Answer:
[tex]0.688M[/tex]
Explanation:
Hello,
In this case, it is widely acknowledged that strong bases usually correspond to those formed with metals in groups IA and IIA which have relatively high activity and reactivity, therefore, when they are dissolved in water the following dissociation reaction occurs (for calcium hydroxide):
[tex]Ca(OH)_2\rightarrow Ca^{2+}+2OH^-[/tex]
In such a way, for the same volume, we can compute the concentration of hydroxyl ions by simple stoichiometry (1:2 molar ratio):
[tex]0.344\frac{molCa(OH)_2}{L}*\frac{2molOH^-}{1molCa(OH)_2} \\\\0.688\frac{mol OH^-}{L}[/tex]
Or simply:
[tex]0.688M[/tex]
Regards.
Given the information below, which is more favorable energetically, the oxidation of succinate to fumarate by NAD+ or by FAD? Fumarate + 2H+ + 2e- → Succinate E°´ = 0.031 V NAD+ + 2H+ + 2e- → NADH + H+ E°´ = -0.320 FAD + 2H+ + 2e- → FADH2 E°´ = -0.219
Answer:
Oxidation by FAD
Explanation:
1. Oxidation by NAD⁺
Succinate ⇌ Fumarate + 2H⁺ + 2e⁻; E°´ = -0.031 V
NAD⁺ + 2H⁺ + 2e⁻ ⇌ NADH + H⁺; E°´ = -0.320 V
Succinate + NAD⁺ ⇌ Fumarate + NADH + H⁺; E°' = -0.351 V
2. Oxidation by FAD
Succinate ⇌ Fumarate + 2H⁺ + 2e⁻; E°´ = -0.031 V
FAD + 2H⁺ + 2e⁻ ⇌ FADH₂; E°´ = -0.219 V
Succinate + FADH₂ ⇌ Fumarate + FAD; E°' = -0.250 V
Neither reaction is energetically favourable, but FAD has a more positive half-cell potential.
FAD is the stronger oxidizing agent.
The oxidation by FAD has a more positive cell potential, so it is more favourable energetically.
The substance nitrogen has the following properties: normal melting point: 63.2 K normal boiling point: 77.4 K triple point: 0.127 atm, 63.1 K critical point: 33.5 atm, 126.0 K At temperatures above 126 K and pressures above 33.5 atm, N2 is a supercritical fluid . N2 does not exist as a liquid at pressures below atm. N2 is a _________ at 16.7 atm and 56.5 K. N2 is a _________ at 1.00 atm and 73.9 K. N2 is a _________ at 0.127 atm and 84.0 K.
Answer:
- N2 does not exist as a liquid at pressures below 0.127 atm.
- N2 is a solid at 16.7 atm and 56.5 K.
- N2 is a liquid at 1.00 atm and 73.9 K
- N2 is a gas at 0.127 atm and 84.0 K.
Explanation:
Hello,
At first, we organize the information:
- Normal melting point: 63.2 K.
- Normal boiling point: 77.4 K.
- Triple point: 0.127 atm and 63.1 K.
- Critical point: 33.5 atm and 126.0 K.
In such a way:
- N2 does not exist as a liquid at pressures below 0.127 atm: that is because below this point, solid N2 exists only (triple point).
- N2 is a solid at 16.7 atm and 56.5 K: that is because it is above the triple point, below the critical point and below the normal melting point.
- N2 is a liquid at 1.00 atm and 73.9 K: that is because it is above the triple point, below the critical point and below the normal boiling point.
- N2 is a gas at 0.127 atm and 84.0 K: that is because it is above the triple point temperature at the triple point pressure.
Best regards.