What is the proposed mechanism for halohydrin formation and how can it explain the observed regioselectivity?

Answers

Answer 1

The proposed mechanism for halohydrin formation can explain the observed regioselectivity through the stereochemistry of the halonium ion.

Proposed of mechanism for halohydrin formation?

The proposed mechanism for halohydrin formation involves the reaction between an alkene and a halogen in the presence of water. The halogen adds to the double bond of the alkene to form a halonium ion, which is then attacked by water to form a halohydrin. The observed regioselectivity of this reaction is determined by the stereochemistry of the halonium ion.

Specifically, the halogen will add to the carbon with the least number of alkyl substituents, resulting in the formation of the more substituted halohydrin product. This can be explained by the fact that the halonium ion is more stable when it is bonded to a more substituted carbon, due to increased electron density and greater hyperconjugation.

The proposed mechanism for halohydrin formation can explain the observed regioselectivity through the stereochemistry of the halonium ion.

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Related Questions

how to balance the hydrogen in Cr(OH)4- ----> CrO4 2-

Answers

To balance the hydrogen atoms in the reaction Cr(OH)₄⁻ → CrO₄²⁻, add two H2O molecules to the product side.

Balancing the hydrogen atoms in a chemical equation involves ensuring that there are an equal number of hydrogen atoms on both sides of the equation. In this case, we have the reaction:
Cr(OH)₄⁻ → CrO₄²⁻
On the reactant side, we have 4 hydrogen atoms in Cr(OH)₄⁻. On the product side, there are currently no hydrogen atoms. To balance the hydrogen atoms, we need to add 2 H₂O molecules to the product side, since each H₂O molecule has 2 hydrogen atoms:
Cr(OH)₄⁻ → CrO₄²⁻+ 2 H₂O
Now, there are 4 hydrogen atoms on both sides of the equation, and the hydrogen atoms are balanced.

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A catalyst: lowers the energy of reactants and products increases the rate of a reaction in both directions always decreases the number of steps of the reaction mechanism changes the stoichiometry of the products in a reaction

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A catalyst increases the rate of a reaction in both directions.

A catalyst is a substance that speeds up the rate of a chemical reaction without being consumed in the reaction itself. It works by providing an alternate pathway with a lower activation energy for the reaction to occur.

This allows for more reactant molecules to overcome the activation energy barrier and form products, resulting in an increased reaction rate.

Furthermore, a catalyst can also increase the rate of the reverse reaction, which means that it speeds up the reaction in both directions.

This is because a catalyst doesn't affect the thermodynamics of the reaction, but rather the kinetics. It does not change the stoichiometry of the products in a reaction, nor does it decrease the number of steps of the reaction mechanism.

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you have a patient currently receiving a dextrose constant rate infusion at 2.5% previously created in a 1000 ml 0.9% nacl bag. the doctor has requested to increase the concentration to 5% utilizing the same bag. there are approximately 400 milliliters of 0.9% nacl remaining in the bag. how many milliliters of 0.9% nacl/2.5% dextrose will you be removing from the bag and injecting of the 50% dextrose solution to achieve 5%?

Answers

There are approximately 400 ml of 0.9% NaCl remaining in the bag, you will remove 400 ml of the 0.9% NaCl/2.5% dextrose solution and inject 5000 ml of the 50% dextrose solution to achieve a 5% dextrose concentration in the bag.

To achieve a 5% dextrose concentration in the 1000 ml bag, you need to calculate the amount of 0.9% NaCl/2.5% dextrose solution that needs to be removed and replaced with 50% dextrose solution.

Let's first calculate the current amount of dextrose in the bag:

Current dextrose amount = 2.5% of 1000 ml = 0.025 * 1000 = 25 grams

Next, let's calculate the desired amount of dextrose in the bag for a 5% concentration:

Desired dextrose amount = 5% of 1000 ml = 0.05 * 1000 = 50 grams

The difference between the desired and current dextrose amounts gives us the amount of dextrose that needs to be added:

Dextrose to be added = Desired dextrose amount - Current dextrose amount = 50 - 25 = 25 grams

Now, let's calculate the volume of 50% dextrose solution needed to provide 25 grams of dextrose:

Volume of 50% dextrose solution = (Dextrose to be added / 0.5) * 100 = (25 / 0.5) * 100 = 5000 ml

Since there are approximately 400 ml of 0.9% NaCl remaining in the bag, you will remove 400 ml of the 0.9% NaCl/2.5% dextrose solution and inject 5000 ml of the 50% dextrose solution to achieve a 5% dextrose concentration in the bag.

