3.97×1023 molecules C2H6 1 mol C2H6
------------------------------------------ x ------------------------------------ = 0.66 mol C2H6
6.022 x 1023 molec. C2H6
what is the polarity of black pepper
Answer:
Polarity in chemistry referred to physical properties of compounds related to solubility, melting and boiling properties.
Polarity of black pepper can be seen when black pepper is sprinkled on water. The balck pepper float on water and get displaced if touched.
It means black pepper is non-polar and have no difference in electronegativity between bonded atoms. Black pepper is so light in weight and non-polar, the surface tension of water keep it floating in the water.
If the NaOH is added to 35.0 mL of 0.167 M Cu(NO3)2 and the precipitate isolated by filtration, what is the theoretical yield of the reaction?
Answer:
The correct answer is - 0.570 grams
Explanation:
The balanced chemical reaction is given by
Cu(NO3)2(aq) + 2NaOH(aq) --------> Cu(OH)2(s) + 2NaNO3(aq)
1.0 mole 2.0 mole 1.0 mole 2.0 mole
number of mol of Cu(OH)2,
n = Molarity * Volume
= [tex]35.0*0.167 = 5.845[/tex] millimoles
As clear in the equation, 1 mole of Cu(NO3)2 gives 1 mole of Cu(OH)2 , So, 5.845 millimoles of Cu(NO3)2 will produce 5.845 millimoles of Cu(OH)2
Mass of Cu(OH)2 = number of mol * molar mass
= [tex]97.5*5.845*10^-3[/tex]
= 0.570 grams
Thus, the correct answer is - 0.570 grams
What is the final pH of a solution with an initial concentration of 2.5mM Ascorbic acid (H2C6H6O6) which has the following Kas: 7.9x10-5 and 1.6x10-12
Answer:
pH = 3.39
Explanation:
The equilibrium in water of ascorbic acid (With its conjugate base) is:
H₂C₆H₆O₆(aq) + H₂O(l) ⇄ HC₆H₆O₆⁻(aq) + H₃O⁺(aq)
Where the acidic dissociation constant is written as:
Ka = 7.9x10⁻⁵ = [HC₆H₆O₆⁻] [H₃O⁺] / [H₂C₆H₆O₆]
H₂O is not taken in the Ka expression because is a pure liquid.
As initial concentration of H₂C₆H₆O₆ is 2.5x10⁻³M, the equilibrium concentration of each species in the equilibrium is:
[H₂C₆H₆O₆] = 2.5x10⁻³M - X
[HC₆H₆O₆⁻] = X
[H₃O⁺] = X
Replacing in the Ka expression:
7.9x10⁻⁵ = [X] [X] / [2.5x10⁻³M - X]
1.975x10⁻⁷ - 7.9x10⁻⁵X = X²
0 = X² + 7.9x10⁻⁵X - 1.975x10⁻⁷
Solving for X:
X = -0.00048566→ False solution, there is no negative concentrations
X = 0.00040666 → Right solution
As [H₃O⁺] = X, [H₃O⁺] = 0.00040666
pH is defined as -log [H₃O⁺];
pH = -log 0.00040666,
pH = 3.39help please !!!!!!!!
Answer:
Option B. 2096.1 K
Explanation:
Data obtained from the question include the following:
Enthalpy (H) = +1287 kJmol¯¹ = +1287000 Jmol¯¹
Entropy (S) = +614 JK¯¹mol¯¹
Temperature (T) =.?
Entropy is related to enthalphy and temperature by the following equation:
Change in entropy (ΔS) = change in enthalphy (ΔH) / Temperature (T)
ΔS = ΔH / T
With the above formula, we can obtain the temperature at which the reaction will be feasible as follow:
ΔS = ΔH / T
614 = 1287000/ T
Cross multiply
614 x T = 1287000
Divide both side by 614
T = 1287000/614
T = 2096.1 K
Therefore, the temperature at which the reaction will be feasible is 2096.1 K
Which of the possible compounds has a mass of 163 grams when
6.13 x 1024 molecules of the compound is put on a scale?
