Relative supersaturation refers to the excess amount of solute present in a solution compared to its equilibrium concentration. It is an important parameter that affects the nucleation and growth of crystals from solution. In this case, we are interested in the effect of relative supersaturation on the primary, homogeneous nucleation of BaSO4 from an aqueous solution at 25°C, given the crystal density and interfacial tension.
Homogeneous nucleation occurs when nucleation sites are created spontaneously throughout the solution, without any external influence. It is a stochastic process that depends on the concentration of the solute, temperature, and interfacial tension. The critical relative supersaturation, S*, is the minimum value of supersaturation required for the onset of nucleation. Below S*, no nucleation occurs, while above S*, nucleation becomes spontaneous and rapid.
The expression for S* is given by the classical nucleation theory as:
S* = (2γv/ρkTln(S))^(1/2)
where γv is the interfacial tension, ρ is the crystal density, k is the Boltzmann constant, T is the temperature, and S is the relative supersaturation.
Substituting the given values, we get:
S* = (2 x 0.12 J/m2 x (4.50 g/cm3) / (1.38 x 10^-23 J/K x 298 K x ln(S)))^(1/2)
Simplifying this expression, we get:
S* = (4.32 x 10^12 / ln(S))^(1/2)
Now, let's assume a relative supersaturation value of 1.5. Substituting this value in the above equation, we get:
S* = (4.32 x 10^12 / ln(1.5))^(1/2)
S* = 3.94 x 10^6
This means that the critical relative supersaturation for homogeneous nucleation of BaSO4 from an aqueous solution at 25°C is 3.94 x 10^6. Any relative supersaturation value above this will lead to spontaneous and rapid nucleation of BaSO4 crystals. It is important to note that this value is only an estimate based on the classical nucleation theory and may not accurately reflect the actual nucleation behavior in a real system.
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Why are different lines used in sketches of possible solutions
Different lines are used in sketches of possible solutions to represent various elements, features, or conditions in a clear and organized manner.
Differentiating components: Different lines help to distinguish between different components or objects in a sketch. For example, solid lines may represent the main parts or visible surfaces, while dashed or dotted lines may indicate hidden or obscured elements.
Showing dimensions: Lines with specific patterns, such as arrows or tick marks, are used to indicate dimensions in a sketch. These lines help provide measurements and convey the size, length, or height of various features accurately.
Depicting movement or alignment: Lines can also be used to represent movement, paths, or alignments. For instance, curved lines might indicate flow or rotation, while straight lines can show linear motion or alignment of elements.
Indicating different materials or sections: Differently styled lines, such as cross-hatching or stippling, are often employed to represent different materials or sections in a sketch. This helps to communicate distinctions in textures, materials, or cross-sectional views.
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Why do chlorine atoms like to form -1 charged anions?
a.because chlorine has a very large atomic radius
b.because chlorine’s electron configuration is one electron short of a filled principal quantum number shell.
c.because chlorine is a relatively heavy atom
d.because chlorine has a very high ionization potential
e.because chlorine is a metallic substance
Option b is the correct answer. The other options are not related to the formation of anions by chlorine.
The reason why chlorine atoms like to form -1 charged anions is because of its electron configuration. Chlorine has one electron short of a filled principal quantum number shell, which means it can gain an electron to achieve a stable octet configuration.
This process results in the formation of a negatively charged ion, or an anion, with a charge of -1. The reason why chlorine atoms like to form -1 charged anions is because chlorine's electron configuration is one electron short of a filled principal quantum number shell (option b).
When a chlorine atom gains one electron, it achieves a stable electron configuration similar to that of a noble gas, which is energetically favorable. This process results in the formation of a negatively charged anion, Cl-.
Therefore, option b is the correct answer. The other options are not related to the formation of anions by chlorine.
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Find the temperature of a gas system constrained to a volume of 1758ml if the pressure is measured as. 84 atm. The system contains 5. 0mol of gas
To find the temperature of a gas system with a volume of 1758 mL and a pressure of 0.84 atm, containing 5.0 mol of gas, we can use the ideal gas law equation PV = nRT.
Where:
P = Pressure (in atm)
V = Volume (in liters)
n = Number of moles
R = Ideal gas constant (0.0821 L·atm/mol·K)
T = Temperature (in Kelvin)
First, we need to convert the volume from milliliters (mL) to liters (L):
V = 1758 mL = 1758 mL / 1000 mL/L = 1.758 L
Next, we can rearrange the ideal gas law equation to solve for temperature:
T = PV / (nR)
Substituting the given values:
T = (0.84 atm) * (1.758 L) / (5.0 mol * 0.0821 L·atm/mol·K)
Calculating this expression gives us:
T = 17.4 K
Therefore, the temperature of the gas system constrained to a volume of 1758 mL, with a pressure of 0.84 atm, and containing 5.0 mol of gas is approximately 17.4 Kelvin.