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the energy of a hypothetical x-x bond is 170kj/mol. calculate the minimum wavelength of light required to break the bond

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To calculate the minimum wavelength of light required to break the bond, we need to use the formula:

λ = hc/E = 705 nm

where λ is the wavelength of light, h is Planck's constant (6.626 x 10^-34 J·s), c is the speed of light (2.998 x 10^8 m/s), and E is the energy of the bond (170 kJ/mol).

First, we need to convert the energy per mole to energy per molecule:

170 kJ/mol / (6.022 x 10^23 molecules/mol) = 2.826 x 10^-19 J/molecule

Now we can plug in the values:

λ = (6.626 x 10^-34 J·s x 2.998 x 10^8 m/s) / 2.826 x 10^-19 J/molecule
λ = 7.02 x 10^-7 m

Therefore, the minimum wavelength of light required to break the bond is 7.02 x 10^-7 meters (or 702 nm).
Hi! To calculate the minimum wavelength of light required to break the x-x bond, we can use the equation:

E = hc/λ

where E is the energy of the bond (170 kJ/mol), h is Planck's constant (6.626 x 10^(-34) Js), c is the speed of light (3.0 x 10^8 m/s), and λ is the wavelength.

First, we need to convert the energy from kJ/mol to J/photon by using Avogadro's number (6.022 x 10^23):

E = (170 x 10^3 J/mol) / (6.022 x 10^23 photons/mol) = 2.82 x 10^(-19) J/photon

Now, we can solve for λ:

λ = hc/E = (6.626 x 10^(-34) Js) (3.0 x 10^8 m/s) / (2.82 x 10^(-19) J/photon)

λ ≈ 7.05 x 10^(-7) m or 705 nm

The minimum wavelength of light required to break the x-x bond is approximately 705 nm.

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if a is the activity and n is the number of atoms. they are proportional to each other because the rate of decay is constant. thus, you can use either activity or number to determine which value?

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You can use either activity or number of atoms to determine the other value, as they are proportional to each other due to the constant rate of decay. So, if you know the activity of a sample, you can determine the number of atoms in it, and vice versa.

Since the activity (a) and the number of atoms (n) are proportional to each other due to the constant rate of decay, you can use either of them to determine the decay constant (λ).
The relationship between activity, number of atoms, and decay constant can be represented as follows:
a = λn
By using either activity or the number of atoms, you can calculate the decay constant or find the other variable if the decay constant is known.

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A compound was found to have a Ka value of 1.2 after calculation. Identify this compound
A weak base
B strong base
C string acid
D weak acid

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The given Ka value of 1.2 indicates that the compound is a weak acid.

What is Ka value ?

Ka value is the acid dissociation constant which represents the strength of an acid in solution.

The strength of an acid in solution is represented by the acid dissociation constant, or Ka. A stronger acid is one with a higher Ka value, whereas a weaker acid is one with a lower Ka value. A weak acid is indicated by a comparatively low Ka value of 1.2.

Therefore, the correct option is D weak acid.

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which one of the following statements concerning the relativistic momentum of an electron moving at a speed very close to the speed of light is false?

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The statement that is false concerning the relativistic momentum of an electron moving at a speed very close to the speed of light is that the relativistic momentum is equal to the electron's rest mass multiplied by the speed of light.

This statement is false because the relativistic momentum of an electron moving at a speed very close to the speed of light is equal to the product of the electron's rest mass and the velocity of the electron divided by the square root of one minus the ratio of the velocity to the speed of light squared. This ratio is known as the Lorentz factor.

The Lorentz factor increases as the speed of the electron approaches the speed of light. As a result, the relativistic momentum of an electron moving at a speed very close to the speed of light is greater than the electron's rest mass multiplied by the speed of light.

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Over the years, scientific advancements have brought both benefits and disadvantages to society. Which of the following is an area which has been both positively and negatively affected by scientific advancements? a. food safety b. waste production c. climate d. all of the above Please select the best answer from the choices provided A B C D

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Scientific advances have helped with the advancement of technologies and to help us solve problems. In the area that these advances have helped positively and negatively is waste production. So the correct option is B.

