nahco3(s) ⇌ naoh(s) co2(g) what is the free-energy change for this reaction at 298 k ? express the free energy in kilojoules to one decimal place.

Answers

Answer 1

The free-energy change for the reaction at 298 K is -94.7 kJ/mol.

The free-energy change for the reaction nahco3(s) ⇌ naoh(s) co2(g) at 298 K can be calculated using the following equation:
ΔG = ΔH - TΔS
where ΔH is the enthalpy change, T is the temperature in Kelvin, and ΔS is the entropy change.
To find the values for these parameters, we can refer to thermodynamic tables. The enthalpy change for the reaction is -52.3 kJ/mol, and the entropy change is 142.2 J/mol·K. Plugging these values into the equation, we get:
ΔG = -52.3 kJ/mol - (298 K)(0.1422 kJ/mol·K)
ΔG = -52.3 kJ/mol - 42.4 kJ/mol
ΔG = -94.7 kJ/mol
Therefore, the free-energy change for the reaction at 298 K is -94.7 kJ/mol.

Thus, we can use thermodynamic equations and tables to calculate the free-energy change for a chemical reaction. The enthalpy and entropy changes are important parameters that determine the overall feasibility of the reaction.

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Related Questions

3. Write a hypothesis that explains your inference about the acidity of the paper. How might you test your hypothesis by extending the experiment? What would you expect to see in this new experiment? (5 points). ​

Answers

A hypothesis that explains your inference about the acidity of the paper could be "The paper has acidic properties because it turned blue when it came in contact with the basic substance."

To test this hypothesis by extending the experiment, one could repeat the experiment by placing a piece of the same paper in an acidic solution. Vinegar, lemon juice, or another acidic solution may be used for this purpose. We will observe the color of the paper after being placed in the acidic solution. If the paper turns red, it indicates that it is acidic.

In this new experiment, one would anticipate that the paper will turn red, which would confirm the hypothesis that the paper has acidic characteristics.

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what is the activation energy of a reaction, and how is this energy related to the activated complex of the reaction?

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Activation energy is the energy required to initiate a chemical reaction, and it is related to the energy of the activated complex. Understanding this relationship is important in designing and optimizing chemical processes.

Activation energy is the minimum amount of energy that must be supplied to a chemical reaction to initiate the formation of products. It represents the energy barrier that must be overcome before reactants can transform into products.

The activated complex, also known as the transition state, is a high-energy intermediate state that forms during a chemical reaction when reactants undergo chemical transformation to form products. This intermediate state represents the highest point on the reaction energy diagram and has a higher energy level than both the reactants and products.

The activation energy is directly related to the energy of the activated complex because it represents the energy difference between the reactants and the activated complex. In other words, the activation energy is the energy required to convert reactants into the activated complex. Once the activated complex is formed, it can either decompose back to reactants or proceed to form products, depending on the stability and energy of the intermediate state.

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what is the osmotic pressure at 20 °c of 0.010 m cacl2 (aq) [note: assume complete dissociation of the cacl2.] give the answer in atm, in 2 sig. figs.

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The osmotic pressure (π) of a solution can be calculated using the equation π = MRT, where M is the molarity of the solution, R is the gas constant (0.08206 L·atm/mol·K), and T is the temperature in Kelvin.


In this case, we have a solution of 0.010 M CaCl₂. Since CaCl₂ is a strong electrolyte, it completely dissociates in water into one Ca²⁺ ion and two Cl⁻ ions. Therefore, the effective concentration of particles in the solution is 0.030 M (1 Ca²⁺ ion + 2 Cl⁻ ions). To convert this concentration to units of moles/L, we divide by the solution's volume, which we assume to be 1 L.

Next, we need to convert the temperature of 20 °C to Kelvin by adding 273.15. This gives us a temperature of 293.15 K.

Now, we can plug in these values into the equation for osmotic pressure:

π = (0.030 M) x (0.08206 L·atm/mol·K) x (293.15 K)

π = 0.717 atm

We round the answer to 2 significant figures, which gives us a final answer of 0.72 atm.

The osmotic pressure of a 0.010 M CaCl₂ solution at 20 °C is 0.72 atm.

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sulfuryl chloride decomposes to sulfur dioxide and chlorine. so2 cl2 (g) ! so2 (g) cl2 (g) kc is 0.045 at 648 k. if an initial concentration of 0.075 m so2 cl2 is allowed to equilibrate, what is the equilibrium concentration of cl2 ?

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When an initial concentration of 0.075 M SO2Cl2 is allowed to reach equilibrium, we can calculate the equilibrium concentration of Cl2 using the given equilibrium constant, Kc.

The balanced equation for the decomposition of sulfuryl chloride (SO2Cl2) is:

SO2Cl2(g) ⇌ SO2(g) + Cl2(g)

The equilibrium constant, Kc, is defined as the ratio of the concentrations of the products to the concentrations of the reactants, each raised to the power of their respective stoichiometric coefficients. In this case, Kc = [SO2][Cl2] / [SO2Cl2].

Given that Kc = 0.045 at 648 K, we can set up an equilibrium expression using the known concentrations:

0.045 = ([SO2][Cl2]) / [SO2Cl2]

Since the initial concentration of SO2Cl2 is 0.075 M, we can assign x as the change in concentration for both SO2 and Cl2.

At equilibrium, the concentration of SO2Cl2 will decrease by x, while the concentrations of SO2 and Cl2 will increase by x.

Using the equilibrium expression, we can substitute the concentrations in terms of x:

0.045 = ([0.075 - x][x]) / [0.075]

Simplifying and solving the equation will give us the value of x, which represents the equilibrium concentration of Cl2.

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(10 points) the concentration of lead in a water supply was 27 ppb. what would this concentration be in terms of molarity? assume a density of 0.997 g/ml for the solution.

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1.304 x 10⁻⁷ M is concentration be in terms of molarity assume a density of 0.997 g/ml for the solution.

To calculate the concentration of lead in the water supply in terms of molarity, we'll first need to convert the given concentration from parts per billion (ppb) to grams per liter (g/L) and then to moles per liter (M).
1. Given concentration: 27 ppb
2. Density of the solution: 0.997 g/mL
First, let's convert ppb to g/L:
27 ppb = 27 x 10⁻⁹ g/mL
Now, using the given density, we can convert g/mL to g/L:
27 x 10⁻⁹ g/mL x (1 L / 1000 mL) = 27 x 10⁻⁶ g/L
Next, we'll need the molar mass of lead (Pb), which is 207.2 g/mol. Finally, we can convert g/L to moles per liter (M):
(27 x 10⁻⁶ g/L) / (207.2 g/mol) = 1.304 x 10⁻⁷ M
So, the concentration of lead in the water supply in terms of molarity is approximately 1.304 x 10⁻⁷ M.

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Write equations to show how ions are produces in the two solutions that conduct electricity (0.1 M HCl - strong and 0.1 M Acetic Acid - weak).

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In a dilute solution, the forward reaction (dissociation of acetic acid) predominates, and the concentration of hydrogen ions is much lower than in a solution of a strong acid like HCl.

The dissociation of HCl in water produces hydrogen ions (H+) and chloride ions (Cl-):

HCl → H+ + Cl-

Since HCl is a strong acid, it completely dissociates into ions in aqueous solution.

The dissociation of acetic acid (CH3COOH) in water produces hydrogen ions (H+) and acetate ions (CH3COO-):

CH3COOH + H2O ⇌ H3O+ + CH3COO-

In this case, acetic acid is a weak acid, which means it only partially dissociates into ions in aqueous solution. The reaction is reversible because acetate ions can also react with hydrogen ions to form acetic acid and water:

CH3COO- + H3O+ ⇌ CH3COOH + H2O

However, in a dilute solution, the forward reaction (dissociation of acetic acid) predominates, and the concentration of hydrogen ions is much lower than in a solution of a strong acid like HCl.

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Find the order of the cyclic subgroup of Z4generated by 3.

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The order of the cyclic subgroup of Z4 generated by 3 is 2.

The cyclic subgroup of Z4 generated by 3 is {3, 1, 3, 1, ...}. This subgroup contains all powers of 3, i.e. {3^0, 3^1, 3^2, 3^3, ...}, where each power is taken modulo 4. To find the order of this subgroup, we need to find the smallest positive integer k such that 3^k ≡ 1 (mod 4).

We can calculate the powers of 3 modulo 4 as follows:

3^0 ≡ 1 (mod 4)
3^1 ≡ 3 (mod 4)
3^2 ≡ 1 (mod 4)
3^3 ≡ 3 (mod 4)
...

We can see that the sequence repeats every two powers. Therefore, the order of the cyclic subgroup generated by 3 is 2. This means that the subgroup contains only two elements, namely {1, 3}.

In summary, the order of the cyclic subgroup of Z4 generated by 3 is 2, and the subgroup contains the elements {1, 3}.

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a 20.0 gram sample of alum is heated to drive off all of the water from the solid . determine the mass of the dehydrated

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A 20.0 gram sample of alum is heated to drive off all of the water from the solid . 16.4 grams is the mass of the dehydrated

The mass of the dehydrated alum can be found by subtracting the mass of water that was driven off from the initial mass of the sample. Since all of the water is being driven off, we can assume that the mass of water is equal to the difference between the initial mass and the mass of the dehydrated alum.
To find the mass of water, we need to know the formula of alum and the percentage of water in it. The formula of alum is usually given as Al₂(SO₄)³·nH₂O, where n represents the number of water molecules per formula unit. In this case, we don't know the value of n, so we need to look it up or calculate it from the percentage of water in the sample.
Let's assume that the percentage of water in the sample is 18%, which is a common value for alum. This means that for every 100 grams of alum, there are 18 grams of water. Therefore, for a 20 gram sample of alum, the mass of water is:
Mass of water = 20 g x 0.18 = 3.6 g
Now we can calculate the mass of the dehydrated alum:
Mass of dehydrated alum = 20 g - 3.6 g = 16.4 g
Therefore, the mass of the dehydrated alum is 16.4 grams.

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The solubility of AgCl in water at 25∘ C is measured to be 0.0019 g/L. Use this information to calculate K_sp for AgCl. Round your answer to 2 significant digits.

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The solubility is defined as degree to which a substance dissolves in a solvent to make a solution. The solubility of [tex]AgCl[/tex] in water at 25°C is given as 0.0019 g/L. The K_sp (solubility product constant) for [tex]AgCl[/tex] is [tex]1.7*10^{-10}[/tex]

[tex]AgCl[/tex] has a molar mass of 143.32 g/mol (107.87 g/mol for [tex]Ag[/tex] and 35.45 g/mol for [tex]Cl[/tex]). So, the solubility in moles/L is:
(0.0019 g/L) / (143.32 g/mol) ≈ 1.32 x 10^-5 mol/L.
When [tex]AgCl[/tex]dissolves, it dissociates into its ions:
[tex]AgCl[/tex](s) ⇌ [tex]Ag[/tex]+(aq) + [tex]Cl[/tex]^-(aq).The concentration of [tex]Ag[/tex]+ and [tex]Cl[/tex]- ions are equal to the solubility, which is 1.32 x 10^-5 mol/L. Now, we can calculate the K_sp: K_sp = [[tex]Ag[/tex]+][[tex]Cl[/tex]-] = (1.32 x 10^-5)(1.32 x 10^-5) ≈ 1.74 x 10^-10.

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which is the correct order from lowest to highest field for the chemical shift

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The correct order from lowest to highest field for the chemical shift is: Deshielded < Shielded < Highly Shielded

The chemical shift is a measure of the magnetic field experienced by a nucleus in a molecule. It depends on the electron density around the nucleus and the external magnetic field.

Shielding occurs when the electrons around the nucleus create a magnetic field that opposes the external magnetic field, leading to a lower chemical shift. Deshielding occurs when the electrons around the nucleus create a magnetic field that reinforces the external magnetic field, leading to a higher chemical shift.

Highly shielded nuclei are those that experience the strongest shielding effect, leading to the lowest chemical shift.

The correct order from lowest to highest field for the chemical shift is Deshielded < Shielded < Highly Shielded.

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NAME: Madsen Binette
CLASS: Blue 4
Percent yield practice
1. Consider the following balanced equation
2 Al + 6 HBr - →2 AlBr3 + 3 H₂
A) If 86.88 grams of Aluminum (Al) reacts with 401.31 grams of
Hydrogen Bromide (HBr) how many grams of H₂ will be produced?
B) which is the limiting reactant?
C) what is the percent yield

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Answer:

I dont understand nd also i need to message u privately

When the half-reaction NO−3⟶NOis balanced for one NO−3in acid solution, .......... electron(s) is (are) ........ .A3 gainedB1 gainedC1 lostD3 lost

Answers

When the half-reaction NO⁻³⟶NO is balanced for one NO⁻³ in acid solution, 3 electrons are gained. Option A is correct.

A half reaction is a chemical equation that shows the oxidation or reduction of species by itself. In other words, it shows either the loss or gain of electrons by a chemical species.

The balanced half-reaction is;

NO₃⁻ + 4H⁺ + 3e⁻ → NO + 2H₂O

In this half-reaction, three electrons (3e⁻) are gained by NO₃⁻ to form NO. This is because NO₃⁻ has a higher oxidation state (+5) compared to NO, which has an oxidation state of +2. In order to balance the oxidation states on both sides of the reaction, NO₃⁻ must gain three electrons to reduce its oxidation state to +2 and form NO.

Hence, A. is the correct option.

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sulfur-containing materials will form which gas when treated with a reducing agent:

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Sulfur-containing materials will form hydrogen sulfide gas (H2S) when treated with a reducing agent.

When sulfur-containing materials are treated with a reducing agent, the gas that will form is hydrogen sulfide (H2S).

Here's a step-by-step explanation:

1. Start with a sulfur-containing material (e.g., a sulfide compound like sodium sulfide, Na2S).

2. Introduce a reducing agent (e.g., hydrogen gas, H2).

3. The reducing agent will react with the sulfur-containing material, reducing the sulfur in the compound.

4. As a result of the reaction, hydrogen sulfide gas (H2S) is formed and released.

Therefore, treating sulfur-containing materials with a reducing agent will form hydrogen sulfide gas.

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what are the actions best to take when fueling an outboard boat with a portable tank?

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When fueling an outboard boat with a portable tank, there are several actions that should be taken to ensure safety and proper fueling.

Firstly, the boat should be in a stable position and the engine should be turned off to prevent any accidental ignition. The portable tank should also be placed on a level surface, away from any potential sources of sparks or flames.

Secondly, it is important to ensure that the fuel nozzle is clean and free from any debris or dirt. This can be done by wiping it down with a clean cloth before inserting it into the tank.

Thirdly, it is recommended to use a funnel to prevent any spillage and to make the fueling process easier.

Lastly, it is important to fill the tank slowly and avoid overfilling, as this can lead to spillage and potential fire hazards.

By following these actions, you can ensure that the fueling process is safe and efficient for your outboard boat with a portable tank.

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Final answer:

When fueling an outboard boat with a portable tank, ensure you're in a well-ventilated area, the engine is off and cool, and there are no static electricity sources. Gradually fill the tank up to the fill line, then securely seal the cap. Finally, check for any signs of leaks or potential damage after fueling.

Explanation:

When fueling an outboard boat with a portable tank, there are several steps you should follow to ensure safety and prevent any issues. First, make sure you're in a well-ventilated area to prevent fumes build-up. Next, ensure the boat engine is off and cool to the touch to avoid igniting any accidental spills. You should also ground the fuel container to prevent static electricity. Now, slowly, fill the tank, being sure to stop at the fill line to avoid overflows. Once the tank is full, securely close the fuel cap and ensure there is no remaining fuel on the deck or hull. After fueling an outboard boat, it is important to carry forward a final check to make sure that there are no leaks or signs of damage in and around the fueling area.

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will lead (ii) chloride be less soluble in 0.10 m mgcl2 or in 0.10 m nacl?

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Chloride (PbCl2) will have the same solubility in 0.10 M MgCl2 and 0.10 M NaCl solutions.

To determine the relative solubility of lead (II) chloride (PbCl2) in 0.10 M MgCl2 and 0.10 M NaCl, we need to consider the common ion effect.

The common ion effect states that the solubility of a salt is decreased when a common ion is present in the solution. In this case, both MgCl2 and NaCl are sources of chloride ions (Cl-), which is a common ion for PbCl2.

Comparing the two solutions, we can see that both solutions have the same concentration of chloride ions (0.10 M). Since the solubility of PbCl2 is primarily determined by the concentration of chloride ions, the solubility of PbCl2 will be the same in both solutions.

Therefore, lead (II) chloride (PbCl2) will have the same solubility in 0.10 M MgCl2 and 0.10 M NaCl solutions.

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which reaction conditions are best suited for the synthesis of 1-methylcyclopentane-1-carbaldehyde?

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The synthesis of 1-methylcyclopentane-1-carbaldehyde achieved through the reaction of 1-methylcyclopentene with ozone, followed by reduction with dimethyl sulfide and oxidation with potassium permanganate.

The best reaction conditions for this synthesis include using ozone in the presence of a suitable solvent such as dichloromethane or tetrahydrofuran, and carrying out the reduction and oxidation steps under mild conditions and in the presence of suitable reagents such as dimethyl sulfide and potassium permanganate, respectively. Other factors such as temperature, pressure, and reaction time may also need to be optimized depending on the specific reaction conditions.

Search for the wedge and sprint bonds, which are often the ones suggesting a chiral centre, to identify the chiral middle. One crucial thing to keep in mind is that a carbon with a double bond cannot be a chiral centre since it no longer has four unique companies.

Chemistry term for a method of displaying the three-dimensional structure of a molecule that uses simple lines to indicate bonds inside the plane of the picture, wedge-shaped lines to represent links facing the viewer, and dashed lines to show bonds facing the viewer in the distance.

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in this reaction 2no h2 = n2o h2o heat what will happen to the h2o

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In this reaction, the H₂O will be formed as a product. The reaction involves the combination of 2 molecules of NO and 2 molecules of H₂ to form 1 molecule of N₂O and 1 molecule of H₂O. The heat serves as a catalyst to drive the reaction forward.

In the reaction 2NO + H₂ = N₂O + H₂O (with heat), H₂O (water) is a product formed as a result of the reaction between nitrogen monoxide (NO) and hydrogen gas (H₂). When heat is applied, the reactants combine to produce dinitrogen monoxide (N₂O) and water (H₂O). The H₂O will exist as a product in the equilibrium mixture.

So, the H₂O will be produced as a result of the reaction and will remain in the mixture.

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4. calculate the ph of a solution in which the concentration of the hydronium ion equals 2.0 x 10-4 m.

Answers

A pH of 3.70 indicates that the solution is slightly acidic. This is because the pH scale ranges from 0 to 14, with pH values less than 7 indicating acidity, pH values greater than 7 indicating basicity, and a pH of 7 indicating neutrality.

To calculate the pH of a solution, we use the formula:

pH = -log[H3O+]

where [H3O+] represents the concentration of the hydronium ion.

Given [H3O+] = 2.0 x 10^-4 M, we can substitute it into the formula to get:

pH = -log(2.0 x 10^-4)

Using a calculator, we find that:

pH = 3.70

Therefore, the pH of the solution is 3.70.

A pH of 3.70 indicates that the solution is slightly acidic. This is because the pH scale ranges from 0 to 14, with pH values less than 7 indicating acidity, pH values greater than 7 indicating basicity, and a pH of 7 indicating neutrality. Since the pH of this solution is less than 7, we can conclude that it is slightly acidic.

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A calorimeter holds 65 g water at 23.0°C. A sample of hot iron is added to the water, and the final temperature of the water and iron is 27.0°C. What is the change in enthalpy associated with the change in the water’s temperature?

Note: The specific heat of water is 4.18 j/g*C

Answers

The change in enthalpy of the reaction, given that a hot iron is added to the water, and the final temperature of the water and iron becomes 27.0°C is 0.301 KJ/mol

How do i determine the change in enthalpy of the reaction?

We shall begin by obtain the heat absorbed by the water. Details below:

Mass of water (M) = 65 gInitial temperature of water (T₁) = 23 °CFinal temperature of statue(T₂) = 27 °CChange in temperature (ΔT) = 27 - 23 = 4 °C Specific heat capacity of water (C) = 4.18 J/gºC Heat absorbed (Q) =?

Q = MCΔT

Q = 65 × 4.18 × 4

Q = 1086.8 J

Finally, we shall determine the change in enthalpy of the reaction. Details below:

Heat absorbed (Q) = 1086.8 J = 1086.8 / 1000 = 1.0868 KJMass of water = 65 gMolar mass of water = 18 g/molMole of water (n) = 65 / 18 = 3.61 molesChange in enthalpy (ΔH) =?

Q = n × ΔH

1.0868 = 3.61 × ΔH

Divide both sides by 3.61

ΔH = 1.0868 / 3.61

ΔH = 0.301 KJ/mol

Thus, we can conclude that the change in enthalpy of reaction is 0.301 KJ/mol

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Asap, I need to finish the skill

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For every molecule of sulfuryl chloride that reacts, 2 molecules each of sulfur dioxide and chlorine are produced.

The balanced chemical equation for the reaction is:

[tex]SO_{2}Cl_{2}[/tex] → [tex]2SO_{2}[/tex] + [tex]2Cl_{2}[/tex]

To determine how many molecules of sulfuryl chloride react, we need to know the amount of sulfur dioxide and chlorine produced. We can use stoichiometry to calculate this.

From the balanced equation, we can see that 1 molecule of [tex]SO_{2}Cl_{2}[/tex] produces 2 molecules of [tex]SO_{2}[/tex] and 2 molecules of [tex]Cl_{2}[/tex]. Therefore, the number of molecules of sulfuryl chloride that react is half the number of molecules of either product.

Let's assume that we start with x molecules of sulfuryl chloride. Then, using the balanced equation, we can calculate the number of molecules of each product produced:

[tex]2SO_{2}[/tex] : 2x molecules

[tex]2Cl_{2}[/tex] : 2x molecules

So, during this reaction, x molecules of sulfuryl chloride react to produce 2x molecules each of sulfur dioxide and chlorine.

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A 0.589 mol sample of nitrogen gas, N2, has a volume of 1.68L at a pressure of 0.975 atm. Calculate the temperature of the nitrogen gas

Answers

To calculate the temperature of the nitrogen gas, we can use the ideal gas law equation:

PV = nRT

Where:
P = pressure (in atm)
V = volume (in liters)
n = number of moles
R = ideal gas constant (0.0821 L·atm/(mol·K))
T = temperature (in Kelvin)

We are given:
n = 0.589 mol
V = 1.68 L
P = 0.975 atm

Rearranging the equation, we get:

T = PV / (nR)

Substituting the given values:

T = (0.975 atm) * (1.68 L) / (0.589 mol * 0.0821 L·atm/(mol·K))

Calculating the expression:

T ≈ 28.4 K

Therefore, the temperature of the nitrogen gas is approximately 28.4 Kelvin.

The temperature of the nitrogen gas is  33.92 Kelvin

How to solve:

To get the temperature of the nitrogen gas, we will use the ideal gas equation:

PV = nRT

where:

P is the pressure, V is the volume, n is the number of moles, R is the ideal gas constant, and T is the temperature. First, let's change the equation to account for temperature:

T = PV/(nR)

Presently, we can connect the given qualities:

The ideal gas constant, R, is 0.0821 L-atm/(mol-K), with P = 0.975 atm and V = 1.68 L and n = 0.589 mol.

Adding the following values to the equation:

T = (0.975 atm * 1.68 L) / (0.589 mol * 0.0821 L atm/(mol K)) T = 1.6332 atm L / (0.04813 L atm/(Kmol))

The nitrogen gas's temperature is 33.92 Kelvin because;

T = 1.6332 / 0.04813 K

T = 33.92 K.

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in a galvanic cell, the ion migration between the two half-cells occurs through the ______________ to complete the circuit and prevent charge built-up in the two half-cells.

Answers

In a galvanic cell, the ion migration between the two half-cells occurs through the salt bridge to complete the circuit and prevent charge built-up in the two half-cells.

Migration of ions is essential for the operation of a galvanic cell, as it allows the flow of electrons to balance the reduction and oxidation reactions occurring in each half-cell. The salt bridge plays a crucial role in maintaining a neutral charge balance between the two half-cells by allowing the migration of positively charged ions from the anode to the cathode, and negatively charged ions from the cathode to the anode. This prevents the accumulation of charges in the half-cells, which could eventually lead to a breakdown of the cell and cessation of the chemical reaction. Therefore, the salt bridge is an essential component of any galvanic cell, and its design and composition must be carefully considered to ensure optimal performance.

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balance the following redox reaction in acidic solution. mn2 (aq)br2(l)(aq)(aq)

Answers

To balance the redox reaction you provided in acidic solution, we need to follow these steps. Split the reaction into two half-reactions, one for oxidation and one for reduction.

The given reaction is:

Mn₂ ₊ (aq) ₊ Br₂(l) → ?

Reduction half-reaction: Br₂(l) → 2 Br₋(aq)

The reduction half-reaction is already balanced.

Multiply the oxidation half-reaction by 2 and the reduction half-reaction by 5 to equalize the number of electrons:

10 Mn₂ ₊ (aq) → 10 MnO₄ ₋(aq) ₊ 25e⁻

5 Br₂(l) → 10 Br₋(aq)

Now we can add the two balanced half-reactions together:

10 Mn₂₊(aq) ₊ 5 Br₂(l) → 10 MnO₄₋(aq) ₊ 25e⁻ ₊ 10 Br₋(aq)

Finally, cancel out the electrons and simplify the equation:

10 Mn₂₊(aq) ₊ 10 Br₂(l) → 10 MnO₄⁻(aq) ₊ 10 Br⁻(aq)

This is the balanced redox reaction in acidic solution.

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TRUE OR FALSE – It’s better for the environment to use a durable, washable, refillable water bottle than it is to buy water bottles, drink the water and recycle the empty plastic bottle.

True
False

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True, It’s better for the environment to use a durable, washable, refillable water bottle than it is to buy water bottles, drink the water and recycle the empty plastic bottle.

Why is it better to to use a durable, washable, refillable water bottle?

In view of the current ecological concerns it is advisable to switch from using disposable plastic water bottles to a sturdy reusable alternative that can be refilled with ease.

This move will help curb the negative impact caused by the manufacturing process of single use bottles such as resource depletion, high energy usage alongside associated emissions.

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which oxoanion, mno4 2 or reo4 2, is expected to be the stronger oxidizing agent? explain your choice

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The higher oxidation state and smaller size of manganese in mno4 2 make it a stronger oxidizing agent compared to rhenium in reo4 2.

The mno4 2 oxoanion is expected to be the stronger oxidizing agent compared to reo4 2. This is because of the higher oxidation state of manganese (+7) compared to rhenium (+6). In general, the higher the oxidation state of an element, the stronger the oxidizing agent it is.
Manganese in mno4 2 is in its highest possible oxidation state, which means it has a greater affinity for electrons and is more likely to gain electrons from other elements. This makes mno4 2 a stronger oxidizing agent compared to reo4 2.
Another factor that contributes to the strength of an oxidizing agent is the size of the atom or ion. In this case, rhenium is a larger atom compared to manganese, which means it is less likely to attract electrons and therefore less likely to act as a strong oxidizing agent.
In summary, the higher oxidation state and smaller size of manganese in mno4 2 make it a stronger oxidizing agent compared to rhenium in reo4 2.

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when a solution is titrated with an base, an indicator ( ) changes from yellow to blue ( ). the of the indicator is . at what will the indicator color change first be visible?

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When a solution is titrated with a base, an indicator (such as phenolphthalein) changes from yellow to blue (or colorless). The pKa of the indicator is around 8.2.

When the system changes colour, neutralisation has taken place and the amounts of base and acid have been balanced.

An acid is any substance that when dissolved in water has a sour taste, turns blue litmus paper red, reacts with certain minerals to release hydrogen, or combines with base to form compounds that aid in chemical reactions.

The medical word for this condition, known as acidosis, is when the body's pH equilibrium is upset by a significant quantity of acid. Too much acid may result in serious health issues if the systems of elimination are unable to eliminate it. Therefore, the indicator color change first becomes visible when the pH of the solution reaches around 8.2.

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a weak acid is titrated with naoh to generated the titration curve gbelow. which acid is it most likely to be? group of answer choices hclo (ka

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The most likely weak acid titrated with NaOH in the given scenario is HClO (hypochlorous acid). This is because its Ka value is consistent with the behavior of a weak acid.

In a titration curve, the acid's strength can be estimated by analyzing the shape of the curve, particularly the pH at the equivalence point and the buffering region. The Ka value of HClO is around 3.5 × 10⁻⁸, which indicates that it is a weak acid. During titration, as NaOH is added, it neutralizes HClO to form water and a salt (NaClO). The curve for a weak acid will show a buffering region where the pH changes slowly as more NaOH is added. At the equivalence point, the curve will have a steep rise in pH. The shape of the given titration curve, along with the provided information, suggests that the most likely weak acid titrated with NaOH is HClO (hypochlorous acid).

