Reaction of HBr with 3-methylcyclohexene yields a mixture of four products cis-and trans-1-bromo-3-methylcyclohexane and cis-and trans-1-bromo-2-methylcyclohexane. The analogous reaction of HBr with 3-bromocyclohexene yields trans-1,2-dibromocyclohexane as the soul product.
Required:
Draw structures of the possible intermediates and mechanismfor the latter reaction.
Answers
Answer:
See explanation
Explanation:
The mechanism of this reaction including intermediates are shown in the image attached to this answer.
The reaction of HBr with 3-bromocyclohexene yields trans-1,2-dibromocyclohexane as the sole product because; the proton first attacks the 3-bromocyclohexene and a brominium ion is formed. This brominium ion is a cyclic intermediate as shown in the image attached.
Attack of a bromine ion afterwards must lead to the formation of trans-1,2-dibromocyclohexane as shown.
Related Questions
If the solubility of salicylic acid is 77.8 g/L of water at 100oC and 1.4 g/L of water at 10oC, a) calculate the minimum amount (in mL) of boiling water necessary to dissolve 2.0 g of impure salicylic acid for recrystallization. b) If the solution is cooled to room temperature and then to 10oC with an ice/water bath, what is the maximum amount of solid salicylic acid isolated after vacuum filtration
Answers
Answer:
a. 25.7mL are necessaries.
b. 1.964g of salicylic acid can be isolated.
Explanation:
a. As the solubility of salicylicic acid in boiling water is 77.8g/L, to dissolve 2.0g of salicylic acid are necessaries:
2.0g * (1L / 77.8g) = 0.0257L =
25.7mL are necessariesb. Then, at 10°C the solution just can dissolve 1.4g/L, that is:
0.0257L * (1.4g/L) = 0.036g of salicylic acid are dissolved.
And will precipitate:
2.0g - 0.036g =
1.964g of salicylic acid can be isolatedIn a sample of neon, carbon, and oxygen gas, the total pressure is 9 atm.
The partial pressure of neon is 2 atm and the partial pressure of oxygen is 2
atm. What is the partial pressure of carbon?
9 atm
3 atm
5 atm
4 atm
Answers
Answer:
5 atm
Explanation:
add boh partial pressures and subtract from total pressure
Which of the following is an example of synthesis?
A) HgO + Cl2-->HgCl + O2
B) Na + Br2 --> NaBr
C) KClO3 --> KCl + O2
D) Cl2 + NaBr --> NaCl + Br2
Answers
Answer:
B
Explanation:
A mole equals 6.02 x 10^23 . Answer these questions below.
1. How many ants are in 1.25 moles of ants?
2. How many moles of pencils are in 4.92 * 10^26 pencils?
3. How many molecules are in 0.26 moles of molecules?
4. How many moles of molecules are in 3.46 * 10^19 molecules?
5. 5.3 * 10^20 atoms are equal to how many moles of atoms?
6. 0.11 moles of atoms are equal to how many atoms?
Answers
Answer:
1. 1.25 mol ants x 6.02*10^23 ants/1 mol ants = 7.53*10^23 ants
2. 4.92*10^26 pencils x 1 mol pencils/6.02*10^23 pencils = 817 mol pencils
3. 0.26 mol molecules x 6.02*10^23 molecules/1 mol molecules = 1.6*10^23 molecules
4. 3.46*10^19 molecules x 1 mol molecules/6.02*10^23 molecules = 5.75*10^-5 mol molecules
5. 5.3*10^20 atoms x 1 mol atoms/6.02*10^23 atoms = 8.8 mol atoms
6. 0.11 mol atoms x 6.02*10^23 atoms/1 mol atoms = 6.6*10^22 atoms
I would suggest looking into "dimensional analysis" for help with this type of material. Dimensional analysis will stick with you all throughout chemistry, so picking it up will be extremely beneficial.
what is an example of an electrolyte solution?
