To calculate changes in concentration for a system not at equilibrium, the first step is to determine the direction the reaction will proceed. To do so, we calculate Q and compare it to the equilibrium concentration, K. We can then determine that a reaction will shift to the right if:__________

Answers

Answer 1

Answer:

We can then determine that a reaction will shift to the right if Q<K

Explanation:

Comparing Q with K allows to find out the status and evolution of the system:

If the reaction quotient is equal to the equilibrium constant, Qc = Kc, the system has reached chemical equilibrium. If the reaction quotient is greater than the equilibrium constant, Qc> Kc, the system is not in equilibrium and will evolve spontaneously, decreasing the value of Qc until it equals the equilibrium constant. In this way, the concentrations of the products will decrease and the concentrations of the reagents will increase. In other words, the reverse reaction is favored to achieve equilibrium. Then the system will evolve to the left (ie products will be consumed and more reagents will be formed).If the reaction quotient is less than the equilibrium constant, Qc <Kc, the system is not in equilibrium and will evolve spontaneously increasing the value of Qc until it equals the equilibrium constant. This implies that the concentrations of the products will increase and those of the reagents will decrease. In other words, to achieve balance, direct reaction is favored. Then the reaction will shift to the right, that is, reagents will be consumed and more products will be formed.

In this case, we can then determine that a reaction will shift to the right if Q<K


Related Questions

A compound is found to contain 11.21 % hydrogen and 88.79 % oxygen by mass. What is the empirical formula for this compound?

Answers

Answer:

H₂O

Explanation:

The empirical formular of the compound is obtained using the following steps;

Step 1: Divide the percentage composition by the atomic mass

Hydrogen = 11.21 / 1 = 11.21

Oxygen = 88.79  / 16 = 5.55

Step 2: Divide by the lowest number

Hydrogen  = 11.21 / 5.55 = 2.02 ≈ 2

Oxygen = 5.55 / 5.55 = 1

This means the ratio of the elements is 2 : 1

The empirical formular (simplest formular of a compound) of the compound is;

H₂O

Answer:Empirical formula ======== H₂O    

Explanation:The empirical formula of a compound shows the whole number ratio for  each atom in a compound.

To find empirical formula. we follow the below steps

The total mass of the compound here  is 100 grams, that is (11.21% of hydrogen + 88.79% of oxygen) we can then  assume 11.21 grams  of hydrogen and 88.79grams of oxygen

                                          Hydrogen                   Oxygen

1.composition by mass    11.21                              88.79

molecular weight              1.007g/mol               15.990g/mol

2.Divide composition by mass  11.21/1.007            88.79/15.99    

by each molecular weight to get 11.13                            5.553

no of moles

3 Divide by the least number of moles

to get atomic ratio                       11.13/5.553          5.553/5.553

                                                         2.004                           1.00

4.Convert  to whole numbers             2                                 1

Empirical formula ======== H₂O    

Which term describes the repeated arrangement of the same molecule?

Answers

Answer:

1. C

Carbon atoms

2. C

CH3CH2OH

3. C

extended structure

AND 4. B

One grey sphere, four white spheres, one red sphere

TOOK THE QUIZ. YOUR WELCOME :))

The term which describe the repeated arrangement of same molecules is extended structure. Thus option D is correct.    

What is extended structure?

Extended structure can be defined as a structure in which the subunits are arranged in a repeating pattern and occur in a consistent ratio.

Sodium chloride and diamond are some of the example of extended structure.

The expanded or extended  structure departs from the bilayer configuration, with well-separated hydrophilic and hydrophobic layers made up of propagating chains along the calixarene cavity axis are some characteristics.  

Thus, the term which describe the repeated arrangement of same molecules is extended structure. Thus option D is correct.  

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Your question is incomplete but probably your complete question was

Which term describes the repeated arrangement of the molecule?

