Phosgene (Cl2CO), a poison gas used in World War I , is formed by the reaction of Cl2 and CO. The proposed mechanism for the reaction is

Cl2⇌2Cl(fast,equilibrium)

Cl+CO⇌ClCO(fast,equilibrium)

ClCO+Cl2→Cl2CO+Cl(slow)


What rate law is consistent with this mechanism?

Answers

Answer 1

Answer:

Rate = k [ClCO][Cl2]

Explanation:

Cl2⇌2Cl(fast,equilibrium)

Cl+CO⇌ClCO(fast,equilibrium)

ClCO+Cl2→Cl2CO+Cl(slow)

The rate determining step from which the rate aw is obtained from is the slowest step of a chemical reaction. In this reaction, the slowest step is;

ClCO+Cl2 → Cl2CO+Cl (slow)

The rate equation for the step is;

Rate = k [ClCO][Cl2]

ClCO is an intermediate and would eventually get cancelled out from the overall rate equation.

Answer 2

Phosgene is the chemical used in the formation of pesticides and ios poisonous. The rate law is given as, k [chloroformylradical][chlorine gas].

What is rate law?

The rate law is the relation of the concentration of the reactants and the products with that the speed of the reaction.

The reaction for the formation of phosgene is given as,

[tex]\rm Cl_{2} \rightleftharpoons 2Cl\; (fast,equilibrium)\\\\\rm Cl+CO \rightleftharpoons ClCO\; (fast,equilibrium)\\\\\\rm ClCO+Cl_{2}\rightarrow Cl_{2} CO+Cl\; (slow)[/tex]

The rate law is determined by the rate-determining step which is the slowest step of the reaction.

[tex]\rm ClCO+Cl_{2}\rightarrow Cl_{2} CO+Cl\; (slow)[/tex]

The rate of the equation is given as,

[tex]\rm Rate = k [ClCO][Cl_{2}][/tex]

As COCl is an intermediate the third step will be the rate-determining step.

Therefore, the slow step determines the rate of the reaction.

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Related Questions

calculate the volume of an object with dimensions measuring 3.o cm x 4.0 cm x 1.0 cm
?cm^3

Answers

Answer:

12cm^3

Explanation:

to find the volume you multiply each dimension

1x3x4=12

is scrap metal pieces an example of a pure substance or a mixture ?

Answers

Answer:

mixture i think

Explanation:

Answer:

mixture

Explanation:

CHAPTER
CHAPTER ASSESSMENT
Understanding Main Ideas (Part A)
In the space at the left, write true if the statement is true; if the statement is false,
change the italicized term to make it true.
1. The overall charge of a formula unit for a compound is never zero.
2. In a crystal lattice, each positive ion is surrounded by negative ions.
3. Delocalized valence electrons are typical of ionic compounds.
4. A sulfate ion contains fewer oxygen atoms than a sulfite ion does.
true
5. Metals tend to be malleable and ductile and to have relatively high
melting points.
6. The more negative the lattice energy is, the stronger is the force of
attraction between the ions of an ionic compound.
7. In naming ionic compounds, the cation is named first.
8. When a metal reacts with a nonmetal, the metal tends to gain electrons.
9. In naming a monatomic anion, the suffix -ide is used.
10. The prefix per- is used in naming the anion with the most oxygen atoms.

Answers

Answer:

The answer is in correct

List the phase changes that result of an increase of molecular kinetic energy pls help!! 30 points!

Answers

Answer:

Explanation:

The term change of phase means the same thing as the term change of state. ... i.e. during phase change, the energy supplied is used only to separate the molecules ; no part of it is used to increase the kinetic energy of the molecules. So its temperature will not rise, since kinetic energy of molecules remains the same.

Using the partial periodic table, which statement is correct?

*Oxygen (O) has more protons than chlorine (Cl).

*Iron (Fe) has more protons than silver (Ag).

*Sodium (Na) has more protons than carbon (C).

*Hydrogen (H) has more protons than helium (He).

Answers

Answer:

Sodium (Na) has more protons than carbon (C).

hope that helps!

Analyze the given diagram of the carbon cycle below. Use complete sentences to explain your answer.
Part 1: Which process does arrow F represent?
Part 2: Explain how matter is conserved during the process.
Part 3: Justify why this process is a recycling of carbon in the carbon cycle.

