\text{mass of solute}}{\text{molar mass of solute}\times \text{weight of solvent in kg}}[/tex]
Given : 26.1 g of ethylene glycol in 100 g of water
Weight of solvent (water)= 100 g = 0.1 kg (1kg=1000g)
Molar mass of solute (ethylene glycol) = 62 g/mol
Mass of solute (ethylene glycol) added = 26.1 g
[tex](0-T_f)^0C=1\times 1.86\times \frac{26.1g}{62g/mol\times 0.1kg}[/tex]
[tex](0-T_f)^0C=7.83[/tex]
[tex]T_f=-7.83^0C[/tex]
Thus the lowest possible melting point for engine coolant that is 26.1% ethylene glycol is [tex]-7.83^0C[/tex]
A sample of a compound is made up of 57.53 g C, 3.45 g H, and 39.01 g F. Determine the empirical formula of this compound.
Answer:
C7H5F3
Explanation:
The following data were obtained from the question:
Mass of Carbon (C) = 57.53g
Mass of Hydrogen (H) = 3.45g
Mass of Fluorine (F) = 39.01g
The empirical formula of the compound can be obtained as follow:
C = 57.53g
H = 3.45g
F= 39.01g
Divide each by their molar mass
C = 57.53/12 = 4.79
H = 3.45/1 = 3.45
F = 39.01/19 = 2.05
Divide each by the smallest
C = 4.79/2.05 = 2.3
H = 3.45/2.05 = 1.7
F = 2.05/2.05 = 1
Multiply through by 3 to express in whole number
C = 2.3 x 3 = 7
H = 1.7 x 3 = 5
F = 1 x 3 = 3
Therefore, the empirical formula for the compound is C7H5F3
What is the value of ΔG at 25°C when the initial concentrations of A, B, and C are 1 M, 1 mM, and 1 μM, respectively?
Answer:
Explanation:
0,44
Chemistry question. Image attached.
Answer:
Pb(NO3)2(aq) + 2NaCl(aq) —> PbCl2(s) + 2NaNO3(aq)
Explanation:
When lead (II) nitrate, Pb(NO3)2 undergoes a double displacement reaction with aqueous sodium chloride, NaCl, the following products are obtained:
Pb(NO3)2(aq) + NaCl(aq) —>
Aqueous Pb(NO3)2 will dissociate in solution as follow:
Pb(NO3)2(aq) —> Pb2+(aq) + 2NO3-(aq)
On the other hand, aqueous NaCl will dissociate as follow:
NaCl(aq) —> Na+(aq) + Cl-(aq)
The double displacement reaction will take place as follow:
Pb(NO3)2(aq) + NaCl(aq) —>
Pb2+(aq) + 2NO3-(aq) + Na+(aq) + Cl-(aq) —> Pb2+(aq) Cl-(aq) + Na+(aq) 2NO3-(aq)
Pb(NO3)2(aq) + NaCl(aq) —> PbCl2(s) + NaNO3(aq)
We simply balance the equation by putting 2 in front of NaCl and 2 in front of NaNO3 as shown below:
Pb(NO3)2(aq) + 2NaCl(aq) —> PbCl2(s) + 2NaNO3(aq)
The addition of 0.275 L of 1.62 M KCl to a solution containing Ag+ and Pb2+ ions is just enough to precipitate all of the ions
as AgCl and PbCl2. The total mass of the resulting precipitate is 62.37 g. Find the mass of PbCl, and AgCl in the precipitate.
Answer:
The mass of PbCl₂ is 45.88 grams and the mass of AgCl is 16.48 grams.
Explanation:
As mentioned in the given question, the addition of 0.275 L of 1.62 M KCl is done in a solution that comprise Ag⁺ and Pb²⁺ ions so that all the ions get precipitated. Therefore, the moles of KCl present is,
Moles of KCl = 0.275 L × 1.62 M = 0.445 moles
Now the reaction will be,
Ag⁺ + Pb²⁺ + KCl ⇒ AgCl + PbCl₂ + 3K⁺
Now let us assume that the formation of x moles of AgCl and y moles of PbCl₂ is taking place.
Therefore, mass of AgCl will be x × molecular mass, which will be equal to x × 143.32 grams = 143.32 x grams
Now the mass of PbCl2 formed will be,
y × molecular mass = y × 278.1 grams = 278.1 y grams
Now the total precipitate will be,
62.37 grams = 143.32 x + 278.1 y -----------(i)
Now as AgCl and PbCl₂ requires 1:2 ratio of KCl, this shows that x moles of AgCl will require x moles of KCl and y mol of PbCl₂ will require 2*y moles of PbCl₂. Therefore,
x + 2y = total mass of KCl
x + 2y = 0.445 moles ------ (ii)
On solving equation (i) and (ii) we get,
x as 0.115 and y as 0.165
Now the mass of AgCl will be,
143.32 × 0.115 = 16.48 grams
The mass of PbCl₂ will be,
278.1 × 0.165 = 45.88 grams.
