How to set up the rate expressions for the following mechanism?

A → B k1
B → A k2
B+C → D k3

If the concentration of B is small compared with the concentrations of A, C, and D, the steady-state approximation may be used to derive the rate law. Derive the rate law, and show that this reaction may follow the first-order equation at high pressures and the second-order equation at low pressures.

Answers

Answer 1

Answer:

Explanation:

From the given information:

A → B k₁

B → A k₂

B + C → D k₃

The rate law = [tex]\dfrac{d[D]}{dt}=k_3[B][C] --- (1)[/tex]

[tex]\dfrac{d[B]}{dt}=k[A] -k_2[B] -k_3[B][C][/tex]

Using steady-state approximation;

[tex]\dfrac{d[B]}{dt}=0[/tex]

[tex]k_1[A]-k_2[B]-k_3[B][C] = 0[/tex]

[tex][B] = \dfrac{k_1[A]}{k_2+k_3[C]}[/tex]

From equation (1), we have:

[tex]\mathbf{\dfrac{d[D]}{dt}= \dfrac{k_3k_1[A][C]}{k_2+k_3[C]}}[/tex]

when the pressure is high;

k₂ << k₃[C]

[tex]\dfrac{d[D]}{dt} = \dfrac{k_3k_1[A][C]}{k_3[C]}= k_1A \ \ \text{first order}[/tex]

k₂ >> k₃[C]

[tex]\dfrac{d[D]}{dt} = \dfrac{k_3k_1[A][C]}{k_2}= \dfrac{k_1k_3}{k_2}[A][C] \ \ \text{second order}[/tex]


Related Questions

100
Continue reflecting on managing the effects of tropical cyclones by a
the phrases below:
I have learned that the Philippine Area of Responsibility
The Philippine Atmospheric, Geophysical, and Astronomical Services Administration
The Philippines is prone to typhoons because
You can trace the path of typhoons using
You will then understand that landmasses and bodies of
water affect the intensity of typhoons causing it to increase when
and decrease when
We should stay informed about the weather. Public Storm Warning Signals indicate
The higher the PSWS, the
the damage felt. Hazards that may
accompany tropical cyclones are
But tropical cyclones also have benefits, such as
Great work! Now that you know more about the effect of typhoons, you can
ssen the damages by knowing what to do. Answer the next activity, to eva
nowledge on precautionary measures to lessen the risk brought about by
10​

Answers

Answer:

?????

Explanation:

...? what...?

Mercury can be obtained by reacting mercury(II) sulfide with calcium oxide. How many grams of Mercury metal are produced when 2.11 g of calcium oxide reacts with excess mercury(II) sulfide?


4HgS+4CaO=4Hf+3CaS+CaSO4


a. 10.1 g

b. 1.80 g

c. 13.4 g

d. 7.56 g

Answers

Answer:

Option D. 7.56 g of Hg.

Explanation:

The balanced equation for the reaction is given below:

4HgS + 4CaO —> 4Hg + 3CaS + CaSO₄

Next, we shall determine the mass of CaO that reacted and the mass of Hg produced from the balanced equation. This is can be obtained as follow:

Molar mass of CaO = 40 + 16

= 56 g/mol

Mass of CaO from the balanced equation = 4 × 56 = 224 g

Molar mass of Hg = 200.59 g/mol

Mass of Hg from the balanced equation = 4 × 200.59 = 802.36 g

SUMMARY

From the balanced equation above,

224 g of CaO reacted to produce 802.36 g of Hg.

Finally, we shall determine the mass of Hg produced by the reaction of 2.11 g of CaO. This can be obtained as follow:

From the balanced equation above,

224 g of CaO reacted to produce 802.36 g of Hg.

Therefore, 2.11 g of CaO will react to produce = (2.11 × 802.36)/224 = 7.56 g of Hg.

Thus, 7.56 g of Hg were obtained from the reaction.

What is it called when instead of getting rid of a product you find another

use for the product?

Answers

Answer:

Recycling.

Explanation:

When instead of getting rid of a product you find another use for the product, it is called recycling.

Recycling can be defined as a process which typically involves gathering, processing and transformation of materials or products that would otherwise be gotten rid of as waste materials or trash into new products that could be used for another purpose.

Basically, the recycling process involves turning a trash or unwanted product into a treasure (new product) that is capable of serving another purpose.

For example, the crown cork of a bottle could be gathered and processed into art forms that can be used for decorations.

the generator is connected to a _____, which supplies our _____ with electricity.

