Answer:
How can you determine which bond in a structure is more polar without using an electronegativity table?
Explanation:
When we say something is polar, it has a very specific meaning. It means that there is a spatial separation of charges, or a dipole moment. In the simplest case, this is given by:
μ=Qr
Where μ is the dipole moment, Q is the charge on each pole (equal and opposite) and r is the distance between the charges.
Anything with charges can have a dipole moment, and therefore be polar. In chemistry, we typically worry about whether or not two things are polar:
Bonds
Molecules
Bond Polarity
Chemists are concerned with the polarity of bonds because polarity affects the character of the bond - the more polar the bond is, the more it behaves like an ionic bond. The less polar, the more it behaves like a covalent bond. This has implications for everything from naming rules to reactivity, but all you need to know for this problem is:
All bonds between two atoms are polar, unless the atoms are identical.
(This is including whatever else the atoms may be bonded to). The only question after that is "how polar is the bond," and that is where tables of electronegativity come in. Using an arbitrarily defined scale, we can measure the relative polarity of bonds by comparing the difference in electronegativity between the two elements.
Molecule Polarity
For molecules, polarity isn't quite so simple. We know that all bonds between dissimilar atoms are polar, but in a molecule, sometimes the dipole moments add up to form a net dipole moment of zero. This is a little bit difficult to explain if you don't have a mathematics and physics background that includes vectors and summations of forces/moments.
If you do, then when I say something like:
The net dipole moment for a molecule is equal to the sum of dipole moments over each bond.
It will make sense to you. If you don't, then you have to get a little more creative. I tell my students to imagine that there are ropes connecting each outer molecule to the central molecule, along each bond. Then imagine pulling each rope towards the side that is more electronegative (has a higher electron density). The more polar the bond, the harder you pull on the rope. Then imagine whether the molecule moves. If the forces balance, it stays put, so the net dipole moment is zero and it is not polar. If it does move, there was a net dipole moment, so it is polar.
This works pretty well - as long as you can visualize the molecular geometry. That's the hard part. To know how the bonds are oriented in space, you have to have a strong grasp of Lewis structures and VSEPR theory. Assuming you do, you can look at the structure of each one and decide if it is polar or not - whether or not you know the individual atom electronegativity. This is because you know that all bonds between dissimilar elements are polar, and in these particular examples, it doesn't matter which direction the dipole moment vectors are pointing (out or in).
Let's look at each one, using wikipedia's geometric pictures.
BrF5
BrF5
As you can see, there is a lone pair at the bottom (this is a square pyramidal geometry). The net dipole moment will be pointing "up", which makes this a polar molecule.
PBr5
PBr5
This one has a trigonal bipyramidal geometry, with each bond symmetrically opposed to each of the others. If you add up the vectors, they result in a net dipole moment of zero. Therefore, it is non-polar.
EDIT: As ron points out in the comments below, this is not really a binary molecular compound, and in reality forms an ionic crystal structure with PBr4+ and Br−. I don't think the author of the question intended you to worry about that, but if they did, the answer is still "non polar," although we wouldn't really call it a "molecule" any more.
CCl4
CCl4
Carbon tetrachloride has a tetrahedral geometry, and all the dipole moment vectors cancel. Therefore, it is non-polar.
XeF2
XeF2
This one is linear - no net dipole moment, so it is non-polar.
XeF4
enter image description here
I could only find the ball-and-stick model for this one. It is square planar - there is a lone pair of electrons (not shown) on each "face" of the square on Xe. There is no net dipole moment, so it is also non-polar.
Out of all of these, the only polar molecule is BrF5 (the first one).
If the net dipole moment is zero, it is non-polar. Otherwise, it is polar.
When looking at the equilibrium between silver bromide and its aqueous ions, what could be added to solution to promote precipitation of silver bromide?