The pressure in an automobile tire is 2.0 atm at 27°C. At the end of a journey on a hot summer day the pressure has risen to 2.2 atm. What is the temperature of the air in the tire? a. 272.72 K b. 330 K c. 0.014 K d. 175 K
Hey there!
For this we can use the combined gas law:
[tex]\frac{P_{1}V_{1} }{T_{1}} = \frac{P_{2}V_{2} }{T_{2}}[/tex]
We are only working with pressure and temperature so we can remove volume.
[tex]\frac{P_{1} }{T_{1}} = \frac{P_{2} }{T_{2}}[/tex]
P₁ = 2 atm
T₁ = 27 C
P₂ = 2.2 atm
Plug these values in:
[tex]\frac{2atm}{27C} = \frac{2.2atm}{T_{2}}[/tex]
Solve for T₂.
[tex]2atm = \frac{2.2atm}{T_{2}}*27C[/tex]
[tex]2atm * T_{2}={2.2atm}*27C[/tex]
[tex]T_{2}={2.2atm}\div2atm*27C[/tex]
[tex]T_{2}=1.1*27C[/tex]
[tex]T_{2}=29.7C[/tex]
Convert this to kelvin and get 302.85 K, which is closest to B. 330 K.
Hope this helps!
0.1 dm³ of argon contains x atoms .How many atoms are there in 0.2 dm³ of hydrogen gas under the same conditions?
A. )×/2
B.)2x
C.)4x
Answer:
B.) 2x
Explanation:
Hello,
In this case, we can apply the following rule of three, knowing that 0.1 dm³ equals x and 0.2 dm³ is the unknown:
[tex]0.1dm^3\longrightarrow x\\0.2dm^3 \longrightarrow ?[/tex]
Thus, solving for the unknown we find:
[tex]?=\frac{0.2dm^3*x}{0.1dm^3} \\\\?=2*x[/tex]
Therefore, the answer is B.) 2x.
Best regards.
Phosphoric acid is a polyprotic acid, with p K values of 2.14, 6.86, and 12.38. Which ionic form predominates at pH 9.3
Answer:
HPO₄⁻² predominates at pH 9.3
Explanation:
These are the equilibriums of the phosphoric acid, a tryprotic acid where 3 protons (H⁺) are realesed.
H₃PO₄ + H₂O ⇄ H₂PO₄⁻ + H₃O⁺ pKa 2.14
H₂PO₄⁻ + H₂O ⇄ HPO₄⁻² + H₃O⁺ pKa 6.86
HPO₄⁻² + H₂O ⇄ PO₄⁻³ + H₃O⁺ pKa 12.38
The H₂PO₄⁻ works as amphoterous, it can be a base and acid, according to these equilibriums.
H₂PO₄⁻ + H₂O ⇄ HPO₄⁻² + H₃O⁺
H₂PO₄⁻ + H₂O ⇄ H₃PO₄ + OH⁻
pH 9.3 is located between 6.86 and 12.38 where we have this buffer system HPO₄⁻² / PO₄⁻³, where the HPO₄⁻² is another amphoterous:
HPO₄⁻ + H₂O ⇄ H₂PO₄⁻ + OH⁻
HPO₄⁻² + H₂O ⇄ PO₄⁻³ + H₃O⁺
The media from the two pKa, indicates the pH where the protonated form is in the same quantity as the unpronated form, so:
(6.86 + 12.38) /2 = 9.62
Above this pH, [PO₄⁻³] > [HPO₄⁻²].
In conclussion, at pH 9.3, [HPO₄⁻²] > [PO₄⁻³]
In which orbital does an electron in a cesium atom experience the greatest effective nuclear charge?
Answer:
The effective nuclear charge in a cesium atom is greatest in the 1s orbital
Explanation:
Effective nuclear charge (Zeff) is the positive nuclear charge that is experienced by an electron in an atom. It is affected by the shielding effect and penetration of electrons of the atoms.
The shielding effect is the decrease in attraction between an electron and the nucleus in any atom with more than one electron shell. Innermost electrons shield the outermost electrons from the positive charge of the nucleus. The more electron shells there are, the greater the shielding effect experienced by the outermost electrons. and the more electron shielding an electron has, the lower the Zeff value.
Penetration is the ability of an electron to approach the nucleus. The closer the electron is to the nucleus, the higher the penetration. Electrons with higher penetration will shield outer electrons from the nucleus more effectively. The s orbital being closest to the nucleus has the highest penetration while the f orbital has the lowest penetration.