Answers

Answer:

neutral and current

Explanation:

sorry if im wrong ;(

5. Why are lonic compounds good conductors of electricity?
lone compounds are electrical in nature
"The strong electrostate attraction between lons allow electricity
Aques solutions of lonie compounds cause to dissociate fons
are free to conduct electricity
de electrostate attraction between crystal lattice of
pound is strong which needs high temperature to melt arb
CO Q2 Science ?​

Answers

Answer:

The options are unclear, however, the correct option is:

Aqueous solutions of ionic compounds cause to dissociate, hence, ions are free to conduct electricity

Explanation:

Ionic compounds are compounds formed from ions (charged atoms). For example, NaCl is an ionic compound from the following ions; Na+ (cation) and Cl- (anion). One characteristics of ionic compounds is their ability to dissociate into the ions that form them when in an aqueous solution i.e. NaCl will dissociate into Na+ and Cl- when in an aqueous solution.

These disssociated ions are free to conduct electricity, hence, making ionic compounds good conductors of electricity.

Which food dyes in the diagram on the right only contain one colour?
( Science, Chromatography )​

Answers

Colored dyes are really bad for you but I drink them anyways

PLEASE HURRY. This is a project please help me as soon as possible.

1. What do you think would have happened if the light pollution had been a permanent condition
on planet Oopsa?


2. What do you think would have happened if the light pollution were green instead of red?

Please help asap. Will give brainliest.

Answers

Answer:

Light pollution is excessive, misdirected or inappropriate outdoor lighting. Too much light pollution washes out the view of the Universe, increasing energy consumption, interferes with astronomical research, disrupts ecosystems, and affects the health and safety of humans and wildlife.

Explanation:

Light pollution radically alters their nighttime environment by turning night into day. ... “Predators use light to hunt, and prey species use darkness as cover,” Kyba explains “Near cities, cloudy skies are now hundreds, or even thousands of times brighter than they were 200 years ago.

03
A force of 20 N acts upon a 5 kg block. Calculate the acceleration of the object.​

Answers

The equation we use is F=ma
(Force = mass x acceleration)

We are going to put each number in the equation:
F=ma
20N = 5kg x (?)

So, to find a (acceleration), we do F/m
[acceleration = force/mass]

a = 20/5 = 4

The answer is 4m/s^2

For most substances the density of a solid form is slightly greater than the density of liquid form water however is different it is slightly less dense in the solid form than it is in liquid form compare water in the solid form with neon argon in oxygen and proposal reason why solid water is less dense liquid water

Answers

Answer:

Answer: When water freezes, water molecules form a crystalline structure maintained by hydrogen bonding. Solid water, or ice, is less dense than liquid water. Ice is less dense than water because the orientation of hydrogen bonds causes molecules to push farther apart, which lowers the density.

Explanation:

From previous experiments, this chemical reaction is known to absorb of energy. The position of the piston is monitored, and it is determined from this data that the system does of work on the piston during the reaction. Is the reaction exothermic or endothermic? exothermic endothermic Does the temperature of the water bath go up or down? up

Answers

Hello. Your question is missing data, which makes it difficult to answer it with exactness, but I will try to help you in the best possible way.

If the reaction absorbs energy it means that the reaction is endothermic. This is because endortemic reactions are those that absorb energy from the environment, as opposed to exothermic reactions that release energy into the environment.

In that case, if the reaction is absorbing energy, it is appropriate for the water bath temperature to drop.

5. Why is picric acid and tannic acid used in the treatment of burns?

Answers

Picric acid has antiseptic and astringent properties. For medical use it is incorporated in a surface anesthetic ointment or solution and in burn ointments. Picric acid is a much stronger acid than phenol; it decomposes carbonates and may be titrated with bases.

1. What is a forensic palyn ologist?
2. Describe the case that Mildenhall worked on in New Zealand.
3. How can a forensic palynologist help a crime investigation?
4. What are the challenges of using a forensic palynologist in crime investigations?

Answers

Answer:

A forensic palynologist is a spore and pollen expert that helps solve crimes.

The case that Mildenhall worked on was about a murder that involved a prostitute. The police couldn’t find a trace to help solve the case, so they called Mildenhall to help with pollen clues. He was able to find trace evidence in the pollen, which helped police connect the victim to a gang hangout by the crime scene.

A forensic palynologist can help with a criminal investigation by comparing pollen from the suspect and the victim using a comparison microscope to determine if the pollen matches.

The challenges of using a forensic palynologist in a criminal investigation are that judges and juries may have a hard time understanding palynologists.