Answer:
CH4
Explanation:
In solving this problem, we must remember that one mole of a compound contains Avogadro's number of elementary entities. These elementary entities include atoms, molecules, ions etc. Recall that one mole of a substance is the amount of substance that contains the same number of elementary entities as 12g of carbon-12. The Avogadro's number is 6.02 × 10^23.
Hence we can now say;
If 163 g of the compound contains 6.13 ×10^24 molecules
x g will contain 6.02 × 10^23 molecules
x= 163 × 6.02 × 10^23 / 6.13 × 10^24
x= 981.26 × 10^23/ 6.13 ×10^24
x= 160.1 × 10^-1 g
x= 16.01 g
x= 16 g(approximately)
16 g is the molecular mass of methane hence x must be methane (CH4)
Which aqueous solution will have the highest boiling point temperature? A. 0.100 molal NiBr2(aq) B. 0.250 molal CH3OH(aq) C. 0.100 molal MgSO4(aq) D. 0.150 molal Na2SO4(aq) E. 0.150 molal NH4NO3(aq)
Answer: 0.150 m [tex]Na_2SO_4(aq)[/tex] will have highest boiling point.
Explanation:
Formula used for Elevation in boiling point :
[tex]\Delta T_b=i\times k_b\times m[/tex]
where
[tex]\Delta T_b=T_b-T^o_b[/tex]= elevation in boiling point
[tex[k_b[/tex] = boiling point constant
m = molality
i = Van't Hoff factor
A) 0.100 m [tex]NiBr_2[/tex]
i = 3 as [tex]NiBr_2\rightarrrow Ni^{2+}+2Br^-[/tex]
concentration will be [tex]3\times 0.100=0.300[/tex]
B) 0.250 m [tex]CH_3OH[/tex]
i = 1 as [tex]CH_3OH[/tex] is a non electrolyte
concentration will be [tex]1\times 0.250=0.250[/tex]
C) 0.100 molal [tex]MgSO_4(aq)[/tex]
i = 2 as [tex]MgSO_4\rightarrrow Mg^{2+}+SO_4^{2-}[/tex]
concentration will be [tex]2\times 0.100=0.200[/tex]
D. 0.150 molal [tex]Na_2SO_4(aq)[/tex]
i = 3 as [tex]Na_2SO_4\rightarrrow 2Na^{+}+SO_4^{2-}[/tex]
concentration will be [tex]3\times 0.150=0.450[/tex]
E. 0.150 molal [tex]NH_4NO_3(aq)[/tex]
i = 2 as [tex]NH_4NO_3\rightarrrow NH_4^{+}+NO_3^{-}[/tex]
concentration will be [tex]2\times 0.150=0.300[/tex]
The solution having the highest concentration of ions will have the highest boiling point and thus 0.150 m [tex]Na_2SO_4(aq)[/tex] will have highest boiling point.
The aqueous solution that would have the highest temperature at boiling point would be:
D). 0.150 molal Na2SO4(aq)
What is a boiling point?The boiling point is described as the temperature at which the solution starts boiling or the vapor pressure becomes equivalent to the provided external/outer pressure.
To determine the elevation in boiling point, we will use:
Δ[tex]T_{b}[/tex] [tex]= i[/tex] × [tex]k_{b}[/tex] × [tex]m[/tex]
with
[tex]T_{b}[/tex] [tex]= T_{b} - T^{0}_{b}[/tex]
[tex]k_b[/tex] [tex]=[/tex] constant of boiling point
Using this formula,
0.150 molal Na2SO4(aq)
Given,
[tex]i = 3[/tex]
[tex]Na2So4[/tex] will have
[tex]2Na^{+}[/tex] [tex]+[/tex] [tex]SO^{2-}_{4}[/tex]
So,
Concentration [tex]= 3[/tex] × [tex]0.15[/tex][tex]0[/tex]
[tex]= 0.45[/tex][tex]0[/tex]
∵ 0.150 molal [tex]Na2SO4[/tex]Na2SO4(aq) has the maximum concentration.