Answer:
NaBr
Explanation:
When AgBr is dissolved in water, the following equilibrium is set up in solution;
AgBr(s)⇄Ag^+(aq) + Br^- (aq)
If we dissolve NaBr in the water, a common ion (Br^-) is now introduced into the system. This increases the concentration of Br^- and favours the reverse reaction hence more AgBr is precipitated. This is known as common ion effect.
Describe the movement of molecules in solids, liquids, and gases.Be sure to explain why the molecules move differently in each state of matter.
Answer:
See explanation
Explanation:
The degree of movement of molecules in each not the three different states of matter depends on the arrangement of the molecules.
In a solid, molecules are packed closely together and are held in fixed positions by strong intermolecular forces such that they can only vibrate or rotate about a fixed point.
In liquids, molecules are less closely packed hence they can flow around each other but possess only little kinetic energy. Intermolecular forces in liquids are much lesser than that of solids.
In gases, intermolecular forces are negligible and gas molecules move with a very high velocity and possess high kinetic energy. There are large spaces between gas molecules and they are always in motion.
In which of the following groups of substances would dispersion forces be the only significant factors in determining boiling points? I. Cl2 II. HF III. Ne IV. KNO2 V. CCl4
Answer:
Cl2,Ne, CCl4
Explanation:
Dispersion forces are quite significant as the predominant intermolecular forces in nonpolar substances. For Cl2,Ne and CCl4, dispersion forces are the primary kind of intermolecular interaction present in the compound.
Hence, the boiling point of these substances will be determined solely by the dispersion forces between the molecules.
Cl2, Ne, CCl4 are the group of substances in which dispersion forces would
help determine the boiling point.
Dispersion force is a type of Van der waals force and is also regarded as
London forces. This type of force occur between the atoms and molecules
when electrons are symmetrically distributed in the nucleus.
This force is a weak intermolecular force and is present in non polar
compounds such as Cl2, Ne, CCl4 . KNO2 is polar and hence doesn't
determine its boiling point.
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Identify the missing nuclide in the following nuclear equation:
214 Pb → 0 e + ?
82 -1
A. Pb-215.
B. Bi-214.
C. Pb-213.
D. TI-215.
E. TI-214.
Answer:
B. Bi-214.
Explanation:
The equation shows beta particle emission of 214/82 Pb which result into 214/83 Bi, in which the mass remain same but the the atomic number increases by one.
During this emission neutron get split into an electron and a proton which are represented as 0/e/-1.
So, the final nuclear equation becomes : 214/82 Pb => 0 e -1 + 214/83 Bi
Hence, the correct answer is "B. Bi-214."
the number of protons in an ato
Answer:
The number of protons in the nucleus of the atom is equal to the atomic number
(Z). The number of electrons in a neutral atom is equal to the number of protons .
The mass number of the atom (M) is equal to the sum of the number of protons
and neutrons in the nucleus.
4.0 g Mg and 4.0 g O2 are placed in a container and magnesium oxide, MgO, forms. The Mg is totally consumed but 1.4 g O2 remains. How much magnesium oxide formed
Answer:
The correct answer is: 6.6 g MgO
Explanation:
First we have to write and balance the chemical reaction as follows:
2Mg(s) + O₂(g) → 2MgO(s)
That means that 2 moles of Mg(s) react with 1 mol of O₂(g) to give 2 moles of MgO(s). If Mg is totally consumed and a mass of O₂ remains unaltered after reaction, the limiting reactant is Mg. We use the limiting reactant to calculate the mass of product.
According to the balanced chemical equation, 2 moles of Mg(s) produce 2 moles of MgO(s).
2 moles Mg = 2 mol x molar mas Mg= 2 mol x 24.3 g/mol = 48.6 g Mg
2 moles MgO= 2 mol x (molar mass Mg + molar mass O) = 2 mol x (24.3 g/mol + 16 g/mol) = 80.6 g MgO
The stoichiometric ratio is 80.6 g MgO/48.6 g Mg. So, we multiply this ratio by the mass of consumed Mg (4.0 g) in order to obtain the produced mass of MgO:
4.0 g Mg x 80.6 g MgO/48.6 g Mg = 6.63 g MgO
6.6 grams of magnesium oxide are formed.