A. Bonds

B. Atoms

C. Molecular Model

D. Extended Structure

What is the concentration of A after 50.7 minutes for the second order reaction A → Products when the initial concentration of A is 0.250 M? (k = 0.117 M⁻¹min⁻¹)

Answers

Answer:

0.101 M

Explanation:

Step 1: Given data

Initial concentration of A ([A]₀): 0.250 MFinal concentration of A ([A]): ?Time (t): 50.7 minRate constant (k): 0.117 M⁻¹.min⁻¹

Step 2: Calculate [A]

For a second-order reaction, we can calculate [A] using the following expression.

1/[A] = 1/[A]₀ + k × t

1/[A] = 1/0.250 M + 0.117 M⁻¹.min⁻¹ × 50.7 min

[A] = 0.101 M

how many moles of oxygen atoms are present in 0.4 moles of oxygen gas​

Answers

Answer:

Each molecule of O2 is made up of 2 oxygen atoms. So 1 mole of O2 molecules is made up of 2 moles of oxygen atoms. Therefore 1 mole of oxygen gas contains 2 moles of oxygen atoms. And 0.4 moles of oxygen gas contains 0.8 moles of oxygen atoms.

There are 0.8 moles of oxygen atoms in 0.4 moles of oxygen gas.

Oxygen gas (O₂) consists of two oxygen atoms bonded together. Therefore, to determine the number of moles of oxygen atoms present in a given amount of oxygen gas, we can simply multiply the number of moles of oxygen gas by the number of oxygen atoms per molecule, which is 2.

Given that we have 0.4 moles of oxygen gas, we can calculate the number of moles of oxygen atoms as follows:

Number of moles of oxygen atoms = Number of moles of oxygen gas × Number of oxygen atoms per molecule

= 0.4 moles × 2

= 0.8 moles

Therefore, there are 0.8 moles of oxygen atoms present in 0.4 moles of oxygen gas.

This calculation is based on the stoichiometry of oxygen gas, which indicates that each molecule of O₂ contains two oxygen atoms. By considering the mole ratio between oxygen gas and oxygen atoms, we can determine the number of moles of oxygen atoms in a given quantity of oxygen gas.

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.) At 500 oC, cyclopropane, C3H6, rearranges to form propene. The reaction is first order with a rate constant of 6.7 x 10-4 s-1. If the initial concentration of C3H6 is 0.0500 M, (a) what is the molarity of C3H6 after 30 min

Answers

Answer:

0.015 M

Explanation:

For a first order reaction;

ln[A] =ln[A]o - kt

[A] = final concentration

[A]o =initial concentration

k= rate constant

t= time taken

ln[A] =ln[A]o - kt

ln[A] = ln(0.0500) - 6.7 x 10-4 (30 × 60)

ln[A] = -2.9957 - 1.206

ln[A] = -4.202

e^ln[A] = e^(-4.202)

A= 0.015 M

The ceramic glaze on a red-orange Fiestaware plate is U2O3 and contains 50.1 grams of 238U, but very little 235U. (a) What is the activity of the plate (in Ci)

Answers

Answer:

The correct answer is 1.68 × 10⁻⁵ Ci

Explanation:

The activity of the uranium is determined by using the formula,  

R = 0.693 N/t1/2 -------------- (i)

The number of atoms is, N = nNA

Here, NA is the Avogadro number and n is the number of moles. The value of n is m/M, that is, mass/molecular mass. Now the value of N becomes,  

N = (m/M) NA

The m or mass of uranium given is 50.1 grams, and the molecular mass is 238 g/mol, now putting the values we get,  

N = (50 g/238 g) (6.023 × 10²³) = 1.26 × 10²³

The half-life of 238U from year to second is,  

t1/2 = (4.468 × 10⁸ year) (3.16 × 10⁷ s/ 1 year) = 1.412 × 10¹⁶ s

Substituting the values of t1/2 as 1.412 × 10¹⁶, and 1.26 × 10²³ for N in equation (i) we get,  

R = 0.639 (1.26 × 10²³) / 1.412 × 10¹⁶ s  

= 6.18 × 10⁶ Bq (2.7027 × 10⁻¹¹ Ci/1 Bq)

= 1.68 × 10⁻⁵ Ci

Hence, the activity of the plate is 1.68 × 10⁻⁵ Ci

A 1 liter solution contains 0.436 M hypochlorous acid and 0.581 M potassium hypochlorite. Addition of 0.479 moles of barium hydroxide will: (Assume that the volume does not change upon the addition of barium hydroxide.)

