Why do you think the reaction between tetraphenylcyclopentadienone and dimethyl acetylenedicarboxylate can be conducted at relatively lower temperature compared to the reaction between tetraphenylcyclopentadienone and diphenylacetylene?

Answers

Answer 1

Answer:

See explanation

Explanation:

The reaction between tetraphenylcyclopentadienone and dimethyl acetylenedicarboxylate as well as the reaction of  tetraphenylcyclopentadienone and diphenylacetylene are  Diels Alder reactions. The former is performed in presence of a solvent while the former is performed neat.

The reaction of tetraphenylcyclopentadienone and dimethyl acetylenedicarboxylate leads to the formation of a more resonance-stabilized aromatic ring(lower energy product) compared to the reaction of  tetraphenylcyclopentadienone and diphenylacetylene.

Hence, the reaction between tetraphenylcyclopentadienone and dimethyl acetylenedicarboxylate can be conducted at relatively lower temperature compared to the reaction between tetraphenylcyclopentadienone and diphenylacetylene.


Related Questions

If 25.00 mL of 6.00 M HCl is transferred by pipet into a volumetric flask and diluted to 5.00 L, what is the molarity of the diluted HCl?

Answers

Answer:

0.03 M

Explanation:

The computation of the molarity of the diluted HCI is given below:

As we know that

(M1) × (V1) = (M2) × (V2)

Now

(M2) = {(M1) × (V1)} ÷ (V2)

or

Molarity of the diluted HCl,(M2) is

= {6 × 25} ÷ 5000

= 0.03 M

How are people and the landscape impacted by earthquake?

Answers

they are impacted because people loose their home due to the wreckage that has happend and landscapes are ruined due to landslides

Answer:

Well the landscape is torn up, it goes through quite a bit of damage. the plants, animals, and water are all affected by it. when a earth quake hits it destroyes most everything, houses fall into the ground and are destroyed, people die. Earthquakes destry electrical wires and many other things

Explanation:

Sorry I did not answer it full, but you can look it up online.

A) Suppose you separate a 3.02 g mixture of sand and salt. You recover 1.43 g of salt and 1.41 g of sand. What is the percent recovery of the mixture?
B) Suppose you separate a 3.02 g mixture of sand and salt. You recover 1.43 g of salt and 1.41 g of sand. What is the percent recovery of the mixture?
C) Calculate the percent by mass of a solution made from 15 g NaCl (the solute) and 69 g water.
D) What percent of 73.0 g is 26.1 g?

Answers

Answer:

A-B) 94 %.

C) 17.9 %.

D) 35.8 %.

Explanation:

Hello!

A-B) In this case, since the total mass of the mixture is 3.02 g and 1.43g+1.41g=2.84 g are recovered in total, we can compute the percent recovery as shown below:

[tex]\%rec=\frac{2.84g}{3.02g}*100\%\\\\\%rec=94\%[/tex]

C) Here, since the solution is made up of NaCl and water, we can say that the mass of the solution is 15g+69g=84g; thus, the percent by mass would be:

[tex]\%=\frac{15g}{84g}*100\%\\\\\%=17.9\%[/tex]

D) In this case, we simply divide 26.1 g by 73.0 g in order to obtain the percent:

[tex]\%=\frac{26.1g}{73.0g}*100\%\\\\\%=35.8\%[/tex]

Best regards!

The percentage in the cases are as follows;

A and B is; 94%C is; 17.9%D is; 35.8%

Questions A and B are similar and can be solved as follows;

The total mass of the mixture is 3.02g.The recovered mass = 1.43g + 1.41g = 2.84g

% recovery = (2.84/3.02) × 100%

% recovery = 94%

Question C can be solved as follows;

Total mass of solution = 15 + 69 = 84gMass of solute = 15g

% by mass = (15/84) × 100%

% by mass = 17.9%

Question D can be solved as follows;

% = (26.1/73) × 100%% = 35.8%

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What is the vapor pressure of a solution in which the mole fraction of the solute is 0.200 and the vapor pressure of the pure solvent is 100.0 torr? (Assume a single nonvolatile, nonelectrolyte solute).
a. 0 torr
b. 80.0 torr
c. 100.0 torr
d. 120.0 torr
e. 20.0 torr

Answers

Answer: The vapor pressure of a solution in which the mole fraction of the solute is 0.200 is 80.0 torr

Explanation:

As the relative lowering of vapor pressure is directly proportional to the amount of dissolved solute.