In the reaction: CH 3COOH(aq) + NH 2 – (aq) CH 3COO – (aq) + NH 3(aq), the conjugate acid-base pairs are:
Answer: CH3COO- & CH3COOH are conjugate
NH2- & NH3 are conjugate
Explanation:
why is the concentration of a solid left out of the equilibrium expression for the solubility of a salt
Answer:
Its concentration remains constant
Explanation:
The concentration of a pure solid is left out of the expression for the equilibrium solubility of a salt because the concentration of a pure solid remains constant. Therefore, the activity of a pure solid is 1.
Being of a constant concentration, the pure solid is not included in equilibrium expression for the solubility of a salt.
What is the stoichiometric coefficient for oxygen when the following equation is balanced using the lowest whole-number coefficients? C3H6O2(l) + O2(g) → CO2(g) + H2O(l)A) 5 B) 7 C) 1 D) 3
Answer:
Option (B) 7
Explanation:
C3H6O2(l) + O2(g) → CO2(g) + H2O(l)
To know the coefficient of O2 in the above equation, let us balance the equation.
The above equation can be balance as follow:
C3H6O2(l) + O2(g) → CO2(g) + H2O(l)
There are 3 atoms of C on the left side and 1 atom on the right side. It can be balance by putting 3 in front of CO2 as shown below:
C3H6O2(l) + O2(g) → 3CO2(g) + H2O(l)
There are 6 atoms of H on the left side and 2 atoms on the right side. It can be balance by putting 3 in front of H2O as shown below:
C3H6O2(l) + O2(g) → 3CO2(g) + 3H2O(l)
There are a total of 4 atoms of O on the left side and a total of 9 atoms on the right side. It can be balance by putting 7/2 in front of O2 as show below:
C3H6O2(l) + 7/2O2(g) → 3CO2(g) + 3H2O(l)
Multiply through by 2
2C3H6O2(l) + 7O2(g) → 6CO2(g) + 6H2O(l)
Now, the equation is balanced.
From the balanced equation above, the coefficient of O2 is 7.
What is the pH of a 0.1 M solution of acetic acid (pKa = 4.75)?
Answer:
[tex]pH=2.88[/tex]
Explanation:
Hello,
In this case, since dissociation of acetic acid is:
[tex]CH_3COOH\rightleftharpoons CH_3COO^-+H^+[/tex]
The equilibrium expression in terms of the acid dissociation constant is:
[tex]Ka=\frac{[CH_3COO^-][H^+]}{[CH_3COOH]}[/tex]
In such a way, in terms of the reaction extent, we write:
[tex]Ka=\frac{x*x}{0.1-x}[/tex]
And Ka is computed from the pKa:
[tex]Ka=10^{-pKa}=10^{-4.75}=1.78x10^{-5}[/tex]
[tex]1.78x10^{-5}=\frac{x*x}{0.1-x}[/tex]
Thus, solving for [tex]x[/tex] we obtain:
[tex]x=0.001325M[/tex]
Which is also equal to the concentration of H⁺ so the pH is:
[tex]pH=-log(0.001325)\\\\pH=2.88[/tex]
Regards.
Which of the following factors has no effect on the rate of SN1 reactions?a. the nature of the alkyl halide. b. the nature of the leaving group c. the concentration of the alkyl halide d. the concentration of the nucleophile e. the value of the rate constant
Answer:
the concentration of the nucleophile
Explanation:
In an SN1 mechanism, the rate determining step is the formation of the carbocation. The nucleophile does not appear in the rate equation because the rate determining step is unimolecular and entirely depends on the concentration of the alkyl halide.
Hence, the concentration of the nucleophile has no effect on the rate of an SN1 reaction because the rate determining step involves only the alkyl halide.