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A mixture of nitrogen and oxygen in a 1:3 ratio has a volume of 4. 00 L.
What is the volume of the nitrogen trioxide when the nitrogen and oxygen
react according to the equation:
N2 (g) + 3 02 (g) → 2 NO, (g)
while keeping pressure and temperature constant?
lol
The volume of nitrogen trioxide produced from a mixture of nitrogen and oxygen in a 1:3 ratio, reacting according to the equation N2 (g) + 3 O2 (g) → 2 NO, (g) while keeping pressure and temperature constant, is 2.67 L.
To determine the volume of nitrogen trioxide produced, we first need to find the limiting reactant. Since the ratio of nitrogen to oxygen is 1:3, we can say that for every 1 unit of nitrogen, we have 3 units of oxygen.
Therefore, the amount of oxygen present in the mixture is 3/4 * 4 L = 3 L, and the amount of nitrogen present is 1/4 * 4 L = 1 L.
Since we need 1 unit of nitrogen for every 3 units of oxygen for the reaction to occur, we can see that nitrogen is the limiting reactant.
Thus, all 1 L of nitrogen will react to form 2 L of nitrogen trioxide (using the stoichiometric coefficients in the balanced equation).
Finally, we apply the ideal gas law to find the volume of nitrogen trioxide at the same pressure and temperature: V2 = n2 * RT / P = (2 mol * 0.082 L*atm / (mol*K) * 298 K) / 1 atm = 2.67 L.
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Rank the following from weakest intermolecular forces to strongest. justify your answers. h2se h2s h2po h2te
The ranking of the given molecules from weakest to strongest intermolecular forces is: H2S < H2Se < H2Te < H2PO
This ranking is based on the size, dipole moments, and polarity of each molecule, which are factors that contribute to the strength of their intermolecular forces. Also ranking is based on the trend of increasing atomic size down the group. As we move down the group, the atomic size increases which results in larger electron clouds and hence stronger intermolecular forces. 1. H2S: Weakest intermolecular forces due to its small size and relatively low dipole moment. 2. H2Se: Slightly stronger intermolecular forces than H2S because it has a larger size and a higher dipole moment. 3. H2Te: Stronger intermolecular forces due to its larger size and higher dipole moment compared to H2Se and H2S. 4. H2PO: Strongest intermolecular forces because it has a significant dipole moment, making its overall polarity higher than the other molecules listed.
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1. Using average bond enthalpies (linked above), estimate the enthalpy change for the following reaction:
CH3Cl(g) + Cl2(g)CH2Cl2(g) + HCl(g)
_______ kJ
2.
Bond Bond Energy (kJ/mol)
H-H 436
O=O 498
O-O 146
H-O 463
Using the values of bond energy from the table above, estimate the enthalpy change for the following reaction:
H2(g) + O2(g) H2O2(g)
_______ kJ
1. The enthalpy change for the reaction is - 104 kJ.
2. The enthalpy change for the reaction is - 138 kJ.
1. The chemical reaction is as :
CH₃Cl(g) + Cl₂(g) ----> CH₂Cl₂(g) + HCl(g)
The Bond Energy (kJ/mol)
The bond energy, C-H = 414
The bond energy, Cl - Cl = 243
The bond energy, H-Cl = 431
The bond energy, C-Cl = 330
The enthalpy change is as :
ΔH = ∑ H reactant - ∑ H product
ΔH = ( 3 × Hc-h + Hc-cl + Hcl-cl ) - ( 2 × Hc-h + 2 × Hc-cl + Hh-cl)
ΔH = ( 3 × 414 + 330 + 243 ) - ( 2 × 414 + 2 × 330 + 431 )
ΔH = - 104 kJ
2. The chemical reaction is :
H₂ + O₂ ---> H₂O₂
The Bond Energy (kJ/mol)
The bond energy, H-H = 436
The bond energy, O=O = 498
The bond energy, O-O = 146
The bond energy, H-O = 463
The enthalpy change is as :
ΔH = ∑ H reactant - ∑ H product
ΔH = ( H-H + O=O ) - ( 2 × O-H + (O-O)
ΔH = ( 436 - 498 ) - (2 ×463 + 146 )
ΔH = - 138 kJ.
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calculate the vapor pressure in a sealed flask containing 15.0 g of glycerol, c3h8o3 , dissolved in 105 g of water at 25.0°c.
The vapor pressure in a sealed flask containing 15.0 g of glycerol, C₃H₈O₃, dissolved in 105 g of water at 25.0°c is approximately 23.10 mmHg.
To calculate the vapor pressure in the sealed flask, we need to use the Raoult's Law formula: P_solution = X_water * P_water, where X_water is the mole fraction of water in the solution, and P_water is the vapor pressure of pure water at 25.0°C.