Thus, option D is the correct answer.
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A volumetric flask contains 25.0 mL of a 14% m/V sugar solution. If 2.5 mL of this solution is added to 22.5 mL of distilled water, what is the % m/V of the new solution.
Answer:
The new solution is 1.4% m/V
Explanation:
The concentration of the new solution, obtained by adding 22.5 mL of distilled water to 2.5 mL of 14 % m/V sugar solution, is 1.4% m/V.
We have 2.5 mL (V₁) of a concentrated solution and add it to 22.5 mL of distilled water. Assuming the volumes are additives, the volume of the new solution (V₂) is:
[tex]2.5 mL + 22.5 mL = 25.0 mL[/tex]
We want to prepare a dilute solution from a concentrated one, whose concentration is 14% m/V (C₁). We can calculate the concentration of the dilute solution (C₂) using the dilution rule.
[tex]C_1 \times V_1 = C_2 \times V_2\\C_2 = \frac{C_1 \times V_1}{V_2} = \frac{14\% m/V \times 2.5 mL}{25.0 mL} = 1.4 \% m/V[/tex]
The concentration of the new solution, obtained by adding 22.5 mL of distilled water to 2.5 mL of 14 % m/V sugar solution, is 1.4% m/V.
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How many water molecules are in a block of ice containing 0.500 mol of water (H2O)?
Answer:
3.01 × 10²³ molecules
Explanation:
Step 1: Given data
Moles of water (n): 0.500 mol
Step 2: Calculate the molecules of water present in 0.500 moles of water
In order to perform this calculation, we will use the Avogadro's number: in 1 mole of water there are 6.02 × 10²³ molecules of water.
0.500 mol × (6.02 × 10²³ molecules/1 mol) = 3.01 × 10²³ molecules
A 2.0 g sample of hydrocarbon was burned in the calorimeter. The temperature rose from 29°c to 32°c and heat and combustion is 11. Kj/g. Thr heat capacity of the calorimeter is
Answer:
THE HEAT CAPACITY OF THE CALORIMETER IS 3666.67 J/C
Explanation:
Mass = 2 g
Temperature difference = 32 C - 29 C = 3 C
Heat of combustion = 11 kJ/g
Heat capacity of the calorimeter = unknown
It is important to note that the heat of combustion of the reaction is the heat absorbed by the calorimeter in raising the mixture by 3 C
So therefore,
Heat = heat capacity * temperature difference
Heat capacity = Heat / temperature difference
Heat capacoty = 11 000 J / 3 C
Heat capacity = 3666.67 J/ C
Calcium carbide, CaC2, reacts with water to form calcium hydroxide and the flammable gas ethyne (acetylene) in the reaction: What mass of ethyne can be produced
Answer:
1 mole of CaC₂ will produce 26g of C₂H₂ or 64.1g of CaC₂ will produce 26g of C₂H₂
Explanation:
Hello,
To solve this question, we'll require a balanced chemical equation of reaction between calcium carbide and water.
