Help, 8th grade Science

Help, 8th Grade Science

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Answer 1
It’s for sure control container

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What is the most highly populated rotational level of Cl2 (i) 25deg C and (ii) 100 deg C? Take B=0.244cm-1.This question should not be resubmitted, it is a textbook question from the Atkins physical chemistry txtbook. 10 e.

Answers

Answer:

i

[tex]J_{m} = 20 [/tex]

ii

[tex]J_{m} = 22.5 [/tex]

Explanation:

From the question we are told that

  The first temperatures is [tex]T_1 =  25^oC =  25 +273 =298 \ K[/tex]

   The second temperature is  [tex]T_2 =  100^oC =  100 +273 = 373 \ K[/tex]

Generally the equation for  the most highly populated rotational energy level is mathematically represented as

     [tex]J_{m} = [ \frac{RT}{2B}]  ^{\frac{1}{2} } - \frac{1}{2}[/tex]

Here R is the gas constant with value [tex]R =8.314 \ J\cdot K^{-1} \cdot mol^{-1}[/tex]

Also  

      B is given as [tex]B=\ 0.244 \ cm^{-1}[/tex]

   Generally the energy require per mole to move 1 cm is  12 J /mole

So   [tex]0.244 \ cm^{-1}[/tex]  will require x J/mole

           [tex]x =  0.244 *  12[/tex]

=>          [tex]x =  2.928 \ J/mol [/tex]

So at the first temperature

     [tex]J_{m} = [ \frac{8.314 * 298  }{2*  2.928 }]  ^{\frac{1}{2} } - 0.5 [/tex]

=>  [tex]J_{m} = 20 [/tex]

So at the second temperature

           [tex]J_{m} = [ \frac{8.314 * 373  }{2*  2.928 }]  ^{\frac{1}{2} } - 0.5 [/tex]

=>  [tex]J_{m} = 22.5 [/tex]

In the laboratory you dissolve 18.7 g of copper(II) bromide in a volumetric flask and add water to a total volume of 375mL.

Required:
a. What is the molarity of the solution?
b. What is the concentration of the copper(II) cation?
c. What is the concentration of the acetate anion?

Answers

Answer:

a) - 0.2 M

b) - 0.2 M

c)- 0

Explanation:

The chemical formula of copper (II) bromide is CuBr₂. Its molar mass (MM) is calculated as follows:

MM(CuBr₂)= MM(Cu) + (2 x MM(Br) = 63.5 g/mol + (2 x 80 g/mol)= 223.5 g/mol

a). Molarity = moles CuBr₂/1 L solution

moles CuBr₂ = mass/MM = 18.7 g x 1 mol/223.5 g = 0.084 mol

Volume in L = 375 mL x 1 L/1000 mL = 0.375 L

M = 0.084 mol/(0.375 L) = 0.223 M ≅ 0.2 M

b). When is added to water, CuBr₂ dissociates into ions as follows:

CuBr₂ ⇒ Cu²⁺ + 2 Br⁻

We have 1 mol Cu²⁺ (copper (II) cation) per mol of CuBr₂. Thus, the concentration of copper (II) cation is:

0.2 mol CuBr₂ x 1 mol Cu²⁺/mol CuBr₂ = 0.2 M

c). The concentration of acetate anion is 0. There is no acetate anion in the solution (the anion from CuBr₂ is bromide Br⁻).

Solid diarsenic trioxide reacts with fluorine gas (F2) to produce liquid arsenic pentafluoride and oxygen gas (O2). Write the Qc for this reaction.

Answers

Answer:

QC= [O2]^3/[F2]^10

Explanation:

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