First, calculate the moles of glycerol and water:
- Glycerol (C₃H₈O₃) has a molar mass of 92.09 g/mol: moles of glycerol = 15.0 g / 92.09 g/mol = 0.163 moles
- Water (H₂O) has a molar mass of 18.01 g/mol: moles of water = 105 g / 18.01 g/mol = 5.83 moles
Next, calculate the mole fraction of water (X_water):
X_water = moles of water / (moles of water + moles of glycerol) = 5.83 / (5.83 + 0.163) = 0.973
Now, use the vapor pressure of pure water at 25.0°C, which is approximately 23.76 mmHg:
P_solution = X_water * P_water = 0.973 * 23.76 mmHg = 23.10 mmHg
Thus, the vapor pressure in the sealed flask containing 15.0 g of glycerol is approximately 23.10 mmHg.
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Draw the major product of this reaction. Ignore inorganic byproducts and CO2. o 1. KMnO4, OH- (warm) 2. H3O+
The given reaction involves the oxidation of an organic compound by potassium permanganate (KMnO4) in basic medium (OH-). The intermediate formed in this step is an unstable compound that further reacts with H3O+ in acidic medium to form the final product.
To draw the major product of the reaction with the given reagents, follow these steps:
1. The reactant undergoes oxidation using KMnO4 and OH- under warm conditions. This step involves the cleavage of any carbon-carbon double bonds and converting them into carbonyl groups (C=O).
2. The addition of H3O+ in the next step results in the hydration of carbonyl groups, forming geminal diols (two -OH groups on the same carbon).
The major product formed in this reaction is a carboxylic acid. The exact compound formed will depend on the starting material. The reaction of KMnO4 with a primary alcohol forms a carboxylic acid as the major product.
Therefore, the answer to the question "Draw the major product of this reaction. Ignore inorganic byproducts and CO2. o 1. KMnO4, OH- (warm) 2. H3O+" is a carboxylic acid. Without knowing the exact structure of the starting material, I cannot provide a specific structure for the major product. However, the general outcome of the reaction involves the conversion of carbon-carbon double bonds to geminal diols.
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a polymer is choose... made of choose... , known as choose... . polymers can be natural, such as choose... , or synthetic, such as choose... .
A polymer is a type of macromolecule made of repeating subunits, known as monomers. Polymers can be natural, such as cellulose or proteins, or synthetic, such as plastics or nylon.
A polymer is a large molecule made of many smaller units called monomers. These monomers bond together to form a long chain. The repeating structure of monomers gives a polymer its unique properties, such as strength and flexibility.
Polymers are a diverse class of materials that are made up of repeating subunits, or monomers. These monomers can be organic or inorganic, and they are connected through covalent bonds to form a chain-like structure. The repeating pattern of monomers gives a polymer its unique properties, such as strength, flexibility, and durability.
Polymers can be natural or synthetic. Natural polymers are produced by living organisms and include proteins, cellulose, and DNA. Synthetic polymers, on the other hand, are produced through chemical reactions in a laboratory. Examples of synthetic polymers include plastics, nylon, and rubber.
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Solve 0. 0853 + 0. 05477 + 0002 report the answer to correct number of significant figures
The sum of 0.0853, 0.05477, and 0.0002, reported to be the correct number of significant figures, is 0.14.
When performing addition or subtraction with numbers, it is important to consider the significant figures in the given values and report the final answer with the appropriate number of significant figures. In this case, the number 0.0853 has four significant figures, 0.05477 has five significant figures, and 0.0002 has only one significant figure.
To determine the correct number of significant figures in the sum, we need to consider the least precise value, which is 0.0002 with one significant figure. Therefore, the final answer should also have one significant figure. Adding up the given values, we get 0.14 as the sum, which is reported to be one significant figure.
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True/False: if the carbon dioxide gas is captured in the bottle, the product is called table wine.
The given statement if the carbon dioxide gas is captured in the bottle, the product is called table wine is False .
Table wine refers to still wine without significant carbonation. Sparkling wine, such as Champagne, has noticeable carbon dioxide bubbles, which are often captured in the bottle during the fermentation process. Whether or not a wine is considered table wine has nothing to do with whether carbon dioxide gas is captured in the bottle. Table wine is a term used to describe still wine that contains between 7% and 14% alcohol by volume (ABV). Wines with higher ABV are typically classified as dessert wines or fortified wines.
Sparkling wine, on the other hand, is wine that contains significant amounts of dissolved carbon dioxide, resulting in bubbles and a fizzy texture. This can be achieved through a secondary fermentation in the bottle or tank, or by adding carbon dioxide artificially.
Therefore, capturing carbon dioxide gas in a bottle alone is not enough to determine whether a wine is table wine or not. Hence, If the carbon dioxide gas is captured in the bottle, the product is not called table wine; instead, it is called sparkling wine.
