Why is it not possible to prepare the following carboxylic acid by a malonic ester synthesis? Select the single best answer. он Malonic ester synthesis cannot be used to prepare monosubstituted carboxylic acids. Compounds of low molecular weight will decarboxylate completely under these reaction conditions. Tertiary alkyl halides are too sterically hindered to undergo an SN2 reaction. The initial compound necessary for this reaction is resonance stabilized and too unreactive to participate in this reaction.

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Answer 1

It is because the reaction requires a compound with two active methylene groups, which are not present in a monosubstituted carboxylic acid.

The reaction involves the substitution of one of the methylene groups with the desired substituent, followed by decarboxylation to form the carboxylic acid.

However, compounds of low molecular weight can also decarboxylate completely under these reaction conditions, making it difficult to obtain the desired product.

Additionally, tertiary alkyl halides are too sterically hindered to undergo an SN2 reaction, which is necessary for the substitution step in the reaction. Finally, the initial compound necessary for this reaction is resonance stabilized and too unreactive to participate in this reaction.

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Related Questions

how many reducing equivalents (equal to electrons) are transferred to electron carriers after one turn of the citric acid cycle? A. 4 B. 6 C. 8 D. 10 E. 16

Answers

After one turn of the citric acid cycle, a total of 8 reducing equivalents (equal to electrons) are transferred to electron carriers.

During the citric acid cycle, also known as the Krebs cycle or the tricarboxylic acid (TCA) cycle, one molecule of acetyl-CoA enters the cycle. In a complete turn of the cycle, this acetyl-CoA molecule is fully oxidized.

In the citric acid cycle, three NADH molecules, one FADH2 molecule, and one GTP (or ATP) molecule are produced per acetyl-CoA molecule that enters the cycle. Both NADH and FADH2 are considered to be reducing equivalents since they carry electrons.

Specifically, the reducing equivalents produced in one turn of the citric acid cycle are:

- Three molecules of NADH, which each carry 2 electrons (3 * 2 = 6 electrons)

- One molecule of FADH2, which carries 2 electrons (2 electrons)

Total reducing equivalents = 6 electrons + 2 electrons = 8 reducing equivalents

Therefore, the correct answer is C. 8 reducing equivalents.

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According to lewis theory which one is acid or base

AlBr3

Answers

According to Lewis theory, an acid is a substance that can accept a pair of electrons, while a base is a substance that can donate a pair of electrons. In the case of AlBr3 (aluminum bromide), it acts as a Lewis acid.

Aluminum bromide is a compound composed of aluminum and bromine atoms a base is a substance that can donate a pair of electrons. In this compound, the aluminum atom has a partial positive charge, making it electron-deficient. It can accept a pair of electrons from a Lewis base. The bromine atoms, on the other hand, have lone pairs of electrons that they can donate to a Lewis acid, making them potential Lewis bases.

Therefore, in the Lewis theory, AlBr3 is considered an acid due to its ability to accept a pair of electrons from a Lewis base.

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Which list shows the compounds in order from most acidic to least acidic? (A) 3>2> 1 (C) 3>1>2 H₂CC C-H 2 H₂CO-H 3 H3CHN-H (B) 2>1>3 (D) 1>3>2

Answers

The order of acidity of these compounds from most acidic to least acidic is option A.  3 > 2 > 1

To determine the order of acidity of these compounds, we need to compare their relative ability to donate a proton (H+). Compounds with a more stable conjugate base (i.e. a weaker acid) will be less likely to donate a proton, while compounds with a less stable conjugate base (i.e. a stronger acid) will be more likely to donate a proton.

Let's examine the compounds in the given list:

H₂CC-C-H

H₂CO-H

H₃CHN-H

Compound 1 is an alkyne with a triple bond between two carbon atoms. The hydrogen attached to one of the carbons is acidic and can be easily removed to form a negatively charged acetylide ion. The acetylide ion is a relatively stable conjugate base, which means that H₂CC-C-H is a strong acid.

Compound 2 is an aldehyde with a hydrogen attached to the carbonyl carbon. The hydrogen in this position is slightly acidic and can be removed to form a relatively unstable conjugate base (i.e. the negative charge is on an oxygen atom). Therefore, H₂CO-H is a weaker acid than H₂CC-C-H.

Compound 3 is an amine with a hydrogen attached to the nitrogen atom. The hydrogen is acidic and can be removed to form a positively charged ammonium ion. The ammonium ion is a relatively stable conjugate acid, which means that H₃CHN-H is a strong acid.

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what is the mass defect of sn the hydrogen atom has a mass of 1.00783 and the neutron has a mass of 1.00867

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The mass defect of Sn is 50.363175 amu. The mass of the nucleus is less than the sum of its individual nucleons due to the release of binding energy during nuclear formation.

The mass defect (Δm) of a nucleus can be calculated using the formula:

Δm = Z(m_p) + N(m_n) - M

where Z is the number of protons, m_p is the mass of a proton, N is the number of neutrons, m_n is the mass of a neutron, and M is the actual mass of the nucleus.

For Sn, the atomic number is 50, so Z = 50. The number of neutrons can vary, but let's assume it has the most stable isotope, which is Sn-120. This means N = 70.