Answers

Answer:

Exceed the buffer capacity and Raise the pH by several units

Explanation:

Options are:

Raise the pH slightly

Lower the pH slightly

Raise the pH by several units

Lower the pH by several units

Not change the pH

Exceed the buffer capacity

The hypochlorous acid, HClO, is in equilibrium with Hypochlorite ion (From potassium hypochlorite, ClO⁻) producing a buffer. Using H-H equation, pH of initial buffer is:

pH = pKa + log [ClO⁻] / [HClO]

pKa for hypochlorous acid is 7.53

pH = 7.53 + log [0.581M] / [0.436M]

pH = 7.65

Barium hydroxide reacts with HClO producing more ClO⁻, thus:

Ba(OH)₂ + 2HClO →  2ClO⁻ + 2H₂O

As 0.479 moles of Barium hdroxide are added. For a complete reaction you require 0.479mol * 2 = 0.958 moles of HClO

As you have just 0.436 moles (Volume = 1L),

The addition will:

Exceed the buffer capacity

The Ba(OH)₂ that reacts is:

0.436 moles HClO * (1mole (Ba(OH)₂ / 2 mol HClO) = 0.218 moles Ba(OH)₂ and will remain:

0.479 mol - 0.218 mol = 0.261 moles Ba(OH)₂

As 1 mole of Ba(OH)₂ contains 2 moles of OH⁻, moles of OH⁻ and molarity is:

0.261 moles* 2 = 0.522 moles OH⁻ = [OH⁻]

pOH = -log [OH⁻]

pOH = 0.28

And pH = 14 - pOH:

pH = 13.72

Thus, after the addition the pH change from 7.65 to 13.62:

Raise the pH by several units

What would happen to the measured cell potentials if 30 mL solution was used in each half-cell instead of 25 mL

Answers

Answer:

The answer is "[tex]\bold{\log \frac{[0] mole}{[R]mole}}[/tex]"

Explanation:

[tex]E_{cell} =E_{cell}^{\circ} - \frac{0.0591}{n}= \log\frac{[0]}{[R]}\\[/tex]

In the above-given equation, we can see from [tex]E_{ceu}[/tex], of both oxidant [tex]conc^n[/tex]as well as the reactant were connected. however, weight decreases oxidant and reduction component concentration only with volume and the both of the half cells by the very same factor  and each other suspend

[tex]\to \log \frac{\frac{\text{oxidating moles}}{25 \ ml}}{\frac{\text{moles of reduction}}{25 ml}} \ \ = \ \ \log \frac{\frac{\text{oxidating moles}}{30 \ ml}}{\frac{\text{moles of reduction}}{30 ml}} \\\\\\[/tex]

[tex]\to {\log \frac{[0] mole}{[R]mole}}[/tex]

The cell potential of the electrochemical reaction has been the same when the volume has been reduced from 30 mL to 25 mL in each half cells.

The cell potential has been given as the difference in the potential of the two half cells in the electrochemical reaction.

The two cells has been set with the concentration of solutions in the oxidation and reduction half cells.

Cell potential change

The cell potential has been changed when there has been a change in the potential of the half cells.

The volume of 30 mL to the solution has been, resulting in the cell potential difference of x.

With the volume of 25 mL, there has been the difference in the potential being similar to the 30 mL solution, i.e. x.

Thus, the cell potential of the electrochemical reaction has been the same when the volume has been reduced from 30 mL to 25 mL in each half cells.

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A 2.87g sample of carbon reacts with hydrogen to form 3.41g of car fuel. What is the empirical formula of the car fuel?