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fill in the blank. a piece of pie rated at 400 calories is equivalent to _________ calories of thermal energy or __________ joules of mechanical energy.
A piece of pie rated at 400 calories is equivalent to 1674.4 calories of thermal energy or 7009.6 joules of mechanical energy.
The calorie is a unit of energy commonly used to measure the energy content of food. One calorie is defined as the amount of energy needed to raise the temperature of one gram of water by one degree Celsius. However, in physics, the unit for energy is the joule. One calorie is equal to 4.184 joules.
When we consume food, the body metabolizes it to release energy in the form of ATP, which is used by the body for various physiological processes. The amount of energy released by the food is equivalent to the amount of calories it contains.
In physics, energy can take many forms, including thermal energy and mechanical energy. Thermal energy refers to the energy associated with the temperature of an object, while mechanical energy refers to the energy associated with the motion or position of an object.
To convert the 400 calories of energy in the pie to thermal energy, we simply multiply it by the conversion factor of 4.184. This gives us 1674.4 calories of thermal energy.
To convert the 400 calories of energy in the pie to mechanical energy, we need to consider the efficiency of the body in converting food energy to mechanical energy. The human body is not very efficient in this regard, with only about 20-25% of the energy in food being converted to mechanical energy.
Therefore, to convert the 400 calories of energy in the pie to mechanical energy, we need to multiply it by the efficiency factor of 0.25. This gives us 100 calories of mechanical energy, which is equivalent to 7009.6 joules.
In summary, the 400 calories of energy in a piece of pie can be converted to 1674.4 calories of thermal energy or 7009.6 joules of mechanical energy. This demonstrates the importance of understanding the unit of energy being used in a particular context, and the conversion factors required to convert between different units of energy.
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what is the ph of a buffer prepared with 0.30 m h2s and 0.15 m hs− , if the ka of hydrosulfuric acid is 9.1 × 10-8? h2s(aq) h2o(l) ⇋ h3o (aq) hs−(aq)
Now, we can plug in the values for [A-] and [HA] into the Henderson-Hasselbalch equation: pH = 3.82 + log(0.15/0.30) pH = 3.52 (long answer)
To find the pH of a buffer prepared with 0.30 M H2S and 0.15 M HS−, we need to use the Henderson-Hasselbalch equation:
pH = pKa + log([A-]/[HA])
where pKa is the acid dissociation constant, [A-] is the concentration of the conjugate base (HS−), and [HA] is the concentration of the acid (H2S).
First, we need to find the pKa of hydrosulfuric acid (H2S) using the given Ka value:
Ka = [H3O+][HS−]/[H2S]
9.1 × 10-8 = x^2/0.30
x = [H3O+] = [HS−] = 1.51 × 10-4 M
pH = -log[H3O+] = 3.82
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a sample of a noble gas has a mass of 980 mg. its volume is 0.270 l at a temperature of 88 °c and a pressure of 975 mmhg. identify the gas by answering with the symbol.
A noble gas is helium, weighs 980 mg and occupies a volume of 0.270 L at a temperature of 88 °C and a pressure of 975 mmHg.
To determine the identity of the gas, we can use the ideal gas law, which relates the pressure (P), volume (V), temperature (T), and number of moles of gas (n) using the gas constant (R): PV = nRT
We can rearrange this equation to solve for the number of moles: n = PV/RT
Substituting the given values and converting units to SI units: P = 975 mmHg = 129,982.8 Pa
V = 0.270 L = 0.270 x 10^-3 m^3
T = 88 °C = 361.15 K
R = 8.314 J/mol•K
We can calculate the number of moles of gas: n = (129,982.8 Pa x 0.270 x 10^-3 m^3) / (8.314 J/mol•K x 361.15 K) = 0.011 mol
Next, we can calculate the molar mass of the gas: M = mass / n = 980 mg / 0.011 mol = 89 g/mol
The molar mass of helium is 4 g/mol, which is much smaller than the calculated molar mass. Therefore, we can conclude that the gas is helium (He), which is a noble gas and has a molar mass of 4 g/mol.
The ideal gas law is a fundamental equation in thermodynamics that relates the physical properties of a gas to each other. It is an equation of state for a gas, which means that it describes the relationship between the state variables of the gas, such as pressure, volume, and temperature.
The ideal gas law assumes that the gas is composed of particles that are in constant random motion, and that the volume of the particles is negligible compared to the volume of the container. The law also assumes that there are no intermolecular forces between the particles of the gas.
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calculate the solubility of naphthalene at 25 egree c in any solvent in which it forms an ideal solution. The melting point of naphthalene is 80'C, and the enthalphy of fusion is 19.29 kJ/mol. The measured solubility of napthalene in benzene is x1=0.296
The solubility of naphthalene at 25°C in an ideal solution can be calculated using Raoult's law:
S = x1 * Psat
where S is the solubility of naphthalene, x1 is the mole fraction of naphthalene in the solution, and Psat is the vapor pressure of pure naphthalene at 25°C.
Since naphthalene is a solid at 25°C, its vapor pressure is negligible, and we can assume Psat = 0. Therefore, the solubility of naphthalene in an ideal solution at 25°C is zero.
However, if we consider the melting point and enthalpy of fusion of naphthalene, we can estimate its solubility in a solvent such as benzene, in which it forms an ideal solution. The enthalpy of fusion indicates the energy required to melt one mole of naphthalene, and the melting point is the temperature at which this occurs.
If we assume that the solubility of naphthalene in benzene is also governed by Raoult's law, we can write:
ΔHfus / R * (1/Tm - 1/T) = ln(x1 / (1-x1))
where ΔHfus is the enthalpy of fusion, R is the gas constant, Tm is the melting point of naphthalene (353 K), T is the temperature at which we want to calculate the solubility, and x1 is the experimentally measured mole fraction of naphthalene in benzene (0.296).
Solving for x1 at 25°C (298 K), we get:
x1 = exp(-ΔHfus / R * (1/Tm - 1/T))
x1 = exp(-19.29 * 10^3 / (8.314 * 353) * (1/353 - 1/298))
x1 = 0.023
Therefore, the estimated solubility of naphthalene in benzene at 25°C is 0.023, assuming that naphthalene forms an ideal solution in benzene and that its solubility is governed by Raoult's law.
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Write a balanced chemical reaction, complete ionic equation and net ionic equation for the following equations
I apologize, but you haven't provided any specific chemical equations for me to generate the balanced chemical reaction, complete ionic equation, and net ionic equation. Please provide the specific chemical equation you would like me to work with.
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Complete question
If it take 87 mL of 6. 4 M Ba(OH)2 solution to completely neutralize 5. 5 M of HI
solution, what is the volume of the Hl solution needed?
The concept of molarity (M) and the stoichiometry of the balanced chemical equation between Ba(OH)2 and HI. The balanced equation is Ba(OH)2 + 2HI -> BaI2 + 2H2O.
From the equation, we can see that 1 mole of Ba(OH)2 reacts with 2 moles of HI. First, we need to calculate the number of moles of Ba(OH)2 used:
Molarity (M) = moles of solute / volume of solution (L)
Rearranging the equation, moles of solute = Molarity × volume of solution (L)
Moles of Ba(OH)2 = 6.4 M × 0.087 L = 0.5568 moles
Since the stoichiometry of the balanced equation tells us that 1 mole of Ba(OH)2 reacts with 2 moles of HI, we can conclude that 0.5568 moles of Ba(OH)2 will react with (0.5568 × 2) = 1.1136 moles of HI.
Now, we can calculate the volume of the HI solution needed:
Volume of HI solution (L) = moles of HI / Molarity of HI
Moles of HI = 1.1136 moles
Molarity of HI = 5.5 M
Volume of HI solution = 1.1136 moles / 5.5 M = 0.2021 L or 202.1 mL Therefore, approximately 202.1 mL of the HI solution is needed to completely neutralize the 87 mL of 6.4 M Ba(OH)2 solution.
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3. write the balanced chemical reaction between sodium oxalate, na2c2o4 , reacts with potassium permanganate in acidic solution.
The balanced chemical equation for the reaction between sodium oxalate (Na2C2O4) and potassium permanganate (KMnO4) in acidic solution is:
5Na2C2O4 + 2KMnO4 + 8H2SO4 → 2MnSO4 + 10CO2 + 5Na2SO4 + K2SO4 + 8H2O
In this reaction, sodium oxalate reacts with potassium permanganate in acidic solution. The acid used in this reaction is sulfuric acid (H2SO4). The reaction results in the formation of manganese sulfate (MnSO4), carbon dioxide (CO2), sodium sulfate (Na2SO4), potassium sulfate (K2SO4), and water (H2O).
To balance the equation, we need to ensure that the number of atoms of each element is equal on both sides of the equation. In the balanced equation, we can see that there are 5 moles of Na2C2O4, 2 moles of KMnO4, and 8 moles of H2SO4 on the left-hand side, and 2 moles of MnSO4, 10 moles of CO2, 5 moles of Na2SO4, 1 mole of K2SO4, and 8 moles of H2O on the right-hand side. This ensures that the law of conservation of mass is followed, and no atoms are lost or gained during the reaction.
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An athlete had 14% body fat by mass. What is the weight of fat, in pounds, of a 82-kg athlete? Express your answer to two significant figures & include the appropriate units
The weight of fat, in pounds, of an 82-kg athlete with 14% body fat by mass is 25.31 lb.
