3. Methyl acetate is hydrolyzed at 25 oC in acidic environment. Aliquots of equal volume are removed and titrated with NaOH solution. The hydrolysis reaction is irreversible. The results are Time/s 339 1242 2745 4546 infinite Volume of base/ mL 26.34 27.80 29.70 31.81 39.81 Write the reaction of hydrolysis of methyl acetate. (3 pts.) Neglect the reverse reaction. Find the order of the hydrolysis reaction and the value of the rate constant at this temperature. (12 pts.) Total 15 pts.

Answers

Answer 1

Solution :

Time (sec)       Volume of NaOH (mL)

339                           26.23

1242                         27.80

2745                        29.70

4546                         3.81

[tex]$\infty$[/tex]                               39.81

Now the example of the first order kinetics w.r.t volumetric analysis is :

[tex]$k=\frac{2.303}{t} \log \left(\frac{v_{\infty}-v_0}{v_{\infty}- v_t}\right)$[/tex]

Here, [tex]$v_{\infty}= \text{ volume at }\infty = 39.81$[/tex]

[tex]$v_{t}= \text{ volume at time 't' } = 27.80$[/tex]

[tex]$v_0$[/tex] = volume at time 0 = 0

Since the interval is not constant, we take the time interval as

[tex]$=\frac{903+1503+1801}{3}$[/tex]

[tex]$=\frac{4207}{3}$[/tex]

= 1402.3333

≈  1402 seconds

[tex]$k=\frac{2.303}{1402} \log \left(\frac{39.81-0}{39.81-27.80}\right)$[/tex]

  [tex]$=(0.001643) \log \left(\frac{39.81}{10.01}\right)$[/tex]

  = 0.001643 x 0.52045

  = 0.00082

  [tex]$= 8.55 \times 10^{-4} \ sec^{-1}$[/tex]

Therefore, the first order rate constant is k [tex]$= 8.55 \times 10^{-4} \ sec^{-1}$[/tex].


Related Questions

If 4.52g of the precipitate is formed, how many grams of sodium chloride reacted?​

Answers

The question is incomplete, the complete question is;

AgNO3(aq)+NaCl(aq)→AgCl(s)⏐↓+NaNO3(aq)

1- If 4.52g of the precipitate is formed, how many grams of sodium chloride reacted?

Answer:

1.8 g

Explanation:

Given the equation;

AgNO3(aq)+NaCl(aq)→AgCl(s)↓+NaNO3(aq)

We can see that the reaction is 1:1 Hence, 1 mole of sodium chloride yielded 1 mole of the precipitate(AgCl).

If this is so,

Number of moles of precipitate formed = 4.52g/143.32 g/mol

Number of moles of precipitate formed = 0.0315 moles

Hence, 0.0315 moles of precipitate was formed by 0.0315 moles of NaCl

Therefore;

Mass of NaCl reacted = 0.0315 moles * 58.5 g/mol = 1.8 g

Hayley woke up to a hot and humid day but knows it is going to cool off later. What should she expect the weather to be like tonight?

Answers

She’s gonna expect the weather to cool down, not to the point where it’s cold but where it’s not that hot.

Answer:

It will most likely rain because cool air cannot hold as much moisture as warm air.

Explanation:

I did the quiz !! :)

I really hope this helps!!!!!!!!!!!!        :)

Help me with this question

Answers

Answer:

your cool

Explanation:

owa owa owa owa owa bob

WHO EVER ANSWERS FIRST IS GETTING BRAINLIEST ( Correctly )
Most geologists rejected Alfred Wegener’s idea of continental drift because



they were afraid of the new idea.


Wegener was too interested in what Earth was like millions of years ago.


Wegener used several different types of evidence to support his hypothesis.


Wegener could not identify what force could move the continents.

Answers

Answer:

Wegener could not identify what force could move the continets.

Explanation:

Which of these materials are insulators? Select the THREE (3) that apply.

aluminum can

wool

rubber

iron nail

copper wire

plastic

Answers

Answer:

wool ,rubber and copper wire should be correct

PLEASE HELP WORTH 100 POINTS !!!!!

Answers

Answer: Imidogen

Explanation: I just looked it up.

Answer:

Imidogen

Explanation:

How many grams do 4.5 moles of oxygen atoms weigh

Answers

Answer:

71.99100

Explanation:

The mass of oxygen equal to one mole of oxygen is 15.998 grams and the mass of one mole of hydrogen is 1.008 g. 15.998*4.5 = 71.99100

What are the coefficients that would correctly balance this equation?