Equation of reaction
CaC₂ + 2H₂O → Ca(OH)₂ + C₂H₂
Molar mass of calcium carbide (CaC₂) = 64.1g/mol
Molar mass of water (H₂O) = 18g/mol
Molar mass of calcium hydroxide (Ca(OH)₂) = 74g/mol
Molar mass of ethyne (C₂H₂) = 26g/mol
From the equation of reaction, 1 mole of CaC₂ will produce 1 mole of C₂H₂
1 mole of CaC₂ = mass / molar mass
Mass = 1 × 64.1
Mass = 64.1g
1 mole of C₂H₂ = mass / molar mass
Mass = 1 × 26
Mass = 26g
Therefore, 1 mole of CaC₂ will produce 26g of C₂H₂
Note: this is a hypothetical calculation since we were not given the initial mass of CaC₂ that starts the reaction
For a given sample of C3H8(g), the enthalpy change during the reaction is -784kJ. How many grams of CO2 are produced? Group of answer choices g
Answer:
[tex]m_{CO_2}=46.6gCO_2[/tex]
Explanation:
Hello,
In this case, considering the combustion of propane:
[tex]C_3H_8(g)+5O_2(g)\rightarrow 3CO_2(g)+4H_2O(g)\ \ \ \Delta _CH=-2220.0 kJ/mol[/tex]
We can compute the burnt moles of propane as shown below:
[tex]n=\frac{-784kJ}{-2220.0 kJ/mol} =0.353molC_3H_8[/tex]
Then, by noticing propane and carbon dioxide are in a 1:3 molar ratio, we can compute the grams carbon dioxide by using the shown below stoichiometric procedure:
[tex]m_{CO_2}=0.353molC_3H_8*\frac{3molCO_2}{1molC_3H_8} *\frac{44gCO_2}{1molCO_2} \\\\m_{CO_2}=46.6gCO_2[/tex]
Best regards.
A substance used as a cleaner and a fuel is 37.48% C, 49.93% O and 12.58% H by mass. A 0.2804-g sample of the substance occupies a volume of 250.0 mL when it is vaporized at 75o C and 1.00 atm of pressure.
R = 0.0821 L atm/ mol K
a) This compound can be made by combining gaseous carbon monoxide with hydrogen gas (with this compound as the only product). What is the maximum mass of this compound that can be prepared if 8.0 kg of hydrogen gas react with 59.0 kg of carbon monoxide gas?
b) If 59.6 kg of the product is actually produced, given the reaction described in (a), what is the percent yield?
c) This compound (the substance you identified in part a) is a potential replacement for gasoline. The products of the complete combustion of this fuel are the same as those for the complete combustion of a hydrocarbon (CO2 and H2O). Calculate the volume of CO2 produced at 27o C and 766 mmHg when 1.00 gallon of this fuel is completely combusted. The density of the fuel is 0.7914 g/mL. 1 gallon = 3.785 liters
d) A claim was made that this fuel is better for the environment because it produces less CO2 per gallon than gasoline, which can be represented by the formula C8H18 (octane). Is this claim true? Octane has a density of 0.6986 g/mL
Answer:
Explanation:
We shall find out the molecular formula of the substance .
Ration of number of atoms of C , O and H
= [tex]\frac{37.48}{12} :\frac{49.93}{16} :\frac{12.58}{1}[/tex]
= 3.12 : 3.12 : 12.58
= 1 : 1 : 4
volume of gas at NTP
= 250 x 273 / 350 mL .
= 195 mL .
Molecular weight of the substance = .2804 x 22400 / 195 g
= 32. approx
Let the molecular formula be
(COH₄)n
n x 32 = 32
n = 1
Molecular formula = COH₄
The compound appears to be CH₃OH
a )
CO + 2H₂ = CH₃OH
28g 4g 32g
59 8
For 8 kg hydrogen , CO required = 56 kg
CO is in excess . hydrogen is the limiting reagent .
mass of product formed
= 32 x 8 / 4
= 64 kg
b )
percentage yield = product actually formed / product to be formed theoretically x 100
= 59.6 x 100 / 64
= 93.12 %
c )
2CH₃OH + 3O₂ = 2CO₂ + 4H₂O .
64 g 2 x 22.4 L
Gram of gas in 1 gallon of fuel
= .7914 x 3785
= 2995.5 g
CO₂ produced at NTP by 2995.5 g CH₃OH
= 2 x 22.4 x 2995.5 / 64 L
= 2096.85 L
At 27° C and 766 mm Hg , this volume is equal to
2096.85 x 300 x 760 / 273 x 766
= 2286.18 L .
d )
C₈H₁₈ = 8CO₂
114g 8 x 22.4 L
gram of fuel per unit gallon
= .6986 x 3785
= 2644.2g
gram of CO₂ produced by 1 gallon of fuel at NTP
= 8 x 22.4 x 2644.2 / 114
= 4156.5 L
So it produces more CO₂ .
