The order of decreasing bond energy of F_2, oxygen: O_2, nitrogen: N_2 is N2>F2>O2 using their bond order to predict relative magnitude.
What is bond energy?Bond energy is directly proportional to the bond order which means multiple bond of higher energies than the single bond.
Bond Order:The no. of chemical bond between pair of atoms is known as its Bond order. For Example,
HCCH i.e. H−C≡C−H has three pairs of bond hence its bond order is 3.
Hence, The order of decreasing bond energy of F_2, oxygen: O_2, nitrogen: N_2 is N2>F2>O2 i.e. from highest to lowest bond energy.
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2. which class of organic molecules had the larger retention times? why? (explain using intermolecular inter- actions)
The class of organic molecules had the larger retention times is the compounds which have strong intermolecular interaction with high boiling points have longer retention time.
The organic molecules that have strong intermolecular interaction with the column coating will favor the stationary phase and they takes the longer time that means they will have longer retention time. the organic molecules that have weak intermolecular interaction with column coating spend little time. the retention time for the organic molecules are affected by then intermolecular interaction.
Thus, the more is the interaction between the analyte and the stationary phase the longer will be the retention time.
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except for the transition and inner transition metals, the octet rule applies to all other elements. true false
False, except for the transition and inner transition metals, the octet rule is not applicable to all other elements.
An element is a substance that can not be damaged down into a simpler layout. They may be distinguished by means of a completely unique atomic range. The elements are organized via their atomic variety in the periodic table, which highlights elements with similar residences.
Carbon is the most important detail of existence. Without this detail, existence, as we are aware of it, might not exist. As you will see, carbon is a vital element in compounds essential for lifestyles.
Kinds of elements :
1.) The elements are categorized as metallic, non-metal, and metalloid.
2.) The intense left aspect factors inside the periodic desk are metals, for example, sodium, calcium, cesium, and many others.
3) Elements on the right side are usually known as non-metals, carbon, chlorine, oxygen, and many others.
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you have been told that you will be teaching several highly heterogeneous classes. according to the text, the most reasonable first step to take would be to
The most reasonable first step to take would be to, In a highly heterogeneous class, a teacher should give everyone the same assignment because it will help him/her be able to track student progress efficiently.
What is heterogeneous?
A predication that means composed of different ingredients or dissimilar factors is called heterogeneous.
What is Reasonable?
A generic and relative one and applies to that which is suitable for a particular condition is called reasonable.
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which phrase is not likely to indicate that a double-displacement reaction has occurred?responsesformation of a precipitateformation of a precipitatechange of a metal ion to a metal elementchange of a metal ion to a metal elementformation of a gasformation of a gasneutralization of acids and bases
A metal ion or perhaps an ammonium ion takes the place of the acid's H+ ion. A neutralization is the process by which a base and an acid combine to form a salt.
How is acid defined?Any substance is called an acid if it tastes bad in water solution, colors blue litmus litmus red, reacts with certain metals so release hydrogen, mixes with bases to form salts, and activates chemical reactions (acid catalysis).
Where does acid come from?In industrial or organic chemistry, acids are utilized as catalysts; for instance, sulfuric acid is often used in extremely high volumes during the alkylation process of creating gasoline. Some acids, including hydrochloric, phosphoric, and sulfuric acid ( h2so4, can also cause condensation and dehydration processes.
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The following are the steps involved in transmission at a Cholinergic synapse. 1. Chemically regulated sodium channels on the postsynaptic membrane are activated. 2. Calcium ions enter the synaptic knob. 3. Acetylcholine is degraded by acetylcholinesterase. 4. An action potential depolarizes the synaptic knob at the presynaptic membrane. 5. The synaptic knob reabsorbs choline. 6. Acetylcholine is released from storage vesicles by exocytosis. 7. Acetylcholine binds to receptors on the postsynaptic membrane. 8. Calcium ions are removed from the cytoplasm of the synaptic knob. The correct sequence for these events is: A) 4,2,6,7,1,8,3,5. B) 4,2,6,7,8,5,3,1. C) 2,4,6,7,1,8,3,5. D) 6,4,2,7,1,8,3,5. E) 2,5,4,6,7,1,8,3
The correct sequence of the events is a)4,2,6,7,1,8,3,5
Cholinergic synapse is a type of chemical synapse that uses acetylcholine (ACh) as its neurotransmitter. This type of synapse is found in the peripheral and central nervous systems and is responsible for the transmission of signals between neurons and other cells. The following steps are involved in cholinergic synapse:
a. Release of Acetylcholine: Neurotransmitter Acetylcholine is released from the presynaptic neuron into the synaptic cleft. This release is regulated by calcium ions and the neurotransmitter is packaged into vesicles which are then transported to the release sites.