The factor which has no effect on the rate of SN¹ reaction is the concentration of the nucleophile.
What is SN¹ reaction?SN¹ reaction is known as unimolecular nucleophilic reaction, which is completed in two steps.
First step in the SN¹ reaction is the rate determining step i.e. that step determines the rate of reaction. And in this step formation of carbocation takes place because of the loss of leaving group from the reactant. So, rate of reaction is not depends on the concentration of attacking nucleophile.
Hence, option (d) is correct.
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1. Which of the following is a valid piece of scientific evidence?
a. The amount of snow pack in the mountains
b. The way a piece of music makes you feel
C. How many people like brownies more than cake
d. The color blue being called a calming color
Answer: A
Explanation: The other options are opinions and can vary in the way that people respond
The valid piece of scientific evidence among the options provided is:
a. The amount of snow pack in the mountains
Scientific evidence refers to observations or data that can be objectively measured, tested, and analyzed. The amount of snow pack in the mountains can be quantitatively measured and observed, making it a valid piece of scientific evidence. It can be used to study climate patterns, water availability, and various other scientific phenomena related to snow and mountain ecosystems.
The other options, b. The way a piece of music makes you feel, c. How many people like brownies more than cake, and d. The color blue being called a calming color, involve subjective experiences, personal preferences, and cultural associations rather than empirical observations that can be tested and measured in a scientific context.
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What is the amount of matter in an object? O Kilograms O Mass O Volume O Weight
Answer:
Mass
Explanation:
Mass measures the amount of matter in a substance or an object. The basic SI unit for mass is the kilogram (kg). Volume measures the amount of space that a substance or an object takes up.
The amount of matter in an object is given in terms of it's mass.
What is the relation between mass and weight?
Mass is defined as the combination of physical properties of an object and the resistance which object undergoes when force is applied to it.It contains total number of protons,electrons and neutrons present in the atom of an object.
Mass does not change according to location but weight does change according to location as the amount of gravity varies from one location to another.Mass can be measured using any kind of balance but weight is measured by using spring balance only.
The SI unit of mass is kilograms.Weight is defined as force exerted on an object due to the gravitational force.Weight and mass are directly proportional to each other.Their relation is based on Newton's second law of motion .Formula of weight is
w=m×g
where, w=weight of object
m=mass of an object
g=gravity acting on the object
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Prospectors are considering searching for gold on a plot of land that contains 2.45 g of gold per bucket of soil. If the volume of the bucket is 5.25L, how many grams of gold are there likely to be in 1.0 cubic feet of soil
Answer:
13.2 g of gold
Explanation:
We'll begin by converting 5.25 L to ft³.
This can be obtained as follow:
Recall:
1 L = 0.0353 ft³
Therefore,
5.25 L = 5.25 × 0.0353
5.25 L = 1.85×10¯¹ ft³
From the question given above,
2.45 g of gold is present in 5.25 L ( i.e 1.85×10¯¹ ft³) of soil.
Therefore, Xg of gold will be present in 1 ft³ of soil i.e
Xg of gold = 2.45/1.85×10¯¹
Xg of gold = 13.2 g
Therefore, 13.2 g of gold is present in 1 ft³ of the soil.
Convert 0.00000000045 to scientific notation.
Answer:
4.5 multiplied by 10, to the -10th power.
[tex](4.5 \times 10 { - }^{10} )[/tex]
Question 4 of 10
Which question asks for an opinion?
A. How much electricity does the average nuclear power plant
generate?
B. Should the government invest more money in nuclear energy than
in solar energy?
C. What are the by-products generated by the manufacture of solar
panels?
D. How efficient is the most advanced solar energy technology?
Answer:
Should the government invest more money in nuclear energy than
in solar energy
Explanation:
This is because some people might think government should invest in nuclear energy while others might want the government to invest in solar energy.