What is waste production?

Waste production occurs as a consequence of any activity in which man is involved, such as residentially, by industry. Some of this waste can be recycled and reused, which makes the process cleaner, but there are some products that remain confined and can cause damage to the environment.

Recycling waste will have benefits such as reducing energy consumption, helping the environment, reducing pollution. But it also has its negative side as it has a high cost and the products, when recycled, will be of low quality.

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what is the boiling point of an aqueous solution of 15.5 g of glucose (c6h12o6) dissolved in 150 g of water?

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The boiling point of an aqueous solution of 15.5 g of glucose dissolved in 150 g of water is approximately 100.293 °C.

The boiling point of an aqueous solution of 15.5 g of glucose (C6H12O6) dissolved in 150 g of water can be determined using the formula:
ΔTb = Kbm
Where ΔTb is the change in boiling point, Kb is the boiling point elevation constant for water (0.512 °C/m), and m is the molality of the solution (moles of solute per kilogram of solvent).
To find the molality of the solution, we need to first calculate the moles of glucose:
moles of glucose = mass of glucose / molar mass of glucose
moles of glucose = 15.5 g / 180.16 g/mol
moles of glucose = 0.086 moles
Next, we need to calculate the mass of water in the solution:
mass of water = 150 g
Finally, we can calculate the molality of the solution:
molality = moles of solute / kilograms of solvent
molality = 0.086 mol / 0.150 kg
molality = 0.573 mol/kg
Now we can use the formula to find the change in boiling point:
ΔTb = Kbm
ΔTb = 0.512 °C/m * 0.573 mol/kg
ΔTb = 0.293 °C
The boiling point of pure water is 100 °C, so the boiling point of the solution is:
boiling point of solution = 100 °C + ΔTb
boiling point of solution = 100 °C + 0.293 °C
boiling point of solution = 100.293 °C
Therefore, the boiling point of an aqueous solution of 15.5 g of glucose dissolved in 150 g of water is approximately 100.293 °C.

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consider a beaker containing a saturated solution of caf2 in equilibrium with undissolved caf2 (s). solid cacl2 is then added to the solution. (a) will the amount of solid caf2 at the bottom of the beaker increase, decrease, or remain the same? (b) will the concentration of ca2 ions in the solution increase or decrease? (c) will the concentration of f- ions in the solution increase or decrease?

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Adding solid CaCl2 to a saturated solution of CaF2 will "increase the amount of solid CaF2" at the bottom of the beaker, "increase the concentration of Ca2+ ions" in the solution, and "decrease the concentration of F- ions" in the solution.

(a) When solid CaCl2 is added to the saturated solution of CaF2, the Ca2+ ions from CaCl2 will react with the F- ions from the CaF2, forming solid CaF2 and soluble CaCl2.

The reaction can be written as:

CaF2(s) + CaCl2(aq) → 2Ca2+(aq) + 2F-(aq) + Cl2(aq)

Since solid CaF2 is produced, the amount of solid CaF2 at the bottom of the beaker will increase.

(b) The concentration of Ca2+ ions in the solution will increase because CaCl2 dissociates in water to form Ca2+ and Cl- ions.

The Ca2+ ions from the dissociation of CaCl2 will add to the Ca2+ ions already present in the solution from the equilibrium of CaF2 dissociation, increasing their concentration.

(c) The concentration of F- ions in the solution will decrease because the F- ions will react with the Ca2+ ions from CaCl2 to form solid CaF2. As a result, there will be fewer F- ions in the solution.

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A reaction has a specific rate constant of 0.002/hr at 27 C. The initial concentration of 10M will have decreased to 10% of the original value at the end of 230 hrs at 47 C. What is the rate constant at 47 C?

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The rate constant at 47°C is 0.0146/hr.

First, we need to find the activation energy (Ea). We know that after 230 hours at 47°C, the concentration has decreased to 10% of its original value (1M). Now, we can plug this value into the Arrhenius equation to find the rate constant at 47°C. However, we do not have enough information to calculate the activation energy (Ea) or the pre-exponential factor (A) in the equation. Therefore, it is not possible to accurately determine the rate constant at 47°C using the given information alone.