Answers

Answer:

I'm not to sure I'll ask one of my frens to help

Solid to Gas

As a change is state takes place, heat _______ and temperature _______.

A. Increases, stay the same
B. Stay the same, changes
C. Increases, increases

Answers

Answer:

c. c. c c c c c cçcc. ccccccccc

Explanation:

ccc cc

When solid converts to gas then heat is required to break the intermolecular forces of attraction between the particles. In this process heat increase but temperature remains the same. So option A is correct option.

What is phase transition?

Phase transition is a process in which transition takes place from one state to another of a medium on changing temperature or pressure.  Phase transition is a physical process as there is no breaking of old bond and forming of new bonds takes place.

During phase transition temperature remain constant as the extra heat that is given to the system that goes into breaking of  intermolecular forces of attraction between the particles. So overall temperature remains same but heat keeps on increasing. Hence option A is correct.

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BRIANLIEST!!!!!!
Use the mass to calculate the number of moles in a 347.89 g samples of ammonium

Answers

Answer:

20.46 moles

Explanation:

1 mole of NH3 contains 17gm of NH3

so 347.89 gm of ammonia is in,

347.89/17 moles

=20.46 moles

NOTE. There should be ammonia instead of ammonium in question because ammonium is an ion not a compound.

3. Charles Law: What is the volume of the air in a Helium balloon that has 135 mL at 67.6 degrees
Fahrenheit if the temperature is raised to 100. degrees Fahrenheit?

Answers

Answer:

199.7mL

Explanation:

Using Charles law equation as follows:

V1/T1 = V2/T2

Where;

V1 = initial volume (mL)

T1 = initial temperature (°F)

V2 = final volume (mL)

T2 = final temperature (°F)

According to the information provided in this question, V1 = 135mL, V2 = ?, T1 = 67.6°F, T2 = 100°F

Using V1/T1 = V2/T2

135/67.6 = V2/100

Cross multiply

135 × 100 = 67.6 × V2

13500 = 67.6V2

V2 = 13500/67.6

V2 = 199.704

The new volume in the air in the helium ballon is 199.7mL.

Answer:

199.7ml

explain;

math

An ice cube, a glass of cold water, and a swimming pool are each exposed to the same amount of sunlight on a hot day. After five minutes, the ice cube is
melted and the cold drink is two degrees warmer, but the temperature of the swimming pool remains unchanged. What is the best explanation for these
observations?
A. The ice cube has a higher heat capacity than the glass of water and the pool.
B. The ice cube has a lower heat capacity than the glass of water and the pool.
C. The ice cube and the glass of water have higher heat capacities than the swimming pool.
D. The ice cube and the glass of water have lower heat capacities than the swimming pool.

Answers

Answer:

D

Explanation:

sana makatulong huhu follow me thanks

Answer:

C. the ice cube and the glass of water have higher heat capacity than the swimming pool

What are calories used for?

hurry pls!

Answers

Answer:

Calories are used for physical activity.

Explanation:

Calories provide energy for consumers. You may notice when you drink or eat, you gain more energy. This is because calories are stored in our drinks and foods.

Answer:

They are

Explanation:

They are used to make people obese. The government uses calories to make people weak and unhealthy. For example, McDonalds is known to have many calories in their food. I hate the government.

Q11
1 point
4.8 g of Magnesium reacts with 3.2g of oxygen.
Choose the correct mass of oxygen that will react with 48g of Magnesium?
68g
18g
32g
36g

Answers

Answer:

Amount of oxygen react with 48 g of magnesium = 32 gram

Explanation:

Given:

Amount of oxygen react with 4.8 g of magnesium = 3.2 g

Find:

Amount of oxygen react with 48 g of magnesium

Computation:

Using Law of equal proportion;

Amount of oxygen react with 48 g of magnesium = 48(3.2/4.8)

Amount of oxygen react with 48 g of magnesium = 32 gram

The shade or pigment of a mineral is known as
Luster
Hardness
Density
Streak
O Color

Answers

Answer:

Streak

Explanation:

The streak of a mineral is the color of the powder produced when it is dragged across an un-weathered surface.

the answer is 4. Streak

help me pleaseeeeeeeeeeeeeeeeeeeeeeeeee

Answers

Carbon dioxide
Is what it should be

Answer: nitrogen

Explanation:

How many moles of Aluminum are in 54.0 grams of Aluminum (Al)?