b. Binding of ACh to receptors: The released ACh diffuses across the synaptic cleft and binds to postsynaptic receptors on the target cell. This binding triggers a cascade of events in the target cell.
c. Postsynaptic responses: The binding of ACh to postsynaptic receptors triggers a variety of responses in the target cell. These responses include the opening of ion channels, the release of additional neurotransmitters, and the activation of second messenger systems.
d. Inactivation of ACh: After the postsynaptic responses have been carried out, the ACh molecule is inactivated by acetylcholinesterase (AChE). This enzyme breaks down ACh into its component parts, which are then recycled or degraded.
e. Reuptake of ACh: The released ACh is also taken up by the presynaptic neuron for reuse. This process is known as reuptake and helps to regulate the amount of ACh in the synaptic cleft.
By following these steps, the cholinergic synapse is able to transmit signals from one neuron to another. This process is essential for the normal functioning of the nervous system.
Hence the correct option is A)
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Simple chemical reactions reflect
Write a reflection about your learning in this unit. Your reflection should be at
least 3 sentences. Use the following sentence starters as a guide.
• I feel confident about identifying the types of bonds between atoms
because...
• I find it challenging to balance chemical equations because...
• To remember trends in the periodic table, one strategy I use is ...
• When I am unsure about how atoms are likely to bond, I can...
It displays the constituent elements and how many atoms of each element are found in a single complex molecule. It also represents the compound's molecular weight.
What are the five primary sorts of reactions?
Combination, decomposition, single-replacement, double-replacement, and combustion are the five fundamental types of chemical reactions. You can categorize a particular reaction by looking at the reactants and products of that reaction.
Which chemical process is most prevalent in daily life?
The method through which autotrophs often produce their food is referred to as photosynthesis. It is a typical chemical reaction that occurs naturally. When there is sunshine and chlorophyll, plants make glucose as a kind of energy.
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for this experiement, the lab instructor had to prepare 650ml of .10 m ca(no3)2. what mass of solid ca(no3)2 was required to prepare this solution
The solution is 5.0 Molar.
A stable is a state of remembering that keeps its form and density while no longer confined. An example of solids is stable ice, sugar, rock, wood, and so forth.
Before everything glances, strong appears to be a simple word, however, it definitely gives sun shades of which means. A stable pal is reliable. if you deliver a solid overall performance, it became excellent, though no longer quite fantastic. Likewise, in case you achieve a solid win, you win by a large, but now not big, majority.
Solids have specific shapes and exact volumes and are not compressible to any quantity. There are two main classes of solid crystalline solids and amorphous solids. Crystalline solids are those in which the atoms, ions, or molecules that make up the solid exist in an ordinary, nicely-described association.
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Why did the volume of Substance 1 change from 3 liters of liquid to just over 0.50 liters after it was boiled and then cooled?
States of mater  interactivity 
Matter are anything that is made up of atoms. The quantity of matter can be observed only on the basis of mass and volume calculation. Therefore, because of the evaporation of upper surface of liquid, volume decreases.
What is matter?Matter is a substance that has some mass and can occupy some volume. The matter is mainly used in science. Matter can be solid, liquid or gas.
Matter is anything that is made up of atoms. Anything around us that can be physically seen and touched are matter. Ice, water and water vapors are example of matter.
The volume of Substance 1 change from 3 liters of liquid to just over 0.50 liters after it was boiled and then cooled because on heating the molecules on the upper surface of liquid evaporates.
Therefore, because of the evaporation of upper surface of liquid, volume decreases.
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Which of the following refers to the movement of buffer ions and solvent relative to the fixed support? a. Electroendosmosis b. Isoelectric focusing c. Iontophoresis d. Zone electrophoresis e. Plasmapheresis
Moving in relation to the fixed support the buffer ions and solvent Electroendosmosis.