We can use the Arrhenius equation to find the rate constant at 47 C, given the rate constant at 27 C:
k2 = k1 * e^[(Ea/R) * ((1/T2) - (1/T1))]
k2 = k1 * e^[(Ea/R) * ((1/320) - (1/300))]
Now we can plug in the values we know:
k1 = 0.002/hr
T1 = 300 K
T2 = 320 K
k2 = 0.002 * e^[(Ea/R) * ((1/320) - (1/300))]
We still need to find the concentration at the end of 230 hours at 47 C, so we can use the first-order integrated rate law:
ln([A]/[A]0) = -kt

t = ln([A]0/[A]) / k
t = ln(10/100) / k
t = -2.303 / k
t = 230 hours
Now we can plug in the values we know:
[A] = 0.1 [A]0 = 1 M
t = 230 hours
ln(0.1/1) = -k * 230
-2.303 = -k * 230
k = 0.01/23.03
k = 0.000434/hr
Now we can plug in this value for k2 in the Arrhenius equation:
k2 = 0.002 * e^[(Ea/R) * ((1/320) - (1/300))]
0.000434 = 0.002 * e^[(Ea/R) * ((1/320) - (1/300))]
ln(0.000434/0.002) = (Ea/R) * ((1/320) - (1/300))
-1.355 = (Ea/R) * ((1/320) - (1/300))
We can assume that R is constant, so we can solve for Ea:
Ea = (-1.355 * R) / ((1/320) - (1/300))
Ea = 25,620 J/mol
Now we can use this value for Ea to find the rate constant at 47 C:
k2 = k1 * e^[(Ea/R) * ((1/T2) - (1/T1))]
k2 = 0.002 * e^[(25,620 / (8.314 J/mol-K)) * ((1/320) - (1/300))]
k2 = 0.016/hr
Therefore, the rate constant at 47 C is 0.016/hr.

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what will happen to the pressure of a gas sample if gas particles are removed from the sample while the temperature and volume are held constant?

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If gas particles are removed from a gas sample while the temperature and volume are held constant, the pressure of the gas will decrease.

This is because the pressure of a gas is directly proportional to the number of gas particles in the sample. Therefore, when particles are removed, there are fewer collisions between gas particles and the walls of the container, resulting in a decrease in pressure. The ideal gas law states that pressure is directly proportional to the number of molecules and inversely proportional to the volume. Therefore, if the number of molecules are reduced while the volume and temperature are held constant, the pressure of the gas will decrease.

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Why you must degas the solvents before they can be used as HPLC mobile phases? How to degas solvents?

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Solvents used as HPLC mobile phases must be degassed before use to avoid introducing gas bubbles into the chromatographic system. Gas bubbles can cause fluctuations in pressure, flow rate, and peak shapes, ultimately leading to inaccurate and irreproducible results.

There are a few methods for degassing solvents, such as sonication, sparging with helium or nitrogen gas, or using a vacuum pump. Sonication involves placing the solvent in a container and using high-frequency sound waves to remove any dissolved gases. Sparging involves passing an inert gas through the solvent, which displaces any dissolved gases. Vacuum degassing involves placing the solvent under reduced pressure, which allows dissolved gases to escape. Regardless of the method used, it is important to ensure that the solvents are fully degassed before use to avoid any issues during HPLC analysis.
In conclusion, degassing solvents is an important step in preparing HPLC mobile phases to ensure accurate and reproducible results. The chosen method of degassing will depend on the specific solvent and equipment available.

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which of the following does not contribute to the creation of the antarctic ozone hole? a. methyl benzoate b. methyl bromide c. chlorofluorocarbons

Answers

Answer:

Methyl Benzoate. I only (a. only)

Explanation:

Got it right on the test!

It wasn't in the lesson's list of ozone-depleting substances (ODSs), whereas all the other options were on the list and are considered an ODS. Methyl Benzoate is correct.

calculate the ph of a buffer solution that is 0.329 m in c6h5nh2 (aniline) and 0.108 m in c6h5nh3br.

Answers

The pH of the buffer solution can be calculated using the Henderson-Hasselbalch equation is 4.008. [tex]pH = pKa + log\frac{[A-]}{[HA]}[/tex].

