Question 11: How does the energy of a photon emitted when the electron moves from the 3rd orbital to the 2nd orbital compare to the energy of a photon absorbed when the electron moves from the 2nd orbital to the 3rd orbital?

Answer:

See explanation

Explanation:

For the first part of the question, we have to check the chiral carbons in 4-methyl-1,2-cyclohexanediol. In this case carbons, 1 and 2 are chiral, if we have 2 chiral carbons we will have 4 isomers. We have to remember that formula 2^n in which "n" is the number of chiral carbons, so:

2^n = 2^2 = 4 isomers

And the isomers that we can have are:

1) (1R,2S)-4-methylcyclohexane-1,2-diol

2) (1S,2S)-4-methylcyclohexane-1,2-diol

3) (1S,2S)-4-methylcyclohexane-1,2-diol

4) (1S,2R)-4-methylcyclohexane-1,2-diol

See figure 1

For the second part of the question, we have to remember that the oxidation with [tex]OsO_4[/tex] is a syn addition. In other words, the "OHs" are added in the same plane. In this case, we have the methyl group with a wedge bond, so the "OH" groups will have a dashed bond due to the steric hindrance. Due to this we only can have 1 isomer ((1S,2R,4S)-4-methylcyclohexane-1,2-diol). Finally, on this molecule, we dont have any symmetry planes (this characteristic will cancel out the optical activity), so the product of this reaction has optical activity.

See figure 2

I hope it helps!

Answer:a

Explanation:

The three characteristics of minerals are that they are solid, have definite crystal structure and definite chemical composition.

Minerals are defined as a chemical compound  which has a well -defined composition and possesses a specific crystal structure.It occurs naturally in the pure form.

If a compound occurs naturally in different crystal structure then each structure is considered as a different mineral.The chemical composition of a mineral varies  depending on the presence of small impurities which are present in small quantities.

Some minerals  can have variable proportions of two or more chemical elements  which occupy equivalent position in the crystal structure.It may also have variable composition which is split into separate species.

Physical properties of minerals include color,streak, luster,specific gravity  and cleavage.

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Answer:

The incorrect statement from the options is OXIDATION IS A "GAIN" OF ELECTRONS

Explanation:

Oxidation in a redox reaction is the loss of electrons. It is also the increase in the oxidation states of an atom or ion or atoms in a molecule. A redox reaction is a type of chemical reaction in which there is a transfer of electrons from an atom or ion to another resulting in a change in oxidation states of the substances involved. The reducing agent in the reaction is undergoes oxidation by losing electrons while the oxidating agent is reduced that is it gains electrons at the end of the reaction. The atom or ion from which electron is lost is said to be oxidized while the other atom or ion involved in the reaction is reduced.

Oxidation is also the combination with O atoms and it is always accompanied by reduction because oxidation forms a half of the whole redox reaction. A substance cannot be oxidized except it has reduced another substance by losing electrons to it.

Answer:

please look at the picture below.

Explanation:

Answer:

pH ≅ 4.80

Explanation:

Given that:

the volume of HN₃ = 25 mL = 0.025 L

Molarity of HN₃ = 0.150 M

number of moles of HN₃ = 0.025 × 0.150

number of moles of HN₃ =  0.00375  mol

Molarity of NaOH = 0.150 M

the volume of NaOH = 13.3 mL = 0.0133

number of moles of NaOH = 0.0133× 0.150

number of moles of NaOH = 0.001995 mol

The chemical equation for the reaction of this process can be written as:

[tex]HN_3 + OH- ---> N^-_{3} + H_2O[/tex]

1 mole of hydrazoic acid react with 1 mole of hydroxide to give nitride ion and water

thus the new number of moles of HN₃ = 0.00375 - 0.001995 = 0.001755 mol

Total volume used in the reaction =  0.025 +  0.0133 = 0.0383  L

Concentration of [tex]HN_3[/tex] = [tex]\dfrac{0.001755}{0.0383}[/tex] = 0.0458 M

Concentration of [tex]N^{-}_3[/tex] = [tex]\dfrac{ 0.001995 }{0.0383}[/tex] = 0.0521 M

GIven that :

Ka = [tex]1.9 x 10^{-5}[/tex]

Thus; it's pKa = 4.72

[tex]pH =4.72 + log(\dfrac{ \ 0.0521}{0.0458})[/tex]

[tex]pH =4.72 + log(1.1376)[/tex]

[tex]pH =4.72 + 0.05598[/tex]

[tex]pH =4.77598[/tex]

pH ≅ 4.80

The pH of the solution 0.150 M hydrazoic acid after 13.3 mL of NaOH base is added is 4.80.

pH of the given solution will be used by using the following equation:

pH = pKa + log[conjugate base] / [weak acid]

Given chemical reaction will be represented as:

HN₃ + OH⁻ → N₃⁻ + H₂O

Moles will be calculated as:

n = M×V, where

M = molarity

V = volume

Moles of 0.150 M hydrazoic acid = (0.150M)(0.025L) = 0.00375  mol

Moles of 0.150 M NaOH = (0.0133)(0.150) = 0.001995 mol

From the above calculation it is clear that moles of hydrazoic acid is present in excess and it will be:

0.00375 - 0.001995 = 0.001755 mol

And 0.001995 mol of N₃⁻ is preduced by the reaction.

Total volume of the solution = 0.025 +  0.0133 = 0.0383  L

To calculate the pH after titration, first we have to calculate the concentration in terms of molarity of N₃⁻ and HN₃ as:

[N₃⁻] = 0.001995 mol / 0.0383  L = 0.0521 M

[HN₃] = 0.001755 mol / 0.0383  L = 0.0458 M

Ka for HN₃ = 1.9 × 10⁻⁵

pKa = -log( 1.9 × 10⁻⁵ ) = 4.72

On putting all these values on the above equation, we get

pH = 4.72 + log (0.0521) / (0.0458)

pH = 4.80

Hence, pH of the solution is 4.80.

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Answer:

NaClO + CH₃COOH ----> HClO + CH3CO- + Na

Explanation:

This reaction occurs between the combination of a salt and an acid, that is, an oxide-reduction reaction

Answer:

THE EMPIRICAL FORMULA FOR THE UNKNOWN COMPOUND IS C7H9O

Explanation:

The empirical formula for the unknown compound can be obtained by following the processes below:

1 . Write out the percentage composition of the individual elements in the compound

C = 75.68 %

H = 8.80 %

O = 15.52 %

2. Divide the percentage composition by the atomic masses of the elements

C = 75 .68 / 12 = 6.3066

H = 8.80 / 1 = 8.8000

O = 15.52 / 16 = 0.9700

3. Divide the individual results by the lowest values

C = 6.3066 / 0.9700 = 6.5016

H = 8.8000 / 0.9700 = 9.0722

O = 0.9700 / 0.9700 = 1

4. Round up the values to the whole number

C = 7

H = 9

O = 1

5 Write out the empirical formula for the compound

C7H90

In conclusion, the empirical formula for the unknown compound is therefore C7H9O

Answer:

A.Electrolysis

Explanation:

A.Electrolysis

For example,  electrolysis of solution of NaCl in water gives H2 and O2.

Answer:

The lewis structure of the compounds can be drawn by making the skeleton of the molecule first. Then the different atoms are arranged and the electrons are arranged in their bonding pattern. The lone pair of the atoms, which are not involved in the bonding are represented by the dots.

So the lewis structures of both the compound methyl mercaptan has been in the attached image:

Spelling of methyl metcaptain is wrong, the correct spelling is methyl mercaptan.

Answer:

Methyl mercaptan is also known as Methanethiol with the chemical formula  CH3SH and it is an organosulfur compound.

For lewis structure of methyl mercaptan (CH3SH), there are total 14 valence electrons. Four hydrogen atoms has one valence electron each, carbon has four valence electrons and sulfur has six valence electrons. Carbon form one bond with three hydrogen atoms by sharing one electron with each, carbon form one single bond with sulfur atom by sharing one electron with it and sulfur form one single bond with hydrogen. Sulfur left with four unpair electrons.