Answers
Answer:
nacl with water
they are capable of conducting electricity
What is the mass in grams of 8.65 mol C8H18?
Answer in standard notation to zero decimal places.
PLEASE HELP THIS IS DUE AT 11:59 AT MIDNIGHT AND IM FREAKING OUT
Answers
Answer:
m = 998 g
Explanation:
Hello there!
In this case, according to the definition of the molar mass as the mass of one mole of the compound, it is possible to state the 1 mole of C8H18 has a mass of 114.26 grams; therefore, the mass in 8.65 moles turn out to be:
[tex]m=8.65mol*\frac{114.26g}{1mol}\\\\m=998g[/tex]
In agreement to the notation requirement.
Best regards!
Help meee??
HNO 3 is an example of Select one :
Triprotic Acid
O Diprotic Acid
O Monoprotic Acid
Tetraprotic Acid
Answers
Bryan is doing a science experiment on the stomata of plants. Bryan has a tomato plant. He uses wax to cover all the stomata on the leaves of the plant. After five days, Bryan observes that the plant is wilting. What is the best explanation for Bryan’s observation?
A. The plant released too much water into the air B. The plant was unable to carry out transpiration. C. Condensation could not occur on the leaves of the plant.
D. The plant was unable to take in water through its leaves
Answers
Answer: The answer is B
The most adequate explanation for the observation done by Bryan would be:
B). The plant was unable to carry out transpiration.
Stomata are characterized as the "tiny pores present in a leaf's epidermis which allows the gas or water vapor to pass."In the given experiment, Bryan has covered these pores which will prevent the process of photosynthesis to take place. This will result in the failure of the transpiration process in the plant to take place and its associated processes as well.
Thus, option B is the correct answer.
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14. If one half-life is the amount of time it takes for a radioactive isotope to decay by a factor of 2,
approximately which percent describes how much of the initial quantity of a substance would
remain after 2.3 half-lives?
Answers
Answer:
Since the equation for amount remaining is (1/2)^n, where n stand for the number of half lives, after 2.3 half lives the equation is (1/2)^2.3. This makes the answer about 1/4.92, which converts to about 20% of the original amount.
Explanation:
Since the equation for amount remaining is (1/2)^n, where n stand for the number of half lives, after 2.3 half lives the equation is (1/2)^2.3. This makes the answer about 1/4.92, which converts to about 20% of the original amount.
. Give an example of a salt that is less soluble when the temperature increases
Answers
Answer:
cerium (iii) sulfate is less soluble
Answer:
cerium sulphate is less solube when the temperature increase
Nitrous oxide (N2O), more commonly known as laughing gas, is used as a mild sedatitive during various dental procedures.As a gas, it has a densityof 1.977 x 10-3g/mL.Wheniron is exposed to oxygen it forms rust (Fe2O3), which is a solid and has a density value of 5.25 g/mL.Why are the density values so different among these substances?
a)The metal atoms weigh more than the atoms of the gas.
b)The metal forms metallic bonds which are more greatly affected by gravity, increasing the mass.
c)The metal is a solid, and solids weigh more based on the principles of their states of matter.
d)There are fewer gas particles than solid particles in the same volume.
Answers
Answer:
B.
Explanation:
The metal forms metallic bonds which are more greatly affected by gravity, increasing the mass.
List four reasons why the temperature of a flame is lower than the adiabatic flame temperature."
Answers
Answer:
substances is never entirely a one way
Explanation:
no possibility of obtaining complete combustion at hig
temperature.
always loss of heat from the temperature
its temperature is lower than the constant volume process because some of the energy is utilized to change the volume of the system
Four reasons why the temperature of flame is lower than adiabatic flame temperature is that there is no possibility of obtaining complete combustion at high temperature due to high thermal energy.There is always loss of heat from temperature,its temperature is lower than constant volume process because some of energy is utilized to change the volume of the system.