Answers

Answer: 2 moles

Explanation:

AM of Al 27

Which statement describes why the viscosity of water is lower than that of
olive oil?
A. The molecules that make up water have more kinetic energy than
the molecules that make up olive oil.
B. The molecules that make up water can more easily slide past one
another than the molecules that make up olive oil.
C. The molecules that make up water have less kinetic energy than
the molecules that make up olive oil.
D. The molecules that make up water are larger than the molecules

Answers

Answer:

Option B. The molecules that make up water can more easily slide past one another than the molecules that make up a olive oil.

The molecules that make up water can more easily slide past one another than the molecules that make up olive oil. Hence, option B is correct.

What is viscosity?

Viscosity is a term used to describe FLUIDS, which includes liquids and gases. Viscosity refers to the ability of a gas or liquid to resist flow.

Olive oil has a higher viscosity than water because it is a much larger molecule than water with larger dispersion forces.

Hence, option B is correct.

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Two students performed a lab to see how the density and salinity of water are related. Both beakers began with the same salinity level. Beaker A was left alone, and B was placed under a heat lamp. Students will check the salinity level in the water after a day. The results of the investigation showed that…

Answers

Answer: the water avaperatid

because of the heat lamp

hope this helps

Explanation:

The chemical reaction shown is called photosynthesis. It involves water reacting with carbon
dioxide to produce glucose (see formulae below) and another gas. The chlorophyll in leaves
acts as a catalyst. ON A PIECE OF PAPER. Write a (BN level) word equation. (G Level)
Equation with formulae. (P-E) Balanced chemical equation with states.*
CoH1206

Answers

Answer:

See explanation

Explanation:

A word equation refers to a representation of a chemical process using word rather than appropriate chemical formulae.

Hence, the word equation for photosynthesis is this;

six moles of carbon dioxide + six moles of water -----> one mole of glucose + six moles of oxygen gas

The equation with formulae is;

6CO2 + 6H20 -------> C6H1206 + 6O2

Balanced chemical equation with states;

6CO2(g) + 6H20(l) -------> C6H1206(s) + 6O2(g)

can someone plz help me im running out of time !!!!

Balance the chemical equation below using the smallest possible whole number
stoichiometric coefficients.

Q1= C(s)+H2(g) -> C2H6(g)
Q2= NH3(g)+O2(g)-> HCN(aq)+H2O(l)

Answers

Answer:

1. C(2)+H2(1) -> C2H6(1)

2. NH3(2)+O2(3)-> HCN(2)+H2O(3)

I am not sure about the second one.

Use the half reaction method to balance the following reaction in acid:

I2 + Na2S2O3 -> Na2S2O4 + NaI

Answers

Answer:

I2 + 2S2O3^2- --------> S4O6^2- + 2I^-

Explanation:

The correct equation is;

2Na2S2O3 + I2 → Na2S4O6 + 2NaI

Oxidation half equation;

2S2O3^2- --------> S4O6^2- + 2e-

Reduction half equation;

I2 + 2e ----------> 2I^-

Overall balanced redox reaction equation;

I2 + 2S2O3^2- --------> S4O6^2- + 2I^-

Picture a neutral S atom. This neutral atom will have
valence electrons. To reach a more stable configuration, this atom will
(gain, lose) electrons. The charge of the ion that forms will be
ASAP PLEASE

Answers

Answer:

has 6 valence electrons as its in group 6

the atom will gain electrons

the charge will be 2- as it will gain 2 electrons to be a full configuration

Plz answer the question in the picture.

Answers

Answer:

a

Explanation:

a mixture is a material made up of two or more different substances which are not chemically combined. A mixture is the physical combination of two or more substances in which the identities are retained and are mixed in the form of solutions, suspensions and colloids.

Answer:

A digram show mixture

Because mixture is formed by simple mixing of many substances

And figure A shows different substances

Explanation:

Select all that are compounds.
H2O
CH4
He
O2
NaCl

Answers

Answer:

NaCl, H2O

Explanation:

Compounds are substances that contain atoms of two or more different elements.

NaCL , H2O ...........