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fluorine-18 undergoes positron emission with a half-life of 1.10 x 102 minutes. if a patient is given a 248 mg dose for a pet scan, how long will it take for the amount of fluorine-18 to drop to 83 mg? (assume that none of the fluorine is excreted from the body.)

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It will take approximately 166 minutes (or 2.77 hours) for the amount of fluorine-18 undergoes positron emission with a half-life to drop from 248 mg to 83 mg.

The decay of a radioactive substance can be modeled by the first-order rate equation:

N(t) = N0 e^(-kt)

where N(t) is the amount of substance remaining at time t, N0 is the initial amount of substance, k is the decay constant, and e is the base of the natural logarithm.

The half-life (t1/2) of fluorine-18 is 1.10 x 10^2 minutes, which means that half of the original amount of fluorine-18 will decay in that time. We can use the following equation to relate the half-life to the decay constant:

t1/2 = ln(2) / k

Rearranging, we can solve for k:

k = ln(2) / t1/2

k = (0.693 / 110) min^-1

We can now use the first-order rate equation to find the time required for the amount of fluorine-18 to drop to 83 mg:

83 mg = 248 mg e^(-kt)

ln(83/248) = -kt

t = -ln(83/248) / k

t = 166 min

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What is the concentration of CN- ion in a 0.100 molar solution of K4Fe(CN)6? Kd for(Fe(CN)6)4- is 1.3 × 10^-37.1. 8.33 × 10^-7 M2. 3.87 × 10^-6 M3. 5.00 × 10^-6 M4. 2.32 × 10^-5 M5. 2.23 × 10^7 M

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The concentration of CN⁻ ions in the 0.100 M solution of K₄Fe(CN)₆ is 3.87 × 10⁻⁶ M . Option 2 is Correct.

To find the concentration of CN- ions in a 0.100 M solution of K₄Fe(CN)₆, we first need to consider the dissociation reaction:
Fe(CN)₆⁴⁻ → Fe³⁺ + 6CN⁻
Since Kd for (Fe(CN)₆⁴⁻) is 1.3 × 10⁻³⁷, we can set up the following expression:

[tex]Kd=\frac{[H+][A-]}{[HA]}[/tex]

The energy needed to produce a complex ion at a specific ion concentration is measured by the equilibrium constant, or Kd. This implies that complexation processes can lead
Kd = [Fe³⁺][CN⁻]⁶ / [Fe(CN)₆⁴⁻]
Assuming the reaction proceeds to completion, we have:
0.100 M Fe(CN)₆⁴⁻ → 0.100 M Fe³⁺ + 0.600 M CN⁻
Now, we can substitute these values into the Kd expression:
1.3 × 10⁻³⁷ = (0.100)(0.600)⁶ / (0.100)
Solving for the concentration of CN⁻ ions:
[CN⁻] = 3.87 × 10⁻⁶ M

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The Complete question is

What is the concentration of CN- ion in a 0.100 molar solution of K₄Fe(CN)₆? Kd forFe(CN)₆ - is 1.3 × 10⁻³⁷.

1. 8.33 × 10⁻⁷ M

2 . 3.87 × 10⁻⁶ M

3. 5.00 × 10⁻⁶ M

4. 2.32 × 10⁻⁵ M

5. 2.23 × 10⁷ M

what would you expect for the magnitude and direction of the bond dipoles in this series?

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The magnitude and direction of the bond dipoles will depend on the electronegativity difference between the atoms involved in the bond and the geometry of the molecule.

In this series, the bond dipoles are expected to have varying magnitudes and directions. The magnitude of the bond dipole is determined by the difference in electronegativity between the two atoms involved in the bond. The greater the difference in electronegativity, the greater the magnitude of the bond dipole.
For example, in a polar covalent bond between hydrogen and chlorine, the electronegativity difference is 0.9, resulting in a strong bond dipole. On the other hand, in a polar covalent bond between two carbon atoms, the electronegativity difference is only 0.3, resulting in a weaker bond dipole.
The direction of the bond dipole is determined by the geometry of the molecule and the orientation of the bond. In a molecule with a linear geometry, the bond dipoles will be in opposite directions, resulting in a net dipole moment of zero. In a molecule with a bent geometry, the bond dipoles will not cancel out, resulting in a net dipole moment.
Therefore, in this series, the magnitude and direction of the bond dipoles will depend on the electronegativity difference between the atoms involved in the bond and the geometry of the molecule.

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