Where pKa is the dissociation constant of the weak acid (aniline), [A-] is the concentration of the conjugate base (C6H5NH2-), and [HA] is the concentration of the weak acid (aniline, C6H5NH2).
First, we need to determine the pKa value for aniline. This can be found in a reference book or online database and is approximately 4.6.
Next, we can plug in the values we have:
[tex][tex]pH = 4.6 + log\frac{[C6H5NH2-]}{[C6H5NH2]}[/tex]
[tex]pH = 4.6 + log\frac{0.108}{0.329}[/tex]
Using a calculator, we get:
pH = 4.6 + (-0.592)
pH = 4.008
Therefore, the pH of the buffer solution is approximately 4.008.
We can use the Henderson-Hasselbalch equation to calculate the pH of a buffer solution. This equation takes into account the dissociation constant of the weak acid and the concentrations of the weak acid and its conjugate base. In this specific example, the pH of the buffer solution containing aniline and C6H5NH3Br is approximately 4.008.

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what is the net ionic equation for formation of iron (iii) hydroxide via mixing aqueous iron (iii) nitrate and potassium hydroxide? assume any insoluble reactants or products are completely insoluble. group of answer choices fe to the power of 3 plus end exponent italic (a q italic )space plus space 3 space oh to the power of minus italic (a q italic )rightwards arrow fe (oh )subscript 3 italic (s italic )fe (no subscript 3 )subscript 3 italic (a q italic )space plus space 3 space oh to the power of minus italic (a q italic )rightwards arrow fe (oh )subscript 3 italic (s italic )space plus space 3 space no subscript 3 to the power of minus italic (a q italic )2 space fe to the power of 3 plus end exponent italic (a q italic )space plus space 3 space straight o to the power of 2 minus end exponent italic (a q italic )rightwards arrow fe subscript 2 straight o subscript 3 italic (s italic )space italic space fe (no subscript 3 )subscript 3 italic (a q italic )space plus space 3 space straight o to the power of 2 minus end exponent italic (a q italic )rightwards arrow fe subscript 2 straight o subscript 3 italic (s italic )space plus space 3 space no subscript 3 to the power of minus italic (a q italic )fe (no subscript 2 )subscript 3 italic (a q italic )space plus space 3 space oh to the power of minus italic (a q italic )rightwards arrow fe (oh )subscript 3 italic (s italic )space plus space 3 space no subscript 2 superscript minus italic (a q italic )

Answers

The net ionic equation for the formation of iron (III) hydroxide via mixing aqueous iron (III) nitrate and potassium hydroxide is: Fe3+(aq) + 3OH-(aq) → Fe(OH)3(s). The reactants and products are completely soluble except for the insoluble product Fe(OH)3, which is written as a solid in the equation.

I understand that you want the net ionic equation for the formation of iron (III) hydroxide via mixing aqueous iron (III) nitrate and potassium hydroxide. Here's the balanced chemical equation and the net ionic equation for the reaction:
Balanced chemical equation:
Fe(NO₃)₃(aq) + 3 KOH(aq) → Fe(OH)₃(s) + 3 KNO₃(aq)
Net ionic equation:
Fe³⁺(aq) + 3 OH⁻(aq) → Fe(OH)₃(s)
In the net ionic equation, we only include the ions that participate in the formation of the insoluble product, iron (III) hydroxide (Fe(OH)₃), which is completely insoluble as you specified.

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38 grams of butane (C4H10) burns completely in air (+O2) to form water and carbon dioxide. How many liters of carbon dioxide will be formed?

Answers

The volume of the carbon dioxide that is formed would be  59 L.

What is the reaction equation?

The first things that we would have to do is that we must be able to balance the reaction equation for the reaction that have been written here. And when we balance the reaction equation then we are going to have what I have written in the line below;

2C4H10 + 13O2 → 8CO2 + 10H2O

Thus;

Number of moles of the butane is

38 g/58 g/mol

= 0.66 moles

If 2 moles of butane produces 179.2 L of CO2

0.66 moles of butane will produce 0.66 * 179.2 /2

= 59 L

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in adipic acid we pipet out all our aq layer t/f

Answers

In the context of adipic acid separation from a mixture, the statement "we pipet out all our aq layer" is true.

Adipic acid is a dicarboxylic acid commonly used in the production of nylon. In order to isolate the adipic acid from the reaction mixture, the aqueous layer must be separated and removed. This can be done by pipetting out the aqueous layer.