____Zn + ____K2CrO4 → ____K + ____ZnCrO4
1, 2, 1, 2
2, 1, 2, 1
1, 1, 2, 1
1, 2, 3, 1

Answers

Answer:

Explanation:

1,2,1,2

Answer:

b

Explanation:

What is the composition of a universal indicator?

Answers

Answer:

The main universal indicator is in the form of a solution and are thymol blue , methyl red , bromothymol blue and phenolphthalein this mixture is important because each component loses or gains protons depending upon the acidity of the solution being tested .

maybe this mighr help u

2) A common "rule of thumb" -- for many reactions around room temperature is that the

rate will double for each ten degree increase in temperature. Does the reaction you hav

studied seem to obey this rule.

Answers

The question is incomplete. The complete question is :

A common "rule of thumb" for many reactions around room temperature is that the rate will double for each ten degree increase in temperature. Does the reaction you have studied seem to obey this rule? (Hint: Use your activation energy to calculate the ratio of rate constants at 300 and 310 Kelvin.)

Solutions :

If we consider the activation energy to be constant for the increase in 10 K temperature. (i.e. 300 K → 310 K), then the rate of the reaction will increase. This happens because of the change in the rate constant that leads to the change in overall rate of reaction.

Let's take :

[tex]$T_1=300 \ K$[/tex]

[tex]$T_2=310 \ K$[/tex]

The rate constant = [tex]$K_1 \text{ and } K_2$[/tex] respectively.

The activation energy and the Arhenius factor is same.

So by the arhenius equation,

[tex]$K_1 = Ae^{-\frac{E_a}{RT_1}}$[/tex]  and [tex]$K_2 = Ae^{-\frac{E_a}{RT_2}}$[/tex]

[tex]$\Rightarrow \frac{K_1}{K_2}= \frac{e^{-\frac{E_a}{RT_1}}}{e^{-\frac{E_a}{RT_2}}} $[/tex]

[tex]$\Rightarrow \frac{K_1}{K_2}= e^{-\frac{E_a}{R}\left(\frac{1}{T_1}-\frac{1}{T_2}\right)}$[/tex]

[tex]$\Rightarrow \ln \frac{K_1}{K_2}= - \frac{E_a}{R} \left(\frac{1}{T_1} -\frac{1}{T_2} \right)$[/tex]

[tex]$\Rightarrow \ln \frac{K_2}{K_1}= \frac{E_a}{R} \left(\frac{1}{T_1} -\frac{1}{T_2} \right)$[/tex]

Given, [tex]$E_a = 0.269$[/tex] J/mol

           R = 8.314 J/mol/K

[tex]$\Rightarrow \ln \frac{K_2}{K_1}= \frac{0.269}{8.314} \left(\frac{1}{300} -\frac{1}{310} \right)$[/tex]

[tex]$\Rightarrow \ln \frac{K_2}{K_1}= \frac{0.269}{8.314} \times \frac{10}{300 \times 310}$[/tex]

[tex]$\Rightarrow \ln \frac{K_2}{K_1}= 3.479 \times 10^{-6}$[/tex]

[tex]$\Rightarrow \frac{K_2}{K_1}= e^{3.479 \times 10^{-6}}$[/tex]

[tex]$\Rightarrow \frac{K_2}{K_1}= 1$[/tex]

∴ [tex]$K_2=K_1$[/tex]

So, no this reaction does not seem to follow the thumb rule as its activation energy is very low.

Scientists examine fossils from three different animals. They determine that all three animals share similar structures and
record their observations as follows
• Animal A and animal B have somewhat similar structures
• Animal A and animal C have very similar structures
• Animal B and animal C have very similar structures
The scientists use the similarities to determine the order in which the fossils should appear in the fossil record. Based on the
scientists' observations, which order is the most reasonable?
ABC
ACB
С, В, А
В, А С

Answers

Answer:

C,B,A

Explanation:

C has the most similar structure

B has the second most similar structure

A has the least similair structure

Based on the scientists' observations, the  order which is the most reasonable is C,B,A.

What are observations?

Observations are defined as a set of statements or facts which are recorded while conducting an experiment.Observations are made through sensing changes in the variables of the experiment.

It is specifically defined as an act of knowing or recording the changes in the variables of the experiment.Recording observations holds importance as recording observations avoid the experiment to be repeated over and over again.

It is important to note down observations so that the testing of hypothesis is made easier.There are four types of observations .Observations need to be descriptive and must be written in complete sentences and should include all the numerical data of the experiment.

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Which of the following cell organelles is NOT found in BOTH plant and animal cells?