Answers

Answer:

The empirical formulae for the car fuel is C4H9

Given that π = n M R T, rearrange the equation to solve for V

Answers

Answer:

V= n/M

Explanation:

From;

π = nRT/V = MRT

Where;

n= number of moles

R= gas constant

T= absolute temperature

M= molar mass

V= volume of the solution

π= osmotic pressure

Thus;

nRT/V = MRT

nRT = VMRT

V= nRT/MRT

V= n/M

clacium hydroxide is slightly soluable in water about 1 gram will dissolve in 1 liter what are the spectator ions in the reaction ions in the reaction of such a dilute solution of calcium hydroxide with hydrochloric acid

Answers

Answer:

Ca²⁺ and Cl⁻

Explanation:

In a chemical reaction, spectator ions are ions that are not involved in the reaction, that means are the same before and after the reaction.

In water, calcium hydroxide, Ca(OH)₂ is dissociated in Ca²⁺ and OH⁻. Also, hydrochloric acid, HCl, dissociates in H⁺ and Cl⁻. The reaction is:

Ca²⁺ + 2OH⁻ + 2H⁺ + 2Cl⁻ → 2H₂O + Ca²⁺ + 2Cl⁻

The ions that react are H⁺ and OH⁻ (Acid and base producing water)

And the ions that are not reacting, spectator ions, are:

Ca²⁺ and Cl⁻

The two common properties of all solids are fixed _____ and _____.

Answers

Answer:

shape

volume

Hope this helps! (づ ̄3 ̄)づ╭❤~

Explanation:

Shape and volume is the correct answer

An unknown gas diffuses 5 times slower than that of H2.The moleculer mass of unknown gas is??

Answers

Answer:

50.

Explanation:

We can write Graham's Law of Diffusion as:

(Rate 1)^2 = Molecular Mass 2

--------------    -------------------------

(Rate 2)^2    Molecular Mass 1

So using the Given Information:

1^2  / (1/5)^2 = Molecular Mass of unknown gas / 2, so:

25 = M/2

M = 50.

Given the balanced chemical equation for the decomposition for INO, and the rate of disappearance of INO, write the expressions for the rates of appearance of I2 and NO.

2INO(g) → I2(g) + 2NO(g)

Reactant: Product(I2): Product(NO):

-∆[INO]/2∆t = ??/??

Answers

Answer:

rate of disappearance of -0.5d[INO]/dt

rate of appearance of I2 = d[I2]/dt

rate of appearance of No = 0.5*d[NO]/dt

Explanation:

According to chemical equilibrium,  d[I₂]/dt and d[NO]/dt is  the expressions for the rates of appearance of I₂ and NO respectively.

What is chemical equilibrium?

Chemical equilibrium is defined as the condition which arises during the course of a reversible chemical reaction with no net change in amount of reactants and products.A reversible chemical reaction is the one wherein the products as soon as they are formed react together to produce back the reactants.

At equilibrium, the two opposing reactions which take place take place at equal rates and there is no net change in amount of the substances which are involved in the chemical reaction.At equilibrium, the reaction is considered to be complete . Conditions which are required for equilibrium are given by quantitative formulation.

Factors which affect chemical equilibrium are change in concentration , change in pressure and temperature and presence of catalyst.

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A critical reaction in the production of energy to do work or drive chemical reactions in biological systems is the hydrolysis of adenosine triphosphate, ATP, to adenosine diphosphate, ADP, as described by the reaction

ATP(aq)+H2O(l)→ADP(aq)+HPO2−4(aq) for which ΔGrxn=30.5 kJ/mol at 37.0∘C and pH 7.0.

