A certain reaction with an activation energy of 155 kJ/mol was run at 495 K and again at 515 K . What is the ratio of f at the higher temperature to f at the lower temperature

Answer:

T = 48.39%

Explanation:

In this case we need to apply the Beer law which is the following:

A = CεL  (1)

Where:

A: Absorbance of solution

C: Concentration of solution

ε: Molar Absortivity (Constant)

L: Length of the cell

Now according to the given data, we have transmittance of 93% or 0.93. We can calculate absorbance using the following expression:

A = -logT (2)

Applying this expression, let's calculate the Absorbance:

A = -log(0.93)

A = 0.03152

Now that we have the absorbance, let's calculate the concentration of the solution, using expression (1).

A = CεL

C = A / εL

Replacing:

C = 0.03152 / 1 *ε   (3)

Now, we want to know the transmittance of the solution with a length of 10 cm. so:

A = CεL

Concentration and ε are constant, so:

A = (0.03152 / ε) * ε * 10

A = 0.3152

Now that we have the new absorbance, we can calculate the new transmittace:

T = 10^(-A)

T = 0.4839 ----> 48.39%

Answer:

it's a two step elimination reaction

Explanation:

it follows a carbocationic pathway. When carbocation is stable, the equation is favourable, that is, double bond is formed by expelling hydrogen atom.

Answer: 9.53 *2= 19.06

Explanation:

The law of multiple proportions states that if two elements combines to form more than one compound the ratio of masses of the second element which combines to the fixed mass of the first element will always be the ratios of the small whole numbers.

in case of carbon monoxide, mass of carbon will be the same of mass of oxygen.

But in case of carbon dioxide, if carbon is 9.53 units then oxygen will be twice as that of carbon.

CO2, so 9.53*2= 19.06 grams of oxygen will combine with 9.53 grams of carbon to form carbon dioxide.

Answer:

B. None of these

Explanation:

Sulfur has less ionization energy than phosphorus because sulfur has a pair of electron in its 3p subshell that increases electron repulsion in sulfur and sulfur electrons can easily remove from its sub-level.

While, there are no electron pairs in 3p subshell of phosphorus, therefore it requires more energy to remove an electron from 3p subshell.

Hence, the reason is electron repulsion and the correct answer is B.

Answer: HZ > HX > HY in order of decreasing strengths.

Explanation: Generally, the rule is that the stronger the acid, the weaker its conjugate base and vice versa; same rule applies for bases and their conjugate acids.

So the weakest base Z- would have the strongest conjugate acid. Consequently, the strongest base Y- would have the weakest conjugate acid.

I hope this was MORE helpful as this is the correct answer.

The ranking of the conjugate acids in order of decreasing strength (i.e from strongest to weakest) is; HZ < HX < HY

First we must know that the stronger a base is, the weaker is it's conjugate acid and the weaker a base is, the stronger is it's conjugate acid.

Therefore, the order of decreasing strength of the conjugate acid is; HZ < HX < HY

Read more:

https://brainly.com/question/23917439

Answer:

a. The rate of the reaction is not proportional to the concentration of the reactant.

Explanation:

The rate expression for a zero order reaction is given as;

A → Product

Rate = k[A]⁰

[A]⁰ = 1

Rate = K

GGoing through the options;

a) This is correct because in the final form of the rate expression, the rate is independent of the concentration.

b) This option is wrong

c) This option is also wrong

d) Like options b and c this is also wrong becaus ethere is no relationship between either the concentration or t.

Answer:

It was because the vaccine generated actively acquired immunity, that is, inoculation of a portion of the measles virus so that the body forms the antibodies for a second contact and thus can destroy it without triggering the pathology.

Explanation:

Vaccines are methods of active acquired immunity since the antibody is not passively inoculated, it is manufactured by the body with a physiological process once part of the virus is inoculated.

The measles virus most of all affected the lives of infants or newborn children with severe rashes and high fevers that led to death.