What is thermal energy?Thermal energy is defined as a type of energy which is contained within a system which is responsible for temperature rise.Heat is a type of thermal energy.It is concerned with the first law of thermodynamics.
Thermal energy arises from friction and drag.It includes the internal energy or enthalpy of a body of matter and radiation.It is related to internal energy and heat .It arises when a substance whose molecules or atoms are vibrating faster.
These vibrating molecules and atoms collide and as a result of which heat is generated in a substance , more the collision of particles , higher is the thermal energy.
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Select the valid ways to make an ammonia/ammonium buffer for use in the laboratory. Mix equal volumes of 1 M NH3 and 0.01 M NH 4. Mix some volume of 1 M NH3 with half as much 1 M HCl. Mix equal volumes of 1 M NH3 and 1 M NH 4. Mix equal volumes of 1 M NH3 and 1 M HCl.
Answers
Answer:
The answer is "Option b and Option c".
Explanation:
This buffer is a buffer of ammonia and ammonium ion. Thus it requires the solution [tex]NH_3 \ \ and \ \ NH_4^{+}[/tex].
In point 1:
The solution containing [tex]NH_3 \ \ and \ \ NH_4^{+}[/tex] at 1M concentration would be given by mixing the two solutions. Thus, this buffer is a legitimate route.
In point 2:
It gives the ions you want but they are not the same.
In point 3:
[tex]1 M[/tex] [tex]NH_3[/tex] and [tex]1 M[/tex][tex]HCl[/tex] volume would not produce the same [tex]NH_3 \ \ and \ \ NH_4^{+}[/tex] concentrations. Therefore, this buffer isn't a valid route.
In point 4:
Some [tex]1 M[/tex] [tex]NH_3[/tex] volume and half [tex]HCl[/tex] . This offers the same rate as half.
A voltaic cell is constructed in which the anode is a Fe|Fe2 half cell and the cathode is a Cd|Cd2 half cell. The half-cell compartments are connected by a salt bridge. (Use the lowest possible coefficients. Be sure to specify states such as (aq) or (s). If a box is not needed, leave it blank.) The anode reaction is:
Answers
Answer: The Anode reaction is [tex]Fe(s)\rightarrow Fe^{2+}(aq)+2e^-[/tex]
Explanation:
Oxidation-reduction reaction or redox reaction is defined as the reaction in which oxidation and reduction reactions occur simultaneously.
Oxidation reaction is defined as the reaction in which a substance looses its electrons.Oxidation occurs at anode.
Anode : [tex]Fe(s)\rightarrow Fe^{2+}(aq)+2e^-[/tex]
Reduction reaction is defined as the reaction in which a substance gains electrons. Reduction occurs at cathode.
Cathode : [tex]Cd^{2+}(aq)+2e^-\rightarrow Cd(s)[/tex]
Which term describes something that displays all the characteristics of life?
a.homeostasis
b.organism
c.stimulus
d.unicellular
Answers
Identify the most and the least basic compound in each of the following sets. Leave the remaining answer in each set blank. a) Sodium acetate: _______ Ammonia: _______ Sodium ethoxide: _______ b) Sodium acetate: _______ Sodium chloroacetate: _______ Sodium fluoroacetate: _______ c) Sodium acetate: _______ Sodium methoxide: _______ Sodium phenoxide:
Answers
Answer:
The correct answer is -
a) Sodium acetate: least Ammonia: _______ Sodium ethoxide: most
b) Sodium acetate: most Sodium chloroacetate: _______ Sodium fluoroacetate: least
c) Sodium acetate: least Sodium methoxide: most Sodium phenoxide:
Explanation:
A) In this case the basicity can be found by the stability of the base, Sodium acetate is the most stable base due to resonance stabilization of acetate anion. Sodium acetate is the least basic as the lone pair of electrons involved in the resonance here. An ethoxide ion has more electrons to donate an electron pair easily.
Thus, the correct answer is - Sodium acetate is the least basic while sodium ethoxide is the most basic.