Required:
Calculate the value of ΔGrxn in a biological cell in which [ATP]=5.0 mM, [ADP]=0.60 mM, and [HPO2−4]=5.0 mM

Answers

Answer:

ΔG  = -49.64 KJ/mol

Explanation:

The actual free energy change of the reaction under the given conditions,  ΔG is given by the formula below;

ΔG = ΔG'° + RT ln([ADP][HPO₂⁴⁻] / [ATP])

where ΔG'° = -30.5 KJ/mol; R = 8.315 J/mol.K; T = 37°C = 310 K; [ADP] = 5.0 mM = 0.005 M; [HPO₂⁴⁻] = 0.60 mM = 0.0006 M; [ATP] = 5.0 mM = 0.005 M

ΔG = -30.5 KJ/mol + (8.315 J/mol.K)(310 K) ln {(0.005)(0.0006)/(0.005)}

ΔG = -30.5 KJ/mol + (2.58 KJ/mol * -7.4186)

ΔG = -30.5 KJ/mol - 19.14 KJ/mol

ΔG  = -49.64 KJ/mol

Complete the following reactions
need answers?

i) P + [H]

ii) O2 + [H]

iii) LiH + H2O

iv) CaC2 +H2O

v) NaH + H2O

vi) CaH2 H2O

Answers

Answer:

this reaction will produce phosphine

P+H---->PH

this reaction will produce water

O2+H---->H2O

this reaction will produce lithium hydroxide and hydrogen gas

LiH+H2O---->LiOH+H2

this reaction will produce calcium hydroxide and acetylene gas

CaC2+H2O---->Ca(OH)2+C2H2

this reaction will produce sodium hydroxide and hydrogen gas

NaH+H2O---->NaOH+H2

this type of reaction will produce calcium hydroxide and hydrogen gas

CaH2+H2O---->CaOH+H2

I hope this helps

What are the correct half reactions for the following reaction: Cu2+ + Mg -> Cu + Mg2+

Answers

Answer:

Cu2 + 2Mg-> 2Cu+ Mg2

Explanation:

Balance the equation and make sure both the reactant and the products are the same

Hope it will be helpful

[tex]Cu^{+2} + 2Mg[/tex]  -> [tex]2Cu + Mg^+2[/tex]  is the correct half-reactions.

What is a balanced equation?

A balanced equation is an equation for a chemical reaction in which the number of atoms for each element in the reaction and the total oxidation numbers is the same for both the reactants and the products.

[tex]Cu^{+2} + 2Mg[/tex]  -> [tex]2Cu + Mg^+2[/tex] is the correct half-reactions.

Magnesium is oxidized because its oxidation state increased from 0 to +2 while Cu is reduced because its oxidation state decreased from +2 to 0.

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When 1604 J of heat energy is added to 48.9 g of hexane, C6H14, the temperature increases by 14.5 ∘C. Calculate the molar heat capacity of C6H14.

Answers

Answer:

THE MOLAR HEAT CAPACITY OF HEXANE IS 290.027 J/ C

Explanation:

1604 J of heat is added to 48.9 g of hexane

To calculate the molar heat capacity of hexane, it is important to note that the molar heat capacity of a substance is the measure of the amount of heat needed to raise 1 mole of a substance by 1 K.

Since 1604 J of heat = 48.9 g of hexane

Molar mass of hexane = 86 g/mol = 1 mole

then;

1604 J = 48.9 g

x = 86 g

x = 1604 * 86 / 48.9

x = 4205.4 J

Hence, 4205.4 J of heat will be added to 1 mole or 86 g of hexane to raise the temperature by 14.5 C.

In other words,

heat = molar heat capacity * temperature change

molar heat capacity = heat/ temperature change

Molar heat capacity = 4205.4 J / 14.5 C

Molar heat capacity = 290.027 J/C

The molar heat capacity of hexane is 290.027 J/ C

Glucose is soluble in water. Why is cellulose, which is made up of glucose, insoluble in water?​

Answers

.....................

Cellulose is insoluble in water which is made up of glucose because it possesses high inter and intramolecular hydrogen bonding between the hydroxyl groups of the neighboring chains.

What is the function of cellulose?

Due to being insoluble in nature, it serves as the fundamental component of the cell membrane in the plant. This is why the cell wall of plant cells are made of cellulose.

The chains of the cellulose are strongly bonded to each other. So, it is very difficult for the molecules of water to rupture or destruct these bonds between the chains. It is a hydrogen bond cross-linked polymer and more complex than glucose.

