Answer:
4.2g of gasoline
Explanation:
In the problem, you need to give energy to the cup from the combustion of gasoline. The energy you need to give is:
Qcup + QWater + QCopper
As you need to increase (110ºC - 21ºC = 89º = Increase 89K) 89K, the Qcup is:
Qcup = 89K × (47J/K) = 4183J.
You can find Qwater using its specific heat, C (4.18Jg⁻¹K⁻¹), its mass (450mL = 450g) and the change of temperature, 89K:
QWater = CₓmₓΔT
QWater = 4.184Jg⁻¹K⁻¹ ₓ 450g×89K
QWater = 167569J
And Q of Copper, QCu, could be obtained in the same way (Specific heat Cu: 0.387 J/g⁻¹K⁻¹:
QCu = CₓmₓΔT
QCu = 0.387 J/g⁻¹K⁻¹ₓ850gₓ89K
QCu = 29277J
Thus, total heat you need is:
Q = Qcup + QWater + QCopper
Q = 4183J + 167569J + 29277J
Q = 201029J = 201kJ
The combustion of gasoline (Octane) produce 47.8kJ/g (Its heat of combustion). that means to produce 201kJ of energy you require:
201kJ × (1g / 47.8kJ) =
4.2g of octane = Gasoline you requireA compound has a mass percentage of 53.46% C, 6.98% H, and 39.56% O. What is the empirical formula for this compound
Answer:
The empirical formula is: C₂H₃O
Explanation:
The empirical formula, also known as the “minimum formula”, is the simplest expression to represent a chemical compound and indicates the elements that are present and the minimum integer ratio between its atoms.
The percentage composition is the percentage by mass of each of the elements present in a compound.
Having 100 g of the compound as a base, it is possible to express the percentages in grams. That is, assuming you have 100 g of the compound, you have 53.46 g of C , 6.98 g of H , and 39.56 g of O.
Taking into account the molecular mass of each substance, the number of relative atoms of each chemical element is calculated:
C: [tex]53.46 g *\frac{1 mol}{12.01 g } = 4.45 moles[/tex]
H:[tex]6.98 g *\frac{1 mol}{1.01 g } = 6.91 moles[/tex]
O:[tex]39.56 g *\frac{1 mol}{16g } = 2.47 moles[/tex]
Now you divide each value obtained by the least of them:
C: [tex]\frac{4.45 moles}{2.47 moles}= 1.80[/tex]
H:[tex]\frac{6.91 moles}{2.47 moles}= 2.8[/tex]
O:[tex]\frac{2.47 moles}{2.47 moles}=1[/tex]
Decimals approach the nearest integer, then:
C: 2
H: 3
O: 1
Therefore the empirical formula is: C₂H₃O
Answer: The other guy is wrong. The correct answer is C9H14O5
Explanation:
et the mass percentages from the percent composition represent grams in a total mass of 100g. Use the grams to calculate the number of moles of each atom present.
%C:53.46%molC=53.46gC=53.46gC×1molC12.011gC=4.451molC
%H:6.98%molH=6.98gH=6.98gH×1molH1.008gH=6.924molH
%O:39.56%molO=39.56gO=39.56gO×1molO15.999gO=2.473molO
Divide by the smallest number of moles.
subscriptC=4.451molC2.473molO≈1.800≈95
subscriptH=6.924molH2.473molO≈2.800≈145
subscriptO=2.473molO2.473molO=1
Now, multiply each subscript by 5 to achieve whole number subscripts. Therefore, the empirical formula is C9H14O5.
. A compound X, containing C, H, and O was found to have a relative molar mass of 6o
whilst 20.0g of X contained 8.0g of C and 1.33g of H. Calculate the empirical formula
of compound X, and hence determine its molecule formula. show calculation
Answer:
empirical formula = CH2O
molecular formula = C2H4O2
2) Which type movement do pivot joints allow?