O cells membrane

O cell wall

O ribosomes

O cytoplasm

Answers

Cell wall might be the answer

which element listed below can conduct heat and electricity, but not as well as metal?

a. copper (Cu)
b. silicon (Si)
c. iron (Fe)
d. neon (Ne)

Answers

Metals are elements that are good conductors of electric current and heat. They also tend to be shiny and bendable

The correct answer is A) copper

Hope this helps!! ♥️

What are two things that interact that determine if there is a phase change or not HELP

Answers

Answer:

phase change always has two phases in contact during the change. melting => solid & liquid; evaporation (boiling) => liquid & vapor. If only one phase is present, then phase change is not occurring. Also, when two phases are in contact, no temperature changes occur. Only the pure phase demonstrates temperature change when measured. Example, when ice is added to water, at thermal equilibrium (temp = 0°C) the water temp will not continue to change. Only when all the ice has melted will the water temperature demonstrate a measured temperature change.

Explanation:


An average bushel of apples has a mass of 10 kg and contains 5 dozen apples.
What would be the average mass of 6 apples?

Answers

Answer:

Average mass of 6 apple  = 1 kg

Explanation:

Given:

Average mass of 5 dozen apple = 10 kg

Find:

Average mass of 6 apple

Computation:

Average mass of 6 apple  = [Average mass of 1 apple] x [6 apple]

Average mass of 6 apple  = [10/(12 x 5)] x [6]

Average mass of 6 apple  = 1 kg

MULTIPLE CHOICE QUESTION
When the frequency increases, the waves
become?
Shorter
Longer

Answers

Answer:

Shorter

Explanation:

As a wavelength increases in size, its frequency, and energy (E) decrease. From these equations, you may realize that as the frequency increases, the wavelength gets shorter. As the frequency decreases, the wavelength gets longer. There are two basic types of waves: mechanical and electromagnetic.

What is the mass of 2 moles of nitrogen gas, N2?

Answers

Answer:

28g

Solution. Hence, 2 moles of nitrogen atoms weigh 28g.

In order for heat to flow there must be... *

A. identical tempatures

B. a difference in tempatures

C. a difference in altitude

D. an electrical current present

Answers

Answer:

B. a difference in temperatures.

Explanation:

Conduction involves the transfer of electric charge or thermal energy due to the movement of particles. When the conduction relates to electric charge, it is known as electrical conduction while when it relates to thermal energy, it is known as heat conduction.

In the process of heat conduction, thermal energy is usually transferred from fast moving particles to slow moving particles during the collision of these particles.

Also, thermal energy is typically transferred between objects that has different degrees of temperature and materials (particles) that are directly in contact with each other but differ in their ability to accept or give up electrons.

In order for heat to flow there must be a difference in temperatures.

This ultimately implies that, the driving force responsible for heat to flow is a difference in temperature between the points from which heat originates and where heat is received.

Additionally, the higher the temperature difference, the greater would be the heat flow; which is usually from a high temperature level to a low temperature level.

can you help me please ​

Answers

I also agree on c but not 100% as I took chem last year

Answer this express as a chemical equation

Answers

Answer:

Pb(No3)2+2Nacl_PbCl2+2NaNO3

If 21.00 mL of a 0.68 M solution of C6H5NH2 required 6.60 mL of the strong acid to completely neutralize the solution, what was the final pH at the equivalence point

Answers

Answer:

pH = 2.46

Explanation:

Hello there!

In this case, since this neutralization reaction may be assumed to occur in a 1:1 mole ratio between the base and the strong acid, it is possible to write the following moles and volume-concentrations relationship for the equivalence point:

[tex]n_{acid}=n_{base}=n_{salt}[/tex]

Whereas the moles of the salt are computed as shown below:

[tex]n_{salt}=0.021L*0.68mol/L=0.01428mol[/tex]

So we can divide those moles by the total volume (0.021L+0.0066L=0.0276L) to obtain the concentration of the final salt:

[tex][salt]=0.01428mol/0.0276L=0.517M[/tex]

Now, we need to keep in mind that this is an acidic salt since the base is weak and the acid strong, so the determinant ionization is:

[tex]C_6H_5NH_3^++H_2O\rightleftharpoons C_6H_5NH_2+H_3O^+[/tex]

Whose equilibrium expression is:

[tex]Ka=\frac{[C_6H_5NH_2][H_3O^+]}{C_6H_5NH_3^+}[/tex]

Now, since the Kb of C6H5NH2 is 4.3 x 10^-10, its Ka is 2.326x10^-5 (Kw/Kb), we can also write:

[tex]2.326x10^{-5}=\frac{x^2}{0.517M}[/tex]

Whereas x is:

[tex]x=\sqrt{0.517*2.326x10^{-5}}\\\\x=3.47x10^-3[/tex]

Which also equals the concentration of hydrogen ions; therefore, the pH at the equivalence point is:

[tex]pH=-log(3.47x10^{-3})\\\\pH=2.46[/tex]

Regards!