Write the following isotope in nuclide notation: oxygen-14
Answer:
[tex]14\\8[/tex]O
Explanation:
The top number always represents the mass number.
The bottom number always represents the atomic number.
The element always goes after the numbers.
If charge is present, that comes after the element.
solution solution solution
Answer:
Oxygen present in food items makes then rancid due to the presence of oils and fats. If the food is flushed with nitrogen, it prevents it from being oxidised (the nitrogen acts as an antioxidant).
Hope it helps ! :)
What is the systematic name for the given compound? (R)-2-bromobutane (S)-2-bromobutane (R)-2-butyl bromide (S)-2-butyl bromide
Answer:
See explanation below
Explanation:
IUPAC came up with the idea of an unambiguous system of nomenclature for organic compounds. This unambiguous system relates the structure of a compound with its name. Thus, IUPAC has established a worldwide standard for the unambiguous naming of organic compounds. Scientists all over the world can now have a uniform system of nomenclature for compounds in order to facilitate easy communication of scientific information.
The systematic names of the following compounds listed in the question are shown below;
(R)-2- butyl bromide has the systematic name (R)-2-bromobutane
(S)-2-butyl bromide has the systematic name (S)-2-bromobutane
This unified system of nomenclature avoids the confusion created by the use of different trivial names in deferent localities and by various scientific academies. This is a major advantage of the systematic nomenclature.
Therapeutic drugs generally need to have some hydrophobic and hydrophilic components to be able to effectively reach their target organs and tissues given there are aqueous and nonaqueous parts of the body. The degree to which a compound is hydrophobic and hydrophilic can be determined by measuring its relative solubility in water and octanol, C8H17OH, and water. To do this, a sample of the compound is added to a mixture of water and octanol and mixed well. Water and octanol are immiscible so after the mixture settles, the concentration of the compound in water and the concentration of the compound in octanol is measured. The ratio of the concentrations is called the partition ratio:
The question is incomplete as some part is missing:
concentration in octanol Partition Ratio = concentration in water
a) What are the intermolecular forces of attraction between octanol molecules? Explain.
b) Which of the intermolecular forces of attraction identified in (a) account for most of the interactions between octanol molecules? Explain. Use the immiscibility in water and the data included in figures 1 and 2 as evidence to support your answer.
c) Would a compound with a partition coefficient less than one be more hydrophobic or more hydrophilic than one with a partition coefficient greater than 10? Explain.
d) Would nonane (figure 2) be more soluble in water or octanol? Explain.
e) Draw another structure for a compound with the same chemical formula as nonane (CH20) that has a lower boiling point. Explain.
f) Are any of the C atoms in the structure you drew for CH20 sp?hybridized? Explain.
Octanol Boiling point = 195°C Figure 2 Nonane (CH20) Boiling point = 151°C
Answer:
1. The forces between octanol molecules would be attractive. These forces include Vanderwaal forces, H-bonds due to the presence of highly polar O-H group.
2. H-bonding ahould account for most of the attractive forces. The O-H bond should behave like and dipole, oxygen of one molecule attracts the hydrogen of the neighbouring molecule forming D-H...A links throughout (D stands for donor of H-Bond and A for acceptor for H-Bond).
3. Partition coefficient less than 1 will be more hydrophilic, generally drugs with low partition coefficients are regarded as hydrophilic. As parition coefficient of 10 mean more of the solute is dispersed in octanol as compared to water.
4. Nonane is non polar, so it would not dissolve in water. It follows the rule like dissolves like. Polar substances dissolve in polar solvents. 1-octanol is able to bind with water through hydrogen bonds thus its soluble in water but nonane doesn't. Nonane will forms a different layer from water.
5) no all carbons in 2-methyloctane are single bonded. Thus sp3 hybrid. A sp2 hybridised carbon would have a double bond C=C.