The mass of a proton is 1.007276 amu, and the mass of a neutron is 1.008665 amu. The actual mass of Sn-120 can be found in the periodic table, which is 119.902199 amu.

Using the formula above, we get:

Δm = 50(1.007276) + 70(1.008665) - 119.902199

= 50.363175 amu

Therefore, the mass defect of Sn-120 is 50.363175 amu.

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At a particular temperature, the solubility of In₂(SO₄)₃ in water is 0.0065 M. You have found Ksp to be 1.3 × 10⁻⁹. If solid In₂(SO₄)₃ is added to a solution that already contains 0.200 M Na₂SO₄, what will the new solubility of the solid be?

Answers

The new solubility of In₂(SO₄)₃ in the presence of 0.200 M Na₂SO₄ is 0.0065 - 1.28 × 10⁻⁵ = 0.0065 M.

To determine the new solubility of In₂(SO₄)₃ in the presence of 0.200 M Na₂SO₄, we need to consider the effect of the common ion on the solubility equilibrium. Na₂SO₄ contains the common ion SO₄²⁻, which is also present in In₂(SO₄)₃. When a common ion is added to a solution, the solubility of the salt containing that ion decreases because the equilibrium shifts to the left to counteract the increased concentration of the common ion.

First, we need to calculate the ion product, Qsp, for the solution containing 0.0065 M In₂(SO₄)₃ and 0.200 M Na₂SO₄. The ion product, Qsp, is calculated in the same way as Ksp, but with the actual ion concentrations instead of the solubility product constant. For In₂(SO₄)₃, we have:

In₂(SO₄)₃(s) ⇌ 2 In³⁺(aq) + 3 SO₄²⁻(aq)

Qsp = [In³⁺]²[SO₄²⁻]³ = (2x)²(0.200+3x)³ = 8(0.200+3x)³

where x is the change in concentration of In³⁺ and SO₄²⁻ due to dissolution of In₂(SO₄)₃.

We can then use the expression Qsp = Ksp to solve for x:

Ksp = 1.3 × 10⁻⁹ = 8(0.200+3x)³

Solving for x gives x = 1.28 × 10⁻⁵ M.

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Using the provided data, determine the temperatures at which the following hypothetical reaction will be spontaneous under standard conditions
A + B → 2C + D
△S°rxn = -281.1 J/K
△H°rxn = -163.0 kJ
at all temperatures above 172.4 °C
at no temperaturesat
all temperatures below 306.9 °C
at all temperatures
at all temperatures above 306.9 °C
at all temperatures below 172.4 °C

Answers

The hypothetical reaction will be spontaneous at all temperatures above 307.4 °C. It will not be spontaneous at any temperatures below 172.4 °C.

The hypothetical reaction is + B → 2C + D

△S°rxn = -281.1 J/K

△H°rxn = -163.0 kJ .

We can use Gibbs free energy (ΔG) to determine the spontaneity of a reaction. The relationship between Gibbs free energy, enthalpy, and entropy is given by:

ΔG° = ΔH° - TΔS°

where ΔG° is the standard free energy change, ΔH° is the standard enthalpy change, ΔS° is the standard entropy change, and T is the temperature in Kelvin.

For a reaction to be spontaneous under standard conditions (i.e., ΔG° < 0), we need:

ΔG° = ΔH° - TΔS° < 0

Solving for T, we get:

T > ΔH° / ΔS°

Plugging in the given values, we get:

T > (-163.0 kJ) / (-281.1 J/K) = 580.5 K = 307.4 °C (rounded to one decimal place)

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A gauge pressure is measuring 4. 66 atm of pressure inside a basketball. What is the absolute pressure inside the basketball?

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The absolute pressure inside the basketball can be calculated by adding the atmospheric pressure to the gauge pressure. Atmospheric pressure is typically around 1 atm at sea level.

Therefore, the absolute pressure inside the basketball can be calculated as the sum of the gauge pressure and the atmospheric pressure.

In this case, the gauge pressure is given as 4.66 atm. Assuming atmospheric pressure is 1 atm, the absolute pressure inside the basketball would be:

Absolute pressure = Gauge pressure + Atmospheric pressure

Absolute pressure = 4.66 atm + 1 atm

Absolute pressure = 5.66 atm

Therefore, the absolute pressure inside the basketball is 5.66 atm. This represents the total pressure exerted by the gas inside the basketball, including both the gauge pressure and the atmospheric pressure.

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what volume (in l) of gas is formed by completely reacting 55.1g of potassium sulfite at 1.34 atm and 22.1˚c.

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We need to know the balanced chemical equation for the reaction as well as the molar mass of potassium sulfite in order to calculate the volume of gas produced by the reaction of 55.1 g of potassium sulfite.

The reaction of potassium sulfite has the following balanced chemical equation:

2KCl + H2O + SO2 = K2SO3 + 2HCl

According to the equation, one mole of potassium sulfite (K2SO3) produces one mole of sulphur dioxide (SO2).

We use the molar mass of K2SO3, which is 174.27 g/mol, to determine how many moles there are in 55.1 g:

K2SO3 moles are equal to 55.1 g/174.27 g/mol, or 0.316 moles.

Since one mole of K2SO3 yields one mole of SO2, 0.316 moles of SO2 are also produced.

We can use the ideal gas law to determine the volume of gas generated:

PV = nRT

where R is the gas constant, n is the number of moles, P is the pressure, V is the volume, and T is the temperature in Kelvin.

The temperature must first be converted from Celsius to Kelvin:

T = 22.1°C + 273.15 = 295.25 K

Next, we can enter the values we are aware of:

R = 0.0821 Latm/molK, P = 1.34 atm, and n = 0.316 moles.

T = 295.25 K

By calculating V, we obtain:

V = (nRT)/P = (0.316 moles * 0.0821 Latm/molK * 295.25 K)/ 1.34 atm 5.69 L

Therefore, at 1.34 atm and 22.1°C, the entire reaction of 55.1 g of potassium sulfite produces around 5.69 L of gas.

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Make an energy graph for a collision method that you tested but have not yet discussed with the class. When making your graph, be sure to decide the following:



What to include in the system


The relative kinetic energy before and after the collision


How to represent the change

Answers

The energy graph for a collision method includes the system under consideration, the relative kinetic energy before and after the collision, and how the change in energy is represented.

In this collision method, let's consider a system consisting of two objects: Object A and Object B. The relative kinetic energy of the system before the collision is represented by a certain value on the y-axis of the graph. This value will depend on the masses and velocities of the objects involved in the collision.

During the collision, energy may be transferred between the objects. If the collision is elastic, the total kinetic energy of the system will remain constant. In this case, the graph would show a horizontal line at the same level as the initial relative kinetic energy.

However, if the collision is inelastic, some kinetic energy will be lost, and the graph would show a decrease in the relative kinetic energy. The extent of the decrease will depend on factors such as the nature of the collision and the objects involved.

To represent the change in energy, we can plot the relative kinetic energy after the collision on the y-axis of the graph. The difference between the initial and final values of the relative kinetic energy will indicate the change in energy resulting from the collision.

By analyzing the energy graph, we can gain insights into the nature of the collision and the energy transformations that occur during the process.

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A student wrote the following response to the question, What are elodea plants


made of?


Elodea plants are made of cells, cell walls, cytoplasm, and chloroplasts.



His friend told him that he forgot to include the levels of complexity.



Improve on the first student’s response, keeping in mind his friend’s suggestion

Answers

Elodea plants are composed of various levels of complexity, including cells, tissues, organs, and organ systems. At the cellular level, they consist of cells with cell walls, cytoplasm, and chloroplasts. The different levels of complexity contribute to the overall structure and functioning of the plant.

Elodea plants exhibit hierarchical levels of organization, from cells to organ systems. At the cellular level, they are composed of plant cells, which are enclosed by cell walls made of cellulose. The cell walls provide structural support and protection. Within the cells, the cytoplasm contains various organelles, including chloroplasts. Chloroplasts are responsible for photosynthesis, where light energy is converted into chemical energy to produce glucose.

Moving beyond the cellular level, elodea plants also possess tissues, which are groups of cells with similar functions. These tissues work together to perform specific tasks. For example, the leaf tissue contains specialized cells that facilitate gas exchange and photosynthesis. Organs, such as leaves, stems, and roots, are formed by different tissues working in coordination. Each organ has specific functions, such as nutrient absorption in roots or photosynthesis in leaves.

At the highest level of complexity, elodea plants have organ systems. The combination of roots, stems, and leaves forms the shoot system, responsible for water and nutrient transport, support, and photosynthesis. The root system anchors the plant, absorbs water and minerals, and stores nutrients.

In summary, elodea plants exhibit various levels of complexity, ranging from cells to organ systems. Understanding these levels helps us appreciate the intricate structure and functioning of these plants.

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if there is 730 ml of champagne in the bottle, how many milliliters of alcohol are present?

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If a bottle of champagne contains 730 ml of liquid, then it contains 87.6 ml of alcohol.

The alcohol content of champagne can vary, but typically it is around 12% alcohol by volume (ABV). Therefore, if there are 730 ml of champagne in the bottle, the amount of alcohol present can be calculated as follows:

Alcohol content = volume of champagne x ABV

Alcohol content = 730 ml x 0.12

Alcohol content = 87.6 ml

Therefore, there are approximately 87.6 milliliters of alcohol present in the 730 ml bottle of champagne.

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When the following redox equation is balanced with smallest whole number coefficients, the coefficient for zinc will be _____.Zn(s) + ReO4-(aq) → Re(s) + Zn2+(aq) (acidic solution)A. 2B. 7C. 8D. 16

Answers

The correct coefficient for zinc is "8", since we need to multiply the coefficient by the subscripts in the formula of Zn. the correct answer is option (D) 16.

To balance the given redox equation, we need to assign oxidation numbers to each element first. Here, zinc has an oxidation number of 0 since it is in its elemental state, and the oxidation number of oxygen in ReO4- is -2. Therefore, the oxidation number of Re is +7.

Next, we can balance the equation using the half-reaction method. First, we balance the oxygen atoms by adding H2O to the side of the equation that needs more oxygen. This gives us:

Zn(s) + ReO4-(aq) + 8H+(aq) → Re(s) + Zn2+(aq) + 4H2O(l)

Next, we balance the hydrogen atoms by adding H+ to the other side:

Zn(s) + ReO4-(aq) + 8H+(aq) → Re(s) + Zn2+(aq) + 4H2O(l) + 8H+(aq)

Now we can balance the electrons by multiplying the zinc half-reaction by 8:

8Zn(s) + ReO4-(aq) + 16H+(aq) → Re(s) + 8Zn2+(aq) + 4H2O(l) + 8H+(aq)

Therefore, the correct answer is option D.

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The balanced equation with smallest whole number coefficients is:

[tex]Zn(s) + 4H+(aq) + ReO4-(aq) → Re(s) + Zn2+(aq) + 2H2O(l)[/tex]

Therefore, the coefficient for zinc is 1.

To balance the redox equation in acidic solution, first, we write down the unbalanced equation:

Zn(s) + ReO4-(aq) → Re(s) + Zn2+(aq)

Next, we identify the oxidation states of each element in the equation:

[tex]Zn(s) → Zn2+(aq) (+2)[/tex]

[tex]ReO4-(aq) → Re(s) (+7)[/tex]

We can see that zinc is being oxidized (losing electrons) while rhenium is being reduced (gaining electrons).

To balance the equation, we add water molecules and hydrogen ions to balance the charge and oxygen atoms:

[tex]Zn(s) → Zn2+(aq) + 2e-[/tex]

[tex]ReO4-(aq) + 8H+(aq) + 3e- → Re(s) + 4H2O(l)[/tex]

Now, we balance the electrons by multiplying the half-reactions by appropriate coefficients:

[tex]Zn(s) + 4H+(aq) + ReO4-(aq) → Re(s) + Zn2+(aq) + 2H2O(l)[/tex]

The coefficient for zinc is 1, which is the smallest whole number coefficient.

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what is the hydronium ion concentration of a 0.100 m hypochlorous acid solution with ka= 3.5x10-8 the equation for the dissociation of hypochlorous acid is: hocl(aq) h2o(l) ⇌ h3o (aq) ocl-(aq)

Answers

The concentration of hydronium ions in a 0.100 M hypochlorous acid solution with a Ka value of 3.5 x 10⁻⁸ is (b) 1.9 × 10⁻⁵ M.

The dissociation reaction for hypochlorous acid is:

HOCl(aq) + H₂O(l) ⇌ H₃O⁺(aq) + OCl⁻(aq)

The equilibrium constant expression for this reaction is:

Kₐ = [H₃O⁺][OCl⁻]/[HOCl]

We are given the value of Kₐ as 3.5 x 10⁻⁸ and the initial concentration of HOCl as 0.100 M. Let the concentration of H₃O⁺ and OCl⁻ at equilibrium be x M. Then we can write:

[tex]K_a = \frac{x^2}{0.100 - x}[/tex]

Since the dissociation constant is very small, we can assume that the change in concentration of HOCl is negligible compared to its initial concentration. This means that we can assume that x ≈ [H₃O⁺] ≈ [OCl⁻]. Substituting this in the above expression, we get:

[tex]K_a = \frac{x^2}{0.100 - x}[/tex]

[tex]3.5 \times 10^{-8} = \frac{x^2}{0.100 - x}[/tex]

x² = 3.5 x 10⁻⁹ (0.100 - x)

x² = 3.5 x 10⁻⁹ (0.100) - 3.5 x 10⁻⁹ x

x² + 3.5 x 10⁻⁹ x - 3.5 x 10⁻¹⁰ = 0

Solving for x using the quadratic formula:

[tex]x = \frac{{-3.5 \times 10^{-9} \pm \sqrt{{(3.5 \times 10^{-9})^2 + 4 \times 1 \times (3.5 \times 10^{-10})}}}}{{2 \times 1}}[/tex]

x = 1.9 × 10⁻⁵ M or x = -1.9 × 10⁻⁵ M

Since the concentration of H₃O⁺ cannot be negative, the only valid solution is:

[H₃O⁺] = [OCl⁻] = 1.9 × 10⁻⁵ M

Therefore, the hydronium ion concentration of the 0.100 M hypochlorous acid solution is 1.9 × 10⁻⁵ M.

The correct answer is (b) 1.9 × 10⁻⁵ M.

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What is the hydronium ion concentration of a 0.100 M hypochlorous acid solution with Ka = 3.5 x 10⁻⁸ The equation for the dissociation of hypochlorous acid is:

HOCl(aq) + H₂O(l) ⇌ H₃O⁺(aq) + OCl⁻(aq)

Group of answer choices

a. 5.9 × 10-4 M

b. 1.9 × 10-5 M

c. 1.9 × 10-4 M

d. 5.9 × 10-5 M

For the following reaction:
N2+3H2⟶2NH3
What is the change in free energy inkJmol? The relevant standard free energies of formation are:
ΔG∘f,N2=0kJmolΔG∘f,H2=0kJmolΔG∘f,NH3=-16.3kJmol
Your answer should include three significant figures.

Answers

The change in free energy for this reaction is -32.6 kJ/mol.

For the given reaction, N2 + 3H2 ⟶ 2NH3, we can determine the change in free energy (ΔG) using the standard free energies of formation (ΔG°f) provided for each component.
The change in free energy for the reaction is calculated as:
ΔG° = Σ (ΔG°f, products) - Σ (ΔG°f, reactants)
For this reaction, we have:
ΔG° = [2 × (ΔG°f, NH3)] - [(ΔG°f, N2) + 3 × (ΔG°f, H2)]
Given the standard free energies of formation:
ΔG°f, N2 = 0 kJ/mol
ΔG°f, H2 = 0 kJ/mol
ΔG°f, NH3 = -16.3 kJ/mol
Substituting these values, we get:
ΔG° = [2 × (-16.3)] - [(0) + 3 × (0)]
ΔG° = -32.6 kJ/mol
Therefore, the change in free energy for this reaction is -32.6 kJ/mol, expressed to three significant figures.

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How many molecules of oxygen are produced when 29.2 g of water is decomposed by electrolysis according to this balanced equation: 2H2O(1) → 2H2 (g) + O2 (g) * a. 3.52 x 10^25 molecules b. 1.76 x 10^25 molecules c. 6.02 x 10^23 molecules d. 8.79 x 10^24 molecules

Answers

To find the number of molecules of oxygen produced, we first need to determine the number of moles of water decomposed using its molar mass:  29.2 g H2O x (1 mol H2O/18.015 g H2O) = 1.62 mol H2O

According to the balanced equation, 1 mole of water produces 1/2 mole of oxygen:

1.62 mol H2O x (1/2) mol O2/1 mol H2O = 0.81 mol O2

Finally, we can use Avogadro's number to convert moles of oxygen to molecules:

0.81 mol O2 x (6.022 x 10^23 molecules/mol) = 4.88 x 10^23 molecules

Therefore, the answer is d. 8.79 x 10^24 molecules is incorrect.

To determine how many molecules of oxygen are produced when 29.2 g of water is decomposed by electrolysis according to the balanced equation: 2H2O(1) → 2H2 (g) + O2 (g), please follow these steps:

1. Find the molar mass of water (H2O): (2 x 1.01 g/mol for H) + (1 x 16.00 g/mol for O) = 18.02 g/mol
2. Calculate the moles of water: 29.2 g / 18.02 g/mol = 1.62 moles of H2O
3. Use the stoichiometry of the balanced equation to determine moles of O2 produced: 1 mole of O2 is produced for every 2 moles of H2O, so (1.62 moles H2O) x (1 mole O2 / 2 moles H2O) = 0.81 moles O2
4. Convert moles of O2 to molecules: (0.81 moles O2) x (6.02 x 10^23 molecules/mol) = 4.87 x 10^23 molecules of O2

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this molecule has formula c21h?no5. how many hydrogens are present?

Answers

The formula for heroin is actually [tex]C_2_1H_2_3NO_5[/tex]. Therefore, there are 23 hydrogen atoms present in a heroin molecule.

The formula for the molecule given is incomplete, as it is missing one or more of the elemental symbols. Assuming that the molecule is heroin, which has the molecular formula [tex]C_2_1H_2_3NO_5[/tex]., we can determine the number of hydrogens present using the formula:

Number of hydrogens = 2n + 2 - (m + x)/2

where n is the number of carbons, m is the number of nitrogens, and x is the number of halogens (in this case, there are no halogens).

Plugging in the values for heroin, we get:

Number of hydrogens = 2(21) + 2 - (1 + 0)/2

= 23

Therefore, there are 23 hydrogens present in heroin.

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Heroin this molecule has formula c21h?no5. how many hydrogens are present?

at 298 k, a cell reaction exhibits a standard emf of 0.21 v. the equilibrium constant for the reaction is 1.31 x 107. what is the value of n for the cell reaction?

Answers

The value of n for the cell reaction is 2, which indicates that two electrons are transferred in the reaction. we can use the relationship between the standard emf (E°), the equilibrium constant (K), and the number of electrons transferred (n) in the cell reaction. The formula is: E° = (0.0592/n) x log(K)

Where 0.0592 is the value of RT/F at room temperature (298K), R is the gas constant, F is the Faraday constant, and log is the base 10 logarithm.

We can rearrange this formula to solve for n:

n = 0.0592 / (E° / log(K))

Plugging in the given values, we get:

n = 0.0592 / (0.21 / log(1.31 x 10^7))
n = 2

Therefore, the value of n for the cell reaction is 2, which indicates that two electrons are transferred in the reaction.

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35. 3 of element m is reacted with nitrogen to produce 43. 5g of compound M3N2. What is the name of element m

Answers

Element M reacts with nitrogen to form compound [tex]M_3N_2[/tex]with a mass of 43.5g. The name of element M is magnesium.

Based on the information provided, the compound [tex]M_3N_2[/tex]is formed when element M reacts with nitrogen. The subscript "3" in the formula indicates that three atoms of element M combine with two atoms of nitrogen.

To determine the name of element M, we need to refer to the periodic table and find an element that can combine with nitrogen to form [tex]M_3N_2[/tex]. By looking at the periodic table, we can identify that the element with the symbol M should have a molar mass that corresponds to the given mass of 43.5g. Comparing the molar masses of elements, we find that the element with the symbol M is magnesium (Mg). Therefore, the name of element M is magnesium.

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consider a substance with a melting point of 176 k. if this substance is in a container at 115 k what will the value be for ∆suniv for the process of melting this substance, in kj? (∆hfus= 239 kj/mol)

Answers

we need to use the formula for Gibbs free energy change (∆G) which is:∆G = ∆H - T∆S ∆H is the enthalpy change, T is the temperature in Kelvin, and ∆S is the entropy change.

we know that the substance has a melting point of 176 K, which means that at temperatures below this point, the substance is a solid and above this point, it is a liquid. We also know that the substance has a heat of fusion (∆Hfus) of 239 kJ/mol.

∆suniv for the melting process, we need to consider both the entropy change (∆S) and the enthalpy change (∆H). The entropy change for the melting process can be calculated using the equation

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Which of the following statement(s) is/are correct? 1) The energy change when 10 is (hypothetically) formed from 8 protons and 8 neutrons is known as the energy defect. ii) The splitting of a heavier nucleus into two nuclei with smaller mass numbers is known as nuclear fission. iii) The first example of nuclear fission involved bombarding 92 235 U with He nuclei.

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Statement (ii) and (iii) are correct, but statement (i) is incorrect. ii) The splitting of a heavier nucleus into two nuclei with smaller mass numbers is known as nuclear fission.  iii) The first example of nuclear fission involved bombarding 92 235 U with He nuclei. are.

Statement (i) is incorrect. The energy change when a nucleus is formed from its constituent nucleons is called the binding energy. It is the energy released when the nucleus is formed and is equivalent to the mass defect, which is the difference between the mass of the nucleus and the sum of the masses of its individual nucleons.

Statement (ii) is correct. Nuclear fission is the process of splitting a heavier nucleus into two nuclei with smaller mass numbers. This process releases a large amount of energy and is the basis for nuclear power generation and nuclear weapons.

Statement (iii) is also correct. In 1938, German scientists Otto Hahn and Fritz Strassmann bombarded uranium-235 with neutrons and observed the formation of barium and krypton. This was the first example of nuclear fission. However, it was Lise Meitner and her nephew Otto Frisch who recognized that the process involved the splitting of the nucleus and explained it using the concept of nuclear fission.

In summary, The correct term for the energy change when a nucleus is formed from its constituent nucleons is binding energy, not energy defect. Nuclear fission involves the splitting of a heavier nucleus into two nuclei with smaller mass numbers, and the first example of nuclear fission involved bombarding uranium-235 with neutrons, not helium nuclei.

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Statement (ii) and (iii) are correct, but statement (i) is incorrect. ii) The splitting of a heavier nucleus into two nuclei with smaller mass numbers is known as nuclear fission.  

Statement (i) is incorrect. The energy change when a nucleus is formed from its constituent nucleons is called the binding energy. It is the energy released when the nucleus is formed and is equivalent to the mass defect, which is the difference between the mass of the nucleus and the sum of the masses of its individual nucleons. Statement (ii) is correct. Nuclear fission is the process of splitting a heavier nucleus into two nuclei with smaller mass numbers. This process releases a large amount of energy and is the basis for nuclear power generation and nuclear weapons. Statement (iii) is also correct. In 1938, German scientists Otto Hahn and Fritz Strassmann bombarded uranium-235 with neutrons and observed the formation of barium and krypton. This was the first example of nuclear fission. However, it was Lise Meitner and her nephew Otto Frisch who recognized that the process involved the splitting of the nucleus and explained it using the concept of nuclear fission. In summary, The correct term for the energy change when a nucleus is formed from its constituent nucleons is binding energy, not energy defect. Nuclear fission involves the splitting of a heavier nucleus into two nuclei with smaller mass numbers, and the first example of nuclear fission involved bombarding uranium-235 with neutrons, not helium nuclei.

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Estimate the enthalpy change for an acid base reaction that increases the temperature of 15.0 g of solution in a coffee cup calorimeter by 100 °C The specific hear of water is approximately 4J/g °C. a) 600J. b) -600J. c) 200J. d) -200J.

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The enthalpy change for the acid-base reaction is ΔH = -6000 J. when an acid base reaction that increases the temperature of 15.0 g of solution in a coffee cup calorimeter by 100 °C The specific hear of water is approximately 4J/g °C.

To estimate the enthalpy change for the acid-base reaction, we can use the equation:

ΔH = mcΔT

where ΔH is the enthalpy change, m is the mass of the solution, c is the specific heat capacity of water, and ΔT is the temperature change.

Given:
m = 15.0 g (mass of the solution)
c = 4 J/g°C (specific heat capacity of water)
ΔT = 100 °C (temperature change)

Now, plug in the values into the equation:

ΔH = (15.0 g) × (4 J/g°C) × (100 °C)

ΔH = 6000 J

Since the temperature increases during the reaction, it means that the reaction is exothermic and the enthalpy change should be negative. So, the correct answer is:

ΔH = -6000 J

However, none of the provided answer choices matches the calculated value. Please double-check the values or answer choices given in the question.