B) Fluroacetate gives a very strong acid and the acetate gives the least strong acid among all three as described in case of a), thus, the most basic is acetate and the least is fluoroacetate.
]C) comparing the acidity of the acids formed by the addition of a proton to the anions is an easy and correct way to find the basicity of compounds.
Acetate ion adds a proton ⇒ acetic acid
methoxide adds a proton ⇒ methanol
phenoxide ion adds proton ⇒ phenol
As it is known that the stronger the acid, the weaker is the conjugate base formed by the loss of the proton.
acetic acid is the strongest acid because it can easily give up its proton to form acetate. Methanol is the weakest among all three and hence methoxide anion is the strongest base.
Thus, the correct answer is - sodium acetate is the least basic while sodium methoxide is the most basic.
how many mg are in 125ml of
phosphoric acid?
Answers
Answer:
125000mg
Explanation:
1ml = 1000mg
125(1000) = 125000mg
Arrange the following substance into acid,base and neutral. sodium chloride, tomato juice, vinegar,sea water,bicorbonate of sodium
Answers
Answer:
sodium chloride: neutral.
tomato juice: acid.
vinegar: acid.
sea water: base.
bicarbonate of sodium: base.
Explanation:
Hello there!
In this case, in agreement to the definition of the pH, as the measure of the acidity and basicity of a substance; it is important to recall that pH's below 7 stand for acidic substances and pH's above 7 stand for basic substances, whereas a pH of 7 defines a neutral one. In such a way, given the pH's of the given substances, 7, 4.05 to 4.65, around 2.5, about 8.1 and about 8.3 respectively for sodium chloride, tomato juice, vinegar, sea water, bicarbonate of sodium, it is possible to assert:
sodium chloride: neutral.
tomato juice: acid.
vinegar: acid.
sea water: base.
bicarbonate of sodium: base.
Best regards!
what is the pH if the H+ is 5.7 x 10^-10 M ?
Answers
Answer:
9.24
Explanation:
-logofH
5 ways light changes objects
Answers
2) it could make the object hot if the light stays on it for long enough
3) it forms energy, such as light helps makes plants grow
4) it can make it change colors, such as if you put a flashlight underneath a balloon making it a lighter colour
5) it can reflect of the objects, such as a mirror
What is the volume of .80 g of O2 gas at STP?
Answers
0.80/32.00=0.025 mol
Now to convert this to liters at STP, you have to multiply that, by 22.4.
0.025*22.4=0.56 L
Answer:0.56L
Explanation:Molar mass of O2=32
N=0.8/32
N=0.025
V=0.025 x 22.4=0.56L
what role does the grass play in the food web?
A. Producer B. Primary Consumer C. secondary Consumer D. Decomposer
Answers
Answer:
Producer
Explanation:
I took the test :)
Estimate the solubility of barium fluoride, BaF2, in a 0.100 M solution of barium nitrate, Ba(NO3)2, given that the K sp of BaF2 is 2.45×10-5.
A)7.83×10-3 M
B)1.57×10-2 M
C)7.83×10-4 M
D)2.45×10-4 M
Answers
Answer:
A) 7.83 x 10^-3 M
Explanation:
7.83 x 10⁻³ M is the solubility of barium fluoride, BaF[tex]_2[/tex], in a 0.100 M solution of barium nitrate, Ba(NO[tex]_3[/tex])[tex]_2[/tex], given that the K sp of BaF[tex]_2[/tex]is 2.45×10-5. The correct option is option A.
What is solubility?The ability of a material, the solute, to combine with some other substance, the solvent, is known as solubility in chemistry. Insolubility, or the solute's inability to create such a solution, is the opposite attribute. The concentration of a solute inside a saturated solution is typically used to determine how much of a substance is soluble in a certain solvent.
The two compounds are said to be just at solubility equilibrium at this time. There might not be a limit for some solutes or solvents, in which case they two are referred to as "miscible in any quantities." Whereas the solvent is often solid or liquid, the solute may be either a solid, liquid, or gas.