Answer:
B. "Should the government..."; the answer to this relies on subjective input (what the audience thinks the government should do).
Explanation:
Think about the differences between statements that are subjective and objective. If you look at A, C, or D, these results of these experiments are all objective:
A) The amount of electricity generated by a power plant isn't "arguable"; it's a definite value that I can't just "make up" or "think" is correct/valid.
C) The byproducts generated by manufacture aren't "arguable" either; if a byproduct is heat, there's no subjective input.
D) Try to use the above reasoning for D!
From this value, and assuming that air contains only molecular nitrogen and molecular oxygen gases, calculate the mass percent of N2 and of O2 in air.
Answer:
60% and 52%
Explanation:
At Standard temperature and volume (STP)
Volume of gas = 22.4L
Density = mass/volume
⇒ 1.186 = [tex]\frac{mass}{22.4}[/tex]
= 26.566g
Molar mass of O2 = 16g/mole
Molar mass of N2 = 14g/mol
% mass of O2 = 16/26.566 × 100
= 60.23 %
% mass of N2 = 14/26.566 × 100
= 52.70 %
(Check: totl composition of gas is 100% i.e 60 + 52 %)
Which of the following equilibria would not be affected by pressure changes at constant temperature?
A) CO(g) + 1/2O2(g) CO2(g).
B) CaCO3(s) CaO(s) + CO2(g).
C) 2H2(g) + O2(g) 2H2O(l).
D) 2Hg(l) + O2(g) 2HgO(s).
E) CO2(g) + H2(g) CO(g) + H2O(g).
Answer:
Option A) CO(g) + 1/2O2(g) <=> CO2(g).
Explanation:
A background knowledge of reaction rates shows that pressure will only affect gaseous reactant.
Further more, we understood that for pressure to effectively affect gaseous molecules, the total volume of the gaseous reactant must be different from the total volume of the gaseous products.
Now, let us consider the equation given in the question:
A) CO(g) + 1/2O2(g) <=> CO2(g).
B) CaCO3(s) <=> CaO(s) + CO2(g).
C) 2H2(g) + O2(g) <=> 2H2O(l).
D) 2Hg(l) + O2(g) <=> 2HgO(s).
E) CO2(g) + H2(g) <=> CO(g) + H2O(g).
From the above, only option A and E has gaseous reactant and product.
For option A:
CO(g) + 1/2O2(g) <=> CO2(g).
Total volume of reactant = 1 + 1/2 = 3/2 L
Total volume of product = 1 L
Since the volume of the reactant and that of the product are different, therefore, a change in pressure will affect the reaction.
For option E:
CO2(g) + H2(g) <=> CO(g) + H2O(g).
Total volume of reactant = 1 + 1 = 2 L
Total volume of product = 1 + 1 = 2 L
Since the volume of the reactant and that of the product are the same, therefore, a change in pressure will have no effect in the reaction.
The equilibrium equation, CO2(g) + H2(g) ⇄ CO(g) + H2O(g), is not affected by pressure changes at constant temperature because there are equal volumes of reactants and products on both sides of reaction equation.
For a gas phase reaction, changes in pressure would affect the direction in which the reaction moves. When the pressure is increased, the reaction moves in the direction of lesser volumes. When the pressure is decreased, the reaction moves in the direction of greater volumes.
For the reaction; CO2(g) + H2(g) ⇄ CO(g) + H2O(g), there are equal volumes of reactants and products on either side of the reaction equation. Therefore, the equilibria would not be affected by pressure changes at constant temperature.
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Water flows over Niagara Falls at the average rate of 2,400,000 kg/s, and the average height of the falls is about 50 m. Knowing that the gravitational potential energy of falling water per second = mass (kg) × height (m) × gravity (9.8 m/s2), what is the power of Niagara Falls? How many 15 W LED light bulbs could it power?