Do you think you could go a week without causing any chemical reactions?
yes yes yes yes
yes
yes
yes
yes
yes
A sample of gold weighs 1.2 oz. The sample is pounded into a thin rectangular sheet with an area of 400. sq. ft. The density of gold is 19.3 grams per cm3. What is the thickness of the foil in centimeters?Given: 28.35 g = 1 oz, 1 ft = 12 inches, 1 inch = 2.54 cm
Answer:
thickness of the gold sheet = 4.74 * 10⁻⁶ cm
Explanation:
mass of gold sample = 1.2 oz,; area of rectangular gold sheet = 400 sq. ft
Converting mass of gold from oz. to g
1 oz. = 28.35 g
mass of gold sample in grams = 1.2 * 28.35 g = 34.02 g
Converting from feet to cm;
1 feet = 12 * 2.54 cm = 30.48 cm
1 sq. ft = (30.48)² = 929.0304 cm²
area of gold in cm² = 400 * 929.0304 cm² = 371612.16 cm²
Since the density of a solid is constant
Density = mass/volume
Volume = mass/density
where volume =area * thickness
therefore, area * thickness =mass/density
thickness = mass/(density * area)
substituting the value; thickness = 34.02 g/(19.3 gcm⁻³ *371612.16 cm²)
thickness of the gold sheet = 4.74 * 10⁻⁶ cm
Steam reforming of methane ( ) produces "synthesis gas," a mixture of carbon monoxide gas and hydrogen gas, which is the starting point for many important industrial chemical syntheses. An industrial chemist studying this reaction fills a tank with of methane gas and of water vapor, and when the mixture has come to equilibrium measures the amount of carbon monoxide gas to be .Calculate the concentration equilibrium constant for the steam reforming of methane at the final temperature of the mixture. Round your answer to significant digits.
The given question is incomplete, the complete question is:
Calculating an equilibrium constant from a partial equilibrium... Steam reforming of methane (CH) produces "synthesis gas," a mixture of carbon monoxide gas and hydrogen gas, which is the starting point for many important industrial chemical syntheses. An industrial chemist studying this reaction fills a 25.0L tank with 8.0 mol of methane gas and 1.9 mol of water vapor, and when the mixture has come to equilibrium measures the amount of carbon monoxide gas to be 1.5 mol. Calculate the concentration equilibrium constant for the steam reforming of methane at the final temperature of the mixture. Round your answer to 2 significant digits.
Answer:
The correct answer is 2.47.
Explanation:
Based on the given information, the equation for the synthesis gas is,
CH₄ (g) + H₂O (g) ⇔ CO (g) + 3H₂ (g)
Based on the given information, 25.0 L is the volume of the tank, the concentration of CH₄ is 8.0 mol, the concentration of water vapor is 1.9 mol, and the concentration of CO gas is 1.5 mol.
Therefore, 25 L of the solution comprise 8.0 mole of CH₄. So, 1 L of the solution will comprise 8.0 / 25 mole CH₄,
= 0.32 mole of CH₄
Thus, the concentration of CH₄ or [CH₄] will be 0.32 mole/L or 0.32 M.
Similarly, the concentration of H₂O or [H₂O] will be 1.9/25 = 0.076 M
and [CO] is 1.5/25 = 0.06 M
The concentration equilibrium constant for the steam will be,
Kc = [CO] pH₂ / [CH₄] [H₂O] (Here pH₂ is the partial pressure of H₂)
Now lets us assume that the reaction has taken place in a constant atmospheric pressure, therefore, pH₂ will be equal to 1.
= 0.06 M/0.32 M × 0.076 M
= 2.47
Define dew point in complete sentences
A piece of bismuth with a mass of 22.5 g is submerged in 46.3 cm3 of water in a graduated cylinder. The water level increases to 48.6 cm3. What is the density of indium to the proper number of significant figures
Answer:
[tex]\rho = 9.78\frac{g}{cm^3}[/tex]
Explanation:
Hello,
In this case, in order to compute the density of bismuth we need to apply the formula:
[tex]\rho =\frac{m_{Bi}}{V_{Bi}}[/tex]
Nonetheless, the volume is computed by the difference:
[tex]V_{Bi}=48.6-46.3=2.30cm^3[/tex]
Therefore:
[tex]\rho = \frac{22.5g}{2.30cm^300}\\\\\rho = 9.78\frac{g}{cm^3}[/tex]
Regards.
When solutions of hydrochloric acid and sodium hydroxide are mixed, a chemical reaction occurs forming aqueous sodium chloride and water. What would you expect to observe if you ran the reaction in the laboratory
Answer:
a change in temperature would be observed(ΔH is -ve)
Explanation:
Hydrochloric acid react with sodium hydroxide to give salt(sodium chloride) and water
HCl(aq) + NaOH(aq) =====> NaCl(aq) + H2O(l)
There would be no notable change since sodium chloride dissolved in water but there would be a change in temperature.
