Identify the most and the least acidic compound in each of the following sets.
a. 2-chlorobutanoic acid:_______ 4-chlorobutanoic acid:_______ 3-chlorobutanoic acid:______.
b. 2,4-dinitrobenzoic acid:______ p-nitrobenzoic acid:______ p-bromobenzoic acid:_______.
c. p-cyanobenzoic acid:________ benzoic acid:_______ p-aminobenzoic acid:______.

Answer:

The effective nuclear charge in a cesium atom is greatest in the 1s orbital

Explanation:

Effective nuclear charge (Zeff) is the positive nuclear charge that is experienced by an electron in an atom. It is affected by the shielding effect and penetration of electrons of the atoms.

The shielding effect is the decrease in attraction between an electron and the nucleus in any atom with more than one electron shell. Innermost electrons shield the outermost electrons from the positive charge of the nucleus. The more electron shells there are, the greater the shielding effect experienced by the outermost electrons. and the more electron shielding an electron has, the lower the Zeff value.

Penetration is the ability of an electron to approach the nucleus. The closer the electron is to the nucleus, the higher the penetration. Electrons with higher penetration will shield outer electrons from the nucleus more effectively. The s orbital being closest to the nucleus has the highest penetration while the f orbital has the lowest penetration.

Cesium has an atomic number of 55 as well as nuclear charge of +55. It has 54 electrons in its filled 1s²2s²2p⁶3s²3p⁶4s²3d¹⁰4p⁶5s²4d¹⁰5p⁶6s¹ shells and an outermost 6s electron. Based on the explanation above, the effective nuclear charge is greatest in the innermost 1s orbital and least in the outermost 6s orbital.

The electron in a cesium atom experience should be considered as the 1st orbital.

It is considered to be the positive nuclear charge i.e. experienced via the electron in an atom. It should be impacted via the effect of shielding and the penetration of the electron with respect to the atoms.

The electronic configuration of cesium should be like

[tex]1s^2 2s^2 2p^6 3s^2 3p^6 3d^10 4s^2 4p^6 4d^10 5s^2 5p^6 6s^1[/tex]

Now

the electron which is in the innermost subshell will experience the highest effective nuclear charge and it should be 1s.

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Answer:

C7H5F3

Explanation:

The following data were obtained from the question:

Mass of Carbon (C) = 57.53g

Mass of Hydrogen (H) = 3.45g

Mass of Fluorine (F) = 39.01g

The empirical formula of the compound can be obtained as follow:

C = 57.53g

H = 3.45g

F= 39.01g

Divide each by their molar mass

C = 57.53/12 = 4.79

H = 3.45/1 = 3.45

F = 39.01/19 = 2.05

Divide each by the smallest

C = 4.79/2.05 = 2.3

H = 3.45/2.05 = 1.7

F = 2.05/2.05 = 1

Multiply through by 3 to express in whole number

C = 2.3 x 3 = 7

H = 1.7 x 3 = 5

F = 1 x 3 = 3

Therefore, the empirical formula for the compound is C7H5F3

Answer:

BF3

Explanation:

Hybridization can be defined as the mixing of two or more atomic pure orbitals. ( s, p ,  and d) to produce two or more hybrid atomic orbitals that are similar and identical in shape and energy e.g sp,sp²,sp³ ,sp³d, sp³d². Usually , the central atom of a covalent molecules or ion undergoes hybridization.

in BF3; Boron is the central atom. Here, A 2s  electron is excited from the ground state of boron ( 1s²2s²2p¹) to one empty orbitals of 2p.

The 2s orbital is then mixed with two orbitals of 2p to form three sp² hybrid orbitals tat are trigonally arranged in the plane in order to minimize repulsion . Each of the three hybrid orbitals overlaps with p-orbital of fluorine atom to form three bonds of equal strength and with bond angles of 120⁰.

                                  Energy                                                                  

B     ⇵  ║   ⇅  ║    ↑     ----------->    *B    ⇵ ║     ↑  ║     ↑  ║   ↑

       1s      2s         2p                              1s       2s           2p  

    Ground state                                        Excited State

The above shows an illustrative example of how electrons  move from the ground state to the excited state.

The question is incomplete, the solute was not given.

Let the solute be K₂CrO₄ and the solvent be water

Complete Question should be like this:

The density of a 0.438 M solution of potassium chromate (K₂CrO₄) at 298 K is 1.063 g/mL.

Calculate the vapor pressure of water above the solution. The vapor pressure of pure water at this temperature is 0.0313 atm. Assume complete dissociation.  

Pvap = ________atm

Answer:

Pvap (of water above the solution) = 0.0306 atm

Dissolution of the solute

K₂CrO₄ => 2K⁺ + Cr₂O₄²⁻

Explanation:

Given

volume of solution = 1 Litre = 1000 mL of the solution

density of the solution = 1.063 g/mL

concentration of the solution= 0.438M

temperature of the solution= 298 K

vapour pressure of pure water = 0.0313atm

Recall: density = mass/volume

∴mass of solution = volume x density

m = 1000 x 1.063 = 1063 g

To calculate the moles of K₂CrO₄ = volume x concentration

= 1 x 0.438 = 0.438 mol

Mass of K₂CrO₄ = moles x molar mass = 0.438 x 194.19 = 85.055 g

Mass of water = mass  of solution - mass of K₂CrO₄

= 1063 - 85.055 = 977.945 g

moles of water = mass/molar mass

∴ moles of water = 977.945/18.02 = 54.27 mol

 Dissolution of the solute

K₂CrO₄ => 2K⁺ + Cr₂O₄²⁻

(dissolution is the process by which solute(K₂CrO₄) is passed into solvent(H₂O) to form a solution

moles of ions = 3 x moles of K₂CrO₄

= 3 x 0.438 = 1.314 mol

Vapor pressure of solution = mole fraction of water x vapor pressure of water  

= 54.27/(54.27 + 1.314) x 0.0313 = 0.0306 atm

Answer:

Gaseous

Explanation:

Gasses can move freely and do not form the shape of their containers

Liquids are more free than solids, but they conform to the shape of their container

Solids are not free

Answer:

[tex]t=2.08s[/tex]

Explanation:

Hello,

In this case, for first order reactions, we can use the following integrated rate law:

[tex]ln(\frac{[A]}{[A]_0} )=kt[/tex]

Thus, we compute the time as shown below:

[tex]t=-\frac{ln(\frac{[A]}{[A]_0} )}{k}=- \frac{ln(\frac{0.220M}{0.690M} )}{0.55s^{-1}} \\\\t=-\frac{-1.14}{0.550s^{-1}}\\ \\t=2.08s[/tex]

Best regards.

Answer:

The mass of PbCl₂ is 45.88 grams and the mass of AgCl is 16.48 grams.

Explanation:

As mentioned in the given question, the addition of 0.275 L of 1.62 M KCl is done in a solution that comprise Ag⁺ and Pb²⁺ ions so that all the ions get precipitated. Therefore, the moles of KCl present is,  

Moles of KCl = 0.275 L × 1.62 M = 0.445 moles

Now the reaction will be,  

Ag⁺ + Pb²⁺ + KCl ⇒ AgCl + PbCl₂ + 3K⁺

Now let us assume that the formation of x moles of AgCl and y moles of PbCl₂ is taking place.  

Therefore, mass of AgCl will be x × molecular mass, which will be equal to x × 143.32 grams = 143.32 x grams

Now the mass of PbCl2 formed will be,  

y × molecular mass = y × 278.1 grams = 278.1 y grams

Now the total precipitate will be,  

62.37 grams = 143.32 x + 278.1 y -----------(i)

Now as AgCl and PbCl₂ requires 1:2 ratio of KCl, this shows that x moles of AgCl will require x moles of KCl and y mol of PbCl₂ will require 2*y moles of PbCl₂. Therefore,  

x + 2y = total mass of KCl

x + 2y = 0.445 moles ------ (ii)

On solving equation (i) and (ii) we get,  

x as 0.115 and y as 0.165

Now the mass of AgCl will be,  

143.32 × 0.115 = 16.48 grams

The mass of PbCl₂ will be,  

278.1 × 0.165 = 45.88 grams.  

Answer:

Answer:

3.7136g/cm³

Explanation:

Density is defined as the ratio between mass of a substance and its volume.

First, we will find the mass of the piece of the metal that is the difference between mass of metal + flask and mass of empty flask. That is:

Mass metal:

143.557g - 44.232g = 99.325g of the metal

Now, to find its volume you must know first the volume of the flask that can be obtained from the mass of water in the filled flask, that is:

153.617g - 44.232g = 109.385g of water = cm³ of water

In the second experiment, the mass of water = its volume is:

226.196g - 143.557g = 82.639g = 82.639cm³ of water

That means the volume the piece of metal is occupying is:

109.385cm³ - 82.639cm³ = 26.746cm³ of piece of metal

And its density is:

99.325g / 26.746cm³ =

Answer:

0.49 mol

Explanation:

Step 1: Write the balanced equation

Mg + 2 HCI ⇒ MgCl₂ + H₂

Step 2: Calculate the moles corresponding to 12 g of Mg

The molar mass of Mg is 24.31 g/mol.

[tex]12g \times \frac{1mol}{24.31g} = 0.49mol[/tex]

Step 3: Calculate the moles of H₂ produced by 0.49 moles of Mg

The molar ratio of Mg to H₂ is 1:1. The moles of H₂ produced are 1/1 × 0.49 mol = 0.49 mol.

Answer:

Mg, Sc, Ca

Explanation:

To figure out increasing atomic radii, we use Periodic Trends applied to the Elements of the Periodic Table to help us out. We know that the trend for atomic radii is increasing left and down. Since Ca is the furthest down and left of the 3, it has the largest atomic radius. Since Sc is next element to Ca, it would be the 2nd largest atomic radius of the 3. Since Mg is above Ca, it has the smallest atomic radius of the 3.

Answer:

B.) 2x

Explanation:

Hello,

In this case, we can apply the following rule of three, knowing that 0.1 dm³ equals x and 0.2 dm³ is the unknown:

[tex]0.1dm^3\longrightarrow x\\0.2dm^3 \longrightarrow ?[/tex]

Thus, solving for the unknown we find:

[tex]?=\frac{0.2dm^3*x}{0.1dm^3} \\\\?=2*x[/tex]

Therefore, the answer is B.) 2x.

Best regards.

Answer:

Joseph Henry.

Explanation:

Hello,

In this case, we define the accuracy based on the degree of deviation a measure has regarding the the true or expected value. In this case, the lower the difference, the more accurate the procedure. In such a way, for the two students, we compute the difference between the expected value and the obtained value:

[tex]Mary=2.300g/mL-2.226g/mL=0.074g/mL[/tex][tex]Joseph=2.335g/mL-2.300mL=0.035g/mL[/tex]

In such a way, since the difference is lower in Joseph's measure, we can say he is the most accurate.

Best regards.

Answer:

The ratio of the mass of an adult rhino to the mass of a small egret is

(1400 kg)/(0.76 kg) = 1842.11

The ratio of the mass of a proton to the mass of an electron is

1836.15

The two ratios are very similar, the ratio of the masses of the proton to the electron being slightly smaller.

Answer:

1661μL of a 6M HCl you need to add

Explanation:

pH is defined as -log[H⁺] ([H⁺] =10^{-pH}), the initial and final concentrations of [H⁺] you need are:

Initial [H⁺] = 10^{-3.5} = 3.16x10⁻⁴M H⁺

Final [H⁺] = 10^{-1} = 0.1M H⁺

In moles, knowing volume of the solution is 0.1L:

Initial [H⁺] = 0.1L ₓ (3.16x10⁻⁴mol H⁺ / L) = 3.16x10⁻⁵moles H⁺

Final [H⁺] = 0.1L ₓ (0.1mol H⁺ / L) = 0.01 moles H⁺.

That means, moles of H⁺ you need to add to the solution is:

0.01mol - 3.16x10⁻⁵moles = 9.9684x10⁻³ moles of H⁺.

A solution of HCl dissociates in H⁺ and Cl⁻ ions, that means moles of HCl added are equal to moles of H⁺. As you need to add 9.9684x10⁻³ moles of H⁺ = 9.9684x10⁻³ moles of HCl:

9.9684x10⁻³ moles of HCl ₓ (1L / 6mol) = 1.6614x10⁻³L

In μL:

1.661x10⁻³L × (1x10⁶μL / 1L) =

Answer:

296.1g of Ag is the maximum amount of silver

Explanation:

A solution of 6.3% Ag by mass contains 6.3g of Ag per 100g of solution. Thus, you need to calculate the mass of the solution and then, the mass of Ag present in solution, thus:

Mass of solution:

Assuming a density of 1g/mL:

[tex]4.7L \frac{1000mL}{1L} \frac{1g}{mL} = 4700g[/tex]

If the solution contains 6.3g of Ag per 100g of solution, the mass of Ag in 4700L is:

4700L × (6.3g Ag / 100g) =

Answer:

HPO₄⁻² predominates at pH 9.3

Explanation:

These are the equilibriums of the phosphoric acid, a tryprotic acid where 3 protons (H⁺) are realesed.

H₃PO₄ + H₂O   ⇄   H₂PO₄⁻   +   H₃O⁺   pKa 2.14

H₂PO₄⁻  +  H₂O   ⇄   HPO₄⁻²  +  H₃O⁺  pKa 6.86

HPO₄⁻²  +  H₂O   ⇄   PO₄⁻³   +   H₃O⁺  pKa 12.38

The H₂PO₄⁻  works as amphoterous, it can be a base and acid, according to these equilibriums.

H₂PO₄⁻ +  H₂O   ⇄   HPO₄⁻²  +  H₃O⁺

H₂PO₄⁻ +  H₂O   ⇄   H₃PO₄  +  OH⁻

pH 9.3 is located between 6.86 and 12.38 where we have this buffer system HPO₄⁻² / PO₄⁻³, where the HPO₄⁻² is another amphoterous:

HPO₄⁻ +  H₂O   ⇄   H₂PO₄⁻  +  OH⁻

HPO₄⁻²  +  H₂O   ⇄   PO₄⁻³   +   H₃O⁺

The media from the two pKa, indicates the pH where the protonated form is in the same quantity as the unpronated form, so:

(6.86 + 12.38) /2 =  9.62

Above this pH, [PO₄⁻³] > [HPO₄⁻²].

In conclussion, at pH 9.3, [HPO₄⁻²] > [PO₄⁻³]

Answer:

[tex]m_{Fe}=23.0gFe[/tex]

Explanation:

Hello,

In this case, the undergoing chemical reaction is:

[tex]FeO+Mg\rightarrow Fe+MgO[/tex]

Thus, for the given masses of reactants we should compute the limiting reactant for which we first compute the available moles of iron (II) oxide:

[tex]n_{FeO}=40.0gFeO*\frac{1molFeO}{72gFeO} =0.556molFeO[/tex]

Next, we compute the consumed moles of iron (II) oxide by the 10.0 g of magnesium, considering their 1:1 molar ratio in the chemical reaction:

[tex]n_{FeO}^{consumed}=10.0Mg*\frac{1molMg}{24.3gMg}*\frac{1molFeO}{1molMg}=0.412molFeO[/tex]

Therefore, we can notice there is less consumed iron (II) oxide than available for which it is in excess whereas magnesium is the limiting reactant. In such a way, the produced mass of iron turns out:

[tex]m_{Fe}=0.412molFeO*\frac{1molFe}{1molFeO}*\frac{56gFe}{1molFe}\\ \\m_{Fe}=23.0gFe[/tex]

Regards.

Answer:

Manganese (II) ion, Mn²⁺

Explanation:

Hello,

In this case, given the overall reaction:

[tex]2Ce^{4+}(aq) + Tl^+(aq) + Mn^{2+}(aq) \rightarrow 2Ce^{3+}(aq) + Tl^{3+}(aq) + Mn^{2+}(aq)[/tex]

Thus, since manganese (II) ion, Mn²⁺ is both at the reactant and products, we infer it is catalyst, since catalysts are firstly consumed but finally regenerated once the reaction has gone to completion. Moreover, since inner steps are needed to obtain it, we can infer that the given rate law corresponds to the slowest step that is related with the initial collisions between Ce⁴⁺ and Mn²⁺

Best regards.

Answer:

- N2 does not exist as a liquid at pressures below 0.127 atm.

- N2 is a solid at 16.7 atm and 56.5 K.

- N2 is a liquid at 1.00 atm and 73.9 K

- N2 is a gas at 0.127 atm and 84.0 K.

Explanation:

Hello,

At first, we organize the information:

- Normal melting point: 63.2 K.

- Normal boiling point: 77.4 K.

- Triple point: 0.127 atm and 63.1 K.

- Critical point: 33.5 atm and 126.0 K.

In such a way:

- N2 does not exist as a liquid at pressures below 0.127 atm: that is because below this point, solid N2 exists only (triple point).

- N2 is a solid at 16.7 atm and 56.5 K: that is because it is above the triple point, below the critical point and below the normal melting point.

- N2 is a liquid at 1.00 atm and 73.9 K: that is because it is above the triple point, below the critical point and below the normal boiling point.

- N2 is a gas at 0.127 atm and 84.0 K: that is because it is above the triple point temperature at the triple point pressure.

Best regards.

Answer:

  C  The experiment shows that the red substance experienced a chemical change.

Explanation:

Apparently, adding heat caused the red substance to decompose into a gas and a metallic liquid. If it were simply a phase change, the original red substance could be expected to return when the temperature cooled. Because the substance apparently decomposed, it is clearly not an element. At no point in the experiment is there any evidence of a plasma being formed.

The observed decomposition is a chemical change.

Answer:

2.29x10⁻¹² is Ksp of the salt

Explanation:

The Ksp of the metal hydroxide is:

M(OH)₂(s) ⇄ M²⁺ + 2OH⁻

Ksp = [M²⁺] [OH⁻]²

As you can see in the reaction, 2 moles of OH⁻ are produced per mole of M²⁺. It is possible to find [OH⁻] with pH, thus:

pOH = 14- pH

pOH = 14 - 10.22

pOH = 3.78

pOH = -log[OH⁻]

1.66x10⁻⁴ = [OH⁻]

And [M²⁺] is the half of [OH⁻], [M²⁺] = 8.30x10⁻⁵

Replacing in Ksp formula:

Ksp = [8.30x10⁻⁵] [1.66x10⁻⁴]²

Ksp = 2.29x10⁻¹² is Ksp of the salt

Answer:

Ecell = +0.25V

Explanation:

the half-cell reactions for a voltanic cell

cathode(reduction): 2H⁺(aq) + 2e⁻ ------- H₂(g)

anode(oxidation): 2AgCl(s) ------- 2Ag⁺(aq) + 2Cl⁻ + 2e⁻

we have the standard cell potential E⁺cell = 0.18V at 80C respectively

Q = [H⁺]/[Cl⁻]

sub for [H+] = 0.10M and [Cl-] = 1.5M

Q= 0.1M/1.5M

Q = 0.067

Ecell = E⁺cell - [tex]\frac{0.059}{n}[/tex] logQ

= 0.18 - [tex]\frac{0.056}{1}[/tex] log 0.067

0.18- 0.059(-1.174)

Ecell = +0.25V

Answer:

The gas evolved because of reaction of acid with metal carbonate or metal hydrogen carbonate turns lime water milky. This shows that the gas is carbon dioxide gas. This happens because of formation of white precipitate of calcium carbonate.

Hope it helps you!

The milky substance formed is CO₂ gas.

The gas evolved because of reaction of acid with metal carbonate or metal hydrogen carbonate turns lime water milky. This shows that the gas is carbon dioxide gas.

This happens because of formation of white precipitate of calcium carbonate.

Lime water turns milky when the gas liberated from an acidified carbonate solution is passed into it.

The liberated CO₂ reacts with lime water to give calcium bicarbonate as the precipitate.

Hence, the milky substance formed is CO₂ gas.

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Answer:

Explanation:

0,44

Answer:

[tex]C_2=0.97M[/tex]

Explanation:

Hello,

In this case, for dilution process, we can notice that the initial moles remain the same once the dilution is completed, therefore, both concentration and volume change considering:

[tex]n_1=n_2\\\\V_1C_1=V_2C_2[/tex]

In such a way for the given final volume, the resulting concentration is noticed to be:

[tex]C_2=\frac{V_1C_1}{V_2} =\frac{10mL*2.5M}{25.8mL}\\ \\C_2=0.97M[/tex]

This is supported by the fact that the higher the volume the lower the concentration.

Best regards.

Answer:

1.41 M

Explanation:

First we must use the information provided to determine the concentration of the aluminum hydroxide.

Mass of aluminum hydroxide= 320mg = 0.32 g

Molar mass of aluminum hydroxide= 78 g/mol

Volume of the solution= 5.00 ml

From;

m/M= CV

Where;

m= mass of aluminum hydroxide= 0.32 g

M= molar mass of aluminum hydroxide = 78 g/mol

C= concentration of aluminum hydroxide solution = the unknown

V= volume of aluminum hydroxide solution = 5.0 ml

0.32 g/78 g/mol = C × 5/1000

C = 4.1×10^-3/5×10^-3

C= 0.82 M

Reaction equation;

Al(OH)3(aq) + 3HCl(aq) -----> AlCl3(aq) + 3H2O(l)

Concentration of base CB= 0.82 M

Volume of base VB= 1.60 ml

Concentration of acid CA= the unknown

Volume of acid VA= 2.80 ml

Number of moles of acid NA = 3

Number of moles of base NB= 1

Using;

CA VA/CB VB = NA/NB

CAVANB = CBVBNA

CA= CB VB NA/VA NB

CA= 0.82 × 1.60 × 3/ 2.80 ×1

CA= 1.41 M

Therefore the concentration of HCl is 1.41 M

Answer:

density = 5.1g/m³

Explanation:

use ideal gas equation

Pv=nRT

28.26 x 3.51 = m/v x 0.08206 x 237

m/v = (28.26 x3.51)/(237 x 0.08206) = 5.1g/m³

Hey there!

For this we can use the combined gas law:

[tex]\frac{P_{1}V_{1} }{T_{1}} = \frac{P_{2}V_{2} }{T_{2}}[/tex]

We are only working with pressure and temperature so we can remove volume.

[tex]\frac{P_{1} }{T_{1}} = \frac{P_{2} }{T_{2}}[/tex]

P₁ = 2 atm

T₁ = 27 C

P₂ = 2.2 atm

Plug these values in:

[tex]\frac{2atm}{27C} = \frac{2.2atm}{T_{2}}[/tex]

Solve for T₂.

[tex]2atm = \frac{2.2atm}{T_{2}}*27C[/tex]

[tex]2atm * T_{2}={2.2atm}*27C[/tex]

[tex]T_{2}={2.2atm}\div2atm*27C[/tex]

[tex]T_{2}=1.1*27C[/tex]

[tex]T_{2}=29.7C[/tex]

Convert this to kelvin and get 302.85 K, which is closest to B. 330 K.

Hope this helps!