Answer:
Power, [tex]P=1.176\times 10^9\ W[/tex]
No of bulbs = 78400000
Explanation:
We have,
Water flows over Niagara Falls at the average rate of 2,400,000 kg/s, it mean it is mass per unit time i.e. m/t.
It falls from a height of 50 m
The gravitational potential energy of falling water is given by :
P = mgh
Power is equal to the work done divided by time taken. So,
[tex]P=\dfrac{W}{t}\\\\P=\dfrac{mgh}{t}\\\\P=\dfrac{m}{t}\times gh[/tex]
So,
[tex]P=2400000\times 9.8\times 50\\\\P=1.176\times 10^9\ W[/tex]
Let there are n bulbs that could power 15 W LED. It can be calculated by dividing the power by 15. So,
[tex]n=\dfrac{1.176\times 10^9}{15}\\\\n=78400000\ \text{bulbs}[/tex]
It means that the number of bulbs are 78400000.
Consider a lithium nucleus, of charge +3q. Calculate the first three electron energies for an electron in a Li++ ion, using the Bohr model.
Answer:
[tex]\mathbf{E_1 = -40.8 \ eV}[/tex]
[tex]\mathbf{E_2= -10.2 \ eV}[/tex]
[tex]\mathbf{E_3=-4.533 \e V}[/tex]
Explanation:
In an hydrogen like atoms, the formula related to the energy of an nth quantum number is:
[tex]E_n =\dfrac{ -13.6 \times Z}{n^2}[/tex]
where;
lithium Z = 3
therefore, the energy levels for Li²⁺ are
n=1 , n=2, n= 3
[tex]E_1 =\dfrac{ -13.6 \times 3}{1^2}[/tex]
[tex]E_1 = -13.6 \times 3[/tex]
[tex]\mathbf{E_1 = -40.8 \ eV}[/tex]
[tex]E_2=\dfrac{ -13.6 \times 3}{2^2}[/tex]
[tex]E_2=\dfrac{ -13.6 \times 3}{4}[/tex]
[tex]\mathbf{E_2= -10.2 \ eV}[/tex]
[tex]E_3=\dfrac{ -13.6 \times 3}{3^2}[/tex]
[tex]E_3=\dfrac{ -13.6 \times 3}{9}[/tex]
[tex]\mathbf{E_3=-4.533 \e V}[/tex]
g the __ of the partial pressures of each gas in a mixture must equal the total pressure of the enntire gas mixture
Answer:
Sum.
Explanation:
Hello,
In this case, the Dalton's law states that the SUM of the partial pressures of each gas in a mixture must equal the total pressure of the entire gas mixture, considering its mathematical definition for a i-containing gas mixture:
[tex]P_t=P_1+P_2+...+P_i[/tex]
Regards.
The atomic number of an atom is always equal to the total number of
neutrons in the nucleus
neutrons plus protons in the atom
protons in the nucleus
protons plus electrons in the atom
The amount of protons in the nucleus multiplied by the atomic number of an atom results in a constant value.
Why do protons exist?a fundamental unit of matter that shares the same structure as the hydrogen atom's nucleus, makes up all other atomic nuclei together with the neutron, has a mass of 1.673 1027 kilograms, and carries a positive charge that is numerically equal to the charge of an electron.
What materials make up protons?Two up quarks as well as a down quark combine to form protons. One up quark with two down quarks make up neutrons. The nucleus is kept together by one of the four basic forces known as the "strong nuclear force."
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What is milk made of?
Answer:
Protein
Explanation:
Answer:
Water, fat, proteins, lactose, and minerals. Milk also contains trace amounts of other substances such as pigments, enzymes, vitamins, phospholipids, and gases.