Therefore, due to high inter and intramolecular hydrogen bonding between the hydroxyl groups of the neighboring chains, cellulose is insoluble in water.

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Which of the following elements is in the same group as Sulfur (S)?

Answers

Answer:

PLEASE SHOW ME THE ELEMENTS OR I WOULD ENLIST ALL THE ELEMENTS.

Explanation:

Group 6A (or VIA) of the periodic table are the chalcogens: the nonmetals oxygen (O), sulfur (S), and selenium (Se), the metalloid tellurium (Te), and the metal polonium (Po)

What do you predict the chemical formula for the compound formed between calcium and sulfur?

Answers

Answer:

calcium donates two vanence electrons to sulfur atom to form Ca2+ ion and an S2+ - ion

Calculate the moles of Iron (Fe) in 3.8 x 10^{21} atoms of Iron. Please show your work

Answers

Answer: 6.31×10⁻³ moles Fe

Explanation:

To calculate moles when given atoms, we need to use Avogadro's number.

Avogadro's number: 6.022×10²³ atoms/mol

[tex](3.8*10^2^1 atoms)*\frac{mol}{6.022*10^2^3 atoms} =6.31*10^-^3 mols[/tex]

The atoms cancel out, and we are left with moles. There are 6.31×10⁻³ moles Fe.

Hey. what is the difference between a boulder and a rock? ]
And bonus: what did the duck say when she bought lipstick?

Answers

Answer:

The difference between a rock and a boulder can be explained in terms of size and detachment. A rock is defined by geologists as an aggregate of minerals. A boulder is a type of rock, specifically a large detached one. All boulders are rocks, but not all rocks are boulders.

Name the following compound from the concise formula:______.
CH3CH(CH3)CHCHCH(CH3)CH2CH3
A. 2,4-dimethyl-3-heptene
B. 2,5-dimethyl-3-heptene
C. 3,5-dimethyl-3-heptene
D. 2,5-dimethyl-4-heptene

Answers

Answer:

B. 2,5-dimethyl-3-heptene

Explanation:

Answer:

B. 2,5-dimethyl-3-heptene

Explanation:

If 75.4 J of energy is absorbed by 0.25 mol of CCl4 at constant pressure, what is the change in temperature? The specific heat of CCl4 is 0.861 J/g·°C.

Answers

Answer:

ΔT = 2.28°C

Explanation:

Heat, H = 75.4J

Number of moles = 0.25 mol

Specific heat capacity, c = 0.861 J/g·°C

Change in temperature, ΔT = ?

These quantities are related by the following equation;

H = mc ΔT

Mass, m = Number of moles * Molar mass

m = 0.25mol * 153.82 g/mol

m = 38.455g

S back to the equation;

H = mc ΔT

Substituting the values;

75.4 = 38.455 * 0.861 * ΔT

ΔT = 75.4 /  33.11

ΔT = 2.28°C

The change in temperature is 2.28 °C

First, we will determine the mass of CCl₄ absorbed

From the given information,

Number of moles of CCl₄ absorbed = 0.25 mol

Using the formula

Mass = Number of moles × Molar mass

Molar mass of CCl₄ = 153.82 g/mol

∴ Mass of CCl₄ absorbed = 0.25 × 153.82

Mass of CCl₄ absorbed = 38.455 g

Now, using the formula

Q = mcΔT

Where Q is the quantity of heat

m is the mass

c is the specific heat of substance

and ΔT is the change in temperature

From the given information

Q = 75.4 J

c = 0.861 J/g.°C

Putting the parameters into the formula, we get  

75.4 = 38.455 × 0.861 ×ΔT

75.4 = 33.109755 × ΔT

∴ ΔT = 75.4 ÷ 33.109755

ΔT = 2.28 °C

Hence, the change in temperature is 2.28 °C

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16. The concentration of a solution of potassium hydroxide is determined by titration with nitric
acid. A 30.0 mL sample of KOH is neutralized by 42.7 mL of 0.498 M HNO3. What is the
concentration of the potassium hydroxide solution?