In a thin layer chromatography experiment, a plate of length 9.3 cm was used and a horizontal line was made at 1.45 cm above the bottom of the plate. After running the experiment (developing and drying), a spot was observed at 5.6 cm from the bottom of the plate, and the solvent front was 7.7 cm from the bottom of the plate. What is the Rf value

Answers

Answer: The [tex]R_f[/tex] value is 0.664

Explanation:

Distance travelled by solvent front = (7.7-1.45)cm = 6.25 cm

Distance travelled by unknown = (5.6-1.45) cm = 4.15 cm

 The retention factor or the [tex]R_f[/tex] value is defined as the ratio of distance traveled by the unknown to the distance traveled by the solvent front.

[tex]R_f=\frac{\text {distance travelled by unknown}}{\text {distance travelled by solvent}}[/tex]

[tex]R_f=\frac{4.15}{6.25}=0.664[/tex]

Thus the [tex]R_f[/tex] value is 0.664

Answer this right and ill give u double points then what there is already

Answers

Answer:

I think it is D. because the lantana reproduces by way of pollination which is the only thing in common with the blue Daze.correct me if im wrong

GIVING 28 POINTS AWAY PLEASE HELP ME WITH BOTH QUESTIONS ASAP!!

Answers

Answer: D

Explanation: for question 2 the answer is D and for 3 it is A. That is very easy and the muscular systen has nothing to do with breathing.

Answer:

2: d

3: b

i think, im not too sure

How does a computer's ability to perform so many calculations in a very short time affect how people communicate (pls help)

Answers

Answer:

A computer's ability to perform so many calculations in a very short time affects how people communicate by stopping them from talking actually. We no longer talk verbally. We don't go out and socialize, we always talk from the phone or text. We have lost our inner touch with talking.

Explanation:

Which of the following statements would be an argument against multiculturalism?

(Click all that apply.)


A) Canadians are a mixture of people from various cultural, religious, racial, and ethnic origins. This mixture helps in relations with other countries.


B) Many cultural and ethnic groups have helped build Canada. We should encourage people to preserve their heritage; their traditions are part of Canadian history.


C) Canadians will learn tolerance through being in contact with other cultures. Multiculturalism can help to eliminate discrimination and prejudice.


D) The Canadian government should not spend citizens' tax dollars on multiculturalism. Our taxes are already too high.

Answers

Answer:

D

Explanation:

if anybody could help with this question i would appreciate it

its not college level but i dont know how to change the grade level

Answers

i think its b im not sure

Answer:

D. Liquid

Explanation:

It's mercury given the density and mercury's a metal that is liquid at room temperature

CuCl2(aq) + Na3PO4(aq) =>?
Net ionic equation

Answers

If you are balancing the equation, your final one should be

Cu3(PO4)2 +6 NaCl.
The reaction is a double replacement reaction

If an old car burns 0.05 mL oil every mile, How much oil will it burn if driven 100,000 miles? Show your answer in mL and L?.

Answers

0.05 * 100000

= 5000ml

= 5L

The number of moles of molecules in a 12.0-gram sample of Cl2 is equal too?

Answers

Answer:

0.3529moles

Explanation:

no of moles =mass ÷molar mass

molar mass =17+17

=34

12÷34

=0.3529moles

According to the mole concept, the number of moles of molecules in a 12.0-gram sample of Cl₂ is equal to 0.169  moles.

What is a mole?

Mole is defined as the unit of amount of substance . It is the quantity measure of amount of substance of how many elementary particles are present in a given substance.

It is defined as exactly 6.022×10²³ elementary entities. The elementary entity can be a molecule, atom ion depending on the type of substance. Amount of elementary entities in a mole is called as Avogadro's number.

It is widely used in chemistry as a suitable way for expressing amounts of reactants and products.For the practical purposes, mass of one mole of compound in grams is approximately equal to mass of one molecule of compound measured in Daltons. Molar mass has units of gram per mole . In case of molecules, where molar mass  in grams present in one mole  of atoms is its atomic mass.Number of moles is mass/molar mass= 12/70.90=0.169 moles.

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