BaF[tex]_2[/tex]=0.100 M
Ba(NO[tex]_3[/tex])[tex]_2[/tex]=0.100 M
K sp of BaF[tex]_2[/tex]=2.45×10⁻⁵
solubility of barium fluoride=2.45×10⁻⁵×0.100 =7.83 x 10⁻³ M
Therefore, the correct option is option A.
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Which layer of the Earth includes the crust? a atmosphere b hydrosphere c asthenosphere d lithosphere
Answers
Answer:
D
Explanation:
Hope that helps :)
What mass of nitrogen (N2) is needed to produce 0.125 mol of ammonia (NH3)? Input a numerical answer only. N2 + 3H2 ---> 2NH:
Please help me
Answers
98 KB
Very sorry if this is wrong!
Suppose you have a 1:1:1 by weight mixture of three solid compounds, salicylic acid 4-nitroaniline naphthalene. You dissolve 1 gram of this mixture in diethyl ether, and place a tiny drop of the ether solution on a TLC plate. After developing the TLC plate, you see three spots. Which compound would would you expect to have the largest Rf value
Answers
Answer:
The correct answer is - 4-nitroaniline.
Explanation:
It is given that all three solid compounds salicylic acid + 4-nitroaniline + naphthalene are equal in the ratio in the mixture and then 1 gram of this mixture is dissolved in the diethyl ether and run a drop of the solution on TLC plate. This plate shows three spots.
The salicylic acid and naphthalene would stay dissolved in the diethyl ether solution due to the 4-nitroaniline could be extracted by adding aqueous acid and involve in the aqueous layer and thus spot of 4-nitroaniline would be with largest Rf value.
Which energy source produces less negative
environmental impacts
A)Renewable Energy Sources
B)Fossil Fuels
Help
Answers
Answer:
A)Renewable Energy Sources
Explanation:
Question List
Question 4 of 8
Total Points: 0 out of 80
Calculate the volume that will be occupied by
240 mL of hydrogen, measured at 360 mm Hg, when
the pressure is changed to 1080 mm Hg.
Answers
Answer:
80 mL
Explanation:
Step 1: Given data
Initial pressure of hydrogen (P₁): 360 mmHgInitial volume of hydrogen (V₁): 240 mLFinal pressure of hydrogen (P₂): 1080 mmHgFinal volume of hydrogen (V₂): ?Step 2: Calculate the final volume of hydrogen
If we assume ideal behavior and constant temperature, we can calculate the final volume occupied by hydrogen using Boyle's law.
P₁ × V₁ = P₂ × V₂
V₂ = P₁ × V₁/P₂
V₂ = 360 mmHg × 240 mL/1080 mmHg = 80 mL
Sodium acetate never precipitates
True or False?
Answers
Answer:
it is false Sodium acetate NEVER precipitates
Answer:
It is indeed true, Sodium acetate never precipitates
2 Nal + Pb(NO3)2
2 NaNO3
+
Pb12
What are the reactants in this equation?
Answers
Answer:
[tex]\boxed {\boxed {\sf A. \ NaI \ and \ Pb(NO_3)_2}}[/tex]
Explanation:
In a chemical reaction, the reactants are the substances that start the reaction and change into other substances. The results at the end of the reaction are products.
Typically, the reactants are to the left of the arrow, while products are to the right.
reactants ⇒ productsWe are given this chemical equation:
[tex]2 \ NaI + Pb(NO_3)_2 \rightarrow 2NaNO_3 +PbI_2[/tex]
We are asked to find the reactants. Remember, these go into the reaction and are on the left.
[tex]\bold {2 \ NaI + Pb(NO_3)_2 } \rightarrow 2NaNO_3 +PbI_2[/tex]
Therefore, the reactants are NaI (sodium iodide) and Pb(NO₃)₂ (lead nitrate). Choice A is correct.