Since neutralization is exothermic(heat is evolved), therefore ΔH is negative
Consider the equilibrium reaction. 4A+B↽−−⇀3C After multiplying the reaction by a factor of 2, what is the new equilibrium equation?
Enter an equation for the formation of CaCO3(s) from its elements in their standard states. Enter any reference to carbon as C(s). Express your answer as a chemical equation. Identify all of the phases in your answer.
Answer:
CaF2 + CO3- ----> CaCO3 + 2 F-
Explanation:
The chemical compounds found on the left side of the date are the reagents and those found on the right are the products, where calcium carbonate appears.
Calcium carbonate is a quaternary salt
A buffer solution is all of the following EXCEPT: a solution that contains both a weak acid and its conjugate base. a solution that resists a change in pH when a base is added. a solution that regulates pH because it is such a strong acid or base. a solution that resists a change in pH when an acid is added. All of the above are true.
Answer:
A SOLUTION THAT REGULATES pH BECAUSE IT IS SUCH A STRONG ACID OR BASE
Explanation:
A buffer solution is an aqueous solution consisting of a weak acid and its conjugate base. It is an aqueous solution used to keep the pH of solution at a nearly constant value in various chemical processes. It resists change in pH when either a strong acid or a strong base is added. So it is very essential in various chemical applications and even in the human body as the blood pH is kept in nearly constant value by the bicarbonate buffer system in conjunction with the kidneys. The buffer solution is able to keep this nearly constant range of values because of the equilibrium between the weak acid and its conjugate base. So therefore, the incorrect statement in the options is that buffer solution is a solution that regulates pH because it is such a strong acid or base. The other options are correct.
Which of the following best identifies where long-range order would be found?
ОООО
in amorphous solids
in crystalline solids
in thermal plasmas
in nonthermal plasmas
Answer:
in crystalline solids
Hope this answers your question, good luck
The crystalline solids represent the best identification where the long-range order should be found.
What are crystalline solids?Crystalline solids refer to the solid where the atoms, molecules should be make the arrangement. The smallest & repeated pattern of this solid should be called as the unit cell. The unit cell should be treated as the bricks in the wall which means it should be homogenous in the nature and repeated
Therefore, The crystalline solids represent the best identification where the long-range order should be found.
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Draw the structure 2 butylbutane
Answer:
please look at the picture below.
Explanation:
Select the oxidation reduction reactions??
Answer:
Explanation:
1 ) Cl₂ + ZnBr₂ = ZnCl₂ + Br₂
In this reaction , oxidation number of Cl decreases from 0 to -1 so it is reduced and oxidation number of Br increases from -1 to 0 so it is oxidised . Hence this reaction is oxidation - reduction reaction .
2 )
Pb( ClO₄)₂ + 2KI = PbI₂ + 2KClO₄
In this reaction oxidation number of none is changing so it is not an oxidation - reduction reaction.
3 )
CaCO₃ = CaO + CO₂
In this reaction also oxidation number of none is changing so it is not an oxidation - reduction reaction.
So only first reaction is oxidation - reduction reaction.
2nd option is correct.
Which correctly lists three characteristics of minerals?
solid, crystal structure, definite chemical composition
organic, crystal structure, definite chemical composition
human-made, solid, organic
crystal structure, definite chemical composition, human-made
Answer:a
Explanation:
The three characteristics of minerals are that they are solid, have definite crystal structure and definite chemical composition.
What are minerals?Minerals are defined as a chemical compound which has a well -defined composition and possesses a specific crystal structure.It occurs naturally in the pure form.
If a compound occurs naturally in different crystal structure then each structure is considered as a different mineral.The chemical composition of a mineral varies depending on the presence of small impurities which are present in small quantities.
Some minerals can have variable proportions of two or more chemical elements which occupy equivalent position in the crystal structure.It may also have variable composition which is split into separate species.
Physical properties of minerals include color,streak, luster,specific gravity and cleavage.
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The constant pressure molar heat capacity of argon, C_{p,m}C
p,m
, is
20.79\text{ J K}^{-1}\text{ mol}^{-1}20.79 J K
−1
mol
−1
at 298\text{ K}298 K. What
will be the value of the constant volume molar heat capacity of argon,
C_{V,m}C
V,m
, at this temperature?
Answer:
Constant-volume molar heat capacity of argon is 12.47 J K ⁻¹mol⁻¹
Explanation:
Argon is a monoatomic gas that behaves as an ideal gas at 298K.
Using the first law of thermodinamics you can obtain:
Work, Q, for constant pressure molar heat capacity,CP:
CP = (5/2)R
For constant-volume molar heat capacity,CV:
CV = (3/2)R
That means:
2CP/5 = 2CV/3
3/5 = CV / CP
As CP of Argon is 20.79 J K ⁻¹mol⁻¹, CV will be:
3/5 = CV / CP
3/5 = CV / 20.79 J K ⁻¹mol⁻¹
12.47 J K ⁻¹mol⁻¹ = CV
Constant-volume molar heat capacity of argon is 12.47 J K ⁻¹mol⁻¹How many moles of gaseous boron trifluoride, BF3, are contained in a 4.3410 L bulb at 788.0 K if the pressure is 1.220 atm What is the complete ground state electron configuration for the neon atom
Answer:
n= 0.08186
{He}2s^2 2p^6
Explanation:
PV=nRT
n=PV/RT
n= (1.220 atm)(4.3410 L) / (0.0821 atm*L/mol*K)(788.0 K)
n=0.08186
As for the electron configuration:
Ne:
{He} 2s^2 2p^6
or long hang:
1s^2 2s^2 2p^6
[tex][Ne]=1s^22s^22p^{10}[/tex]
Given:
A gaseous boron trifluoride in a 4.3410 L bulb at 788.0 K, if the pressure is 1.220 atm.Neon atom.To find:
The moles of gaseous boron trifluoride in a container.The electronic configuration of neon in the ground state.1.
The pressure of the gaseous boron trifluoride = P = 1.220 atm
The volume of the gas in bulb = V = 4.3410 L
The moles of the gaseous boron trifluoride = n
The temperature of gaseous boron trifluoride = T = 788.0 K
Using an ideal gas equation:
[tex]PV = nRT\\\\1.220 atm\times 4.3410 L=n\times 0.0821 atm L/mol K\times 788.0 K\\\\n=\frac{1.220 atm\times 4.3410 L}{0.0821 atm L/mol K\times 788.0 K}\\\\n=0.08186 mol[/tex]
The moles of gaseous boron trifluoride is 0.08186 moles.
2.
The atomic number of neon atom = 10
The electronic configuration in the ground state is the most stable arrangement of the electrons in the lowest energy levels.
The ground state electronic configuration of neon is:
[tex][Ne]=1s^22s^22p^{10}[/tex]
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The authors state in the general procedures that the reaction was monitored by TLC. How would this be done? What would you spot in each lane? How would you know the reaction was done?
Answer:
Thin Layer Chromatography (TLC) can be used to analyze chemical reactions. During this reaction monitoring, a typical TLC plate would have three spots: the reactant lane, the reaction mixture lane, and a "co-spot" where reaction product would be spotted directly on top of reactant.
The co-spot serves as a reference point and is vital for reactions where reactant and product have similar Rfs, and many other variations of eluent tracking.
To indicate completion of the reaction, the disappearance of a spot (usually the starting reactant) is observed.
Searches related to If 0.75 grams of iron (Fe) react according to the following reaction, how many grams of copper (Cu) will be produced? Fe + CuSO4 -> Cu + FeSO4
Answer:
0.83 g
Explanation:
Step 1: Write the balanced equation
Fe + CuSO₄ ⇒ Cu + FeSO₄
Step 2: Calculate the moles corresponding to 0.75 g of Fe
The molar mass of Fe is 55.85 g/mol.
[tex]0.75g \times \frac{1mol}{55.85g} = 0.013 mol[/tex]
Step 3: Calculate the moles of Cu produced from 0.013 moles of Fe
The molar ratio of Fe to Cu is 1:1. The moles of Cu produced are 1/1 × 0.013 mol = 0.013 mol.
Step 4: Calculate the mass corresponding to 0.013 moles of Cu
The molar mass of Cu is 63.55 g/mol.
[tex]0.013mol \times \frac{63.55g}{mol} = 0.83 g[/tex]
Answer:
If 0.75 grams of iron (Fe) react, 0.85 grams of copper (Cu) will be produced.
Explanation:
You know the following balanced reaction:
Fe + CuSO₄ ⇒ Cu + FeSO₄
By stoichiometry of the reaction (that is, the relationship between the amount of reagents and products in a chemical reaction), the following quantities react and are produced:
Fe: 1 moleCuSO₄: 1 moleCu: 1 moleFeSO₄: 1 moleBeing:
Fe: 55.85 g/moleCu: 63.54 g/moleS: 32 g/moleO: 16 g/molethe molar mass of the compounds participating in the reaction is:
Fe: 55.85 g/moleCuSO₄: 63.54 g/mole + 32 g/mole+ 4* 16 g/mole= 159.54 g/moleCu: 63.54 g/moleFeSO₄: 55.85 g/mole + 32 g/mole+ 4* 16 g/mole= 151.85 g/moleThen, by stoichiometry of the reaction, the amounts of reagent and product that participate in the reaction are:
Fe: 1 mole*55.85 g/mole= 55.85 gCuSO₄: 1 mole* 159.54 g/mole= 159.54 gCu: 1mole* 63.54 g/mole= 63.54 gFeSO₄: 1 mole* 151.85 g/mole= 151.85 gThen you can apply a rule of three as follows: if 55.85 grams of Fe produces 63.54 grams of Cu, 0.75 grams of Fe how much mass of Cu does it produce?
[tex]mass of Cu=\frac{0.75 grams of Fe*63.54 grams of Cu}{55.85 grams of Fe}[/tex]
mass of Cu= 0.85 grams
If 0.75 grams of iron (Fe) react, 0.85 grams of copper (Cu) will be produced.
A(n) _____ reaction occurs when an acid and a base are present in the same solution.
Answer:
The answer is Neutralization reaction
It occurs when an acid and a base are present in the same solution and react to form salt and water only
Hope this helps you
A critical reaction in the production of energy to do work or drive chemical reactions in biological systems is the hydrolysis of adenosine triphosphate, ATP, to adenosine diphosphate, ADP, as described by the reactionATP(aq)+ H2O(l) → ADP(aq)+ HPO4^-2 (aq)for which ΔGrxn = -30.5 kj/mol at 37.0C and pH 7.0. Required:a. Calculate the value of ΔGrxn in a biological cell in which [ATP] = 5.0 mM, [ADP] = 0.30 mM, and HPO4^-2= 5.0mMb. Is the hydrolysis of ATP spontaneous under these conditions?
Answer:
Δ [tex]G_{rxn}[/tex] = −51. 4 kJ/mol
However, since Δ [tex]G_{rxn}[/tex] is negative. The hydrolysis of ATP for this reaction is said to be spontaneous
Explanation:
From the question; The equation for this reaction can be represented as :
[tex]ATP_{(aq)} + H_2O_{(l)} \to ADP_{(aq)}+ HPO_4^{2-}} _{(aq)}[/tex]
where:
[tex]\Delta G ^0 _{rxn} =[/tex]-30.5 kJ/mol
= -30.5 kJ/mol × 1000 J/ 1 kJ
= -30.5 × 10 ⁻³ J/mol
Temperature T = 37 ° C
= (37+273)
= 310 K
pH = 7.0
[ATP] = 5.0 mM
= 5.0mM × 1M/1000mM
= 0.005 M
[ADP] = 0.30 mM
= 0.30 mM × 1M/1000mM
= 0.0003 M
[tex][HPO_4^{2-}}][/tex] = 5.0 mM
= 5.0mM × 1M/1000mM
= 0.005 M
The objective is to calculate the value for Δ [tex]G_{rxn}[/tex] in the biological cell and to determine if the hydrolysis of ATP is spontaneous under these conditions.