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resonance structures contribute to the stability of the given carbocation. follow the directions to complete the resonance structure drawn. Add one curved arrow to show the movement of an electron pair that results in the positive charge moving to the 1-position of the ring. Draw two double bonds to complete the resonance structure that has a positive charge at the 1-position of the ring. H H 1 BrH BrH Q2 Q Q2 Q

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The two double bonds are drawn between the carbon at the 1-position and the adjacent carbons, which both have a negative charge. This structure shows that the positive charge is delocalized throughout the ring, making the carbocation more stable.

Resonance structures are important in determining the stability of carbocations. To complete the resonance structure drawn, we need to add one curved arrow to show the movement of an electron pair that results in the positive charge moving to the 1-position of the ring. This movement of electrons creates a new bond between the carbon at the 1-position and the adjacent carbon, which now has a positive charge.
To complete the resonance structure, we need to draw two double bonds that have a positive charge at the 1-position of the ring.
Overall, resonance structures are important in stabilizing carbocations by spreading out the positive charge throughout the molecule. By completing the resonance structure with two double bonds that have a positive charge at the 1-position of the ring, we can see the importance of delocalization of charge in creating a more stable carbocation.

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Use the model to answer the question.


Examine the model.


(x Х


1. 1.


Х


х


Х


1. 1.


X


How does the process inside the box on the model influence the genes of an offspring?


The process creates new genes, which increases the genetic variation in the offspring.


The process exchanges genes, which results in genetic variation in the offspring.


The process duplicates chromosomes, which results in more genetic information in the offspring


The process removes chromosomes, which results in less genetic information in the offspring

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The process inside the box on the model that influences the genes of an offspring is not clearly defined or described.

Without specific information about the process, it is difficult to determine its impact on the genes of an offspring. The options provided in the question are speculative and do not align with known biological processes. To accurately understand how a process influences the genes of an offspring, it is necessary to provide more details about the specific process in question. Genetic variation in offspring can arise through various mechanisms, including genetic recombination, mutation, and meiosis. Each process has distinct effects on the genetic information passed on to offspring.

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alculate the osmotic pressure of a solution that contains 0.110 mol ethanol in 0.100 l at 294 k.

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Answer:Main answer: The osmotic pressure of a solution containing 0.110 mol of ethanol in 0.100 L at 294 K is approximately 2.18 atm.

Supporting explanation: The osmotic pressure (π) of a solution is given by π = MRT, where M is the molarity of the solution, R is the gas constant, and T is the temperature in kelvins. To calculate the osmotic pressure of the given solution, we need to first calculate its molarity (M). Molarity is defined as the number of moles of solute per liter of solution. Therefore, the molarity of the given solution is 0.110 mol/0.100 L = 1.10 M.

Substituting the values of M, R, and T into the equation, we get π = (1.10 mol/L) x (0.0821 L atm/K mol) x (294 K) = 2.18 atm (approx). Therefore, the osmotic pressure of the given solution is approximately 2.18 atm.

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Based on the equation and the information in the table, what is the enthalpy of the reaction? Use Delta H r x n equals the sum of delta H f of all the products minus the sum of delta H f of all the reactants. –453. 46 kJ –226. 73 kJ 226. 73 kJ 453. 46 kJ.

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To determine the enthalpy of the reaction, we can use Hess's Law, which states that the enthalpy change of a reaction is equal to the sum of the enthalpies of formation of the products minus the sum of the enthalpies of formation of the reactants.

The enthalpy of the reaction is -453.46 kJ.

To calculate the enthalpy of the reaction, we need to know the enthalpies of formation (ΔHf) for all the reactants and products involved in the reaction. The enthalpy of formation is the enthalpy change when one mole of a compound is formed from its constituent elements in their standard states.

Once we have the enthalpies of formation for all the reactants and products, we can substitute them into the equation ΔHrxn = ΣΔHf(products) - ΣΔHf(reactants) to calculate the enthalpy change of the reaction.

Since the information provided in the question does not include the enthalpies of formation for the reactants and products, we cannot determine the specific enthalpy value using the given equation and table. Therefore, without the necessary data, we cannot provide a specific enthalpy value for the reaction.

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NH.NO, dissolves spontaneously and endothermically in water at room temperature. What can you deduce about the sign and size of As for this solution process relative to the size and sign of AH?

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NH₄NO₃ dissolves endothermically and non-spontaneously in water, with positive ∆H and ∆S.


How does NH.NO dissolve?

Since NH₄NO₃ dissolves spontaneously and endothermically in water at room temperature, it implies that the solution process is non-spontaneous in the opposite direction, and the sign of ∆G for this process is positive. Therefore, the sign of ∆S must be positive, indicating an increase in disorder, and the sign of ∆H must be positive, indicating an endothermic process.

Regarding the relationship between the magnitudes of As and AH, it is not possible to make any definitive conclusions without additional information. The magnitude of As depends on the increase in entropy of the system and the surroundings, while the magnitude of AH depends on the amount of heat absorbed by the system during the process.

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sodium carbonate and zinc sulfate express your answer as an ion. if there is more than one answer, separate each by using a comma.

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Sodium carbonate can be expressed as Na+ and CO3 2-, while zinc sulfate can be expressed as Zn2+ and SO4 2-.