Explanation:

Answers of the following points regarding forensic palynologist are given below:

What is forensic palynology?

This is a internal branch of palynology that deals with the relationship among different objects to prove or disprove, which may belongs to both criminal and civil cases.

(1). Forensic palynologist is a person who do the case study of the crime seen,  and deals with a spore and pollen.

(2). Mildenhall worked on a murder case in New Zealand where a prostitute was involved. Police were not able to solve the crime, so they called Mildenhall to help with pollen clues. Mildenhall who is a spore and pollen expert was able to study the pollen clues and gave hint to the police as they were do further process to connect with the victim.

(3). A forensic palynologist by comparing the pollen clues from the crime scene and the victim, can help with a criminal investigation by using a comparison microscope to determine if the pollen matches.

(4). As forensic palynology is a science study which can not be general understand by normal people; so that judges, juries and advocates may have a hard time understanding palynologists and this is the challenges of using a forensic palynologist in crime investigations.

To learn more about forensic palynologist, visit below link:

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1. How many grams does 10 moles of Carbon weigh?

Answers

Answer:120

Explanation: I think

Answer:

1321.177 grams.

Explanation:

each mole of carbon is 12.0107 grams.

2. Which of the following could the flame test be used for?

Answers

No options are shown mate

Which statement best describes how an electromagnetic motor works?


Electrons are moved through a magnet, creating a current. That current interacts with a circuit, moving the

conductor in the orientation of the field


Electrons are moved through a current, creating a circuit That circuit interacts with a magnet, moving the

conductor in the orientation of the field.


Electrons are moved through a circuit, creating a current That current interacts with a magnet, moving the

conductor in the orientation of the field


Electrons are moved through a magnet, creating a circuit That circuit interacts with a current, moving the

conductor in the orientation of the field

Answers

Answer:

Electrons are moved through a magnet, creating a current. That current interacts with a circuit, moving the conductor in the orientation of the field.

Explanation:

Electro magnetic fields are used to create electric current by the movement of electrons. When a coil of wire is wrapped around a magnet it pushes electrons and they flow through a magnet to create current. This current interacts with circuit to move conductor.

Learning Task 4: Think of two animals that reproduce sexually. In the first
box, draw an animal that fertilization occurs inside the body. In the second
box, draw an animal that exhibits external fertilization.

please help for me​

Answers

In the first box, you should draw a chicken. In the second box, you should draw a cow or a horse.

I hope it helps you!!!! :D

[ pls mark me brainliest i need one more to rank up tysm if u do ]

How many mL of 14.5M lithium carbonate solution must be used to deliver 4.20 g of lithium ion

Answers

Answer:

10.3 g Li) / (6.9410 g Li/mol) x (1 mol Li3PO4 / 3 mol Li) / (0.750 mol/L Li3PO4) = 0.6595 L = 660. mL

Explanation:

A student connects a battery to a wire and wraps the wire around an iron nail to produce an electromagnet. Which action

should the student take to increase the number of paper clips the electromagnet can pick up?


He should replace the iron nail with a plastic spoon.


He should add another battery.


He should decrease the current through the wire


He should reduce the number of turns

Answers

Answer:

He should add another battery.

Explanation:

An electromagnet is a type of magnet in which the magnetic field is produced by an electric current. Electromagnets usually consist of wire wound into a core of magnetic material usually an iron core. When an electric current-producing battery is connected to the wire, an electric current will begin to flow and the iron core will become magnetized. When the battery is disconnected, the iron core will lose its magnetism.

Electromagnets works based on the electromagnetic field which is a field force due to the interaction of the electric and magnetic fields. the force on the wire is proportional to the size of the current, the length and thickness of the iron core, as well as the number of turns of wire around the iron core.

Therefore, from the number of possible action given that the student can take in order to increase the magnetism of his electromagnet, adding another battery, thereby increasing the current will be the best way to increase the number of paper clips tat his electromagnet can pick up.

Answer:

they are correct he should add another battery trust me

Rocks are classified on the basis of

Answers

Answer:

Rocks are classified according to characteristics such as mineral and chemical composition, permeability, texture of the constituent particles, and particle size. This transformation produces three general classes of rock: igneous, sedimentary and metamorphic. Those three classes are subdivided into many groups.

Explanation:

Molten zinc chloride can be electrolysed.
Describe how this experiment can be carried out in a laboratory, explaining how the products of this electrolysis are formed.


(6) marks

Answers

Answer: The products of electrolysis are Zn(l) and [tex]Cl_2[/tex] gas

Explanation:

Electrolysis of a subastance is breaking it into its constituents by the action of electrical current.  