Explain how the transfer of heat causes air to rise?
plzzzzzz help mee
also friction is not the answer

Answers

Answer:

Air in the atmosphere acts as a fluid. The sun's radiation strikes the ground, thus warming the rocks. As the rock's temperature rises due to conduction, heat energy is released into the atmosphere, forming a bubble of air which is warmer than the surrounding air. This bubble of air rises into the atmosphere.

Explanation:

I hope this helps and pls mark me brainliest :)

please help
find the impractical formula of the compound that contains 46.6 g of magnesium 61.4 g of sulfur and 92.0 g of oxygen. type subscripts for each element

Answers

Answer: The empirical formula is [tex]MgSO_3[/tex]

Explanation:

Mass of Mg= 46.6 g

Mass of S= 61.4 g

Mass of O = 92.0 g

Step 1 : convert given masses into moles.

Moles of Mg =[tex]\frac{\text{ given mass of Mg}}{\text{ molar mass of Mg}}= \frac{46.6g}{24g/mole}=1.942moles[/tex]

Moles of S =[tex]\frac{\text{ given mass of S}}{\text{ molar mass of S}}= \frac{61.4g}{32g/mole}=1.918moles[/tex]

Moles of O =[tex]\frac{\text{ given mass of O}}{\text{ molar mass of O}}= \frac{92.0g}{16g/mole}=5.75moles[/tex]

Step 2 : For the mole ratio, divide each value of moles by the smallest number of moles calculated.

For Mg = [tex]\frac{1.942}{1.918}=[/tex]

For S= [tex]\frac{1.918}{1.918}=1[/tex]

For O =[tex]\frac{5.75}{1.918}=3[/tex]

The ratio of Mg: S: O = 1: 1: 3

Hence the empirical formula is [tex]MgSO_3[/tex]

How many moles of NaF are produced in the resction between sodium bromide and calcium fluoride when 550 grams of sodium bromide are used

Answers

Answer: 5 moles of NaF would be produced when 550 grams of Sodium bromide are used.

Explanation:

From the question, the balanced chemical formula is illustrated below:

2NaBr + CaF2 → 2NaF + CaBr2

From the equation above;

Molecular mass of NaBr = 23 + 80 = 103g/ mol

Molecular mass of CaF2= 40+ (19×2)= 78g/ mol

Molecular mass of NaF = 23+19 = 42g/ mol

From the balanced chemical equation;

2 moles of NaBr reacted with 1mole of CaF to give 2 moles of NaF.

That is, 2 moles of NaBr= 2× 103 = 206g

2moles of NaF = 2×42= 84g

If 206g of NaBr yielded 84g of NaF

Therefore 550g of NaBr will yield Xg of NaF

X= 550×84/206

X= 224.27g of NaF

But 42g = 1 mole of NaF

Therefore 224.27g = X mole of NaF

X= 224.27 ×1/42

X is approximately 5moles.

Help please! This is due in 15 mins

Answers

9 Total atoms
Four hydrogen atoms
Four oxygen atoms
9 total atoms

In the following compound (HCl) How many electrons are gained and lost by each atom?
In the following compound (NaCl) How many electrons are gained and lost by each atom

Answers

Explanation:

In HCL, one positive atom is given to chlorine from hydrogen so that it can complete it's octate. chlorine take one electron from hydrogen.

In NaCl, Sodium takes one electron from chlorine to complete its orbit with eight electrons. Chlorine gives one electron to sodium.

The substance(s) to the left of the arrow in a chemical equation are called reactants. A reactant is a substance that is present at the start of a chemical reaction. ... A product is a substance that is present at the end of a chemical reaction.

Answers

Answer:

✓ Reactants

✓Reactants

✓ product

Explanation:

The substance(s) to the left of the arrow in a chemical equation are called ..................

A ............... is a substance that is present at the start of a chemical reaction.

A ................. is a substance that is present at the end of a chemical reaction.

Reactants are substances that undergo chemical reaction and are present at the beginning of the reaction and are consumed during the process of the reaction to form a product.

2H2 + O2 ------>2H2O

Here H2 and O2 are Reactants while water H2O is the product ( water)

Products are species that are produced after the chemical reaction have taken place.

200cm3 of hydrogen diffused through a porous pot in 40secs. How long will it take 300cm3 of chlorine to diffuse the same pot?

Answers

Answer: time taken by chlorine to diffuse is 60 secs
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