If the following enthalpies are known: A+2B arrow 2C+D delta H= -95kJ B+X arrow C delta H=+50 kJ What is delta H for the following reaction: A arrow 2X+D

Answers

Answer 1

The delta H for the reaction A → 2X + D If the following enthalpies are known: A + 2B → 2C + D delta H= -95kJ and B + X → C delta H=+50 kJ is -195 kJ.

We can manipulate the given reactions to find the desired reaction:

1) A + 2B → 2C + D (delta H = -95 kJ)

2) B + X → C (delta H = +50 kJ)

First, reverse reaction 2 and multiply by 2 to have 2X on the product side:

2') 2C → 2B + 2X (delta H = -100 kJ)

Now, add reaction 1 and 2' together:

A + 2B → 2C + D (-95 kJ)

2C → 2B + 2X (-100 kJ)

-------------------------

A → 2X + D (delta H = ?)

Adding the delta H values of reactions 1 and 2' gives the delta H for the desired reaction:

delta H = (-95 kJ) + (-100 kJ) = -195 kJ

So, the delta H for the reaction A → 2X + D is -195 kJ.

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Related Questions

for the hypothetical reaction a 3b → 2c, the rate should be expressed as

Answers

The coefficients (1/3 and 1/2) account for the stoichiometry of the reaction.

For the hypothetical reaction 3A + 3B → 2C, the rate can be expressed in terms of the change in concentration of reactants or products over time. The rate expression would be:

Rate = -(1/3)d[A]/dt = -(1/3)d[B]/dt = (1/2)d[C]/dt

Here, d[A]/dt, d[B]/dt, and d[C]/dt represent the change in concentrations of A, B, and C over time, respectively.

The negative signs for A and B indicate that their concentrations decrease as the reaction proceeds, while the positive sign for C indicates that its concentration increases.

The coefficients (1/3 and 1/2) account for the stoichiometry of the reaction.

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An elution fraction from a Ni+2 agarose column that has a high rGFP florescence will also have a high purity.
True
False

Answers

The given statement "An elution fraction from a Ni+2 agarose column that has a high rGFP fluorescence will also have a high purity" is generally true because rGFP is usually only present in the elution fraction if it has been successfully purified by the column. However, there may be some rare cases where contaminants can also cause fluorescence.

Ni+2 agarose column chromatography is a common method for purifying recombinant proteins, such as rGFP, which contain a His-tag. The His-tag binds specifically to the nickel ions on the column and allows for purification of the protein from other cellular components.

If a elution fraction from the column contains high levels of rGFP fluorescence, it is an indication that the protein has been successfully purified and is present in that fraction. However, it is possible that some contaminants could also fluoresce and contribute to the overall fluorescence signal.

Therefore, the purity of the elution fraction should be confirmed using additional methods, such as SDS-PAGE or mass spectrometry, to ensure that the rGFP is the only protein present.

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2.) concentrated hcl is 36.0 y mass hcl and has a density of 1.18 g/ml. calculate the molality and molarity of concentrated hcl.

Answers

The molality is 9.84 mol/kg and molarity of concentrated hcl is 32.30 mol/L.

To determine the molality (m) of concentrated HCl, first determine the moles of HCl present in 1 kg of solution.

To begin, we can convert the supplied density of 1.18 g/mL to kg/L as follows:

1.18 kg/L = 1.18 g/mL x (1 kilogramme / 1000 g) x (1000 mL / 1 L)

This means that one litre of concentrated HCl solution weighs 1.18 kilogramme. Because the solution contains 36.0% HCl by mass, the mass of HCl in one litre of solution is:

1.18 kg x 0.36 = 0.4248 kilogramme

Because HCl has a molar mass of 36.46 g/mol, the number of moles of HCl in 0.4248 kg is:

11.63 mol = 0.4248 kg x (1000 g / 1 kilogramme) / 36.46 g/mol

The molality (m) of a solute (in this case, HCl) is defined as the number of moles of solute per kilogramme of solvent (in this case, water).  As a result, the molality is:

9.84 mol/kg = m = 11.63 mol / 1.18 kg

To calculate the molarity (M) of concentrated HCl, we must first determine the volume of the solution containing one mole of HCl.

Using its molar mass and density, the volume of 1 mole of HCl may be calculated:

30.93 mL/mol = 36.46 g/mol / 1.18 g/mL

As a result, one litre of concentrated HCl solution contains:

1000 mL divided by 30.93 mL/mol equals 32.30 mol

As a result, the molarity of concentrated HCl is as follows:

M = 32.30 mol/L

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The molality is 9.84 mol/kg and molarity of concentrated hcl is 32.30 mol/L.To determine the molality (m) of concentrated HCl, first determine the moles of HCl present in 1 kg of solution.

To begin, we can convert the supplied density of 1.18 g/mL to kg/L as follows:1.18 kg/L = 1.18 g/mL x (1 kilogramme / 1000 g) x (1000 mL / 1 L)This means that one litre of concentrated HCl solution weighs 1.18 kilogramme. Because the solution contains 36.0% HCl by mass, the mass of HCl in one litre of solution is:1.18 kg x 0.36 = 0.4248 kilogrammeBecause HCl has a molar mass of 36.46 g/mol, the number of moles of HCl in 0.4248 kg is:11.63 mol = 0.4248 kg x (1000 g / 1 kilogramme) / 36.46 g/molThe molality (m) of a solute (in this case, HCl) is defined as the number of moles of solute per kilogramme of solvent (in this case, water).  As a result, the molality is:9.84 mol/kg = m = 11.63 mol / 1.18 kgTo calculate the molarity (M) of concentrated HCl, we must first determine the volume of the solution containing one mole of HCl. Using its molar mass and density, the volume of 1 mole of HCl may be calculated:30.93 mL/mol = 36.46 g/mol / 1.18 g/mLAs a result, one litre of concentrated HCl solution contains:1000 mL divided by 30.93 mL/mol equals 32.30 molAs a result, the molarity of concentrated HCl is as follows:M = 32.30 mol/L

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Ca(OH)2(s) ? Ca2+(aq) + 2OH-(aq)
Predict the expected shift, if any, caused by adding the various ions (Ca2+, Na+, Ag+, H+, OH-, NO3-) to a saturated calcium hydroxide solution?

Answers

The addition of Ca²⁺ and OH⁻ ions would not cause a shift in the equilibrium of the saturated calcium hydroxide solution, while the addition of Na⁺, H⁺, and NO₃⁻ ions would shift the equilibrium to the left, and the addition of Ag⁺ ions would cause a precipitation reaction.

In a saturated calcium hydroxide solution, the solid Ca(OH)₂ is in equilibrium with its ions in solution: Ca(OH)₂(s) ⇌ Ca²⁺(aq) + 2OH⁻(aq). The addition of Ca²⁺ and OH⁻ ions would not cause a shift in the equilibrium since they are already present in the solution.

The addition of Na⁺ ions, which are spectator ions and do not participate in the reaction, would increase the ionic strength of the solution and shift the equilibrium to the left. The addition of H⁺ ions, which would react with OH⁻ ions to form H₂O, and NO₃⁻ ions, which are spectator ions and do not participate in the reaction, would also shift the equilibrium to the left.

The addition of Ag⁺ ions, which have a low solubility product with OH⁻ ions, would cause a precipitation reaction and shift the equilibrium to the left.

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What is the vapor pressure of the solution if 25.0 g of water is dissolved in 100.0 g of ethyl alcohol at 25 °C? The vapor pressure of pure water is 23.8 mm Hg, and the vapor pressure of ethyl alcohol is 61.2 mm Hg at 25 °C.

Answers

The vapor pressure of the solution is 43.4 mm Hg.

To determine the vapor pressure of the solution, we need to use Raoult's law, which states that the vapor pressure of a solution is proportional to the mole fraction of the solvent in the solution.

First, we need to calculate the mole fraction of water in the solution:

moles of water = 25.0 g / 18.015 g/mol = 1.387 mol

moles of ethyl alcohol = 100.0 g / 46.068 g/mol = 2.171 mol

mole fraction of water = 1.387 / (1.387 + 2.171) = 0.390

Using Raoult's law, we can calculate the vapor pressure of the solution:

vapor pressure of solution = mole fraction of water x vapor pressure of pure water + mole fraction of ethyl alcohol x vapor pressure of pure ethyl alcohol

vapor pressure of solution = (0.390)(23.8 mm Hg) + (0.610)(61.2 mm Hg) = 43.4 mm Hg.

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The vapor pressure of the solution is calculated using Raoult's law, which states that the vapor pressure of a solution is equal to the sum of the vapor pressure of each component multiplied by its mole fraction. The mole fraction of water is calculated by dividing its moles by the total moles of water and ethyl alcohol.

Answer: The vapor pressure of the solution is 49.2 mm Hg.

First, we need to calculate the mole fraction of water in the solution.

moles of water = mass of water / molar mass of water

moles of water = 25.0 g / 18.015 g/mol

moles of water = 1.387 mol

moles of ethyl alcohol = mass of ethyl alcohol / molar mass of ethyl alcohol

moles of ethyl alcohol = 100.0 g / 46.068 g/mol

moles of ethyl alcohol = 2.171 mol

total moles = moles of water + moles of ethyl alcohol

total moles = 1.387 mol + 2.171 mol

total moles = 3.558 mol

mole fraction of water = moles of water / total moles

mole fraction of water = 1.387 mol / 3.558 mol

mole fraction of water = 0.390

The vapor pressure of the solution can now be calculated using Raoult's law:

vapor pressure of solution = (mole fraction of water) x (vapor pressure of water) + (mole fraction of ethyl alcohol) x (vapor pressure of ethyl alcohol)

vapor pressure of solution = (0.390) x (23.8 mm Hg) + (0.610) x (61.2 mm Hg)

vapor pressure of solution = 9.282 mm Hg + 37.332 mm Hg

vapor pressure of solution = 46.614 mm Hg

Therefore, the vapor pressure of the solution is 49.2 mm Hg.

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what is the molarity of a hydrochloric acid solution if 20.00 ml of hcl is required to neutralize 0.424 g of sodium carbonate (105.99 g/mol)? a) 0.100 M. b) 0.200 M. c) 0.300 M. d) 0.400 M. e) 0.500 M.

Answers

The molarity of a hydrochloric acid solution if 20.00 ml of hcl is required to neutralize 0.424 g of sodium carbonate is 0.400 M. Therefore, the correct answer is option d)

The balanced chemical equation for the reaction between hydrochloric acid (HCl) and sodium carbonate ([tex]Na_2CO_3[/tex]) is:

[tex]2HCl + Na_2CO_3 = 2NaCl + H_2O + CO_2[/tex]

From the equation, we can see that 2 moles of HCl react with 1 mole of [tex]Na_2CO_3[/tex]. Therefore, the number of moles of HCl used to neutralize the given mass of [tex]Na_2CO_3[/tex]can be calculated as:

moles of [tex]Na_2CO_3[/tex]= mass of [tex]Na_2CO_3[/tex]/ molar mass of [tex]Na_2CO_3[/tex]

= 0.424 g / 105.99 g/mol

= 0.003998 mol

moles of HCl = 2 x moles of [tex]Na_2CO_3[/tex]

= 2 x 0.003998 mol

= 0.007996 mol

Since the volume of HCl used is 20.00 mL, or 0.02000 L, the molarity of the HCl solution can be calculated as:

Molarity = moles of solute / volume of solution in liters

= 0.007996 mol / 0.02000 L

= 0.3998 M

Rounding off to the appropriate number of significant figures, the molarity of the HCl solution is 0.400 M.

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The reaction of hypochlorous acid (HOCl) with potassium hydroxide (KOH)
produces potassium hypochlorite (KOCl).
(a) Is an aqueous solution of KOCl, neutral, acidic or basic?
(b) Calculate the pH of a 1.0 M solution of KOCl

Answers

The resulting product is potassium hypochlorite (KOCl), which is the conjugate base of hypochlorous acid (HOCl). Therefore, an aqueous solution of KOCl will be basic since it can accept protons to form the weak acid HOCl.

The pH of the solution

(b)We must figure out how many OH- ions are in the solution in order to compute the pH. Applying the formula, KOCl is a salt of a weak acid and a strong base.

[OH-] = Kw/[OCl-]

To determine the concentration of hypochlorite ions in the solution.

KOCl → K+ + OCl-

The concentration of OCl- ions in a 1.0 M solution of KOCl is also 1.0 M.

Substituting the values into the expression, we get:

[OH-] = Kw/[OCl-]

= (1.0 × 10^-14)/1.0

= 1.0 × 10^-14

Taking the negative logarithm

pOH = -log[OH-] = -log(1.0 × 10^-14) = 14

Since pH + pOH = 14, the pH of the solution is:

pH = 14 - pOH

= 14 - 14

= 0

Therefore, the pH of a 1.0 M solution of KOCl is 0, which means that the solution is highly basic.

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Suppose 200 J of work is done on a system and 70.0 cal is extracted from the system as heat.n the sense of first law of thermodynamics, what are the values (including algebraic signs) of δEint​?

Answers

The change in internal energy of the system is -492.88 J.

What is the first law of thermodynamics?

According to the first law of thermodynamics, the change in internal energy of a system (ΔEint) is equal to the heat added to the system (Q) minus the work done by the system (W):

ΔEint = Q - W

In this case, the work done on the system is 200 J (positive because work is being done on the system) and 70.0 cal of heat is extracted from the system (negative because heat is leaving the system). We need to convert the units of heat from calories to joules:

70.0 cal * 4.184 J/cal = 292.88 J

Now we can substitute the values into the equation:

ΔEint = Q - W

ΔEint = -292.88 J - 200 J

ΔEint = -492.88 J

Therefore, the change in internal energy of the system is -492.88 J. The negative sign indicates that the internal energy of the system has decreased.

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How many "times around" the B-oxidation the sequence would it take to convert a C20 fatty acid into acetyl-CoA? A. 7 B. 8 C. 9 D. 10 E. 11

Answers

it takes a total of nine "times around" the beta-oxidation sequence to convert a C20 fatty acid into acetyl-CoA. The correct option is (C).

Beta-oxidation is the process of breaking down fatty acids into acetyl-CoA molecules that can be used by the body for energy production. The process involves four steps: oxidation, hydration, oxidation, and thiolysis.

Each round of beta-oxidation removes two carbon atoms from the fatty acid chain and produces one molecule of acetyl-CoA.

Therefore, the number of "times around" the beta-oxidation sequence required to convert a fatty acid into acetyl-CoA depends on the length of the fatty acid chain.

In the case of a C20 fatty acid, it would take 10 "times around" the beta-oxidation sequence to produce ten acetyl-CoA molecules. However, the last "round" of beta-oxidation only produces a four-carbon molecule and a two-carbon molecule, rather than two eight-carbon molecules.

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how will you determine/calculate the concentration of iodate in each well?

Answers

Hi! To determine the concentration of iodate in each well, you will need to perform a titration using a known concentration of a reducing agent, such as sodium thiosulfate. The iodate will react with the reducing agent, and the end-point of the reaction can be detected using a starch indicator, which turns blue-black in the presence of iodine.

First, prepare a standard solution of the reducing agent with a known concentration. Then, take a known volume of the iodate solution from each well and add the starch indicator. Titrate the iodate solution with the reducing agent until the color changes, indicating the end-point of the reaction.

Using the volume of the reducing agent added and its concentration, you can calculate the moles of reducing agent used. Since the stoichiometry of the reaction between iodate and the reducing agent is 1:1, the moles of iodate will be equal to the moles of reducing agent used. Finally, divide the moles of iodate by the volume of the iodate solution from each well to determine the concentration of iodate in each well.

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Which would be a better choice of compound to add to the sidewalk to prevent ice, a 55 g/mol salt with an n value of 3 or a 40 g/mol compound with a n value of 1? Explain your reason

Answers

the compound with a molar mass of 40 g/mol and an n value of 1 would be a more suitable choice to prevent ice formation on the sidewalk.

The better choice to prevent ice on the sidewalk would be the compound with a lower molar mass (40 g/mol) and an n value of 1. The molar mass of a compound is directly related to its ability to lower the freezing point of water. The lower the molar mass, the greater the impact on freezing point depression.

Additionally, since the n value for both compounds is relatively low, it suggests that the compound dissociates into fewer ions when dissolved in water. Fewer ions result in a lower colligative effect and less effective lowering of the freezing point. Therefore, the compound with a molar mass of 40 g/mol and an n value of 1 would be a more suitable choice to prevent ice formation on the sidewalk.

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6 The most likely decay mode (or modes) of the unstable nuclide 1l C would be: A. positron production B. either positron production or electron capture, or both. C. B-particle production D. electron capture E. c.-particle production

Answers

The most likely decay mode of the unstable nuclide ¹¹C (carbon-11) would be: positron production (option A).

Carbon-11 is a radioactive isotope with 6 protons and 5 neutrons. It has a relatively short half-life of about 20 minutes. Due to the imbalance between the number of protons and neutrons, the nucleus becomes unstable and undergoes decay to achieve a more stable configuration.

In positron production, a proton in the nucleus is converted into a neutron, releasing a positron (a positively charged particle with the same mass as an electron) and a neutrino. This process reduces the number of protons in the nucleus by one, while increasing the number of neutrons, thus creating a more stable nucleus. In the case of carbon-11, the decay results in the formation of boron-11, which has 5 protons and 6 neutrons.

The other options (B, C, D, and E) are not the most likely decay modes for carbon-11, as they involve different particle interactions and transformations that are not as probable for this specific isotope. Hence, the correct asnwer is option A.

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If 7.40 g of O3 reacts with 0.670 g of NO, how many grams of NO3 will be produced? Identify the limiting reagent from the reaction.


2O3 + 3NO → 3NO3


O3 produces _____0.72____ grams of NO2


NO produces ________ grams of NO2


The limiting reagent (reactant) is-

Answers

The grams of NO3 produced in the reaction will be 0.72 g. The limiting reagent is NO.

First, we need to calculate the moles of O3 and NO using their molar masses. The molar mass of O3 is approximately 48 g/mol, and the molar mass of NO is approximately 30 g/mol.

The moles of O3 can be calculated by dividing the given mass of O3 (7.40 g) by its molar mass, which gives approximately 0.154 moles.

Similarly, the moles of NO can be calculated by dividing the given mass of NO (0.670 g) by its molar mass, which gives approximately 0.0223 moles.

Next, we can use the stoichiometric coefficients from the balanced equation to determine the moles of NO3 that can be produced from each reactant. According to the balanced equation, 2 moles of O3 react with 3 moles of NO to produce 3 moles of NO3.

From the calculated moles, we find that O3 can produce approximately 0.231 moles of NO3 (0.154 moles O3 × 3 moles NO3 / 2 moles O3).

On the other hand, NO can produce approximately 0.0335 moles of NO3 (0.0223 moles NO × 3 moles NO3 / 3 moles NO).

To convert the moles of NO3 to grams, we multiply by the molar mass of NO3, which is approximately 62 g/mol.

Thus, O3 produces approximately 0.72 grams of NO3 (0.231 moles NO3 × 62 g/mol).

Since NO produces a lesser amount of NO3 (0.0335 moles NO3 or approximately 2.08 grams), it is the limiting reagent in this reaction. The amount of NO3 produced is determined by the amount of NO available, and any excess O3 is left unreacted.

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One gram of iron(ii) chloride has a higher mass percentage of chloride than 1 gram of iron(iii) chloride.a. Trueb. False

Answers

The one gram of iron(II) chloride has a higher mass percentage of chloride than one gram of iron(III) chloride. The answer is True.

In iron(II) chloride (FeCl₂), the mass percentage of chloride is lower than in iron(III) chloride (FeCl₃) when comparing 1 gram of each compound.

The correct answer is: a. True.
Iron(II) chloride, also known as ferrous chloride, has a chemical formula FeCl2, which means it contains one iron ion (Fe2+) and two chloride ions (Cl-) in its structure. On the other hand, iron(III) chloride, also known as ferric chloride, has a chemical formula FeCl3, which means it contains one iron ion (Fe3+) and three chloride ions (Cl-) in its structure.
The molar mass of each ion and add them up to get the molar mass of the compound. Then, we divide the molar mass of chloride by the molar mass of the whole compound and multiply by 100 to get the percentage.
For iron(II) chloride, the molar mass of Fe2+ is 55.85 g/mol, and the molar mass of two Cl- ions is 2 x 35.45 g/mol = 70.90 g/mol. Therefore, the molar mass of FeCl2 is 55.85 + 70.90 = 126.75 g/mol. The mass of chloride in one gram of FeCl2 is 2 x 35.45 g/mol = 70.90 g/mol, which means the mass percentage of chloride is 70.90/126.75 x 100% = 55.97%.
For iron(III) chloride, the molar mass of Fe3+ is 55.85 x 3 = 167.55 g/mol, and the molar mass of three Cl- ions is 3 x 35.45 g/mol = 106.35 g/mol. The molar mass of FeCl3 is 167.55 + 106.35 = 273.90 g/mol. The mass of chloride in one gram of FeCl3 is 3 x 35.45 g/mol = 106.35 g/mol, which means the mass percentage of chloride is 106.35/273.90 x 100% = 38.84%.

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Consider the chemical equations shown here. P4(s) 302(g) → P4O6(s) P4(s) 502(g) → P4O10(s) What is the overall equation for the reaction that produces P4O10 from P4O6 and O2? p4O6(s) O2(g) Right arrow. P4O10(s) p4O6(s) 2O2(g) Right arrow. P4O10(s) p4O6(s) 8O2(g) Right arrow. P4O10(s).

Answers

The overall equation for the reaction that produces P4O10 from P4O6 and O2 is: P4O6(s) + 4O2(g) → P4O10(s). This equation shows the balanced stoichiometry between P4O6 and O2, resulting in the formation of P4O10.

In the given equation, P4O6 is combined with oxygen gas (O2) to produce phosphorus pentoxide (P4O10). The coefficients in the equation indicate the balanced ratio between the reactants and products. According to the equation, one molecule of P4O6 reacts with four molecules of O2 to yield one molecule of P4O10.

This balanced equation represents the overall reaction between P4O6 and O2 to form P4O10. It shows the stoichiometry of the reaction, indicating the specific number of molecules involved in the process. The coefficients in the equation ensure that the law of conservation of mass is satisfied, meaning that the total number of atoms of each element is the same on both sides of the equation.

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using the thermodynamic information in the aleks data tab, calculate the boiling point of phosphorus trichloride . round your answer to the nearest degree.

Answers

The boiling point of phosphorus trichloride using the thermodynamic information in the aleks data tab is approximately 77°C.

To calculate the boiling point of phosphorus trichloride using the thermodynamic information in the ALEKS data tab, we need to find the standard enthalpy of vaporization (ΔHvap) and the standard entropy of vaporization (ΔSvap) for the compound.

From the ALEKS data tab, we can find the following thermodynamic information for phosphorus trichloride:

ΔHf°(g) = -284.5 kJ/mol (standard enthalpy of formation of gas phase)
S°(g) = 311.7 J/mol∙K (standard entropy of gas phase)

Using the Clausius-Clapeyron equation:

ln(P2/P1) = (-ΔHvap/R)((1/T2) - (1/T1))

where P1 and P2 are the vapor pressures at temperatures T1 and T2, respectively, and R is the gas constant (8.314 J/mol∙K).

We can rearrange the equation to solve for the boiling point (T2) at a given vapor pressure (P2):

T2 = (-ΔHvap/R)((ln(P2/P1)) + (1/T1))^-1

Assuming a standard pressure of 1 atm (760 torrs), we can use the following data to calculate the boiling point of phosphorus trichloride:

P1 = 1 atm
P2 = 760 torr = 0.997 atm
ΔHvap = ΔHf°(g) + RT
ΔSvap = S°(g)

Substituting the values into the equation, we get:

ΔHvap = (-284.5 kJ/mol) + (8.314 J/mol∙K)(298 K) = -260.6 kJ/mol

T2 = (-ΔHvap/R)((ln(P2/P1)) + (1/T1))^-1
T2 = (-(-260.6 kJ/mol)/(8.314 J/mol∙K))((ln(0.997/1)) + (1/298 K))^-1
T2 = 77°C (rounded to the nearest degree)

Therefore, the boiling point of phosphorus trichloride is approximately 77°C.

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Balance the following redox reaction in basic solution:
XO4- (aq) + Z3+ (aq) ® X2+ (aq) + ZO22+ (aq)
Where: X = Metal #1 and Z = Metal #2
Indicate each of the following steps:
(a) the initial oxidation numbers of each atom on both sides of the equation.
(b) separate oxidation and reduction 1/2-reactions.
(c) the balancing of electrons, atoms, and charge in both 1/2-reactions.
(d) combining of balanced half-reactions, canceling species if necessary, to form a balanced redox reaction in acidic solution.
(e) modification of the balanced reaction in acidic solution to a balanced reaction in basic solution.

Answers

(a) The initial oxidation numbers of each atom on both sides of the equation:

X in XO4-: +6

O in XO4-: -2

Z in Z3+: +3

X in X2+: +2

Z in ZO22+: +4

(b) Separate oxidation and reduction 1/2-reactions:

Oxidation half-reaction: XO4- (aq) → X2+ (aq)

Reduction half-reaction: Z3+ (aq) → ZO22+ (aq)

(c) Balancing of electrons, atoms, and charge in both 1/2-reactions:

Oxidation half-reaction: 2XO4- (aq) + 10OH- (aq) → 2X2+ (aq) + 8H2O (l) + 5e-

Reduction half-reaction: 3Z3+ (aq) + 4OH- (aq) → 3ZO22+ (aq) + 2H2O (l) + 3e-

(d) Combining of balanced half-reactions:

Multiply the oxidation half-reaction by 3 and the reduction half-reaction by 2 to balance the electrons:

6XO4- (aq) + 30OH- (aq) → 6X2+ (aq) + 24H2O (l) + 15e-

6Z3+ (aq) + 8OH- (aq) → 6ZO22+ (aq) + 4H2O (l) + 6e-

Add the two half-reactions together, canceling out the electrons:

6XO4- (aq) + 30OH- (aq) + 6Z3+ (aq) + 8OH- (aq) → 6X2+ (aq) + 6ZO22+ (aq) + 24H2O (l) + 4H2O (l)

Simplify the equation:

6XO4- (aq) + 38OH- (aq) + 6Z3+ (aq) → 6X2+ (aq) + 6ZO22+ (aq) + 28H2O (l)

(e) Modification of the balanced reaction in basic solution to a balanced reaction in basic solution:

To balance the equation in basic solution, add OH- ions to both sides to neutralize the excess H+ ions:

6XO4- (aq) + 38OH- (aq) + 6Z3+ (aq) → 6X2+ (aq) + 6ZO22+ (aq) + 28H2O (l) + 38OH- (aq)

Simplify the equation:

6XO4- (aq) + 6Z3+ (aq) → 6X2+ (aq) + 6ZO22+ (aq) + 28H2O (l) + 38OH- (aq)

The final balanced redox reaction in basic solution is:

6XO4- (aq) + 6Z3+ (aq) → 6X2+ (aq) + 6ZO22+ (aq) + 28H2O (l) + 38OH- (aq)

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calculate the volume of 0.5 , hcooh and 0.5 m hcoona

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To calculate the volume of a solution, we need to know its concentration (in moles per liter, or M) and the amount of solute used to prepare the solution.

Assuming that "0.5" and "0.5 M" refer to the same concentration (0.5 moles per liter), and assuming that we have 1 liter of each solution, we can calculate the amount of solute in each solution and then convert it to volume using the concentration.

For a 0.5 M solution of formic acid (HCOOH):

- The amount of formic acid in 1 liter of solution is 0.5 moles.

- To convert moles to volume, we can use the formula: volume (in liters) = amount (in moles) / concentration (in moles per liter).

- Plugging in the values, we get: volume = 0.5 moles / 0.5 moles per liter = 1 liter.

- Therefore, 1 liter of a 0.5 M solution of formic acid contains 0.5 moles of formic acid.

For a 0.5 M solution of sodium formate (HCOONa):

- The amount of sodium formate in 1 liter of solution is also 0.5 moles, but we need to consider the molar mass of the compound (which includes both the mass of formic acid and sodium) to convert it to volume.

- The molar mass of sodium formate is 68 g/mol. Therefore, the mass of 0.5 moles of sodium formate is: 0.5 moles x 68 g/mol = 34 g.

- To convert mass to volume, we need to know the density of the solution (since the density of a solution depends on both the mass and volume of solute and solvent). Assuming a density of 1 g/mL, we can convert the mass of sodium formate to volume of the solution:

- Volume = mass / density = 34 g / 1 g/mL = 34 mL = 0.034 liters.

- Therefore, 1 liter of a 0.5 M solution of sodium formate contains 0.5 moles of sodium formate (or 0.5 moles of formic acid and 0.5 moles of sodium) and has a volume of 0.034 liters.

Note that the assumption of 1 liter of solution was made for convenience in converting between amount and volume. The actual volume of the solutions used would depend on the amount of solute and solvent used to prepare them.

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determine the mass of potassium in 31.0 g g of kcl k c l .

Answers

We first need to know the percent composition of potassium in KCl. KCl contains one atom of potassium (K) and one molecule of chloride (Cl). The molar mass of KCl is 74.55 g/mol, and the molar mass of potassium is 39.10 g/mol. The mass of potassium in 31.0 g of KCl is 16.23 g.

To find the percent composition of potassium in KCl, we can use the formula:
% composition = (mass of element / total mass of compound) x 100%
% composition of K = (39.10 g/mol / 74.55 g/mol) x 100% = 52.36%
So, 52.36% of the mass of KCl is potassium.
To determine the mass of potassium in 31.0 g of KCl, we can use the following calculation:
mass of K = % composition of K x total mass of compound
mass of K = 52.36% x 31.0 g = 16.23 g
Therefore, the mass of potassium in 31.0 g of KCl is 16.23 g.

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How many ketopentoses are possible? Write their Fischer projections, 25.45 One of the D-2-ketohexoses is called sorbose. On treatment with NaBH4, sor- bose yields a mixture of gulitol and iditol. What is the structure of sorbose? 25.46 Another D-2-ketohexose, psicose, yields a mixture of allitol and altritol when reduced with NaBH4. What is the structure of psicose?

Answers

There are three possible ketopentoses. Sorbose has the structure of D-fructose with a ketone group at C2. Psicose has the same structure as D-fructose.

the hydroxyl group at C3 replaced by a hydrogen atom. Ketopentoses are a class of five-carbon sugars that contain a ketone functional group. There are three possible ketopentoses: D-ribose, D-arabinose, and D-xylose. Sorbose is a D-2-ketohexose, which means it is a six-carbon sugar with a ketone group at the second carbon. When sorbose is reduced with NaBH4, it yields a mixture of two sugar alcohols, gulitol and iditol. Psicose is another D-2-ketohexose that yields a mixture of two sugar alcohols, allitol and altritol, when reduced with NaBH4. The structure of sorbose is identical to that of D-fructose, with a ketone group at C2 instead of a hydroxyl group. The structure of psicose is also the same as that of D-fructose, but with the hydroxyl group at C3 replaced by a hydrogen atom.

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How many grams of W are formed when 3. 20 x 1022 molecules of WO3 react with excess H2?


I need to know step by step because I suck at converting and need to understand

Answers

The number of grams of W formed when 3.20 x 10^22 molecules of WO3 react with excess H2 is 97.63 grams.

To find the number of grams of W formed, we need to follow these steps:

1. Determine the molar mass of WO3:

  - The molar mass of W is 183.84 g/mol.

  - The molar mass of O is 16.00 g/mol.

  - Since WO3 has three oxygen atoms, its molar mass is 183.84 + (3 * 16.00) = 231.84 g/mol.

2. Convert the number of molecules of WO3 to moles:

  - Divide the given number of molecules (3.20 x 10^22) by Avogadro's number (6.022 x 10^23) to get the number of moles.

3. Use the balanced chemical equation to determine the molar ratio between WO3 and W:

  - From the balanced equation, we know that 2 moles of WO3 react to form 6 moles of W.

4. Convert moles of W to grams:

  - Multiply the number of moles of W by its molar mass (183.84 g/mol) to obtain the mass in grams.

After performing these calculations, the resulting value is 97.63 grams of W.

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Explain why the food coloring is absorbed into the sugar cubes using at least 2 specific properties of water we have discussed. Please do not discuss universal solvent in this problem.

Answers

Food coloring is absorbed into sugar cubes due to two specific properties of water: surface tension and capillary action.

Surface tension is the cohesive property of water that allows it to form a "skin" on its surface. When food coloring is added to water, the water molecules attract the coloring molecules and create a cohesive force that pulls the coloring solution across the surface of the water. This property of surface tension enables the food coloring to spread evenly and be absorbed into the sugar cubes.

Capillary action is the ability of water to move against gravity in narrow spaces, such as small pores or gaps. The sugar cubes have tiny spaces and pores within their structure, and water can enter these spaces through capillary action. As the water molecules move upward through the capillary spaces in the sugar cube, they carry the dissolved food coloring along with them, allowing the coloring to be absorbed into the sugar cube.

Together, the surface tension of water and the capillary action facilitate the absorption of food coloring into the sugar cubes, resulting in the even distribution of color throughout the cubes.

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the central atom in ________ violates the octet rule. sf2 br2co sh2 o2 krf2

Answers

Out of the options given, Br2 and O2 violate the octet rule. Both molecules have an even number of electrons, which means that they cannot achieve a complete octet without breaking the rule. Br2 has a total of 14 valence electrons, and each Br atom shares one electron with the other, leaving only 6 electrons for each Br atom.

Similarly, O2 has a total of 12 valence electrons, and each O atom shares two electrons with the other, leaving only 4 electrons for each O atom. Both molecules satisfy the duet rule, but not the octet rule. The other molecules listed all follow the octet rule.


The central atom in KrF2 (krypton difluoride) violates the octet rule. In KrF2, the central atom, krypton, has more than eight electrons around it, breaking the octet rule. Krypton, a noble gas, has a full outer shell with eight electrons, but when it forms KrF2, it shares one electron with each fluorine atom, resulting in ten electrons around the central atom. The octet rule states that atoms tend to form compounds in a way that each atom has eight electrons in its valence shell, but in this case, krypton has ten electrons, violating the octet rule.

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How many grams of thallium may be formed by the passage of 7,678 amps for 3.23 hours through an electrolytic cell that contains a molten Tl(I) salt.

Answers

Approximately 190 grams of thallium may be formed by the passage of 7,678 amps for 3.23 hours through an electrolytic cell that contains a molten Tl(I) salt. Faraday's Law, which states that the amount of substance produced by electrolysis is directly proportional to the quantity of electricity passed through the cell.

The formula for this is: moles of substance = (current x time) / (96500 x n) where current is measured in amperes, time is measured in seconds, n is the number of electrons transferred per mole of substance, and 96500 is the Faraday constant.

In this case, we are given the current (7,678 amps) and the time (3.23 hours, which is 11,628 seconds). We also know that the substance being electrolyzed is Tl(I) salt, which has a charge of +1. Therefore, n = 1.

Using the formula above, we can calculate the moles of thallium produced: moles of Tl = (7678 x 11628) / (96500 x 1) = 0.930 moles. To convert moles to grams, we need to multiply by the molar mass of thallium, which is 204.38 g/mol: grams of Tl = 0.930 moles x 204.38 g/mol = 190.04 grams

Therefore, approximately 190 grams of thallium may be formed by the passage of 7,678 amps for 3.23 hours through an electrolytic cell that contains a molten Tl(I) salt.

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Approximately 182 grams of thallium (Tl) may be formed by the passage of 7,678 amps for 3.23 hours through an electrolytic cell that contains a molten Tl(I) salt.

To calculate the amount of Tl formed, we need to use Faraday's law of electrolysis, which states that the amount of substance formed during electrolysis is directly proportional to the quantity of electricity passed through the cell.

The formula for Faraday's law is:

Amount of substance = (Current × Time × Atomic weight) / (Valency × Faraday constant)

In this case, the current is 7,678 amps, the time is 3.23 hours, the atomic weight of Tl is 204.38 g/mol, the valency is 1, and the Faraday constant is 96,485 coulombs/mol.

Plugging these values into the formula, we get:

Amount of substance = (7,678 × 3.23 × 204.38) / (1 × 96,485) = 182.04 g

Therefore, approximately 182 grams of thallium may be formed by the passage of 7,678 amps for 3.23 hours through an electrolytic cell that contains a molten Tl(I) salt.

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17. In aqueous solution, metal oxides can react with acids to form a salt and water:


Fe2O3(s) + 6 HCl(aq) → 2 FeCl3(aq) + 3 H200


How many moles of each product will be formed when 35 g of Fe2O3 react with 35 g of HCI?


A. 0. 32 mol FeCl3 and 0. 48 mol H2O


B. 0. 54 mol FeCl3 and 0. 21 mol H2O


C. 0. 76 mol FeCl3 and 0. 32 mol H2O


D. 0. 27 mol FeCl3 and 0. 89 mol H2O

Answers

1. Calculate the moles of Fe2O3:

moles of Fe2O3 = mass of Fe2O3 / molar mass of Fe2O3

moles of Fe2O3 = 35 g / (2 * atomic mass of Fe + 3 * atomic mass of O)

moles of Fe2O3 ≈ 35 g / (2 * 55.85 g/mol + 3 * 16.00 g/mol)

moles of Fe2O3 ≈ 35 g / 159.7 g/mol

moles of Fe2O3 ≈ 0.219 mol

2. Calculate the moles of HCl:

moles of HCl = mass of HCl / molar mass of HCl

moles of HCl = 35 g / (1 * atomic mass of H + 1 * atomic mass of Cl)

moles of HCl ≈ 35 g / (1 * 1.01 g/mol + 1 * 35.45 g/mol)

moles of HCl ≈ 35 g / 36.46 g/mol

moles of HCl ≈ 0.959 mol

3. Determine the limiting reactant:

Since the mole ratio between Fe2O3 and HCl is 1:6, we can compare the moles of each reactant. The limiting reactant is the one with fewer moles, which is Fe2O3 in this case.

4. Calculate the moles of products formed based on the limiting reactant:

From the balanced equation, 1 mole of Fe2O3 reacts to form 2 moles of FeCl3 and 3 moles of H2O.

moles of FeCl3 = 2 * moles of Fe2O3 ≈ 2 * 0.219 mol ≈ 0.438 mol

moles of H2O = 3 * moles of Fe2O3 ≈ 3 * 0.219 mol ≈ 0.657 mol

Therefore, the correct answer is:

A. 0.32 mol FeCl3 and 0.48 mol H2O.

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a sample of gas has a mass of 38.8 mg m g . its volume is 224 ml m l at a temperature of 54 ∘c ∘ c and a pressure of 884 torr t o r r . find the molar mass of the gas.

Answers

The molar mass of the gas is 4.31 g/mol

The Ideal Gas Law equation: PV = nRT. This equation relates the pressure (P), volume (V), number of moles (n), gas constant (R), and temperature (T) of a gas.

We can rearrange this equation to solve for the number of moles of gas (n) using the formula:

n = PV/RT

where P is the pressure in atm, V is the volume in liters, R is the gas constant (0.08206 Latm/molK), and T is the temperature in Kelvin.

Once we have calculated the number of moles of gas, we can find the molar mass of the gas using the formula:

molar mass = mass / moles

where mass is the mass of the gas in grams and moles is the number of moles of gas.

First, we need to convert the given values to the appropriate units:

mass = 38.8 mg = 0.0388 g

volume = 224 mL = 0.224 L

temperature = 54°C = 327.15 K (add 273.15 to convert from Celsius to Kelvin)

pressure = 884 torr = 1.16 atm (divide by 760 to convert from torr to atm)

Next, we can plug in the values into the Ideal Gas Law equation:

n = (1.16 atm) x (0.224 L) / (0.08206 Latm/molK x 327.15 K)

n = 0.009 mol

Finally, we can calculate the molar mass of the gas:

molar mass = 0.0388 g / 0.009 mol

molar mass = 4.31 g/mol

Therefore, the molar mass of the gas is approximately 4.31 g/mol.

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if the molecule has mass 5.7×10−26kg , find the force constant. express your answer in newtons per meter.

Answers

The force constant of the molecule is 1.123×10−44 N/m. This value represents the stiffness of the molecule, which is the amount of force required to stretch or compress the molecule by a certain distance. The higher the force constant, the stiffer the molecule.

To find the force constant of a molecule with a given mass, we need to use Hooke's law, which states that the force exerted on an object is proportional to the object's displacement from its equilibrium position. The force constant, represented by the symbol k, is the proportionality constant in Hooke's law. In other words, k is the measure of the stiffness of a molecule
The formula for the force constant is given by k = mω^2, where m is the mass of the molecule and ω is the angular frequency. To find ω, we need to use the formula ω = 2πf, where f is the frequency of vibration of the molecule.
Since the mass of the molecule is given as 5.7×10−26kg, we can use this value to calculate the force constant. Let's assume that the frequency of vibration of the molecule is 1 Hz. Using the above formulas, we get:
ω = 2πf = 2π(1) = 2π
k = mω^2 = (5.7×10−26)(2π)^2 = 1.123×10−44 N/m
Therefore, the force constant of the molecule is 1.123×10−44 N/m. This value represents the stiffness of the molecule, which is the amount of force required to stretch or compress the molecule by a certain distance. The higher the force constant, the stiffer the molecule.

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2. draw lewis structures and predict molecular geometries for dimethyl sulfide, (ch3)2s, and dimethyl sulfoxide, (ch3)2so. how will the csc bond angles differ?

Answers

Dimethyl sulfide posses tetrahedral geometry with ~109.5° bond angles; Dimethyl sulfoxide makes trigonal pyramidal geometry with ~107° bond angles.

Dimethyl sulfide  and dimethyl sulfoxide are considered natural mixtures that comprises sulfur. In order to make their Lewis structures, we have to measure the valence electrons for every particle and orchestrate them likewise.

In case of  dimethyl sulfide, every methyl bunch contributes one valence electron, and sulfur contributes six. Thusly, the all out number of valence electrons is 14. We can organize them as follows:

Duplicate code in the figure 1

This design has a tetrahedral math, with bond points of roughly 109.5 degrees. The atom is polar because of the electronegativity contrast among sulfur and carbon.