In the electrolysis of molten zinc chloride, zinc metal is produced at the cathode which is a negative electrode and chlorine gas produces as the anode which is a positive electrode.

[tex]ZnCl_2(l)\rightarrow Zn^{2+}+2Cl^-[/tex]

At anode : [tex]2Cl^-(l)\rightarrow 2e^-+Cl_2(g)[/tex]

At cathode : [tex]Zn^{2+}(l)+2e^-\rightarrow Zn(l)[/tex]

helllppp pls

Explain how human body maintains normal body temperatur

Answers


Much like a thermostat regulates the temperature inside your home, the hypothalamus regulates your body temperature, responding to internal and external stimuli and making adjustments to keep the body within one or two degrees of 98.6 degrees.

Where did the magma and sediment that formed the rock of the Great Plains and the Rocky
Mountains come from?
Which claim do you think is more likely to be true?
Claim 1: The sediment that formed the Great Plains came from the rock of the Rocky
Mountains.
Claim 2: The magma that formed the Rocky Mountains came from the rock of the Great Plains.

Answers

Answer:

1

Explanation seems right

The magma and sediments formed in the great plains are came from the rocks of the rocky mountains. Therefore, claim 1 is correct.

What is sedimentation?

Sedimentation is the geographical process of accumulation or deposition of the minerals and organic particles from the earth's surface is called sedimentation. This process results in the formation of sedimentary rocks.

Weathering or erosion of rocks by wind, water or other chemicals leads to the geological debris which then move to other places  deposits somewhere.

Rocks in the rocky mountains undergo erosion and the mass movements created by wind or water leads to the sedimentation of these rocky solids to other places. The rocks in the Great planes are reached there by the mass movement of the rocks of rocky mountains. Hence, claim 1 is correct.

To find more on sedimentation, refer here:

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Determine the empirical and molecular formulas of the mandelic acid​

Answers

Answer:

Both empirical and molecular are C₈H₈O₃.

Explanation:

Hello!

In this case, according the attached picture, it is possible to figure out the molecular formula of the mandelic acid by counting each carbon, hydrogen and oxygen in the molecule.

In such a way, we can see the presence of eight carbon atoms, eight hydrogen atoms and three carbon atoms; thus, the molecular formula is:

C₈H₈O₃

Furthermore, since the empirical formula is the smallest representation of the molecular formula when we are able to simplify it, we evidence no simplification is possible, consequently, the empirical formula equals the molecular one.

Best regards!

Which of the following accurately represents the relationship between ceramic and
metal?

Answers

Relationship between metal and ceramic is accurately represented by the statement that metal is a better conductor than ceramics.

What are conductors?

Conduction is defined as a process as a means of which heat is transferred from the hotter end of the body to it's cooler end.Heat flows spontaneously from a body which is hot to a body which is cold. Substances which enable conduction are called conductors.Conductors allow passage heat and electricity through the material.

In the process of conduction,heat flow is within the body and through itself.In solids the conduction of heat is due to the vibrations and collisions of molecules while in liquids and gases it is due to the random motion of the molecules .

When conduction takes place, heat is usually transferred from one molecule to another as they are in direct contact with each other.There are 2 types of conduction:1) steady state conduction 2) transient conduction.According to the type of energy conduction is of three types:

1) heat conduction

2) electrical conduction

3)sound conduction

Learn more about conductors,here:

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how does a buffer work?
A. it prevents added acids or bases from dissociating
B. it neutralizes acids or bases by precipitating a salt
C. it forms new conjugate pairs with the added ions
D. it bonds with the added H+ or OH- in solution​

Answers

Answer:

It bonds with the added H+ or OH in solution.

Explanation:

How might the shoot systems and the digestive system in a human be similar? Help please

Answers

Answer: The both Deal with digesting and getting rid of waste

Explanation:

Digestive system deals with getting rid of waste in your body and breaking down food.

The digestive system in a human is similar to the shoot system in a plant because both systems are involved in the transport of food materials and waste products in the organism.

The plant is composed of the root system and shoot system. The root system is beneath the ground while the shoot system is above the ground.

In humans, the digestive system carries food materials and waste from the alimentary canal to the small intestine. In plants, the shoot system also performs the same function of carrying food materials and waste products.

Hence, In the shoot system in plants performs a similar function to the digestive system in humans.