What are a solvent and an instance?Example of a solvent Water, ethanol, methanol, and acetone are examples of common solvents. In order to create a solution with a particular solute, a substance must be able to dissolve it. This is what is meant by the term "solvent."
As a solvent, why is water referred to?Because it can dissolve a greater variety of chemicals than any other natural liquid, water is referred to be a "universal solvent," yet it does not dissolve all substances. Because oppositely charged particles are poorly soluble in water, it cannot dissolve hydroxides, waxes, or fats, for instance.
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1. What are the 5 pieces of evidence that prove a chemical change has taken place?
a species that contains a lone (unpaired) electron is referred to as . select the best answer. multiple choice question. a free radical an exception being electron deficient having an extended valence
A species that contains a lone (unpaired) electron is referred to as a free radical.
The electron is a subatomic particle with a bad standard electric charge. Electrons belong to the primary technology of the lepton particle's own family and are typically thought to be fundamental particles because they have no recognized additives or substructure.
For most realistic purposes, an electron is a structureless particle with an intrinsic angular momentum or spin. simply two numbers — the electron's mass and its electric price — gasoline the equations that describe its behavior. From this 'sensible electron' version, physicists constructed present-day microelectronics.
By using the best values for the wavelength and the scattering by a matter of tough X-rays and ?-rays, the radius of the electron is anticipated as approximately 2 × 10-10 cm.
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explain why there is no minus sign in this equation for heat (unlike the equation for work). (think in terms of microscopic definition of entropy.)
When heat is absorbed by the solution, the solution's q value is negative. This denotes that the reaction is endothermic, absorbs heat from the solution, and has a positive reaction q.
Yes, it can be negative, in which case one needs a heat sink. Examples of such sinks include melting or evaporation. The source term in an equation for energy conservation could be positive or negative. The temperature of the node will drop if the magnitude of the negative heat source is greater than the heat flow into the system.
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a sample of tin is heated until it finishes melting. the sample absorbs a total of 1050 j of heat. if the sample requires 460 j of heat to reach its melting point, how much heat is needed to completely melt the sample of tin?
The heat of fusion is the amount of heat energy needed to turn anything solid into a liquid. There is a formula, Q = mHf. Because matter doesn't affect temperature, the temperature is not a factor.
Will the addition of heat cause the temperature to rise during a phase change?There is no increase in the kinetic energies of the particles, and hence no rise in temperature, because the energy required for phase shifts is employed to break bonds. Similarly, energy is required to evaporate a liquid to defeat the attraction forces between the liquid's particles.
Does the temperature drop when a phase shift occurs?The energy that is given during a change in the state of matter is used to alter the binding energies rather than boost the kinetic energy of the molecules. As a result, the temperature doesn't change.
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select the correct order of steps during rcr. group of answer choices annealing, initiation, termination denaturation, extension, termination initiation, extension, termination initiation, denaturation, extension
Denaturation, annealing, and extension are the proper PCR (Polymerase Chain Reaction) stages to take. So, C is the correct response.
What exactly does termination mean?The word terminate has a noun form called termination, which means to put an end to. It also implies to terminate someone from a job, and termination is perhaps the word most frequently used to describe this action or its outcome, as in His employment with the firm came to an end after termination.
Are termination and firing the same thing?In the event that you are dismissed, your job is over. Your employer should explain the circumstances behind your termination to you. Due to wrongdoing or subpar work, you could be dismissed.
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the procedures instructs a student to measure 7.55 ml of solution 1. the student measures 11.89 ml of solution 1. what is the percent (by volume) of extra liquid measured by the student?
The procedures tells a student to measure 7.55 ml of solution 1 but the student measures 11.89 ml of solution 1. The percent by volume of extra liquid measure by the student added is 36.50%.
The percent by volume for any solution is calculated as
%(v/v)=(volume of solute/volume of solution)×100
In the given problem, the volume of solution is 11.89 ml and the volume of the solute is
volume of solute=(11.89-7.55)ml
volume of solute=4.34ml
We cannot consider the volume used to measure by procedure because the total volume is increased by extra addition of the solute. Plug all values in the formula
%(v/v)=(4.34 ml/11.89 ml)×100
%(v/v)=0.36501×100
%(v/v)=36.501%
%(v/v)=36.50%
Therefore, the percent of extra volume of a liquid measured by the student is 36.50 ml.