The formula for relative lowering of vapor pressure will be,

[tex]\frac{p^o-p_s}{p^o}=i\times x_2[/tex]

where,

[tex]p^0[/tex]= vapor pressure of pure solvent = 100.0 torr

[tex]p_s[/tex] = vapor pressure of solution = ?

i = Van'T Hoff factor = 1 for nonvolatile, nonelectrolyte solute

[tex]x_2[/tex] = mole fraction of solute  = 0.200  

[tex]\frac{100.0-p_s}{100.0}=1\times 0.200[/tex]

[tex]p_s=80.0torr[/tex]

The vapor pressure of a solution in which the mole fraction of the solute is 0.200 is 80.0 torr

Which word best describes the relationship between polyps and algae
exoskeletal
Bleached
Photosynthetic
Symbiotic

Answers

Answer:

symbiotic

Explanation:

There like a close friendship

The average adult heart pumps about 84./mLs of blood at 72 beats per minute. Suppose you need to calculate how long it would take the average heart to circulate 1700.mL of blood. Set the math up.

Answers

Answer:

1700 mL / 84 mLs

Explanation:

Given that:

Volume of blood pumped per minute = 84 /mLs

Time it takes to circulate 1700 mL of blood :

Time taken = Volume of blood circulate / Rate

Hence, to circulate 1700 mL of blood :

Time taken = 1700 mL / 84 mLs

3. Noble gases are sometimes called "inert gases." What can you infer about the meaning of the word "inert" in chemistry?

Answers

Answer:

Noble gases are sometimes called "inert gases." What can you infer about the meaning of the word "inert" in chemistry? It refers to substances that easily lose electrons. It refers to substances that do not react with other substances. It refers to substances that have strong electrochemical charges.

Explanation:

Attempt 2
Four marbles are made of different metals. Each marble has the same mass, but a different volume. The density of each
metal is given in the table.
Metal
Density (g/mL)
aluminum
2.70
silver
10.5
rhenium
20.8
nickel
8.90
Place the marbles in order from largest to smallest.
Largest

Answers

Lets let our mass equal 3 on alletals and solve using d=m/v equation

Aluminum
V=3/2.70=1.11
Silver
V=3/10.5=.286
Rhenium
V=3/20.8=.144
Nickel
V=3/8.90=.337
This gives us the following list from largest to smallest Aluminum, Nickel, Silver, and Rhenium

The order of marbles can be Aluminum, Nickel, Silver, and Rhenium.

What is volume?

If volume is the amount of three-dimensional space contained by a closed surface, such as the amount of space within a given cube, cylinder, or other three-dimensional shape.

Liquid volume is a way to measure an amount of liquid by describing how much three-dimensional space it occupies.

The mass of something is the amount of stuff it is made of. The volume of an object is the amount of space it usually takes up.

Density provides an easy way to calculate a body's mass from its volume or vice versa.

The mass is equal to the volume multiplied by the density (M = Vd), and the volume is equal to the mass divided by the density (V = M/d).

As per the density given, the volume of aluminum can be 1.11mL, Silver is 0.286mL, Rhenium is 0.144mL, Nickel is 0.337mL.

Thus, the order from largest to smallest will be Aluminum, Nickel, Silver, and Rhenium.

For more details regarding volume, visit:

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Using the van der Waals equation, determine the pressure exerted by 4.30 mol Ar in 3.6 L at 325K.

Answers

Answer:

37.7 atm

Explanation:

Using the relation;

(P + an^2/V^2) (V - nb) = nRT

(P + an^2/V^2) = nRT/(V - nb)

a = 0.0341 atm dm^2 Mol^2

b = 0.0237 dm/mol

P = nRT/(V - nb) - an^2/V^2

P = [4.3 * 0.082 * 325 / (3.6 - (4.3 * 0.0237))] - (0.0341 * (4.3^2))/(3.6^2)

P = 114.595/(3.498) - 0.0487

P = 37.7 atm

1 In general, how many major glands are found in human body?
A. Eight
B. Ten
C! Thirty-two,
D. Forty six

Answers

Answer:

A. Eight

Explanation:

Although there are eight major endocrine glands scattered throughout the body, they are still considered to be one system because they have similar functions, similar mechanisms of influence, and many important interrelationships.

which one of the following a compounds a.sugar b.rock salt c.iron d.alloy
which one of the following a
compound ?
a.sugar c.alloy
brock salt d.iron

Answers

Answer:

a

Explanation:

sugar is composed of different elements combined in a manner form

PLS HELP ME WITH THIS ILL GIVE BRAINLIEST

Answers

Answer:

1 qualiative physical  

2 qualiative   chemical

3 quantitative physcial

4 quantiative chemical

5qualiative   physcial

6quatiative    chemcial

7quanatiative physcial

8 qualiative   chemical

9quatliate  physcial

Is energy absorbed or released during cellular respiration?

Absorbed

Released​

Answers

Answer:

Released

Explanation:

they convert into a form of energy that can be used by cells

4. Calculate the molarity of a solution made by dissolving 23.0 g NaCl in enough water to make 0.040 L
of solution?

Answers

Answer:

The molarity (M) of a solution is the number of moles of solute dissolved in one liter of solution. To calculate the molarity of a solution, you divide the moles of solute by the volume of the solution expressed in liters.

Explanation:

Calculate how many grams of BeCl2 are required to produce 0.52 grams of MnCl2

Answers

Answer:

65.0cp

Explanation:

How many moles in 2.33E25 molecules of NO?
0.0258 mol
3.87E20 mol
38.7 mol
2.58E48 mol
please show work ​

Answers

Answer:

0.0258 mol Answer .......

Rank the following compounds in order of increasing stability, putting the least stable first. Group of answer choices II < I < III I < II < III III < II < I III < I < II

Answers

Hello. You forgot and show the compounds. The compounds are in the attached image.

Answer:

I < II < III

Explanation:

The stability of the presented compounds must be analyzed, taking into account the free electrons to form arrangements between the atoms. In this case, the molecules of greater stability follow the concept of valence and are characterized as those that manage to reach a large number of elements that manage to obey the octet rule.

complete the equation C14H30 = ________ + C7H14

Answers

Answer:

C14H30 -----> C7H14 + C2H4 +C5H10

Explanation:

What is the difference between an introduced species and an invasive species?

Answers

Answer and Explanation:

The introduced species is, literally, a species that was introduced into an environment by human action. In other words, an introduced species is one that is not native to a region, does not occur naturally, but has been taken by humans to that region.

An invasive species, on the other hand, is one that was introduced naturally in an environment, but multiplied in a harmful way, causing a strong imbalance in the region.

Consider the reaction 2H2(g)+O2(g)→2H2O(l) 2 H 2 ( g ) + O 2 ( g ) → 2 H 2 O ( l ) What is the mass of water, H2O(l) H 2 O ( l ) , produced when 5.70 g g of O2(g) O 2 ( g ) reacts with excess H2(g) H 2 ( g ) ?hen 5.70 g g of O2(g) O 2 ( g ) reacts with excess H2(g) H 2 ( g ) ?

Answers

Answer:

mH₂O = 6.4116 g

Explanation:

Let's write the given reaction:

2H₂ + O₂ -------> 2H₂O

The problem states that 5.7 g of oxygen reacts with excess hydrogen, hence, the limiting reagent is the oxygen. With this mass of oxygen, we can determine the moles, and then, the moles of water with the mole ratio:

moles = mass / atomic weight        AW of O₂ = 16 g/mol

Replacing we have:

moles O₂ = 5.70 / (16 * 2)

moles O₂ = 0.1781 moles

According to the balanced reaction, 1 mole of Oxygen produces 2 moles of water, so we have a mole ratio 1:2, therefore the moles of water would be twice the moles of oxygen:

moles H₂O = 0.1781 * 2 = 0.3562 moles

Finally the mass of water can be calculated solving for the mass from the expression of moles, and using molecular mass of water:

m = moles * MM          MM H₂O = 18 g/mol

m = 0.3562 * 18

mH₂O = 6.4116 g

Hope this helps

Explain why NO is more soluble in water than either N2 or O2. Fill in the following blanks.

a. Compared to nitrogen, the ____________of ethylene makes it more soluble in water.
b. The high solubility of sulfur dioxide can be explained by its ______________
c. Nitric oxide is more soluble than nitrogen and oxygen because of its ______________
d. Compared to oxygen, nitrogen's _____________ makes it more difficult for water molecules to surround the nitrogen molecules.

1. Polarity
2. Ability to react with water
3. Shorter bond length
4. Larger molecular size

Answers

Answer:

a. Larger molecular size

b. Ability to react with water

c. Polarity

d. Shorter bond length

Explanation:

Ethene is a larger molecule than oxygen and nitrogen hence it is more soluble than the both other gases .

SO2 dissolves readily in water to yield an acid solution. It is an acid anhydride.

Nitric oxide is a polar compound. It remains very much polar while nitrogen and oxygen are non polar.

Nitrogen is sp hybrized, this leads to a very short bond and does not easily interact with oxygen and nitrogen

the first step in mitosis is the separateion of each pair of chromosomes true or false?

Answers

Answer:

true

Explanation:

Prophase is the first stage in mitosis, occurring after the conclusion of the G2 portion of interphase. During prophase, the parent cell chromosomes which were duplicated during S phase condense and become thousands of times more compact than they were during interphase.

how many grams of na2co3 would be needed to produce 1000g of nahco3

Answers

Answer:

630.95 grams of Na₂CO₃ would be needed to produce 1000g of NaHCO₃

Explanation:

The balanced reaction is:

Na₂CO₃ + CO₂+ H₂O → 2 NaHCO₃

By stoichiometry of the reaction (that is, the relationship between the amount of reagents and products in a chemical reaction), the following amounts of each compound participate in the reaction:

Na₂CO₃: 1 moles CO₂: 1 moleH₂O: 1 mole NaHCO₃: 2 moles

Being the molar mass:

Na₂CO₃: 106 g/moleCO₂: 44 g/moleH₂O: 18 g/moleNaHCO₃: 84 g/mole

Then by stoichiometry the following quantities of mass participate in the reaction:

Na₂CO₃: 1 mole* 106 g/mole= 106 gCO₂: 1 mole* 44 g/mole= 44 gH₂O: 1 mole* 18 g/mole= 18 gNaHCO₃: 2 moles* 84 g/mole= 168 g

You can apply the following rule of three: if 106 grams of Na₂CO₃ are needed to produce 168 grams of NaHCO₃, how much mass of Na₂CO₃ is necessary to produce 1000 grams of NaHCO₃?

[tex]mass of Na_{2} CO_{3}=\frac{1000grams ofNaHCO_{3} *106gramsofNa_{2} CO_{3} }{168grams ofNaHCO_{3}}[/tex]

mass of Na₂CO₃= 630.95 grams

630.95 grams of Na₂CO₃ would be needed to produce 1000g of NaHCO₃

To a flask, 15.0 mL of 1.25 M hydrofluoric acid is added. Then, 3.05 M NaOH is used to titrate the acid sample. Write the balanced net ionic equation for the acid-base reaction.

HF(aq) + OH^- → H2O(I) + F^-

Answers

Answer:

H^+(aq) + OH^-(aq) --------> H2O(l)

Explanation:

We must first obtain the molecular equation, the net ionic equation before we obtain the net ionic equation.