After the reaction is complete, the mixture is usually allowed to settle in order to separate the organic and aqueous layers. The organic layer contains the adipic acid and is usually on top, while the aqueous layer is on the bottom. To remove the aqueous layer, a pipette can be used to carefully extract it from the bottom of the container. It is important to avoid disturbing the organic layer as much as possible during this process. Once the aqueous layer has been removed, the adipic acid can be further purified using techniques such as recrystallization or chromatography.
In the context of adipic acid separation from a mixture, the statement "we pipet out all our aq layer" is true.
During the separation process of adipic acid, the mixture containing the adipic acid is often dissolved in an aqueous (aq) solution. By using a pipette, you can carefully remove the aqueous layer containing the adipic acid, thus separating it from other compounds or impurities in the mixture. This step is crucial to isolate and obtain a purified form of adipic acid for further analysis or use.

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which substance can be added to a saturated solution to decrease the solubility of calcium hydroxide?

Answers

To decrease the solubility of calcium hydroxide in a saturated solution, you can add a common ion such as calcium chloride (CaCl2) or sodium hydroxide (NaOH).

This will introduce a common ion effect, which reduces the solubility of calcium hydroxide in the solution.

Solubility is a term used in chemistry to describe a material's capacity to mix with another substance, the solvent. The opposing property is called insolubility, or the solute's inability to produce such a solution.

A solute's capacity to dissolve in a solvent is known as its solubility. The term "solubility" refers to a substance's maximal capacity for solvent dissolution. Solubility, molar solubility, and solubility product are crucial ideas that facilitate understanding of the dissolution and equilibrium of sparingly soluble substances using the chemistry.

The term "solubility" is used to describe the greatest quantity of a chemical that may dissolve in a given amount of solvent at a particular temperature, using the chemical CaHCl (silver chloride) as an example. Due to its limited solubility in water, silver chloride only partially dissolves to form a saturated solution. On the other hand, molar solubility is the quantity of CaCl that may dissolve in a liter of solvent to form a saturated solution.

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Select all that apply: elementary reactions occur exactly as written. elementary reactions can often be broken down into simpler steps. elementary reactions must add up to give the overall reaction. a reaction mechanism is the pathway by which a reaction occurs.

Answers

The correct statements are: Elementary reactions occur exactly as written, A reaction mechanism is the pathway by which a reaction occurs.

Elementary reactions occur exactly as written means that the reaction occurs in a single step and there are no intermediate species involved in the reaction.

A reaction mechanism is a series of elementary reactions that occur in a specific sequence to give the overall reaction. Hence, elementary reactions can often be broken down into simpler steps.

Elementary reactions must add up to give the overall reaction means that the stoichiometric coefficients of the elementary reactions must be adjusted in such a way that they add up to give the stoichiometry of the overall reaction. However, this statement is not always true, as some reactions may involve non-elementary steps or have an overall reaction mechanism that is not well understood.

The complete question is:

which of the following is false? select the correct answer below: a reaction mechanism is the pathway by which a reaction occurs. elementary reactions can often be broken down into simpler steps. elementary reactions occur exactly as written. reactive intermediates are produced in one step and consumed in a subsequent step.

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what are the colours of Sc3+ and Zn2+

Answers

The color of Sc3+ is usually pale yellow, and the color of Zn2+ is colorless.

When transition metal ions are present in a solution, they absorb certain wavelengths of light and transmit others, which results in their characteristic colors. Scandium (Sc3+) ions usually exhibit a pale yellow color due to their electronic structure, which causes them to absorb blue-green light.

On the other hand, zinc (Zn2+) ions do not absorb any particular wavelengths of light, so they do not exhibit any color and are considered colorless.

This lack of color is due to the full d-orbitals in Zn2+ ion which does not absorb light in the visible range. The color of metal ions is an important characteristic in analytical chemistry as it can help identify and quantify the presence of certain ions in a solution.

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Which term refers to the energy cost required for a reaction to proceed?
O energy of enthalpy
Oreaction rate energy
O activation energy
O energy of entropy

Answers

The term that refers to the energy cost required for a reaction to proceed is activation energy.

What type of Born-Haber cycle is the best one to use when ask to construct a Born-Haber cycle in an examination?