In 1.00 mol of potassium zirconium sulfate trihydrate, K4Zr(SO4)4.3 H20, there are
A
3 x 6.02 x 10 hydrogen atoms
23
B
6.02 x 1023 sulfur atoms
с
4* 6.02 x 1023 potassium atoms
D
4 moles of oxygen atoms
E
4 moles of zirconium atoms
Answer:
C. 4 × 6.02 × 10²³ potassium atoms.
Explanation:
In 1.00 mol of potassium zirconium sulfate trihydrate, K₄Zr(SO₄)₄.3 H₂O, there are
A . 3 × 6.02 × 10²³ hydrogen atoms. NO. There are 3 × 2 moles of hydrogen atoms = 6 moles of hydrogen atoms = 6 × 6.02 x 10²³ hydrogen atoms
B. 6.02 × 10²³ sulfur atoms. NO. There are 4 moles of sulfur atoms = 4 × 6.02 × 10²³ sulfur atoms
C. 4 × 6.02 × 10²³ potassium atoms. YES. There are 4 moles of potassium atoms = 4 × 6.02 × 10²³ potassium atoms
D . 4 moles of oxygen atoms. NO. There are 4 × 4 moles of oxygen atoms = 16 moles of oxygen atoms
E . 4 moles of zirconium atoms NO. There is 1 mole of zirconium atoms
Identify the predominant intermolecular forces in each of these substances.
1. H2O
2. CaCl2
3. CH3CH(CH3)OH
4. CH4
5. NH3
Answer:
H2O- hydrogen bonding
CaCl2- ion-ion interaction
CH3CH(CH3)OH- hydrogen bonding
CH4- dispersion forces
NH3- hydrogen bonding
Explanation:
Intermolecular forces are secondary bond forces that hold the molecules of a substance together in a given state of matter.
Intermolecular forces account for quite a number of the observed physical properties of a substance such as the boiling and melting point.
If a compound contains hydrogen atom bonded to a highly electronegative element, hydrogen bonding becomes the most dominant intermolecular force, e.g in water and ammonia.
For nonpolar molecules, dispersion forces are the most dominant intermolecular forces. In ionic substance, ion-ion interaction becomes quite prominent.
A sample of ammonia gas was allowed to come to equilibrium at 400 K. 2NH3(g) <---> N2(g) 3H2(g) At equilibrium, it was found that the concentration of H2 was 0.0551 M, the concentration of N2 was 0.0183 M, and the concentration of NH3 was 0.383 M. What is Kc for this equilibrium
Answer:
Kc for this equilibrium is 2.30*10⁻⁶
Explanation:
Equilibrium occurs when the rate of the forward reaction equals the rate of the reverse reaction and the concentrations of reactants and products are held constant.
Being:
aA + bB ⇔ cC + dD
the equilibrium constant Kc is defined as:
[tex]Kc=\frac{[C]^{c}*[D]^{d} }{[A]^{a} *[B]^{b} }[/tex]
In other words, the constant Kc is equal to the multiplication of the concentrations of the products raised to their stoichiometric coefficients by the multiplication of the concentrations of the reactants also raised to their stoichiometric coefficients. Kc is constant for a given temperature, that is to say that as the reaction temperature varies, its value varies.
In this case, being:
2 NH₃(g) ⇔ N₂(g) + 3 H₂(g)
the equilibrium constant Kc is:
[tex]Kc=\frac{[N_{2} ]*[H_{2} ]^{3} }{[NH_{3} ]^{2} }[/tex]
Being:
[N₂]= 0.0551 M[H₂]= 0.0183 M[NH₃]= 0.383 Mand replacing:
[tex]Kc=\frac{0.0551*0.0183^{3} }{0.383^{2} }[/tex]
you get:
Kc= 2.30*10⁻⁶
Kc for this equilibrium is 2.30*10⁻⁶
At 25°C, an aqueous solution containing 35.0 wt% H2SO4 has a specific gravity of 1.2563. A quantity of the 35% solution is needed that contains 195.5 kg of H2SO4.
A) Calculate the required volume (L) of the solution using the given specific gravity.
B) Estimate the percentage error that would have resulted if pure-component specific gravities of H2SO4 (SG = 1:8255) and water had been used for the calculation instead of the given specific gravity of the mixture.