Grams of cl in 38g of cf3cl
Answer:
114 grams
Explanation:
3chlorines per compound*38grams=114
Recall that when a reaction is at equilibrium, the forward and reverse reactions occur at the same rate. To illustrate this idea, consider the reaction of A (small, red spheres) and B (large, blue spheres) to form AB.
A+B ⇌ AB
Notice that the reaction never stops. Even after several minutes, there is A and B left unreacted, and the forward and reverse reactions continue to occur. Also note that amounts of each species (i.e., their concentrations) stay the same.
Required:
What is the value of the equilibrium constant for this reaction?
Assume each atom or molecule represents a 1 M concentration of that substance.
Answer:
Equilibrium constant Kc = [x]² / [A - x] [B - x]
Explanation:
The equilibrium constant is defined as the ratio of the concentration of the products to that of the reactants at equilibrium
ie Kc = [products] / [reactants].
The balanced equation of the reaction is given as : A + B ⇄ AB
At the beginning of the reaction,
Initial concentration I = A = 1M
B = 1M
AB = 0M
After a period of time and assuming 'x' to be the concentration of product AB formed, the concentrations become
C = reactant A = [A - x] M
rectant B = [B - x] M
Product AB = [x] [x] M
At equilibrium, the concentrations are,
E = rectant A = [A - x] M
reactant B = [B - x] M
product AB = [x]² M
therefore , the equilibrium constant, Kc = [products]/[reactants]
= [x]² / [A - x] [B - x]
According to valence bond theory, which orbitals overlap in the formation of the bond in HCl?
a) 1s on H and 3p on Cl
b) 1s on H and 4s on Cl
c) 1s on H and 2p on Cl
d) 2s on H and 3p on Cl
e) 2s on H and 2p on Cl
The NaOH solution is standardized (or its true concentration) is found by reacting it with KHSO4. One of the two products from when NaOH reacts with KHSO4 is H2O. The other product is is a salt consisting of what?
a. NaK (aq)
b. (aq)
c. NaS (aq)
d. None of the above
Determine the rate of a reaction that follows the rate law:
rate = k[A]”[B]", where:
k= 1.5
[A] = 1 M
[B] = 3 M
m = 2
n = 1
Answer:
k= 1.5
[A] = 1 M
[B] = 3 M
m = 2
n = 1
Explanation:
rate = k[A]”[B]"
The rate of the reaction is 4.5 mol L⁻¹s⁻¹.
What is meant by rate of a reaction ?Rate of a reaction is defined as the change in concentration of any one of the reactants or products of the reaction, in unit time.
Here,
The concentration of A, [A] = 1 M
The concentration of B, [B] = 3 M
The partial order with respect to A, m = 2
The partial order with respect to B, n = 1
The rate constant of the reaction, k = 1.5
The rate of the reaction,
r = k[A]^m [B}^n
r = 1.5 x 1² x 3
r = 4.5 mol L⁻¹s⁻¹
Hence,
The rate of the reaction is 4.5 mol L⁻¹s⁻¹.
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Based on the Valence Shell Electron Pair Repulsion Theory (or VSEPR), molecules will arrange to keep the following as far apart as physically possible
a) mobile electrons
b) valence electron pairs
c) inner shell electrons
d) the electrons closest to the nuclei
Answer:
B. Valence Electron Pairs
Explanation:
Valence-shell electron-pair repulsion, or VSEPR, describes the shape of molecules by determining the repulsion of valence electrons. Therefore, our answer is B.
A 32.3-gram sample of gas is found to have a volume of 1.9 liters at 301 K and 1.21 atm. What is the molar mass of this gas? Show all of the work used to solve this problem.
Answer:
351.1g/mol
Explanation:
you can find the answer using The ideal gas equation
n= PV/RT
n=(1.21*1.9/0.082*301)mol
n=0.092 mol
molar mass=Mass/mole
m=32.3g/0.092mol
m=351.1g/mol
Identify the correctly written chemical reaction
A. Reactant + Reactant = Product
B. Reactant + Reactant → