Identify the most acidic hydrogens in each of the following molecules. Give the structure of the enolate ion arising from deprotonation. (a) Acetaldehyde; (b) propanal; (c) acetone; (d) 4-heptanone; (e) cyclopentanone.

Answers

Answer 1

Answer:

See explanation below (Brainlist please)

Explanation:

First of all, we need to understand what is an acidic hydrogen.

An acidic hydrogen, is the atom of hydrogen which is more propense to undergo an acid base reaction, and form a stable ion or molecule in the process.

In other words, is the hydrogen that is more vulnerable to get substracted in an acid base reaction to form another compound.

Knowing this information, gives us an idea of how a molecule can be formed and which kind of compound is formed.

Now, in this question, we have 5 molecules. Each of them is either a ketone or aldehyde, so this mean that we have the carbonile group (C = O), which means that is easier to identify the acidic hydrogen. This is because the Carbonile group is an attractor group, so, it will attract the charges by inductive effect (in some cases by resonance), and the molecule is more stable.

This can be shown by drawing the enolate ion that is formed once the molecule undergo the acid base reaction. As it's an enolate form that we are looking for, then it means that the ketone or aldehyde is undergoing an electrofilic attack with a base. This base will substract the most acidic hydrogen to form a better and stable enolate. The acidic hydrogen and the enolate form can be seen in the attached picture.

a) In the case of acetaldehyde, the most acidic will be the hydrogen of carbon 2, because the hydrogen from the carbonile, once it's substracted, the charge of the carbon cannot be stabilized by resonance. Carbon 2 hydrogens, can do this job easily.

b) Propanal happens something similar to acetaldehyde, the terminal hydrogen cannot be substracted, and carbon 3, once the hydrogen is gone, the negative charge cannot be stabilized by resonance, so hydrogens of carbon 2 can do this.

c) in the case of acetone, is easier to look because we only have the C = O between two methyl group, so you can use either carbon 1 or 3 to do the job.

d) 4 heptanone the most acidic hydrogen would be carbon 3 or 5, because they are closer to the C=O and the ion can be stabilized by resonance.

e) Finally in ciclopentanone, the most acidic hydrogen would be carbon 2 or 5.

See picture for a better understanding.

Hope it helps.

Identify The Most Acidic Hydrogens In Each Of The Following Molecules. Give The Structure Of The Enolate

Related Questions

Element X has two naturally occurring isotopes, 65X (isotopic mass 65.0457 amu, abundance 20.53%) and 67X (isotopic mass 66.9704 amu, abundance 79.47%). Calculate the atomic mass of element X.

Answers

Answer:

66.5753 amu

Explanation:

From the question given above, the following data were obtained:

Isotope A (⁶⁵X):

Mass of A = 65.0457 amu

Abundance of A = 20.53%

Isotope B (⁶⁷X):

Mass of B = 66.9704 amu

Abundance of B = 79.47%

Atomic mass of X =?

The atomic mass of X can be obtained as follow:

Atomic mass = [(mass of A × A%)/100] + [(mass of B × B%)/100]

= [(65.0457 × 20.53)/100] + [(66.9704 × 79.47)/100]

= 13.3539 + 53.2214

= 66.5753 amu

Therefore, the atomic mass of X is 66.5753 amu.

Element X, with an atomic mass of 66.58 amu, has 2 naturally occurring isotopes, ⁶⁵X (65.0457 amu, 20.53%) and ⁶⁷X (66.9704 amu,  79.47%).

What is the average atomic mass?

The average atomic mass (atomic mass) of an element is the sum of the masses of its isotopes, each multiplied by its natural abundance.

Element X has 2 isotopes:

⁶⁵X with an isotopic mass of 65.0457 amu and an abundance of 20.53% (0.2053).⁶⁷X with an isotopic mass of 66.9704 amu and an abundance of 79.47% (0.7947).

We can calculate the average atomic mass of X using the following expression.

mX = m⁶⁵X × ab⁶⁵X + m⁶⁷X × ab⁶⁷X

mX = 65.0457 amu × 0.2053 + 66.9704 amu × 0.7947

mX = 66.58 amu

Element X, with an atomic mass of 66.58 amu, has 2 naturally occurring isotopes, ⁶⁵X (65.0457 amu, 20.53%) and ⁶⁷X (66.9704 amu,  79.47%).

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Please help me ASAP I’ll mark Brainly

Answers

Answer:

Batteries hold chemical energy

Explanation:

The battery acid in a battery leads to chemical energy.

Work and energy unit test

Answers

Answer:

whats your question

Explanation:

In a lab, you produce a quantity of the radioactive isotope thorium-234. Over the course of several weeks, the unstable isotope decays, and you measure the amount of thorium-234 remaining in the sample. You obtain the following data. What is the half life of Thorium-234? How much Thorium 234 will there be after two half lives?
Days Elapsed Grams of Thorium 234 Remaining
0 16
12 11
24 8
36 6
a. 36 days
b. 12 days
c. 24 days / 4 grams

Answers

Answer:

Option C. 24 days / 4 grams

Explanation:

From the question given above, the following data were obtained:

Days Elapsed >>>> Mass Remaining

0 >>>>>>>>>>>>>>> 16

12 >>>>>>>>>>>>>>> 11

24 >>>>>>>>>>>>>>> 8

36 >>>>>>>>>>>>>>> 6

A. Determination of the half-life of Thorium-234.

To determine the half-life, it is important to know the definition of half life.

Half-life is defined as the time taken for a substance to reduce to half its original mass.

From the table given above, we can see that the original mass of the isotope is 16 g (i.e at 0 day). By day 24, the mass of the isotope is 8 g (i.e half the original mass). Thus, the half-life of the isotope is 24 days.

B. Determination of the mass of the isotope remaining after 2 half lives.

Original amount (N₀) = 16 g

Number of half-lives (n) = 2

Amount remaining (N) =?

N = 1/2ⁿ × N₀

N = 1/2² × 16

N = 1/4 × 16

N = 4 g

Thus, 4 g of the isotope is remaining after 2 half lives.

Summay:

Half-life = 24 days

Amount remaining after 2 half-lives = 4 g

Option C gives the correct answer to the question.

1. What 3 types of bonds are typically found in biological organisms?

Answers

Answer:

Chemical bonds. Chemical bonds are the connections between atoms in a molecule. ...

Covalent Bonds. Chemical bonds are the forces of attraction that tie atoms together. ...

Ionic Bonds. ...

Bonds, Stability, and Compounds.

Answer:

Ionic bonding.

Covalent bonding.

Metallic bonding.

A covalent bond forms when

Answers

It happens when H20 gets dislocated back into the atmosphere to an massive heat level
it’s the second answer

In the following pair, determine whether the two represent resonance contributors of a single species or depict different substances. If two structures are not resonance contributors, explain why. Select the single best answer.

N-N ≡ N: and N=N=N:

Answers

Answer:

They are resonance contributors

Explanation:

Resonance structures are structures that differ only in the distribution or placement of electrons.

Considering the two structures, we can easily see that the two species have the same total number of bonds and electrons differing only in the distribution of these electrons.

Hence, they are resonance contributors.

The atomic number of sodium (Na) is 11. The element phosphorus (P) is the fourth element to the right of sodium in the periodic table.


The atomic number of phosphorus is ____. It has zero charge because it had ____ electrons.

Answers

atomic number of phosphorous is 15. It has zero charges because it has equal number of protons and electrons

Answer:

atomic number of phosphorous is 15. It has zero charges because it has equal number of protons and electrons

Explanation:

7. Based on the conclusion in question 5, what type of leaves would be most beneficial for plants indigenous (native) to a desert?* O Wide leaves, with high surface area O Thin narrow leaves, with low surface area It wouldn't make a difference - any leaves will work in any area. PLEASE HElP ASAP PLEASEEEEEEE​

Answers

Answer:

I don't know what question 5's conclusion is but if i were to take a guess here i would say wide leaves with a high surface area

Explanation:

to soak up water and maybe provide shade for the roots and dirt under the plant.

has DNA that tells the rest of the organelles what to do

Answers

Answer:

No

Explanation:

i honestly don't know

the diagram below represents the electromagnetic spectrum with some of the regions labeled with letters. Visble light is represented by which letter?

Answers

Answer:D

Explanation:

What is The Magnus Effect/Force? Explain.

Answers

Answer:

dk

Explanation:

A 1.00-L flask was filled with 2.00 moles of gaseous and 2.00 moles of gaseous and heated. After equilibrium was reached, it was found that 1.21 moles of gaseous was present. Assume that the reaction

SO2 + NO2 ⇌ SO3 + NO

occurs under these conditions. Calculate the value of the equilibrium constant, K, for this reaction.

Answers

Answer:

2.35

Explanation:

A 1.00-L flask was filled with 2.00 moles of gaseous SO₂ and 2.00 moles of gaseous NO₂ and heated. After equilibrium was reached, it was found that 1.21 moles of gaseous NO was present. Assume that the reaction

SO₂ + NO₂ ⇌ SO₃ + NO

occurs under these conditions. Calculate the value of the equilibrium constant, K, for this reaction.

Step 1: Calculate the molar concentrations

Since the reaction takes place in a 1.00 L flask, the molar concentrations are:

[SO₂]i = 2.00 M

[NO₂]i = 2.00 M

[NO]eq = 1.21 M

Step 2: Make an ICE chart

        SO₂ + NO₂ ⇌ SO₃ + NO

I       2.00   2.00       0        0

C        -x       -x         +x       +x

E    2.00-x  2.00-x    x         x

Step 3: Calculate the concentrations at equilibrium

The concentration of NO at equilibrium is 1.21 M. Then, x = 1.21.

[SO₂]eq = 2.00-1.21 = 0.79 M

[NO₂]eq = 2.00-1.21 = 0.79 M

[SO₃]eq = x = 1.21 M

[NO]eq = x = 1.21 M

Step 4: Calculate the value of the equilibrium constant, K, for this reaction

K = [SO₃] × [NO]/[SO₂] × [NO₂]

K = 1.21²/0.79² = 2.35

2055 Q. No. 10^-2
mole of KOH is dissolved in 10 litres of
water. What will be the pH of the solution?
12
Ans: pH = 11​

Answers

Answer:

11

Explanation:

Moles of KOH = [tex]10^{-2}[/tex]

Volume of water = 10 liters

Concentration of KOH is given by

[tex][KOH]=\dfrac{10^{-2}}{10}\\\Rightarrow [KOH]=10^{-3}\ \text{M}[/tex]

[tex][KOH][/tex] is strong base so we have the following relation

[tex][KOH]=[OH^{-}]=10^{-3}\ \text{M}[/tex]

[tex]pOH=-\log [OH^{-}]=-\log10^{-3}[/tex]

[tex]\Rightarrow pH=14-3=11[/tex]

So, pH of the solution is 11

DEFINITION: ABILITY OF A SUBSTANCE TO BE DISSOLVED

Answers

Answer:

Solubility

Explanation:

If its not that the answer is Dissolvable.... you didn't give a word bank.

:))))))))))

The moons of Jupiter
orbit Jupiter because
they are pulled toward
Jupiter. The moons of
Jupiter are too far to
be pulled into Earth's
orbit.
Yes or No

Answers

Answer:

Yes

Explanation:

Jupiter is a very large planet. Larger planets usually have stronger gravity, which pulls planets toward each other.

The moons of Jupiter are by Jupiter. (I know, that wasn't a smart thing to say because you know that, but, hey, I had to.) With this being the case, Jupiter is also an inside planet.

- Inside Planets

Planets that are closest to the sun and orbits the sun

There are 2 things that are the cause of the moons of Jupiter not being pulled by earth.

1. Jupiter has strong gravity which pulls the moons, and Jupiter is being pulled by the sun's INCREDIBLE gravity.

2. Earth is an outside planet. It is too far away from Jupiter to attract Jupiter's moons.

- Outside Planet

A planet that is away from the sun, but still orbits the sun

Hope this helps! :D

If you want to know more about the sun, just call on me!!!!

Yes, The moons of Jupiter orbit Jupiter because they are pulled toward Jupiter. The moons of Jupiter are too far to be pulled into Earth'orbit.

What is orbit ?

A planet's orbit around a star, a natural satellite's orbit around a planet, or an artificial satellite's orbit around a space object or location like a planet, moon, asteroid, or Lagrange point are all examples of curved objects that follow this path.

A planet's orbit around a star, a natural satellite's orbit around a planet, or an artificial satellite's orbit around a space object or location like a planet, moon, asteroid, or Lagrange point are all examples of curved trajectories in celestial mechanics known as orbits.

Around a star, a natural satellite's orbit around a planet, or an artificial satellite's orbit around a space object or location like a planet, moon, asteroid, or Lagrange point are all examples of curved objects that follow this path.

Yes, The moons of Jupiter orbit Jupiter because they are pulled toward Jupiter. The moons of Jupiter are too far to be pulled into Earth'orbit.

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Calculate the number of moles of aluminum, sulfur, and oxygen atoms in 3.00 molesmoles of aluminum sulfate, Al2(SO4)3Al2(SO4)3. Express the number of moles of AlAl, SS, and OO atoms numerically, separated by commas.

Answers

Answer:

[tex]n_{Al}=6.00molAl\\\\n_{S}=9.00molS\\\\n_{O}=36.0molO[/tex]

Explanation:

Hello!

In this case, when analyzing the moles of an element inside a compound, we need to keep in mind that a mole ratio should be set up; thus, for aluminum sulfate, we have the following ones:

[tex]\frac{2molAl}{1molAl_2(SO_4)_3} \\\\\frac{3molS}{1molAl_2(SO_4)_3} \\\\\frac{12molO}{1mol1molAl_2(SO_4)_3}[/tex]

Thus, starting by 3.00 moles of aluminum sulfate, the moles of each element turn out:

[tex]n_{Al}=3.00molAl_2(SO_4)_3*\frac{2molAl}{1molAl_2(SO_4)_3} =6.00molAl\\\\n_{S}=3.00molAl_2(SO_4)_3*\frac{3molS}{1molAl_2(SO_4)_3} =9.00molS\\\\n_{O}=3.00molAl_2(SO_4)_3*\frac{12molO}{1molAl_2(SO_4)_3}=36.0molO[/tex]

Best regards!