Given,
The percentage of body fat by mass = 14%
Weight of the athlete = 82 kg
Now we need to calculate the weight of fat in pounds of the athlete.
Let's use the following conversion factors,1 kg = 2.205 lb1% = 0.01
Thus,
The weight of fat = Percentage of body fat by mass × Weight of the athlete
= 14% × 82 kg
= 0.14 × 82 kg
= 11.48 kg
Now we need to convert kg to pounds,
11.48 kg = 11.48 kg × 2.205 lb/kg = 25.31 lb
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Can a hydrocarbon molecule (i.e., a molecule with only C and H atoms) ever have a trigonal bipyramidal geometry? a. Yes, there are lots of examples. b. No, hydrocarbons are too electronegative c. Yes, but only if the hydrocarbon contains at least one double or triple bond d. No, hydrocarbons only have single bonds, but the trigonal bipyramidal geometry requires double or triple bonds e. No, one needs an expanded valence shell to get the trigonal bipyramidal geometry, and that requires a period three or lower (on the periodic table) element.
E. No, one needs an expanded valence shell to get the trigonal bipyramidal geometry, and that requires a period three or lower (on the periodic table) element.
A hydrocarbon molecule consists only of carbon and hydrogen atoms, which have a valence of 4 and 1, respectively. Thus, hydrocarbons only have single bonds between carbon atoms, and the maximum number of atoms that can be bonded to a carbon atom is four.
Trigonal bipyramidal geometry is a shape in which five atoms or groups are arranged around a central atom, with three in one plane and two in another plane perpendicular to the first. This shape requires an expanded valence shell, which means that the central atom has more than eight valence electrons. Elements in period three or lower of the periodic table, such as phosphorus, sulfur, and chlorine, can have an expanded valence shell and form trigonal bipyramidal molecules.
Since hydrocarbons only have carbon and hydrogen atoms, which cannot form an expanded valence shell, they cannot have a trigonal bipyramidal geometry. Therefore, option e) is the correct answer.
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A sample of a diatomic ideal gas occupies 33.6 L under standard conditions. How many mol of gas are in the sample?a) 3b) .75c) 3.25d) 1.5
the answer is (d) 1.5 mol.
Under standard conditions, which are defined as 1 atmosphere (101.325 kPa) and 0°C (273.15 K), the molar volume of an ideal gas is 22.4 L.
Therefore, if a diatomic ideal gas occupies 33.6 L under standard conditions, the number of moles of gas in the sample can be calculated as follows:
n = V / Vm
where n is the number of moles, V is the volume of the gas, and Vm is the molar volume of the gas at standard conditions.
Substituting the given values, we get:
n = 33.6 L / 22.4 L/mol = 1.5 mol
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show the reaction by which you will prepare small amounts of elemental chlorine (cl2)
Preparing small amounts of elemental chlorine gas (Cl2) is done by using hydrochloric acid (HCl) and potassium permanganate (KMnO4).
What are other methods to prepare Chlorine gas?One common laboratory method for preparing small amounts of elemental chlorine gas (Cl2) is by using hydrochloric acid (HCl) and potassium permanganate (KMnO4). Here is the balanced chemical equation for the reaction:
2 HCl + KMnO4 → KCl + MnO2 + Cl2 + 2 H2O
To carry out the reaction, you would need to mix small amounts of concentrated hydrochloric acid and solid potassium permanganate in a suitable reaction vessel. The reaction will produce elemental chlorine gas, manganese dioxide solid, potassium chloride, and water vapor.
It is important to note that chlorine gas is a highly toxic and reactive substance that should be handled with extreme care. Proper safety measures, such as using appropriate protective equipment and working in a well-ventilated area, should always be taken when working with this gas.
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Water is a polar solvent and hexane is a non-polar solvent. Determine which solvent each of the following is most likely to be soluble in. Potassium chloride, KCL Octane, C8H18, a compound in gasoline Sodium bicarbonate, NaHCO3
The solubility of each compound in water (polar solvent) and hexane (non-polar solvent). Potassium chloride (KCl) is soluble in water. Octane (C8H18) is soluble in hexane. Sodium bicarbonate (NaHCO3) is soluble in water.
1. Potassium chloride (KCl):
KCl is an ionic compound, and it tends to dissolve well in polar solvents due to the electrostatic interaction between the polar solvent molecules and the charged ions. Therefore, KCl is most likely to be soluble in water, the polar solvent.
2. Octane (C8H18):
Octane is a non-polar compound, as it is comprised of only carbon and hydrogen atoms with non-polar covalent bonds. Non-polar compounds usually dissolve well in non-polar solvents due to the similar dispersion forces between the molecules. Thus, octane is most likely to be soluble in hexane, the non-polar solvent.