Now;
From the equation given; the equilibrium constant [tex]K_{eq}[/tex] can be expressed as:
[tex]K_{eq} = \dfrac{[ADP][ HPO_4^{2-}]} {[ATP]}[/tex]
[tex]K_{eq} = \dfrac{(0.0003 \ M)(0.005 \ M)} {(0.005 \ M)}[/tex]
[tex]K_{eq} = 3*10^{-4}[/tex]
The Δ [tex]G_{rxn}[/tex] in the biological cell can now be calculated as:
Δ [tex]G_{rxn}[/tex] = [tex](-30.5 * 10 ^3 \ J/mol) + (8.314 \ J/mol.K)(310 K ) In ( 3*10^{-4})[/tex]
Δ [tex]G_{rxn}[/tex] = [tex](-30.5 * 10 ^3 \ J/mol) + (-20906.68126)[/tex]
Δ [tex]G_{rxn}[/tex] = −51406.68 J/mol
Δ [tex]G_{rxn}[/tex] = −51. 4 × 10³ J/mol
Δ [tex]G_{rxn}[/tex] = −51. 4 kJ/mol
Thus since Δ [tex]G_{rxn}[/tex] is negative. The hydrolysis for this reaction is said to be spontaneous
The activation energy for the decomposition of HI is 183 kJ/mol. At 573 K, the rate constant was measured to be 2.91 x 10^{-6} M/s. At what temperature in Kelvin does the reaction have a rate constant of 0.0760 M/s
Answer:
[tex]T_2=453.05K[/tex]
Explanation:
Hello,
In this case, the temperature-variable Arrhenius equation is written as:
[tex]\frac{k(T_2)}{k(T_1)}=exp(\frac{Ea}{R}(\frac{1}{T_2}-\frac{1}{T_1} ))[/tex]
Now, for us to solve for the temperature by which the reaction rate constant is 0.0760M/s we proceed as shown below:
[tex]ln(\frac{k(T_2)}{k(T_1)})=\frac{Ea}{R}(\frac{1}{T_2}-\frac{1}{T_1} )\\ln(\frac{0.0760M/s}{0.00000291M/s} )=\frac{183000J/mol}{8.314J/(mol*K)} *(\frac{1}{T_2} -\frac{1}{573K} )\\\frac{1}{T_2} -\frac{1}{573K} =\frac{10.17}{22011.06K^{-1}} \\\\\frac{1}{T_2}=4.62x10^{-4}K^{-1}+\frac{1}{573K}\\\\\frac{1}{T_2}=2.21x10^{-3}K^{-1}\\\\T_2=453.05K[/tex]
Regards.
Perform the following
mathematical operation, and
report the answer to the correct
number of significant figures.
5.446 x 0.14156
Arrange the following set of atoms in order of decreasing atomic size: Sn, I, Sr
Which atom has the largest atomic size?
a) Sn
b) I
c) Sr
Which atom has the smallest atomic size?
a) Sn
b) I
c) Sr
Suppose that you add 26.7 g of an unknown molecular compound to 0.250 kg of benzene, which has a K f of 5.12 oC/m. With the added solute, you find that there is a freezing point depression of 2.74 oC compared to pure benzene. What is the molar mass of the unknown compound
Answer: The molar mass of the unknown compound is 200 g/mol
Explanation:
Depression in freezing point is given by:
[tex]\Delta T_f=i\times K_f\times m[/tex]
[tex]\Delta T_f=2.74^0C[/tex] = Depression in freezing point
i= vant hoff factor = 1 (for molecular compound)
[tex]K_f[/tex] = freezing point constant = [tex]5.12^0C/m[/tex]
m= molality
[tex]\Delta T_f=i\times K_f\times \frac{\text{mass of solute}}{\text{molar mass of solute}\times \text{weight of solvent in kg}}[/tex]
Weight of solvent (benzene)= 0.250 kg
Molar mass of solute = M g/mol
Mass of solute = 26.7 g
[tex]2.74^0C=1\times 5.12\times \frac{26.7g}{Mg/mol\times 0.250kg}[/tex]
[tex]M=200g/mol[/tex]
Thus the molar mass of the unknown compound is 200 g/mol
The molar mass of an unknown solute compound in the solution has been 199.626 g/mol.