Answer: The volume of the balloon at this altitude is 46.3 L

Explanation:

Combined gas law is the combination of Boyle's law, Charles's law and Gay-Lussac's law

The combined gas equation is,

[tex]\frac{P_1V_1}{T_1}=\frac{P_2V_2}{T_2}[/tex]

where,

[tex]P_1[/tex] = initial pressure of gas = 755 mm Hg

[tex]P_2[/tex] = final pressure of gas (at STP) = 385 mm Hg

[tex]V_1[/tex] = initial volume of gas = 27.6 L

[tex]V_2[/tex] = final volume of gas = ?

[tex]T_1[/tex] = initial temperature of gas = [tex]29.9^0C=(29.9+273)K=302.9K[/tex]

[tex]T_2[/tex] = final temperature of gas = [tex]-14.1^0C=((-14.1)+273)K=258.9K[/tex]

Putting all the values we get:

[tex]\frac{755\times 27.6}{302.9}=\frac{385\times V_2}{258.9}[/tex]

[tex]V_2=46.3L[/tex]

Thus the volume of the balloon at this altitude is 46.3 L

Answer:

a) Fe(s) + Ni^2+(aq) ----> Fe^2+(aq) + Ni(s)

b) no reaction

c) no reaction

d) 2Mg(s) + 2H2O(l)-----> 2Mg^2+(aq) + O2(g) +4H^+(aq)

e) no reaction

Explanation:

It is important to say here that the ability of a particular chemical specie to displace another chemical specie is dependent on the relative standard reduction potentials of the species involved.

All the reactions stated above are redox reactions. Let us take reaction E as an example. Mg^2+ has a reduction potential of -2.37 V while Cr^3+ has a reduction potential of -0.74V. Since the reduction potential of magnesium is more negative than that of chromium, there is no reaction when a piece of chromium metal is dipped into a solution of Mg^2+.

Similarly, though metals displace hydrogen gas from dilute acids, metals that are less than hydrogen in the reactivity series cannot do that. This explains why there is no reaction when copper and silver are dipped into dilute acid solutions.

Reaction occurs when iron is dipped into a nickel solution because the reduction potential of Fe^2+ is far more negative than that of Ni^2+.

Answer:

997.65cmH2O

Explanation:

Barometric pressure = 739 mmHg

density of Hg = 13.5 g/ml

density of water (H2O) = 1.00 g/ml

Calculate Barometric pressure in centimetres of water ( cmH20)

equate the barometric pressure of Hg and water

739 * 13.5 * 9.8 = x * 1 * 9.81

x ( barometric pressure of water in mmH2O ) = 739 *13.5 / 1 = 9976.5mmH2O

in cmH2O = 997.65cmH2O

Answer:

Option C. Keq = [SO2]² [O2] /[SO3]²

Explanation:

The equilibrium constant keq for a reaction is simply the ratio of the concentration of the products raised to their coefficient to the concentration of the reactants raised to their coefficient.

Now, let us determine the equilibrium constant for the reaction given in the question.

This is illustrated below:

2SO3(g) <==> 2SO2(g) + O2(g)

Reactant => SO3

Product => SO2, O2

Keq = concentration of products /concentration of reactants

Keq = [SO2]² [O2] /[SO3]²

Answer:

315mL

Explanation:

Data obtained from the question include the following:

Molarity of stock solution (M1) = 0.135 M

Volume of stock solution needed (V1) =?

Molarity of diluted solution (M2) = 0.0851 M

Volume of diluted solution (V2) = 500mL

The volume of the stock solution needed can be obtain as follow:

M1V1 = M2V2

0.135 x V1 = 0.0851 x 500

Divide both side by 0.135

V1 = (0.0851 x 500) / 0.135

V1 = 315mL

Therefore, the volume of the stock solution needed is 315mL

Answer:

H = 4,034,250 J

Explanation:

Mass, m = 165kg = 165,000g (Converting to grams)

Initial temperature = 15.7°C

Final temperature = 95.7°C

Temperature change, ΔT = 95.7 - 15.7 = 50°C

Specific heat capacity, c = 0.489 J/g·°C

Heat = ?

All the parameters are related with the equation below;

H = m * c * ΔT

H = 165000 * 0.489  * 50

H = 4,034,250 J

Answer:

- Both energy and matter cannot be neither created nor destroyed.