3. Sodium bicarbonate (NaHCO3):
Sodium bicarbonate is an ionic compound with polar covalent bonds in the bicarbonate ion. It will likely dissolve in polar solvents because of the electrostatic interactions between the polar solvent molecules and the ions in the compound. Consequently, sodium bicarbonate is most likely to be soluble in water, the polar solvent.
In summary:
- Potassium chloride (KCl) is soluble in water.
- Octane (C8H18) is soluble in hexane.
- Sodium bicarbonate (NaHCO3) is soluble in water.
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Potassium chloride (KCl) is most likely to be soluble in water, a polar solvent. Octane (C₈H₁₈), is most likely to be soluble in hexane, a non-polar solvent. Sodium bicarbonate (NaHCO₃) is soluble in water, a polar solvent.
Water is a polar solvent, meaning it has a partial positive charge on the hydrogen atom and a partial negative charge on the oxygen atom. Potassium chloride (KCl) is an ionic compound composed of positively charged potassium ions (K⁺) and negatively charged chloride ions (Cl⁻). The positive and negative charges of the ions are attracted to the opposite charges of water molecules, allowing KCl to dissolve in water.
Hexane is a non-polar solvent composed of carbon and hydrogen atoms. Octane (C₈H₁₈) is a hydrocarbon with only carbon and hydrogen atoms, making it non-polar as well. Non-polar substances tend to dissolve better in non-polar solvents, so octane is most likely to be soluble in hexane.
Sodium bicarbonate (NaHCO₃) is an ionic compound composed of positively charged sodium ions (Na⁺), negatively charged bicarbonate ions (HCO₃⁻), and a hydrogen ion (H⁺). The ionic nature of sodium bicarbonate allows it to dissociate into ions in water, making it soluble in water.
Overall, the solubility of these compounds depends on the polarity of the solvents and the nature of the compounds themselves.
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The compound Ni(NO2)2 is an ionic compound. What are the ions of which it is composed? Cation formula Anion formula
The compound Ni(NO2)2 is composed of two different ions, a cation and an anion.
The cation in this compound is nickel (Ni) and the anion is nitrite (NO2). The nickel cation has a charge of +2, which is balanced by the two nitrite anions, each with a charge of -1. The overall charge of the compound must be neutral, so the two charges of the nitrite anions cancel out the charge of the nickel cation. Therefore, the cation formula for Ni(NO2)2 is Ni2+ and the anion formula is NO2-. The nitrite anion is a polyatomic ion consisting of one nitrogen atom and two oxygen atoms.
It is important to note that although Ni(NO2)2 is considered an ionic compound, the nitrite anion is a covalent compound due to the sharing of electrons between the nitrogen and oxygen atoms. However, when combined with the positively charged nickel cation, it forms an ionic compound.
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0.100 l solution of 0.270 m agno3 is combined with a 0.100 l solution of 1.00 m na3po4. calculate the concentration of ag and po3−4 at equilibrium after the precipitation of ag3po4 (sp=8.89×10−17).
The equilibrium concentration of Ag⁺ and PO₃⁻⁴ are 2.35 x 10⁻⁶ M and 7.05 x 10⁻⁶ M, respectively.
First, we need to write the balanced chemical equation for the precipitation of Ag₃PO₄;
3AgNO₃ + Na₃PO₄ → Ag₃PO₄ + 3NaNO₃
According to the stoichiometry of the equation, 3 moles of AgNO₃ are required to react with 1 mole of Na₃PO₄ to form 1 mole of Ag₃PO₄. So, we need to find out which reactant is limiting.
The number of moles of AgNO₃ present in 0.100 L of 0.270 M solution is:
0.100 L x 0.270 mol/L = 0.027 mol AgNO₃
The number of moles of Na₃PO₄ present in 0.100 L of 1.00 M solution is:
0.100 L x 1.00 mol/L = 0.100 mol Na₃PO₄
According to the stoichiometry of the equation, 0.100 mol Na₃PO₄ would require 0.300 mol AgNO₃ (3 times as many moles). However, we only have 0.027 mol AgNO₃, which is the limiting reactant.
Therefore, all 0.027 mol of AgNO will react to form Ag₃PO₄. The amount of Ag₃PO₄ that will precipitate can be calculated using its solubility product constant (Ksp);
Ksp = [Ag⁺]³ [PO₃⁻⁴]
Ksp = (x)(3x)³ = 8.89 x 10⁻¹⁷
Solving for x gives;
x = [Ag⁺] = 2.35 x 10⁻⁶ M
[PO₃⁻⁴] = 3x = 7.05 x 10⁻⁶ M
Therefore, the concentrations of Ag⁺ is 2.35 x 10⁻⁶ M and the concentration of PO3-4 is 7.05 x 10⁻⁶ M, respectively.