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How can a construction of a road affects water quality and flow within a watershed??
based on the position of the elements on the periodic table, which hydrogen bond would result in the greatest difference in electronegativity?
According to the position of the elements in the periodic table, the nitrogen bond contains the greatest difference in the electronegativity.
Electronegativity is defined as the tendency of an atom, which participates in a bond formation to attract the electrons. The nitrogen when bonded with hydrogen, shows a greatest difference in the electronegativity. The electronegativity value of N and H is 3.04 and 2.20 respectively. Hence, their difference is
ΔE=(3.04-2.20)=0.84
For boron and hydrogen, it is
ΔE=(2.20-1.57)=0.63
For phosphorus and hydrogen
ΔE=(2.20-2.19)=0.01
Therefore, according to the position of the elements in the periodic table, the nitrogen bond with hydrogen contains the greatest difference in the electronegativity.
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according to the collision model, why does increasing the temperature increase the rate of a reaction?
Increasing the temperature increase the rate of a reaction because it increases the number of collisions.
What is collision model?
According to the collision model, chemical reaction can occur only when reactant molecules, atoms, or ions collide with more than a particular amount of kinetic energy and in the right direction. The collision model explains why most molecular collisions do not result in a chemical reaction.
What is the effect of temperature on collision model?
Temperature influences both the rate of collision and the energy of molecules during collisions, according to collision theory. As the temperature rises, so does the amount of energy in the system, and therefore more molecules will have energy greater than the activation barrier. This accelerates the reaction.
Increasing the temperature increase the rate of a reaction because it increases the number of collisions.
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consider the reaction below. h2s so2−4⇌hs− hso−4 which of the above chemical species is the brønsted-lowry base in the forward reaction?
HS is the Bronsted-Lowry base in the forward reaction.
The Brnsted-Lowry theory is an acid-base reaction theory that was independently proposed in 1923 by Johannes Nicolaus Brnsted and Thomas Martin Lowry.
An acid is a proton (H+) donor in the Brnsted-Lowry definition of acids and bases, and a base is a proton acceptor. A conjugate base is formed when a Brnsted-Lowry acid loses a proton. A conjugate acid is formed when a Brnsted-Lowry base gains a proton.
A Bronsted-Lowry base is a compound that accepts a proton or an H+ ion from another compound. A conjugated acid can donate a proton and reform the base. An acid-base reaction, according to the Bronsted-Lowry theory, involves the exchange of protons or H+ ions between the acid and base.
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a. consider the molecule pentane. i. how many carbon atoms does this molecule have? (1 point) ii. what kinds of bonds does it have? (1 point)
Five carbon atoms make up the chemical pentane, which also contains one type of covalent bond and five carbon atoms.
What is atom and example?The quantity of protons an atom has makes it distinct from other atoms. Consequently, a particle devoid of proton not an atom. But even a single proton constitutes a atom (of hydrogen). Single particles of the periodic table elements like sodium, plutonium, argon, and chlorine are examples of atoms.
How is an atom formed?Atoms are made up of a nucleus in the middle that is surrounded by protons, neutrons, and electrons. Uranium is split into smaller atoms during the fission process, creating new atoms. Event such as the Big Bang or Supernova serve as instances .
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calculate the ph of the following two buffer solutions: (a) 1.0 m ch3coona/2.0 m ch3cooh. (b) 0.1 m ch3coona/0.2 m ch3cooh. which is the more effective buffer? a. 1.0 m ch3coona/2.0 m ch3cooh b. 0.1 m ch3coona/0.2 m ch3cooh
pH of (a) = 5.081 and pH of (b) = 4.479. The effective buffer is 1.0M CH3COONa / 2.0 m CH3COOH.
What is buffer solution?
Buffer Solution is a water-based solvent-based solution composed of a weak acid and its conjugate base, or a weak base and its conjugate acid.
We know that,
pH = pKa + log[salt] / [acid]
For 1.0M CH3COONa / 2.0 m CH3COOH
Given,
[Salt] = CH3COONa = 1.0M
[Acid] = CH3COOH = 2.0M
pKa of CH3COOH = 4.78
Subsituting the values,
pH = 4.78 + log[1.0] / [2.0]
pH = 4.78 + 0.3010
pH = 5.081
For 0.1M CH3COONa / 0.2M CH3COOH
Given,
[Salt] = CH3COONa = 0.1M
[Acid] = CH3COOH = 0.2M
Subsituting the values,
pH = 4.78 + log[0.1] / [0.2]
pH = 4.78 + (-0.3010)
pH = 4.479
The effective buffer is 1.0M CH3COONa / 2.0 m CH3COOH because the higher the concentrations, the bigger the total buffer capacity.