The molecular reaction equation is;

HF(aq) + NaOH(aq) -------> H2O(l) + NaF(aq)

The complete ionic equation is;

H^+(aq) + F^-(aq) + Na^+(aq) + OH^-(aq) --------> H2O(l) + Na^+(aq) + F^-(aq)

The net ionic equation is;

H^+(aq) + OH^-(aq) --------> H2O(l)

Discuss why it is not necessary to know exactly how much salt was added to the water in making the salt solution to just float the egg?

Answers

Answer and Explanation:

It is not necessary to know the amount of salt in the aqua, because we know that the presence of salt in the water will increase its density.

In this case, salt increases the mass of the water, without increasing the volume of water. as the egg will not change in volume or water, we know that the density of the egg will be constant, while the change in the mass of the water with the addition of salt, will change the density of the water which will increase progressively until it becomes denser than the egg and, consequently, it will not let the egg sink.

What is limited reactant?

Answers

Answer:

The limiting reagent is the reactant that is used up completely. This stops the reaction and no further products are made. ... The limiting reagent can also be derived by comparing the amount of products that can be formed from each reactant.

Answer:

The limiting reagent is the reactant that is used up completely. This stops the reaction and no further products are made. ... The limiting reagent can also be derived by comparing the amount of products that can be formed from each reactant.

Explanation:

Disclaimer not my answer I looked it up

Billy and Susie heat a 78.9 g sample of Unobtanium at 18.0C. Using a lab burner, they burn propane and the unobtanium absorbs 13,240 J of heat untill the temperature reaches the melting point 109C. what is the specific heat of unobtanium

Answers

Answer:

1.8 J/g·°C (2 sig.figs. per ΔT)

Explanation:

Given:

mass (m) = 78.9 grams

specific heat (c) = ?

Temp. Change (ΔT) = 109°C - 18°C = 91°C

Heat flow (q) = 13,240 Joules

q = m·c·ΔT => c = q/m·ΔT

∴c = 13,240J / 78.9g·91°C = 1.844 J/g·°C ≅ 1.8 J/g·°C (2 sig.figs. per ΔT)

What is the major organic product obtained from the reaction of 2,2-dimethyl-1-propanol aqueous HBr at reflux

Answers

Answer:

See explanation

Explanation:

The mechanism involves SN1 nucleophilic substitution reaction. The -OH group of the alcohol is first protonated. Since water is a good leaving group, -OH2 leaves the substrate creating a primary carbo cation.

A 1,2 methyl shift now occurs to create a tertiary carbo cation which is more stable leading to the major product shown in the image attached to this answer.

What a main difference between Earth and Jupiter?

A. Earth is an inner planet with a solid rock surface composition, while Jupiter is an outer planet with a gas surface composition.

B. Earth is an inner planet with a relatively long distance from the sun, while Jupiter is an outer planet with a relatively short distance from the sun.

C. Earth is an outer planet with a gas surface composition, while Jupiter is an inner planet with a solid rock surface composition.

D. Earth is an outer planet with a relatively short distance from the sun, while Jupiter is an inner planet with a long distance from the sun.

Answers

Answer: A. Earth is an inner planet with a solid rock surface composition, while Jupiter is an outer planet with a gas surface composition.

Answer: What a main difference between Earth and Jupiter?

Earth is an inner planet with a solid rock surface composition, while Jupiter is an outer planet with a gas surface composition.

Earth is an inner planet with a relatively long distance from the sun, while Jupiter is an outer planet with a relatively short distance from the sun.

Earth is an outer planet with a gas surface composition, while Jupiter is an inner planet with a solid rock surface composition.

Earth is an outer planet with a relatively short distance from the sun, while Jupiter is an inner planet with a long distance from the sun.

Explanation:

Consider the reaction between an alcohol and tosyl chloride, followed by a nucleophile. Write the condensed formula of the expected main organic product.

Answers

Answer:

RCl

Explanation:

Here, let us take ROH to represent the formula of our alcohol where R is the alkyl group.

The reaction of ROH with  tosyl chloride yields an ester called a tosylate. It is the O-H bond not the C-O bond that is cleaved when the tosylate is formed.

Tosylates are good leaving groups, attack of a nucleophile such as Cl^- completes the mechanism leading to the formation of RCl.

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