Cesium has an atomic number of 55 as well as nuclear charge of +55. It has 54 electrons in its filled 1s²2s²2p⁶3s²3p⁶4s²3d¹⁰4p⁶5s²4d¹⁰5p⁶6s¹ shells and an outermost 6s electron. Based on the explanation above, the effective nuclear charge is greatest in the innermost 1s orbital and least in the outermost 6s orbital.
The electron in a cesium atom experience should be considered as the 1st orbital.
What is an Effective nuclear charge (Zeff)?It is considered to be the positive nuclear charge i.e. experienced via the electron in an atom. It should be impacted via the effect of shielding and the penetration of the electron with respect to the atoms.
The electronic configuration of cesium should be like
[tex]1s^2 2s^2 2p^6 3s^2 3p^6 3d^10 4s^2 4p^6 4d^10 5s^2 5p^6 6s^1[/tex]
Now
the electron which is in the innermost subshell will experience the highest effective nuclear charge and it should be 1s.
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If the particles of matter that make up a substance are relatively far apart and can move freely, the substance is in what state?
gaseous
liquid
solid
Answer:
Gaseous
Explanation:
Gasses can move freely and do not form the shape of their containers
Liquids are more free than solids, but they conform to the shape of their container
Solids are not free
A 10.0 mL sample of a 2.5 M NaCl solution is diluted to 25.8 mL. What is the new concentration?
Answer:
[tex]C_2=0.97M[/tex]
Explanation:
Hello,
In this case, for dilution process, we can notice that the initial moles remain the same once the dilution is completed, therefore, both concentration and volume change considering:
[tex]n_1=n_2\\\\V_1C_1=V_2C_2[/tex]
In such a way for the given final volume, the resulting concentration is noticed to be:
[tex]C_2=\frac{V_1C_1}{V_2} =\frac{10mL*2.5M}{25.8mL}\\ \\C_2=0.97M[/tex]
This is supported by the fact that the higher the volume the lower the concentration.
Best regards.
g If 1.00 mol of ethane gas and 5.00 mol of oxygen gas react, what is the limiting reactant and how many moles of water are produced from the reaction
Answer:
First, write a balanced equation of the reaction.
A hydrocarbon reacting with oxygen usually gives out carbon dioxide and water (combustion)
2C2H6 + 7O2 ---> 4CO2 + 6H2O
From the equation, we can see the mole ratio of ethane : oxygen is 2:7, meaning 2 moles of ethane reacts with 7 moles of oxygen.
If there's 1 mole of ethane gas, we need y moles of oxygen gas for complete reaction.
[tex]\frac{2}{7} =\frac{1}{y}[/tex]
y= 3.5 moles
Since 5 moles of oxygen is more than the required 3.5 moles, we can deduce oxygen gas is in excess, meaning ethane is limiting.
(You can get the same results too if you take y as ethane gas required).
The no. of moles of product produced ALWAYS depend on the no. of moles of the limiting reactant, since they are the ones which reacts completely.
So, from the equation, since the mole ratio of ethane : water = 2:6,
hence, (take the no. of moles of water produced as z),
[tex]\frac{2}{6} =\frac{1}{z} \\z= 3[/tex]
Therefore, 3 moles of water is produced.
Ethane is the limiting reagent in the given reaction. The number of moles of water produced from the reaction is 3 moles.
What is a limiting reagent?A limiting reagent can be defined as that reactant in the chemical reaction which is consumed first among the other reactants during the completion of a chemical reaction.
The limiting reagent is the reactant which decides the yield of the product when the quantity of the reactants is not taken in stoichiometry.
Given, chemical reaction of ethane and oxygen is:
[tex]C_2H_6 + \frac{7}{2} O_2 \longrightarrow 2CO_2 +3H_2O[/tex]
Given, the number of moles of ethane = 1 mol
The number of moles of oxygen = 5 mol
One more of ethane reacts with moles of oxygen = 3.5 mol
Therefore, ethane is the limiting reagent in this reaction as the oxygen is given in excess.
From the balanced equation, one mole of ethane produces moles of water equal to 3 moles.
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Of the following, only ________ has sp2 hybridization of the central atom. Of the following, only ________ has sp2 hybridization of the central atom. ICl3 PBr3 SiH2Br2 HCN BF3
Answer:
BF3
Explanation:
Hybridization can be defined as the mixing of two or more atomic pure orbitals. ( s, p , and d) to produce two or more hybrid atomic orbitals that are similar and identical in shape and energy e.g sp,sp²,sp³ ,sp³d, sp³d². Usually , the central atom of a covalent molecules or ion undergoes hybridization.
in BF3; Boron is the central atom. Here, A 2s electron is excited from the ground state of boron ( 1s²2s²2p¹) to one empty orbitals of 2p.
The 2s orbital is then mixed with two orbitals of 2p to form three sp² hybrid orbitals tat are trigonally arranged in the plane in order to minimize repulsion . Each of the three hybrid orbitals overlaps with p-orbital of fluorine atom to form three bonds of equal strength and with bond angles of 120⁰.