Sodium carbonate (Na2CO3) and zinc sulfate (ZnSO4) can be expressed as ions as follows:
Sodium carbonate dissociates into 2 sodium ions (Na+) and 1 carbonate ion (CO3²⁻).
Zinc sulfate dissociates into 1 zinc ion (Zn²⁺) and 1 sulfate ion (SO4²⁻).
Sodium carbonate can be expressed as the ions Na+ (sodium cation) and CO3 2- (carbonate anion). Zinc sulfate can be expressed as the ions Zn2+ (zinc cation) and SO4 2- (sulfate anion). Therefore, the ionic forms of sodium carbonate and zinc sulfate are Na2CO3 and ZnSO4, respectively. Both sodium carbonate and zinc sulfate are important industrial chemicals with a wide range of applications in various fields. Understanding their chemical properties and behaviors is important for their safe handling and effective use in different applications.

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The pH of a 0.19 M solution of acid HCN is found to be 5.02. What is the Ka of the acid? The equation described by the Ka value is HCN(aq)+H2O(l)⇌CN−(aq)+H3O+(aq) Report your answer with two significant figures.

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The Ka of HCN is [tex]3.3 * 10^{(-10)}[/tex] with two significant figures.

The Ka of the acid HCN can be determined using the given pH and concentration information. The first step is to calculate the concentration of H3O+ ions in the solution using the pH:

[tex]pH = -log[H_3O+] \\\\5.02 = -log[H_3O+] \\\\[H_3O+] = 10^{(-5.02) }= 7.94 * 10^{(-6)} M[/tex]

Next, use the balanced chemical equation for the ionization of HCN and the equilibrium expression for Ka to set up an equation to solve for Ka:

[tex]HCN(aq) + H_2O(l)[/tex] ⇌[tex]CN-(aq) + H_3O+(aq)[/tex]

[tex]Ka = [CN-][H_3O+] / [HCN][/tex]

At equilibrium, the concentration of CN- ions is equal to the concentration of H+ ions, since HCN is a weak acid and does not completely dissociate.

Therefore, [CN-] ≈ [tex][H_3O+] = 7.94 * 10^{(-6)} M[/tex]. The concentration of HCN is given as 0.19 M.

Substituting these values into the expression for Ka:

[tex]Ka = (7.94 * 10^{(-6)} M)^2 / 0.19 M = 3.3 * 10^{(-10)}[/tex]

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Write the full electron configuration for S2- full electron configuration: What is the atomic symbol for the noble gas that also has this electron configuration? atomic symbol:

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The full electron configuration for S2- is 1s2 2s2 2p6 3s2 3p6. The atomic symbol for the noble gas that also has this electron configuration is Ar, which stands for Argon.

Neutral sulfur (S) atom and then add 2 electrons to account for the 2- charge.

The atomic number of sulfur is 16, so a neutral sulfur atom has 16 electrons. The electron configuration for a neutral sulfur atom is:

1s² 2s² 2p⁶ 3s² 3p⁴

Now, to account for the 2- charge, we need to add 2 electrons to the configuration. This will give us:

1s² 2s² 2p⁶ 3s² 3p⁶

Therefore, This electron configuration corresponds to a noble gas, which is argon (Ar). The atomic symbol for the noble gas that has the same electron configuration as S2- is Ar.

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knowing the following: mp = 1.0073 amu, mn = 1.0087 amu, and me- = 0.00055 amu, calculate the energy released by the fusion of one mole of br-81 (mass = 80.9163 amu)

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Using Einstein's equation, we can calculate the energy released by the fusion of one mole of br-81: E = Delta m * c² * Avogadro's number
E = -1.9885 amu * (2.998 x 10⁸ m/s)² * 6.022 x 10²³/mol
E = -3.17 x 10¹¹ J/mol

To calculate the energy released by the fusion of one mole of br-81, we need to first determine the mass of the products after fusion.

The fusion of br-81 involves the combination of a bromine atom with a hydrogen atom to form krypton-83 and a neutron. The mass of krypton-83 is 82.91413 amu (80.9163 amu + 1.0073 amu + 0.00055 amu) and the mass of the neutron is 1.0087 amu.

Therefore, the total mass of the products after fusion is 83.92283 amu (82.91413 amu + 1.0087 amu).

To calculate the energy released by fusion, we can use the famous Einstein's equation E = mc², where E is the energy, m is the mass, and c is the speed of light.

The change in mass during fusion is given by the difference between the mass of the reactants (br-81 and hydrogen) and the mass of the products (krypton-83 and neutron), which is:

Delta m = (mass of reactants) - (mass of products)
Delta m = (80.9163 amu + 1.0073 amu) - (82.91413 amu + 1.0087 amu)
Delta m = -1.9885 amu

The negative sign indicates that mass is lost during fusion.

Using Einstein's equation, we can calculate the energy released by the fusion of one mole of br-81:

E = Delta m * c² * Avogadro's number
E = -1.9885 amu * (2.998 x 10⁸ m/s)² * 6.022 x 10²³/mol
E = -3.17 x 10¹¹ J/mol

Note that the negative sign indicates that energy is released during fusion, as expected. The magnitude of the energy released is quite large, which highlights the potential of fusion as a source of energy.

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