What is the ratio of carbon, hydrogen, and oxygen in most carbohydrates?
A.
1:1:1
B.
1:2:1
C.
1:2:3
D.
2:1:1
E.
2:2:1

Answers

Answer:

1:2:1

Explanation:

i just think hai .its just a guess from my side...sorry if i m wrong...

Answer:

1:2:1

Explanation:

Hello person in the future. Good luck with your test and I hope you do great things with your life. You got this!! :D

determine the mass of 840 cm3 of oxygen gas, O2 at rtp​

Answers

Answer:

Mass = 0.96 g

Explanation:

Given data:

Volume of oxygen = 840cm³

Temperature = at room = 25°C

Pressure = at room = 1 atm

Mass of oxygen = ?

Solution:

Volume of oxygen = 840 cm³ × 1 L /1000 cm³ = 0.84 L

Temperature  = 25 +273.15k = 298.15 K

Formula:

PV = nRT

n = PV/RT

R = 0.0821 atm.L/mol.K

n = 1 atm × 0.84 L / 0.0821 atm.L/mol.K ×  298.15 K

n = 0.84 atm.L / 24.48 atm.L/mol

n = 0.03 mol

Mass of oxygen:

Mass = number of moles × molar mass

Mass = 0.03 mol × 32 g/mol

Mass = 0.96 g

what would be a logical explanation for why carbon dioxide increased over the time shown in the graph.
A. the area of land for crops incresed
b. the amount of plants eaten by animal increased
c. the amount of fossil fuels being burned increased
d. the amount of wood being burned by pepole increased

Answers

Answer:

c. the amount of fossil fuels being burned increased

Explanation:

Carbon dioxide gas concentration increased over the time due to burning of fossil fuels increased. Fossil fuels are organic compounds which releases carbondioxide gas as a result of burning of fossil fuels in the engines of vehicles and industries. With the passage of time, number of vehicles increases in the world which needs more fossil fuels and due to burning of that fossil fuels, more carbondioxide gas is released.

Nitrogen can exist as a solid, a liquid, or a gas. Which of the following lists the
phases of nitrogen in order of increasing density?
1. liquid, gas, solid
2. gas, liquid, solid
3. gas, solid, liquid
4. solid, liquid, gas

Answers

The phases of nitrogen in order of increasing density is solid, liquid, and gas.

Nitrogen is known to be odorless and colorless. Nitrogen makes up about 78% of the gases that we've in the atmosphere. It has an atomic number of 7 and is represented with the symbol N.

It should be noted that nitrogen can be a solid, a liquid or a gas. When nitrogen is at ordinary pressure, it is known to be a gas. In a case whereby nitrogen is below 77°K, then it's a liquid and it's a solid when it's below 63°K.

The density explains the mass per unit volume that nitrogen has when it's either at gaseous, solid or liquid state. It should be noted that the highest density is at its gaseous state.

Therefore, the phases of nitrogen in order of increasing density will then be solid, liquid, and gas.

In conclusion, the correct option is D.

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The density of gold is 19.3 g/cm³. Which of the following shows the mass of a gold bar that is 4.50 cm × 8.00 cm × 20.00 cm?

Answers

Answer:

13896g

Explanation:

volume = 4.50×8.00×20.00 = 720 cm³

mass = density × volume

mass= 19.3 × 720 = 13896g

Is the enzyme lactase a catalyst? why or why not?

Answers

Answer:

Explanation:

The enzyme lactase acts as a catalyst to facilitate the reaction and make it happen very quickly. This enzyme is made u.

do the rest

hope it helps

Enzyme lactase catalyzes the hydrolysis of the glycosidic bond of lactose to form galactose and glucose.

What is lactase?

Lactase can be described as an enzyme produced by many organisms. Lactase is located in the small intestine of humans and other mammals. It is essential to accomplish the digestion of milk and it breaks down lactose that gives milk its sweetness.

A person with a deficiency of lactase, and who consume dairy products, may experience the symptoms of lactose intolerance. Lactase is a part of the β-galactosidase family of enzymes and is a glycoside hydrolase involved in the hydrolysis of lactose into constituent galactose and glucose monomers.

The β-glycosidic bond in D-lactose in metabolism is hydrolyzed to form D-galactose and D-glucose, which can be absorbed into the bloodstream. The optimum temperature of the human lactase is about 37 degrees Celcius and the optimum pH of the human lactase is equal to 6.

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