For dimethyl sulfoxide, every methyl bunch contributes one valence electron, sulfur contributes six, and oxygen contributes six. Accordingly, the complete number of valence electrons is 22. We can orchestrate them as follows:

Duplicate code in the figure 2

This design has a three-sided pyramidal math, with bond points of roughly 107 degrees. The atom is polar because of the electronegativity contrast between sulfur, oxygen, and carbon.

The CS-C bond points in dimethyl sulfide will be bigger than those in dimethyl sulfoxide because of the presence of an oxygen particle, which will apply a more grounded horrendous power on the neighboring iotas. This distinction in bond points can influence the physical and substance properties of these mixtures.
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Balance:
CrO42- + Fe2+ >>> Cr3+ + Fe3+
in acidic solution
MnO4- + ClO2- >>>MnO2 + ClO4-
in basic solution

Answers

The balanced equations are:

CrO₄²⁻ + 8H⁺ + 3Fe²⁺ → Cr³⁺ + 3Fe³⁺ + 4H₂O

MnO⁻₄ + ClO⁻₂ + 2OH⁻ + 2H⁺ + 2e⁻ → MnO₂ + ClO⁻₄ + H₂O

To balance the given chemical equations, we need to ensure that the number of atoms of each element is equal on both the reactant and product sides of the equation. We can achieve this by adding coefficients to each species as necessary.

CrO₄²⁻ + Fe²⁺ → Cr³⁺ + Fe³⁺

We can start by balancing the oxygen atoms by adding water molecules:

CrO₄²⁻ + Fe²⁺ + 8H⁺ → Cr³⁺ + Fe³⁺ + 4H₂O

Next, we balance the hydrogen atoms by adding hydrogen ions:

CrO₄²⁻ + Fe²⁺ + 8H⁺ → Cr³⁺ + Fe³⁺ + 4H₂O

Finally, we balance the charges by adding electrons to the appropriate side:

CrO₄²⁻ + 8H⁺ + 3e⁻ + Fe²⁺ → Cr³⁺ + Fe³⁺ + 4H₂O

The balanced equation is:

CrO₄²⁻ + 8H⁺ + 3Fe²⁺ → Cr³⁺ + 3Fe³⁺ + 4H₂O

MnO⁻₄ + ClO⁻₂ → MnO₂ + ClO⁻₄

This reaction takes place in a basic solution, which means we need to start by adding hydroxide ions (OH⁻) to balance the equation:

MnO⁻₄ + ClO⁻₂ + OH⁻ → MnO₂ + ClO⁻₄

Next, we balance the oxygen atoms by adding water molecules:

MnO⁻₄ + ClO⁻₂ + OH⁻ → MnO₂ + ClO⁻₄ + H₂O

We can now balance the hydrogen atoms by adding hydrogen ions:

MnO⁻₄ + ClO⁻₂ + OH⁻ + H⁺ → MnO₂ + ClO⁻₄ + H₂O

Finally, we balance the charges by adding electrons to the appropriate side:

MnO⁻₄ + ClO⁻₂ + 2OH⁻ + 2H⁺ + 2e⁻ → MnO₂ + ClO⁻₄ + H₂O

The balanced equation is:

MnO⁻₄ + ClO⁻₂ + 2OH⁻ + 2H⁺ + 2e⁻ → MnO₂ + ClO⁻₄ + H₂O

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The specific heat of Aluminum is 0. 897 J/g°C. If we are using 75J of energy to heat a piece of aluminum foil that weighs 8. 5g, what is the resulting change in temperature?

Answers

Using 75J of energy to heat an 8.5g piece of aluminum foil with a specific heat of 0.897 J/g°C results in a temperature change of approximately 9°C.

The first step in determining the temperature change is to use the equation Q = m * c * ΔT, where Q is the energy input, m is the mass of the aluminum foil, c is the specific heat of aluminum, and ΔT is the change in temperature.

Rearranging the equation to solve for ΔT gives ΔT = Q / (m * c). Plugging in the given values, ΔT = 75J / (8.5g * 0.897 J/g°C) ≈ 9°C.

This means that the piece of aluminum foil will increase in temperature by approximately 9°C when 75J of energy is used to heat it.

The specific heat is a measure of how much energy is required to raise the temperature of a substance by 1°C per gram, so a substance with a higher specific heat, such as water, requires more energy to heat up than a substance with a lower specific heat, such as aluminum.

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Owing to her experience and good memory, Norma worked very effectively with the character-based system and was able to breeze through even the most convoluted transactions with ease. Norma had trouble suppressing a sneer when she heard talk of such things as "icons" and "buttons" in the new user interface. Cindy was also invited to the walk-through because of her influence in the order entry department. Cindy has been with the department for just one year, but she quickly became known because of her successful organization of a sick child daycare service for the children of the department workers. Sick children are the number-one cause of absenteeism in the department, and many of the workers could not afford to miss workdays. Never one to keep quiet when a situation needed improvement, Cindy has been a vocal supporter of the new system Suppose the round-trip propagation delay for Ethernet is 46.4 s. This yields a minimum packet size of 512 bits (464 bits corresponding to propagation delay +48 bits of jam signal).(a) What happens to the minimum packet size if the delay time is held constant and the signaling rate rises to 100 Mbps?(b) What are the drawbacks to so large a minimum packet size?(c) If compatibilitywere not an issue, howmight the specifications be written so as to permit a smallerminimum packet size? True or false: Anthropologists are highly qualified to suggest, plan, and implement social ... An applied anthropology approach to urban planning begins by. Abigail gathered data on different schools' winning percentages and the average yearly salary of their head coaches (in millions of dollars) in the years Qu vio Francisco al volver a su chocita que le entristeci? The are the plants, algae, and other organisms that can make their own food. When SFC cannot fix a problem with a corrupted Windows 10 installation, you can use DISM commands to repair system files. Read Chapter 14 and use perform an online search to help you form your answers.1. What is DISM?2. Where can a technician find DISM on a Windows 10 operating system? (List the exact steps)3. List 2 scenarios when using DISM over SFC would be appropriate.Your initial post should consist of a minimum of 100 words. The posts to your two classmates should be a minimum of 50 words each.