With the addition of the solute to the solution, there has been a depression in the freezing point. The depression in the freezing point can be expressed as:
Depression in freezing point = Van't Hoff factor × Freezing point constant × molality
The molality can be defined as the moles of solute per kg solvent
Molaity = [tex]\rm \dfrac{Mass\;of\;solute\;(g)}{Molecular\;mass\;of\;solute}\;\times\;\dfrac{1}{Mass\;of\;solvent\;(kg)}[/tex]
The depression in freezing point can be given as:
Depression in freezing point = Van't Hoff factor × Freezing point constant × [tex]\rm \dfrac{Mass\;of\;solute\;(g)}{Molecular\;mass\;of\;solute}\;\times\;\dfrac{1}{Mass\;of\;solvent\;(kg)}[/tex] ......(i)
Given, the depression in freezing point = 2.74 [tex]\rm ^\circ C[/tex]
Van't Hoff factor = 1 (Molecular compound)
Freezing point constant (Kf) = 5.12 [tex]\rm ^\circ C[/tex]/m
Mass of solute = 26.7 g
Mass of solvent = 0.250 kg
Substituting the values in equation (i):
2.74 [tex]\rm ^\circ C[/tex] = 1 × 5.12
[tex]\rm \dfrac{2.74}{5.12}[/tex] = [tex]\rm \dfrac{1}{Molecular\;mass\;of\;solute}\;\times\;\dfrac{26.7}{0.250\;kg}[/tex]
0.535 = [tex]\rm \dfrac{1}{Molecular\;mass\;of\;solute}\;\times\;106.8[/tex]
Molecular mass of solute = [tex]\rm \dfrac{106.8}{0.535}[/tex] g/mol
Molecular mass of solute = 199.626 g/mol
The molar mass of an unknown solute compound in the solution has been 199.626 g/mol.
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Hypochlorous acid is formed in situ by reaction of aq. sodium hypochlorite solution with acetic acid. Draw balanced chemical equations to show the formation of hypochlorous acid and protonated hypochlorous acid.
Answer:
NaClO + CH₃COOH ----> HClO + CH3CO- + Na
Explanation:
This reaction occurs between the combination of a salt and an acid, that is, an oxide-reduction reaction
What is the main side reaction that competes with elimination when a primary alkyl halide is treated with alcoholic potassium hydroxide, and why does this reaction compete with elimination of a primary alkyl halide but not a tertiary alkyl halide
Answer:
The main competing reaction when a primary alkyl halide is treated with alcoholic potassium hydroxide is SN2 substitution.
Explanation:
The relative percentage of products of the reaction between an alkyl halide and alcoholic potassium hydroxide generally depends on the structure of the primary alkylhalide. The attacking nucleophile/base in this reaction is the alkoxide ion. Substitution by SN2 mechanism is a major competing reaction in the elimination reaction intended.
A more branched alkyl halide will yield an alkene product due to steric hindrance, similarly, a good nucleophile such as the alkoxide ion may favour SN2 substitution over the intended elimination (E2) reaction.
Both SN2 and E2 are concerted reaction mechanisms. They do not depend on the formation of a carbocation intermediate. Primary alkyl halides generally experience less steric hindrance in the transition state and do not form stable carbocations hence they cannot undergo E1 or SN1 reactions.
SN2 substitution cannot occur in a tertiary alkyl halides because the stability of tertiary carbocations favours the formation of a carbocation intermediate. The formation of this carbocation intermediate will lead to an SN1 or E1 mechanism. SN2 reactions is never observed for a tertiary alkyl halide due to steric crowding of the transition state. Also, with strong bases such as the alkoxide ion, elimination becomes the main reaction of tertiary alkyl halides.
warming oceans temperatures directly lead to all of the following except A sea level rising B coral bleaching C ocean deoxigenation D pollution
Answer:
D. pollution
Explanation:
Increase in ocean temperature is one of the major consequence of global warming which directly leads to rise in sea level, coral bleaching and ocean deoxygenation.
Warming ocean temperatures do not leads to pollution directly whereas pollution leads to warming ocean temperatures. So, in the case of pollution, the effect is opposite.
Hence, the correct option is D.
g A laboratory analysis of an unknown compound found the following composition: C 75.68% ; H 8.80% ; O 15.52%. What is the empirical formula of the compound?
Answer:
THE EMPIRICAL FORMULA FOR THE UNKNOWN COMPOUND IS C7H9O
Explanation:
The empirical formula for the unknown compound can be obtained by following the processes below:
1 . Write out the percentage composition of the individual elements in the compound
C = 75.68 %
H = 8.80 %
O = 15.52 %
2. Divide the percentage composition by the atomic masses of the elements
C = 75 .68 / 12 = 6.3066
H = 8.80 / 1 = 8.8000
O = 15.52 / 16 = 0.9700
3. Divide the individual results by the lowest values
C = 6.3066 / 0.9700 = 6.5016
H = 8.8000 / 0.9700 = 9.0722
O = 0.9700 / 0.9700 = 1
4. Round up the values to the whole number
C = 7
H = 9
O = 1
5 Write out the empirical formula for the compound
C7H90
In conclusion, the empirical formula for the unknown compound is therefore C7H9O