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A sample of 0.600 mol of a metal M reacts completely with excess fluorine to form 46.8 g of MF2.?
a) How many moles of F are in the sample of MF2 that forms? (1.20 mol F)
b) How many grams of M are in this sample of MF2?
c) What element is represented by the symbol M? (Ca)

Answers

Answer:

See Explanation

Explanation:

Given:

moles M = 0.600 mole

moles F = excess (for rxn stoichiometry)

Formula Weight (F.Wt.) of F = 19 grams/mole (from Periodic Table)

Yield in grams = 46.8 grams (assuming theoritical yield)

Rxn:         M          +        F₂       =>   MF₂

         0.600mol         Excess          0.600mol (1:1 rxn ratio for M:MF₂)

a. moles of F in MF₂ = 2(0.600) moles F = 1.2 moles F

b. mole weight MF₂ = 46.8g/0.600mol = 78g/mole

    F.Wt. MF₂ = F.Wt. M + 2(F.Wt. F)

     => mass M = F.Wt. M = [F.Wt. MF₂ - 2(F.Wt. F)] = 78g/mol. - 2(19g/mol.)

     = (78 - 38) grams/mole = 40 grams/mole

c. Calcium (Ca) has F.Wt. = 40 grams/mole (compared to Calcium on Periodic Table.

From the question, the metal is the limiting reactant and must be used to obtain the required results which are;

a) There are 1.20 mol F in MF2.

b) There are 40g of M in MF2.

c) M is calcium.

From the reaction equation;

M + F2 ----> MF2

Since the reaction is 1:1, 0.600 mol of MF2 is formed

Note that 1 mole of MF2 contains two moles of F and one mole of M

Hence, number of moles of F in MF2 = 2 *  0.600 mol = 1.20 mol F

Since 1 mole of M is contained in MF2, there are 0.600 moles of M in MF2.

If 1 mol of M forms 1 mole of MF2

And, 0.600 mol of M form 0.600 mol of MF2

Number of moles of MF2 = mass/molar mass

Number of moles of MF2 =  0.600 mol

Mass of MF2 formed = 46.8 g

Molar mass of MF2 = mass/Number of moles of MF2

Molar mass of MF2 = 46.8 g/0.600 mol

Molar mass of MF2 = 78 g/mol

Molar mass = Sum of Relative atomic mass of component atoms.

Hence;

78 = M + 2(19)

M = 78 - 2(19)

M = 40 g

The element must be calcium

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Consider a 0.70 M solution of HOCl. If the molarity was decreased to 0.3 M, what would happen to the percent dissociation?

Answers

Answer:

The percent dissociation would increase

Explanation:

Percent dissociation is the ratio of amount dissociated to the initial concentration.

Decreasing the concentration of the solution leads to an increase in percent dissociation.

A 32.4 L gas sample at STP is compressed to a volume of 28.4 L, and the temperature is increased to 352 K. What is the new pressure of the gas in atmospheres

Answers

Answer:

1.47 atm

Explanation:

Step 1: Given data

Initial volume (V₁): 32.4 LInitial pressure (P₁): 1 atm (standard pressure)Initial temperature (T₁): 273 K (standard temperature)Final volume (V₂): 28.4 LFinal pressure (P₂): ?Final temperature (T₂): 352 K

Step 2: Calculate the final pressure of the gas

We can calculate the final pressure of the gas using the combined gas law.

P₁ × V₁ / T₁ = P₂ × V₂ / T₂

P₂ = P₁ × V₁ × T₂ / T₁ × V₂

P₂ = 1 atm × 32.4 L × 352 K / 273 K × 28.4 L = 1.47 atm

Starting with 5.00 g barium chloride n hydrate yields 4.26 g of anhydrous barium chloride after heating. Determine the integer n.

Answers

Answer:

BaCl₂·(H₂O)₂

Explanation:

The reaction that takes place is:

BaCl₂·(H₂O)ₙ → BaCl₂ + nH₂O

The information given by the problem tells us that 5.00 g of reactant were consumed. Of those 5.00 g, 4.26 g were converted into BaCl₂, this means that the other 0.74 g were converted into water.

We convert 0.74 g of water into moles, using its molar mass:

0.74 g H₂O ÷ 18 g/mol = 0.041 mol H₂O

Then we convert 4.26 g of BaCl₂ into moles:

4.26 g BaCl₂ ÷ 208.23 g/mol = 0.0204 mol BaCl₂

We can write these results as (BaCl₂)₀.₀₂·(H₂O)₀.₀₄. We multiply those coefficients by 50 in order to make them integers, and we're left with:

BaCl₂·(H₂O)₂
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