Answer:
a) volume₁ = 444.6 L
b) Volume₂ = 306 L and percentage Error = 31.2%
Explanation:
Given that;
the solution contains 35.0 wt% H₂SO₄
A quantity of the 35% solution is needed that contains 195.5 kg of H₂SO₄
Lets say mass of solution containing 195.5 kg H₂SO₄ is 'A' kg
Now since the question saysm it is a 35% wt solution,
so
(35/ 100) × Akg = 195.5kg
0.35A = 195.5
A = 558.6kg
So A = 558.6 kg
therefore mass of the solution is 558.6kg
a)
also Specific gravity is 1.2563
since density of water = 1kg/ L
density of solution = SG of H₂SO₄ × density of water
therefore density of solution = 1.2563 ×1kg/ L = 1.2563 kg/ L
Now to calculate the required volume (L) of the solution
we say;
Volume of solution = mass / density
Volume = 558.6kg / 1.2563kg/L
Volume₁ = 444.6 L
b)
Now If pure-component specific gravity is to be used,
Specific Gravity = 1.8255
which means Density will be = 1.8255 kg/ L
Therefore will be
Volume = 558.6kg / 1.8255kg/L
Volume₂ = 306 L
To calculate the error
we say volume₁ - volume₂
Error = 444.6L - 306L = 138.6
So
Percent error = ( 138.6L / 444.6L) × 100
percentage Error = 31.2%
For each pair, give the relationship between the two compounds. Making models will be helpful.
(a) (2R, 3S)-2, 3-dibromohexane and (2S, 3R)-2, 3-dibromohexane
(b) (2R, 3S)-2, 3-dibromohexane and (2R, 3R)-2, 3-dibromohexane
Answer:
(a) Enantiomers
(b) Diastereomers
Explanation:
In the first pair of molecules, we have an opposite configuration. That is, in the first molecule we have an R and S configuration and in the second an S and R configuration. Therefore we have a mirror image, if this is true, we will have a mirror image and we will have "enantiomers". (See figure 1)
In the second pair of molecules, we do not have a mirror image. Since the first molecule has an R, S configuration (the mirror image would be S, R). In the second molecule, we have an R, R configuration (the mirror image would be S, S). Therefore, the relationship between these molecules is "diastereoisomers". (See figure 2)
Convert a speed of 857 mi/h to units of feet per minute. Also, show the unit analysis by dragging components into the
unit-factor slots.
Answer Bank
857 mi
х
1 h
f)x()
1 min
60 s
12 in
60 min
1 mi
3 ft
1 h
60 h
5280 ft
1 ft
857 mi/h =
ft
min
Answer:
The answer would be 75,416 feet / minute.
And the conversion would be: 857 miles / 1 h = (1h / 60 minutes) (5280 feet / 1 mile)
Explanation:
Conversion factors are mathematical operations used to make unit changes of the same magnitude, in magnitudes of weight, time, or length. etc.
It consists of multiplying one or more fractions several times in which the numerator and the denominator are equal quantities expressed in different ways.
For example: 1 hour = 60 minutes = 3600 seconds.
857 miles / 1 hr = (1h / 60 minutes) (5280 feet / 1 mile)
Write the formulas for: Ca and CI, Na and CI, H and 0, Al and 0, and K and F.
Answer:
Below
Explanation:
Combination of Calcium(Ca) and Chlorine(Cl); Calcium chloride
[tex]Ca+Cl_2 -> CaCl_2[/tex]
Combination of Sodium(Na) and Chlorine(Cl); Sodium chloride(salt)
[tex]Na+Cl_2 -> NaCl[/tex]
Combination of Hydrogen(H) and Oxygen(O);(water)
[tex]H_2 +O_2-> H_2O[/tex]
Combination of Potassium (K) and Fluorine(f) ; Potassium fluoride
[tex]K+F ->KF[/tex]