Answers

When constructing a Born-Haber cycle in an examination, it is best to use the Hess's Law type of Born-Haber cycle. This type of cycle involves breaking down the overall enthalpy change into a series of smaller steps, allowing for easier calculation and better understanding of the process. Additionally, this type of cycle allows for the inclusion of intermediate steps and the use of various thermodynamic data, such as enthalpies of formation and ionization energies, which can further aid in the calculation process.

In an examination, when asked to construct a Born-Haber cycle, the best approach is to use the standard Born-Haber cycle, which includes the following steps:

1. Formation of gaseous atoms from the solid elements (sublimation or atomization)
2. Ionization of gaseous atoms to form positive ions (ionization energy)
3. Formation of gaseous negative ions from non-metal atoms (electron affinity)
4. Formation of the crystal lattice from gaseous ions (lattice energy)

By using the standard Born-Haber cycle, you'll be able to systematically represent the formation of an ionic compound and provide a clear, concise, and accurate answer in an examination setting.

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Which of the following statements are true regarding the second-law analysis of vapor-compression refrigeration cycles?
(Multiple select question)
-Exergy destruction in a component can be determined directly from the exergy balance equation.
-The second-law efficiency is equal to the ratio of actual and maximum COPs for the refrigeration cycle.
-For the condenser, if the temperatures of the high-temperature medium and the environment are the same, then recoverable exergy is zero.
-COPR is inversely proportional to the temperature difference TH - TL for both ideal and actual refrigeration cycles.
-Actual refrigeration cycles can be as efficient as ideal ones like the Carnot cycle

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The true statements regarding the second-law analysis of vapor-compression refrigeration cycles are:

- Exergy destruction in a component can be determined directly from the exergy balance equation.
- The second-law efficiency is equal to the ratio of actual and maximum COPs for the refrigeration cycle.
- For the condenser, if the temperatures of the high-temperature medium and the environment are the same, then recoverable exergy is zero.
- COPR is inversely proportional to the temperature difference TH - TL for both ideal and actual refrigeration cycles.

However, actual refrigeration cycles cannot be as efficient as ideal ones like the Carnot cycle due to irreversibilities and exergy destruction in the components.

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Can all Halogens be used in haogenation of alkenes why or why not ?

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All halogens can be used in the halogenation of alkenes because their electrophilic nature allows them to react with the nucleophilic carbon-carbon double bond in alkenes, forming a new compound with halogen atoms attached to the carbon atoms.

Halogens can be used in haogenation?

All halogens can be used in the halogenation of alkenes. Halogens are a group of elements including fluorine, chlorine, bromine, iodine, and astatine. Halogenation is a chemical reaction in which a halogen is added to a substrate, such as an alkene.

Alkenes are hydrocarbons with a carbon-carbon double bond. The reason why all halogens can be used in the halogenation of alkenes is due to the electrophilic nature of the halogens, which can react with the nucleophilic carbon-carbon double bond in alkenes. This results in the formation of a new compound with the halogen atoms attached to the carbon atoms.

All halogens can be used in the halogenation of alkenes because their electrophilic nature allows them to react with the nucleophilic carbon-carbon double bond in alkenes, forming a new compound with halogen atoms attached to the carbon atoms.

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To calculate the cell potential at non-standard-state conditions, one uses the equation,

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Nernst equation is used to find the cell potential under non-standard-state conditions by considering the temperature, the number of electrons transferred in the reaction, and the concentrations of the reactants and products.

To calculate the cell potential at non-standard-state conditions, one uses the equation,

Ecell = E°cell – (RT/nF) ln Q


Where:
- Ecell is the cell potential at non-standard-state conditions
- E°cell is the standard cell potential
- R is the gas constant (8.314 J/mol K)
- T is the temperature in Kelvin
- n is the number of electrons transferred in the redox reaction
- F is the Faraday constant (96,485 C/mol)
- Q is the reaction quotient, which is the ratio of concentrations of products to reactants raised to their respective stoichiometric coefficients.

The reaction quotient takes into account the concentrations of the species involved in the reaction at non-standard conditions. If the reaction quotient is less than the equilibrium constant, the cell potential will be higher than the standard potential. If the reaction quotient is greater than the equilibrium constant, the cell potential will be lower than the standard potential.

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What is the half-life (in seconds) of a zero-order reaction which has an initial reactant concentration of 0. 934 M with a k value of 5. 43 × 10–2 M/s?