- An equilibrium temperature will be reached.

Explanation:

Hello,

In this case, the law of conservation is applied to both matter and energy, and it states that both energy and matter cannot be neither created nor destroyed. Specifically, in chemical reactions, it states that in closed systems, the mass of the reactants equals the mass of the products even when the number of moles change. Moreover, for energy, if two substances at different temperatures come into contact, the hot one will cool down and the cold one will heat up until an equilibrium temperature so the energy lost by the hot one is gained by the cold one, which accounts for the transformation of energy.

Best regards.

Answer:

K = 150, C = - 123.15°

Explanation:

Kelvin = Celcius + 273.15 / 0 Kelvin = - 273.14 C

_____________________________________

Thus,

150 K = Celcius + 273.15,

150 - 273.15 = C,

C = -123.15 degrees

Solution, C = - 123.15°

Answer:

C=-123.15

Explanation:

This is easy

Answer:

Zero

Explanation:

Hello,

The question require us to calculate the mass of nitrogen present in aluminium carbonate.

This can easily be calculated using Avogadro's number as a constant with some minor calculations but however in this case, we can't because there's no single atom of nitrogen present in aluminium carbonate hence we can't calculate the mass of nitrogen present in it.

Chemical formula of aluminium carbonate = Al₂(CO₃)₃.

From the above chemical formula, we can see that there's no single atom of nitrogen present in the formula hence the mass of nitrogen present in aluminium carbonate that contains 1.23×10²³ carbon atoms is zero.

Answer:

The answer is A

Explanation:

Answer:

A) How many hydrogen atoms are in the molecule?

Answer:

See explanation

Explanation:

In this case, we have 2 types of reactions. [tex]CH_3CH_2ONa[/tex] is a strong base but only has 2 carbons therefore we will have less steric hindrance in this base. So,  the base can remove hydrogens that are bonded on carbons 1 or 6, therefore, we will have a more substituted alkene (1-methylcyclohex-1-ene).

For the  [tex]KOC(CH_3)_3[/tex] we have more steric hindrance. So, we can remove only the hydrogens from carbon 7 and we will produce a less substituted alkene (methylenecyclohexane).

See figure 1

I hope it helps!

Answer:

Even all compounds are neutral.

Explanation:

Some of them exhibit polarity. Because of the difference in electron affinity of the constituent atoms, the shared electrons are pulled towards the atom with high affinity to electrons.

Answer:

Ba(+2)(aq) + SO4(-2)(aq) -----> BaSO4(s)

Explanation:

Take a look at the attachment below;

Answer:

An ion is an atom that has lost or gained one or more electrons.

Explanation:

Ions are positively or negatively charged atoms of elements. This is because they can give, take, or share electrons with other elements to encourage the formation of chemical bonds.

Protons are what decide the chemical identity of the element. So, for example, if an atom has 11 protons, we know that will be a Sodium (Na) atom. A loss or gain of protons completely changes the chemical identity of the element and it will then become another element.

Electrons are what give an atom a neutral electrical charge (if that atom has the number of protons and neutrons normally described for the element - otherwise, a discrepancy or gain in neutrons is referred to as an isotope and declares that ions have nothing to do with the mass of an element).

With this information, you can realize that neutrons and protons have nothing to do with ions and you can confirm that ions are atoms that have lost or gained one or more electrons.

Answer: their amounts vary throughout the atmosphere

Explanation:

There is very little that travels over the atmosphere

Vary=very little

Hope that helps

Answer:

Explanation:

Stereoisomers are two or more atoms that  have the same bonding order of atoms but there is a difference  spatial arrangement of  the  atoms in space.

A plane of symmetry divides a molecule into two equal halves.

A chiral stereoisomer are not superimposed on a mirror image , Hence they do not posses a plane of symmetry.

As a result to that. these non-superimposable mirror images are said to be Enantiomers.

However, a Fischer Projection emanates from a two - dimensional figure which is used for presenting a three - dimensional organic molecules.

From the given question;

Fischer projection for an enantiomer of 2-bromo-2,3-dihydroxypropanal with the bromine oriented horizontally to the left and the hydroxide group oriented horizontally to the right.

we can sketch the way the enantiomer of 2-bromo-2,3-dihydroxypropanal can  be seen like the one shown below:

              CH₂OH

                   |

                   |

                   |

Br -------------|----------------OH

                   |

                   |

                   |

                 CHO

The objective of this question is to drawn the perspective formula of the molecule.

So , from the attached file below; we can see the perspective formula of the molecule in a well structured 3-D format.

Answer:

The lock-and-key model:

c. Enzyme active site has a rigid structure complementary

The induced-fit model:

a. Enzyme conformation changes when it binds the substrate so the active site fits the substrate.

Common to both The lock-and-key model and The induced-fit model:

b. Substrate binds to the enzyme at the active site, forming an enzyme-substrate complex.

d. Substrate binds to the enzyme through non-covalent interactions

Explanation:

Generally, the catalytic power of enzymes are due to transient covalent bonds formed between an enzyme's catalytic functional group and a substrate as well as non-covalent interactions between substrate and enzyme which lowers the activation energy of the reaction. This applies to both the lock-and-key model as well as induced-fit mode of enzyme catalysis.

The lock and key model of enzyme catalysis and specificity proposes that enzymes are structurally complementary to their substrates such that they fit like a lock and key. This complementary nature of the enzyme and its substrates ensures that only a substrate that is complementary to the enzyme's active site can bind to it for catalysis to proceed. this is known as the specificity of an enzyme to a particular substrate.

The induced-fit mode proposes that binding of substrate to the active site of an enzyme induces conformational changes in the enzyme which better positions various functional groups on the enzyme into the proper position to catalyse the reaction.

Answer:

D. rate = k [(CH3)3CCl]

Explanation:

(CH3)3CCl + OH- → (CH3)3COH + Cl-

The mechanisms are;

Step 1)

(CH3)3CCl → (CH3)3C+ + Cl- (slow)

Step 2)

(CH3)3C+ + OH- → (CH3)3COH (fast)

In kinetics, the slowest step is the ratee determining step.

For a given reaction;

A → B + C, the rate law expression is given as;

rate = k [A]

In this problem, from step 1. The rate expression is;

rate = k [(CH3)3CCl]

Answer:

Explanation:

Calculate ΔG (in kJ) for the following reaction at 1.0 atm for C2H6,

0.5 atm for O2, and

2.0 atm for CO2, and

25 oC:

C2H6 (g) + O2 (g) ---> CO2 (g) + H2O (l) (unbalanced)

ΔGfo C2H6 (g) = - 32.89 kJ/mol;

ΔGfo CO2 (g) = - 394.4 kJ/mol;

ΔGfo H2O (l) = - 237.13 kJ/mol

The balance equation of this reaction is

[tex]2C_2H_6 (g) + 7O_2 (g) ---> 4CO_2 (g) + 6H_2O (l)[/tex]

[tex]\Delta G_{rxn}=\sum G^o_f(product)-\sum G^o_f(reactant)[/tex]

[tex]=4G^o_f(CO_2)+6G^o_f(H_2O)-7G^o_f(O_2)-2G^o_f(C_2H_6)\\\\[/tex]

[tex][4(-394.4)+6(-237.13)-7(0)-2(-32.89)]kJ/mol\\\\=-1577.6-1422.78+65.78\\\\=-3000.38+65.78\\\\=-2934.6kJ/mol[/tex]

Answer:

2.92 mol

Explanation:

Step 1: Write the balanced equation

2 B(s) + 6 HCI(aq) ⇒ 2 BCl₃(aq) + 3 H₂(g)

Step 2: Establish the appropriate molar ratio

The molar ratio of hydrochloric acid to boron chloride is 6:2.

Step 3: Calculate the moles of boron chloride produced from 8.752 moles of hydrochloric acid

[tex]8.752molHCl \times \frac{2molBCl_3}{6molHCl} = 2.92molBCl_3[/tex]

Answer:

8

Explanation:

When you balance the entire equation, you should get:

C5H12 + 8O2 ---> 5CO2 + 6H2O