Energy
B ⇵ ║ ⇅ ║ ↑ -----------> *B ⇵ ║ ↑ ║ ↑ ║ ↑
1s 2s 2p 1s 2s 2p
Ground state Excited State
The above shows an illustrative example of how electrons move from the ground state to the excited state.
How many moles of hydrogen gas will be produced when 12 g of Mg will react completely with excess of an acid according to the following reaction? 2 Mg + 2 HCI — 2 MgCl2 + H,
Answer:
0.49 mol
Explanation:
Step 1: Write the balanced equation
Mg + 2 HCI ⇒ MgCl₂ + H₂
Step 2: Calculate the moles corresponding to 12 g of Mg
The molar mass of Mg is 24.31 g/mol.
[tex]12g \times \frac{1mol}{24.31g} = 0.49mol[/tex]
Step 3: Calculate the moles of H₂ produced by 0.49 moles of Mg
The molar ratio of Mg to H₂ is 1:1. The moles of H₂ produced are 1/1 × 0.49 mol = 0.49 mol.
The rate constant for this first‑order reaction is 0.550 s−10.550 s−1 at 400 ∘C.400 ∘C. A⟶products A⟶products How long, in seconds, would it take for the concentration of AA to decrease from 0.690 M0.690 M to 0.220 M?
Answer:
[tex]t=2.08s[/tex]
Explanation:
Hello,
In this case, for first order reactions, we can use the following integrated rate law:
[tex]ln(\frac{[A]}{[A]_0} )=kt[/tex]
Thus, we compute the time as shown below:
[tex]t=-\frac{ln(\frac{[A]}{[A]_0} )}{k}=- \frac{ln(\frac{0.220M}{0.690M} )}{0.55s^{-1}} \\\\t=-\frac{-1.14}{0.550s^{-1}}\\ \\t=2.08s[/tex]
Best regards.
Calculate the vapor pressure of water above the solution. The vapor pressure of pure water at this temperature is 0.0313 atm. Assume complete dissociation of the solute. Express your answer in atmospheres to three significant figures. Pvap = atm
The question is incomplete, the solute was not given.
Let the solute be K₂CrO₄ and the solvent be water
Complete Question should be like this:
The density of a 0.438 M solution of potassium chromate (K₂CrO₄) at 298 K is 1.063 g/mL.
Calculate the vapor pressure of water above the solution. The vapor pressure of pure water at this temperature is 0.0313 atm. Assume complete dissociation.
Pvap = ________atm
Answer:
Pvap (of water above the solution) = 0.0306 atm
Dissolution of the solute
K₂CrO₄ => 2K⁺ + Cr₂O₄²⁻
Explanation:
Given
volume of solution = 1 Litre = 1000 mL of the solution
density of the solution = 1.063 g/mL
concentration of the solution= 0.438M
temperature of the solution= 298 K
vapour pressure of pure water = 0.0313atm
Recall: density = mass/volume
∴mass of solution = volume x density
m = 1000 x 1.063 = 1063 g
To calculate the moles of K₂CrO₄ = volume x concentration
= 1 x 0.438 = 0.438 mol
Mass of K₂CrO₄ = moles x molar mass = 0.438 x 194.19 = 85.055 g
Mass of water = mass of solution - mass of K₂CrO₄
= 1063 - 85.055 = 977.945 g
moles of water = mass/molar mass
∴ moles of water = 977.945/18.02 = 54.27 mol
Dissolution of the solute
K₂CrO₄ => 2K⁺ + Cr₂O₄²⁻
(dissolution is the process by which solute(K₂CrO₄) is passed into solvent(H₂O) to form a solution
moles of ions = 3 x moles of K₂CrO₄
= 3 x 0.438 = 1.314 mol
Vapor pressure of solution = mole fraction of water x vapor pressure of water
= 54.27/(54.27 + 1.314) x 0.0313 = 0.0306 atm
How many grams of C are required to react with 64.6 g of Fe2O3 ?
Answer:
14.6 g
Explanation:
Fe₂O₃ + 3 C → 2 Fe + 3 CO₃
First, convert grams of Fe₂O₃ to moles. The molar mass is 159.69 g/mol.
(64.6 g)/(159.69 g/mol) = 0.4045 mol
Now, use stoichiometry to convert moles of Fe₂O₃ to moles of C. By looking at the chemical equation, you can see that for every 1 mole of Fe₂O₃, you need 3 moles of C. Use this relationship.
(0.4045 mol Fe₂O₃) × (3 mol C/1 mol Fe₂O₃) = 1.214 mol C
Now, convert moles of C to grams. The molar mass is 12.01 g/mol.
(1.214 mol C) × (12.01 g/mol) = 14.58 g
You need to use significant figures.
14.58 g ≈ 14.6 g