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The period in which half of the reactant (half-life) has typically already reacted is 8.61 seconds for a zero-order reaction.

The rate law for a zero-order reaction is rate = k[A]⁰ = k, where [A]⁰ is the reactant concentration and k is the rate constant.

Half-life is the amount of time it takes for a reaction's reactant to react or degrade in half. A zero-order reaction's half-life is determined by:

[tex]t_{1/2}[/tex] = [A]₀/2k, where

[A]₀ = reactant's initial concentration, and k is the rate constant.

Inputting the values provided yields:

[A]₀/2k

= 0.934 M / (2 x 5.43 x 10⁻² M/s)

As a result, the reaction's half-life is 8.61 seconds.

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true/false. the toxic chemicals present in coal ash including mercury, selenium and arsenic infiltrate into streams, lakes, and groundwater, ultimately being absorbed by plants and fish. these contaminated plants and fish, when consumed by humans and animals, can have severe consequences on their health.

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Answer: True. The toxic chemicals present in coal ash can leach into streams, lakes, and groundwater, contaminating the water and ultimately being absorbed by plants and fish. When humans and animals consume these contaminated plants and fish, it can have severe consequences on their health.

Coal ash is the waste product produced from the burning of coal for energy generation. This waste product contains a number of toxic chemicals, including mercury, selenium, and arsenic. When coal ash is not properly stored or disposed of, it can infiltrate into streams, lakes, and groundwater, contaminating the water and ultimately being absorbed by plants and fish.

Once these toxic chemicals are absorbed by plants and fish, they can have severe consequences on the health of humans and animals that consume them. Mercury, for example, is a neurotoxin that can cause brain and nervous system damage, especially in developing fetuses and young children. Selenium toxicity can cause hair and nail loss, damage to the liver and kidneys, and even death in severe cases. Arsenic is a carcinogen that can cause cancer in humans, as well as skin lesions, cardiovascular disease, and other health problems.

The contamination of water sources by coal ash is a serious environmental and public health concern, especially in areas where coal-fired power plants are prevalent. Proper storage and disposal of coal ash is crucial in preventing the spread of these toxic chemicals and protecting the health of humans and wildlife.

Part A Which of the following statements describes ideal gas according to the kinetic-molecular theory of gases? View Available Hint(s) O Gas molecules lose energy when coliding into the wall of a container O Gas molecules attract each other through weak intermolecular forces O Volume occupied by gas molecules themselves is not comparable to the volume between molecules. O Average kinetic energy of gas molecules is proportional to Celsius temperature

Answers

The kinetic-molecular theory of gases, an ideal gas is one where the volume occupied by the gas molecules themselves is not comparable to the volume between molecules, and gas molecules do not attract each other through weak intermolecular forces.

The average kinetic energy of gas molecules is proportional to Celsius temperature. Therefore, the statement that describes an ideal gas according to the kinetic-molecular theory of gases is: "The volume occupied by gas molecules themselves is not comparable to the volume between molecules, and the average kinetic energy of gas molecules is proportional to Celsius temperature." the kinetic-molecular theory of gases, an ideal gas has the following characteristic "Average kinetic energy of gas molecules is proportional to Celsius temperature." In an ideal gas, the kinetic-molecular theory assumes that gas molecules are in constant random motion, there are no intermolecular forces between them, and the volume occupied by the gas molecules themselves is negligible compared to the volume between molecules.

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a gas occupies a volume of 257 ml at a pressure of 99.8 kpa and a temperature of 295 k. when the pressure is changed, the volume becomes 116 ml. if there has been no change in the temperature and amount of gas, what is the new pressure in kpa?

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The new pressure is approximately 221.2 kPa when the volume changes to 116 mL, and there is no change in temperature or amount of gas.

Using the combined gas law (PV = nRT), we can solve for the new pressure. Since the temperature and amount of gas have not changed, we can simplify the equation to P1V1 = P2V2.
P1 = 99.8 kPa
V1 = 257 mL
V2 = 116 mL
P2 = (P1 x V1)/V2
P2 = (99.8 kPa x 257 mL)/116 mL
P2 = 221.4 kPa
The new pressure is approximately 221.2 kPa when the volume changes to 116 mL, and there is no change in temperature or amount of gas.

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