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the human resource manager at a pharmaceutical company is beginning the selection process for a new chemist. she would begin with the
A pharmaceutical company's human resource manager is starting the hiring process for a new chemist. She would start by going through orientation.
What is human resources management?The strategic method of developing and assisting people and providing a positive work environment is known as human resource management. Although its duties vary across various organizations and industries, they often include hiring, paying and providing benefits, providing training and development, and managing employee relations.
What is the role of HR in pharmaceutical company?To appreciate the significance of hiring and staffing should be aware of Orientation and Induction's significance. being aware of the significance of training and development to appreciate the significance of performance management and evaluation in order to appreciate the significance of employee retention
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Nuclear decay occurs according to first-order kinetics. What is the rate constant for radon-220, which has a half-life of 55. 6 seconds?.
The rate for radon-220, that has a quarter of 55.6 seconds, is 1.246*10⁻² seconds.
What exactly qualifies as nuclear?Identifying the causes of it. The essential components of a family, frequently its offspring and their parents, are referred to as the "nuclear family" in this context. Nuclear can also indicate "kernel" or, more simply, "something essential," therefore it has a long history of use in figurative language before being associated with "nuclear energy."
Briefing:Given:
Rate constant for radon = 220
Half-life = 55.6 seconds
(Nt) = (N₀)e⁻λt
At t = [tex]t_{1/2}[/tex] , (Nt) = (N₀)/2
(N₀)/2 = (N₀)e-λ[tex]t_{1/2}[/tex]
[tex]t_{1/2}[/tex] = ln₂/λ
λ is rate constant
55.6 = ln₂/λ
λ = ln₂/55.6
λ ≅ 1.246*10⁻² seconds
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What is required for both the light-dependent and light-independent reactions to proceed?energyco2wateratp and nadph.
Energy is required for both the light-dependent and light-independent reactions to proceed.
In order to produce ATP and NADPH, the light-dependent reactions of photosynthesis must first collect energy from the sun. Then, these two molecules that store energy are employed in the light-independent reactions. Chlorophyll absorbs solar energy during the light-dependent reactions and transforms it into chemical energy that is then stored. The chemical energy obtained during the light-dependent reactions powers the assembly of sugar molecules from carbon dioxide in the light-independent reactions.
Hence, Water and light energy are needed for the L-D reactions, while ATP, NADPH, and CO2 are needed for the L-IND reactions.
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the following alkene is treated with one equivalent of n-bromosuccinimide in dichloromethane in the presence of light to give bromination product(s). draw a line-angle formula for each product formed. you do not have to consider stereochemistry. draw organic products only. draw one structure per sketcher. add additional sketchers using the drop-down menu in the bottom right corner. separate multiple products using the sign from the drop-down menu.
karl Ziegler reported that alkenes react with N- bromo succinamide in the presence of light to give products resulting from substitution of hydrogen by bromine at the allylic .
Hydrogen's potential as a domestic alternative fuel source, capacity to power fuel cells in zero-emission cars, quick filling time, and hydrogen hashigh efficiency all contribute to its appeal as a transportation fuel.Important nutritional sources of bromine include grains, nuts, shellfish, and sea salt. For making bread and other baked items, brominated flour is occasionally used.The signs and symptoms of poisoning include lacrimation and redness of the eyes, irritation of the nose and throat, coughing, and dyspnea. Abdominal discomfort, hemorrhagic gastroenteritis, and subsequent shock can all result from ingesting liquid bromine.
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Ionic compounds are compounds composed of ions, charged particles that form when an atom (or group of atoms, in the case of polyatomic ions) gains or loses electrons.
A cation is a positively charged ion
An anion is a negatively charged ion.
Covalent or molecular compounds form when elements share electrons in a covalent bond to form molecules. Molecular compounds are electrically neutral.
Ionic compounds are (usually) formed when a metal reacts with a nonmetal (or a polyatomic ion). Covalent compounds are formed when two nonmetals react with each other. Since hydrogen is a nonmetal, binary compounds containing hydrogen are also usually covalent compounds.
