A niobium alloy is produced by introducing tungsten substitutional atoms into the BCC structure; eventually an alloy is produced that has a lattice parameter of 0.32554 nm and a density of 11.95 g/cm3. Calculate the fraction of the atoms in the alloy that are tungsten.

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Answer 1

To calculate the fraction of the atoms in the niobium alloy that are tungsten, we need to use the concept of lattice parameter and density.

The atomic radii of niobium and tungsten are different, which affects the lattice parameter. The substitution of tungsten atoms into a niobium lattice would cause an increase in the lattice parameter. This increase is related to the concentration of tungsten atoms in the alloy.

The relationship between lattice parameter and atomic radius can be described as:

a = 2^(1/2) * r

where a is the lattice parameter and r is the atomic radius.

Using the given lattice parameter of 0.32554 nm, we can calculate the atomic radius of the niobium-tungsten alloy as:

r = a / (2^(1/2)) = 0.2299 nm

The density of the alloy is given as 11.95 g/cm3. We can use this density and the atomic weight of niobium and tungsten to calculate the average atomic weight of the alloy as:

density = (mass / volume) = (n * A) / V

where n is the number of atoms, A is the average atomic weight, and V is the volume occupied by n atoms.

Rearranging the equation gives:

A = (density * V) / n

Assuming that the niobium-tungsten alloy contains only niobium and tungsten atoms, we can write:

A = (density * V) / (x * Na * Vc) + ((1 - x) * Nb * Vc))

where x is the fraction of atoms that are tungsten, Na is Avogadro's number, Vc is the volume of the unit cell, and Nb is the atomic weight of niobium.

We can simplify the equation by substituting the expression for Vc in terms of the lattice parameter a:

Vc = a^3 / 2

Substituting the given values, we get:

A = (11.95 g/cm3 * (0.32554 nm)^3 / (x * 6.022 × 10^23 * (0.2299 nm)^3)) + ((1 - x) * 92.91 g/mol * (0.32554 nm)^3 / 2)

Simplifying and solving for x, we get:

x = 0.0526 or 5.26%

Therefore, the fraction of atoms in the niobium-tungsten alloy that are tungsten is 5.26%.

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Related Questions

if the message number is 64bits long. how many messages could be numbered. b) choose an authentication function for secure channel, the security factor required is 256bits.

Answers

If the message number is 64 bits long, then there could be a total of 2^64 possible message numbers. This is because each bit has two possible states (0 or 1) and there are 64 bits in total, so 2 to the power of 64 gives us the total number of possible message numbers.

For the authentication function, a common choice for a secure channel with a security factor of 256 bits would be HMAC-SHA256. This is a type of message authentication code (MAC) that uses a secret key and a cryptographic hash function to provide message integrity and authenticity. HMAC-SHA256 is widely used in secure communication protocols such as TLS and VPNs.


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Calculate the maximum torsional shear stress that would develop in a solid circular shaft, having a diameter of 1. 25 in, if it is transmitting 125 hp while rotating at 525 rpm. (5 pts)

Answers

To calculate the maximum torsional shear stress (τmax) in a solid circular shaft, we can use the following formula:

τmax = (16 * T) / (π * d^3)

Where:T is the torque being transmitted (in lb·in or lb·ft),

d is the diameter of the shaft (in inches).

First, let's convert the power of 125 hp to torque (T) in lb·ft. We can use the following equatio

T = (P * 5252) / NWhere:

P is the power in horsepower (hp),

N is the rotational speed in revolutions per minute (rpm).Converting 125 hp to torque

T = (125 * 5252) / 525 = 125 lbNow we can calculate the maximum torsional shear stress

τmax = (16 * 125) / (π * (1.25/2)^3)τmax = (16 * 125) / (π * (0.625)^3

τmax = (16 * 125) / (π * 0.24414)τmax = 8000 / 0.76793τmax ≈ 10408.84 psi (rounded to two decimal places)

Therefore, the maximum torsional shear stress in the solid circular shaft is approximately 10408.84 psi.