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11) cesium-131 has a half-life of 9.7 days. what percent of a cesium-131 sample remains after 60 days? a) 100 b) 0 c) 1.4 d) 98.6 e) more information is needed to solve the problem answer: c
After 60 days, the amount of cesium-131 that remains is option (c) 1.4% of the original sample.
The half-life of cesium-131 is 9.7 days, which means that after 9.7 days, half of the initial amount of the sample remains. After another 9.7 days (total of 19.4 days), half of that remaining amount remains, and so on.
To find the percent of the sample that remains after 60 days, we can divide 60 by 9.7 to get the number of half-life periods that have elapsed:
60 days / 9.7 days per half-life = 6.19 half-life periods
This means that the initial sample has undergone 6 half-life periods, so only 1/2⁶ = 1.5625% of the initial sample remains. Therefore, the answer is c) 1.4%.
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for a particular redox reaction, no−2 is oxidized to no−3 and cu2 is reduced to cu . complete and balance the equation for this reaction in basic solution. phases are optional.
Therefore, the balanced equation for the redox reaction in basic solution is:
2NO2- + Cu2+ + 4OH- → 2NO3- + Cu + 2H2O
The balanced equation for the redox reaction in basic solution is:
2NO2- + Cu2+ + 4OH- → 2NO3- + Cu + 2H2O
In this reaction, NO2- is oxidized (loses electrons) to NO3- and Cu2+ is reduced (gains electrons) to Cu. The reaction takes place in basic solution, which means that we need to balance the equation by adding OH- ions to balance out the H+ ions.
To balance the equation, we first balance the atoms in each half-reaction:
Oxidation half-reaction:
NO2- → NO3-
Add 2H2O and 4e- to the left side to balance the charge and atoms:
NO2- + 2H2O + 4e- → NO3-
Reduction half-reaction:
Cu2+ → Cu
Add 2e- to the left side to balance the charge:
Cu2+ + 2e- → Cu
Next, we balance the number of electrons transferred by multiplying each half-reaction by the appropriate factor:
Multiply oxidation half-reaction by 2:
2NO2- + 4H2O + 8e- → 2NO3-
Multiply reduction half-reaction by 4:
4Cu2+ + 8e- → 4Cu
Now we add the two half-reactions together, canceling out the electrons on both sides:
2NO2- + 4H2O + 8e- + 4Cu2+ → 2NO3- + 4Cu + 8OH-
Finally, we simplify the equation by canceling out the H2O molecules and reducing the coefficients:
2NO2- + 4Cu2+ + 4OH- → 2NO3- + 4Cu + 2H2O
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If it takes 15.0 mL of 0.40 M NaOH to neutralize 5.0 mL of HCI, what is the molar concentration of the HCI solution?
Answer:
The molar concentration of the HCl solution = 1.2 M
Explanation:
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FILL IN THE BLANK The equilibrium constant for reaction 1 is K. The equilibrium constant for reaction 2 is __________.
(1) SO2(g)+(1/2)O2(g) <-> SO3(g)
(2) 2SO3(g) <-> 2SO2(g)+O2(g)
The equilibrium constant for reaction 2 i.e. 2SO3(g) <-> 2SO2(g)+O2(g) is K^2.
The equilibrium constant for reaction 2 can be determined by using the equilibrium constant for reaction 1 and the law of mass action. The law of mass action states that for a chemical reaction at equilibrium, the product of the concentrations of the products raised to their stoichiometric coefficients divided by the product of the concentrations of the reactants raised to their stoichiometric coefficients is equal to the equilibrium constant. Using this law, we can write the equilibrium constant expression for reaction 2 as:
K2 = ([SO2]^2[O2])/([SO3]^2)
where [SO2], [O2], and [SO3] are the molar concentrations of SO2, O2, and SO3 at equilibrium. The stoichiometric coefficients of the reactants and products in reaction 2 are used as exponents in the expression.
Therefore, the equilibrium constant for reaction 2 is K^2 = ([SO2]^2[O2])/([SO3]^2).
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the reaction of 4-pentanoylbiphenyl and hydrazine without potassium hydroxide is a net? a. substitution b. addition c. rearrangement d. elimination
The reaction of 4-pentanoylbiphenyl and hydrazine without potassium hydroxide is a net addition reaction. The correct option is b.
When 4-pentanoylbiphenyl reacts with hydrazine in the absence of potassium hydroxide, the carbonyl group of the 4-pentanoylbiphenyl undergoes addition reaction with hydrazine to form a hydrazone product. This is an example of a net addition reaction, where two molecules combine to form a single product.
The reaction does not involve the substitution of any functional groups, rearrangement of atoms or elimination of any functional group. The absence of potassium hydroxide in the reaction mixture does not influence the mechanism of the reaction but rather affects the rate of reaction. Potassium hydroxide is often used as a catalyst in the reaction to increase the rate of the reaction. Therefore, the correct option is b.
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