Metal + Nonmetal —> ionic compound (usually)
Metal + Polyatomic ion —> ionic compound (usually)
Nonmetal + Nonmetal —> covalent compound (usually)
Hydrogen + Nonmetal —> covalent compound (usually)
Metal + nonmetal = ionic compound (usually) Typically, nonmetal + nonmetal forms a covalent combination, whereas metal + polyatomic ion forms an ionic compound (usually) Compound formed by hydrogen and a nonmetal (usually).
How is polyatomic distinguished?Only a few of the periodic table's elements have a second letter that is lowercase after their capital initial. As a result, you will recognize a polyatomic ion if it contains two capital letters together.
O2: Is it polyatomic?The majority of elements, however, are found in molecules made up of two or more atoms. They are referred to as polyatomic elements. The oxygen family, which includes oxygen, ozone, nitrogen, carbon dioxide, and water, is made up of the most prevalent polyatomic elements.
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what does the detector measure, and how are these numbers used to calculate transmittance and absorbance?
Absorbance is measured using a spectrophotometer or microplate reader, which is an instrument that shines light of a specified wavelength through a sample and measures the amount of light that the sample absorbs.
A spectrophotometer or microplate reader, which is a device that shines light of a certain wavelength through a sample and measures the amount of light that the sample absorbs, is used to quantify absorbance.Utilizing the ratio of light entering and leaving the sample, transmission is calculated in a photometer. From the transmission's negative decadic logarithm, absorbance is computed. After this, the detector gauges the sample's transmittance and absorbance. The amount of light that totally penetrates the sample and reaches the detector is referred to as transmittance. The amount of light that the sample is able to absorb is measured by its absorbance.To learn more about transmittance visit:
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The periodic table is an arrangment of the chemical elements, ordered by atomic number, into families, and by doing so illustrates the periodic properties of the elements. Considering the organization of the periodic table, which element would make a good conductor of electricity? what properties of that element would support this choice?.
The properties of that element is Copper, Cu.
A solid metal that is ductile and malleable.
Ductility and malleability are properties of metals with specific properties. It is the properties of ductility and formability that aid in the deformation of metals.
Ductility is the ability of a material to stretch without being damaged. A ductile metal can be stretched into a wire. An example is copper wire.Formability is the property of a material to deform under pressure. A malleable metal can be rolled or stamped into sheet. An example is aluminum foilIn metals, the two properties, formability and ductility, do not always correlate. For example, gold is both malleable and malleable, and lead is only malleable.
Therefore, The properties of that element is Copper, Cu.
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Nuclear decay occurs according to first-order kinetics. What is the half-life of polonium-218 if a sample decays from 55. 4 g to 31. 7 g in 2. 50 minutes?.
3.09 minutes is the half-life of polonium-218 if a sample decays from 55. 4 g to 31. 7 g in 2. 50 minutes.
What is half-life?
The half-life of a radioactive sample is the amount of time it takes for half of its atomic nuclei to spontaneously transform into different nuclear species and emit particles and energy, or, more precisely, the amount of time it takes for the radioactive sample to disintegrate at a rate of one disintegration per second.
The rate constant for a first-order reaction and its half-life are connected by the constant t1/2 = 0.693/k.
Therefore, 3.09 minutes is the half-life of polonium-218 if a sample decays from 55. 4 g to 31. 7 g in 2. 50 minutes.
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would the substance below (h2o2 with geometry given) be soluble in water (a polar solvent) or in benzene (a nonpolar solvent)?
Since H2O2 is an acid, its molecules react with water molecules to produce H3O+ and Br ions, which give the solution conductivity.
What differentiates polar from nonpolar solvents?
n contrast to nonpolar solvents, which dissolve nonpolar substances, polar solvents dissolve in polar compounds. The major difference between polar and nonpolar solvents is this. Additionally, polar liquids contain molecules with polar bonds, whereas nonpolar fluids contain molecules with comparable electronegativity values.
A nonpolar or polar solvent?
Polar solvents contain bonds between atoms with widely differing electronegativities, such as oxygen and hydrogen, and have strong dipole moments (also known as "partial charges"). Bonds between elements with comparable electronegativities, such as carbon and hydrogen, are found in non-polar fluids (think hydrocarbons, such as gasoline)
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