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what is the difference between an argument that is valid and one that is invalid? construct an example each.

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An argument is said to be valid when its conclusion follows logically from its premises. In other words, if the premises are true, then the conclusion must also be true.

On the other hand, an argument is said to be invalid when its conclusion does not follow logically from its premises. This means that even if the premises are true, the conclusion may not necessarily be true.
For example, consider the following argument:
Premise 1: All cats have tails.
Premise 2: Tom is a cat.
Conclusion: Therefore, Tom has a tail.
This argument is valid because if we accept the premises as true, then the conclusion logically follows. However, consider the following argument:
Premise 1: All dogs have tails.
Premise 2: Tom is a cat.
Conclusion: Therefore, Tom has a tail.
This argument is invalid because even though the premises may be true, the conclusion does not logically follow from them. In this case, the fact that all dogs have tails does not necessarily mean that all cats have tails, so we cannot use this premise to support the conclusion.
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is &(&i) ever valid in c? explain.

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In C programming, the expression "&(&i)" is not considered valid.

Here's a step-by-step explanation:
1. "i" represents a variable, which can store an integer value. To declare a variable "i" as an integer, you would write "int i;".
2. "&i" refers to the memory address of the variable "i". The ampersand (&) is known as the "address-of" operator, and it is used to get the address of a variable in memory.
3. Now, let's consider "&(&i)": this expression attempts to get the address of the address of the variable "i". However, this is not valid in C, because the "address-of" operator cannot be applied to the result of another "address-of" operator.
In summary, the expression "&(&i)" is not valid in C programming, as you cannot use the "address-of" operator on the result of another "address-of" operator.

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Consider the method createTriangle that creates a right triangle based on any given character and with the base of the specified number of times.
For example, the call createTriangle ('*', 10); produces this triangle:
*
**
***
****
*****
******
*******
********
*********
**********
Implement this method in Java by using recursion.
Sample main method:
public static void main(String[] args) {
createTriangle('*', 10);

Answers

The createTriangle method uses recursion to create a right triangle with a specified character and base size in Java.

Here's a possible implementation of the createTriangle method in Java using recursion:

public static void createTriangle(char ch, int base) {

   if (base <= 0) {

       // Base case: do nothing

   } else {

       // Recursive case: print a row of the triangle

       createTriangle(ch, base - 1);

       for (int i = 0; i < base; i++) {

           System.out.print(ch);

       }

       System.out.println();

   }

}

This implementation first checks if the base parameter is less than or equal to zero, in which case it does nothing and returns immediately (this is the base case of the recursion). Otherwise, it makes a recursive call to createTriangle with a smaller value of base, and then prints a row of the triangle with base characters of the given character ch. The recursion continues until the base parameter reaches zero, at which point the base case is triggered and the recursion stops.

To test this method, you can simply call it from your main method like this:

createTriangle('*', 10);

This will create a right triangle using the '*' character with a base of 10. You can adjust the character and base size as desired to create different triangles.

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dealized electron dynamics. A single electron is placed at k=0 in an otherwise empty band of a bcc solid. The energy versus k relation of the band is given by €(k)=-a –8y cos (kxa/2); At 1 = 0 a uniform electric field E is applied in the x-axis direction Describe the motion of the electron in k-space. Use a reduced zone picture. Discuss the motion of the electron in real space assuming that the particle starts its journey at the origin at t = 0. Using the reduced zone picture, describe the movement of the electron in k-space. Discuss the motion of the electron in real space assuming that the particle starts its movement at the origin at t= 0.

Answers

The motion of the electron in k-space can be described using a reduced zone picture.

How to explain the motion

The Brillouin zone of the bcc lattice can be divided into two identical halves, and the reduced zone is defined as the half-zone that contains the k=0 point.

When the electric field is applied, the electron begins to accelerate in the x-axis direction. As it gains kinetic energy, it moves away from k=0 in the positive x direction in the reduced zone. Since the band has a periodic structure in k-space, the electron will encounter the edge of the reduced zone and wrap around to the other side. This is known as a band crossing event.

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What is a unifier of each of the following terms. Assume that occurs-check is true. (a) (4 point) f(X,Y,Z) = f(Y,Z,X) A. {X/Y, Y/Z} B. {X/Y, Z/y} C. {X/A, Y/A, Z/A} D. None of the above. (b) (4 point) tree (X, tree (X, a)) tree (Y,Z) A. Does not unify. B. {X/Y, Z/tree(X, a)} C. {X/Y, Z/tree(Y, a)} D. {Y/X, Z/tree(Y, a)} (c) ( point) (A,B,C] = [(B,C),b,a(A)] A. Does not unify. B. {A/(b, a(A)), B/b, C/a(A)} C. {A/(b, a(C)), B/b, C/a(A)} D. None of the above

Answers

(a) (4 point) f(X,Y,Z) = f(Y,Z,X)

A. {X/Y, Y/Z}

B. {X/Y, Z/y}

C. {X/A, Y/A, Z/A} D. None of the above.

Answer: C. {X/A, Y/A, Z/A}

(b) (4 point) tree (X, tree (X, a)) tree (Y,Z)

A. Does not unify.

B. {X/Y, Z/tree(X, a)} C. {X/Y, Z/tree(Y, a)} D. {Y/X, Z/tree(Y, a)}

Answer: C. {X/Y, Z/tree(Y, a)}

(c) ( point) (A,B,C] = [(B,C),b,a(A)]

A. Does not unify.

B. {A/(b, a(A)), B/b, C/a(A)}

C. {A/(b, a(C)), B/b, C/a(A)} D. None of the above

Answer: B. {A/(b, a(A)), B/b, C/a(A)}

The terms have different structures and cannot be unified. The brackets, parentheses, and commas in the terms do not match, so unification is not possible.

What is The unifier in the terms?

(a) The unifier of the terms f(X,Y,Z) and f(Y,Z,X) is:

B. {X/Y, Z/y}

This unifier substitutes X with Y and Z with y, resulting in f(Y,Z,y) = f(Y,Z,y).

(b) The unifier of the terms tree(X, tree(X, a)) and tree(Y,Z) is:

D. {Y/X, Z/tree(Y, a)}

This unifier substitutes Y with X and Z with tree(Y, a), resulting in tree(X, tree(X, a)) = tree(X, tree(X, a))

(c) The unifier of the terms (A,B,C] and [(B,C),b,a(A)] is:

A. Does not unify.

The terms have different structures and cannot be unified. The brackets, parentheses, and commas in the terms do not match, so unification is not possible.

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Ch-Sup01 Determine 60.H7/p6a. If this fit specification is shaft based or hole based. b. If this is a clearance, transitional or interference fit. c. Using ASME B4.2, find the hole and shaft sizes with upper and lower limits.

Answers

60.H7/p6a refers to a fit specification according to the ISO for limits and fits. The first symbol, 60, indicates the tolerance grade for the shaft, while the second symbol, H7, indicates the tolerance grade for the hole. In this case, the fit specification is shaft based, meaning the tolerances are based on the shaft dimensions.



To determine if this is a clearance, transitional, or interference fit, we need to compare the shaft tolerance (60) to the hole tolerance (p6a). In this case, the shaft tolerance is larger than the hole tolerance, indicating a clearance fit. This means that there will be a gap between the shaft and the hole, with the shaft being smaller than the hole.

Using ASME B4.2, we can find the hole and shaft sizes with upper and lower limits. The upper and lower limits will depend on the specific application and the desired fit type. However, for a clearance fit with a shaft tolerance of 60 and a hole tolerance of p6a, the hole size will be larger than the shaft size.

The upper limit for the hole size will be p6a, while the lower limit for the shaft size will be 60 - 18 = 42. The upper limit for the shaft size will be 60, while the lower limit for the hole size will be p6a + 16 = p6h.

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