Answers

Answer:

[tex]M_{base}=0.709M[/tex]

Explanation:

Hello,

In this case, since the reaction between potassium hydroxide and nitric acid is:

[tex]KOH+HNO_3\rightarrow KNO_3+H_2O[/tex]

We can see a 1:1 mole ratio between the acid and base, therefore, for the titration analysis, we find the following equality at the equivalence point:

[tex]n_{acid}=n_{base}[/tex]

That in terms of molarities and volumes is:

[tex]M_{acid}V_{acid}=M_{base}V_{base}[/tex]

Thus, solving the molarity of the base (KOH), we obtain:

[tex]M_{base}=\frac{M_{acid}V_{acid}}{V_{base}} =\frac{0.498M*42.7mL}{30.0mL}\\ \\M_{base}=0.709M[/tex]

Regards.

oxide. b) Silicon dio
43. What is the nature of an enzyme?
a) Vitamin. b) Lipid. c) Carbohydrate. d) Protein
44. Name the enzyme which catalyzes the oxidation-reduction reaction?
a) Transaminase. b) Glutamine synthetase. c) Phosphofructokinase. d) Oxidoreductase
nontido

Answers

Answer:

43) protein

44) oxidoreductase

For the reaction CO2(g) + H2(g)CO(g) + H20(g)
∆H°=41.2 kJ and ∆S°=42.1 J/K
The standard free energy change for the reaction of 1.96 moles of Co2(g) at 289 K, 1 atm would be_________KJ.
This reaction is (reactant, product)___________ favored under standard conditions at 289 K.
Assume that ∆H° and ∆S° are independent of temperature.

Answers

Answer:

The ΔG° is 29 kJ and the reaction is favored towards reactant.

Explanation:

Based on the given information, the ΔH°rxn or enthalpy change is 41.2 kJ, the ΔS°rxn or change in entropy is 42.1 J/K or 42.1 * 10⁻³ kJ/K. The temperature given is 289 K. Now the Gibbs Free energy change can be calculated by using the formula,  

ΔG° = ΔH°rxn - TΔS°rxn

= 41.2 kJ - 289 K × 42.1 × 10⁻³ kJ/K

= 41.2 kJ - 12.2 kJ

= 29 kJ

As ΔG° of the reaction is positive, therefore, the reaction is favored towards reactant.  

Calculate the [H+] and pH of a 0.0010 M acetic acid solution. The Ka of acetic acid is 1.76×10−5. Use the method of successive approximations in your calculations.

Answers

Answer:

[tex][H^+]=0.000123M[/tex]

[tex]pH=3.91[/tex]

Explanation:

Hello,

In this case, dissociation reaction for acetic acid is:

[tex]CH_3COOH\rightleftharpoons CH_3COO^-+H^+[/tex]

For which the equilibrium expression is:

[tex]Ka=\frac{[CH_3COO^-][H^+]}{[CH_3COOH]}[/tex]

Which in terms of the reaction extent [tex]x[/tex] could be written as:

[tex]1.74x10^{-5}=\frac{x*x}{[CH_3COOH]_0-x}=\frac{x*x}{0.0010M-x}[/tex]

Thus, solving by using a solver or quadratic equation we obtain:

[tex]x_1=0.000123M\\\\x_2=-0.000141M[/tex]

And clearly the result is 0.000123M, which also equals the concentration of hydronium ion in solution:

[tex][H^+]=0.000123M[/tex]

Now, the pH is computed as follows:

[tex]pH=-log([H^+])=-log(0.000123)\\\\pH=3.91[/tex]

Best regards.

Identify a homogeneous catalyst. Identify a homogeneous catalyst. Pd in H2 gas N2 and H2 catalyzed by Fe SO2 over vanadium (V) oxide Pt with methane H2SO4 with concentrated HCl

Answers

Answer:

H2SO4 with concentrated HCl

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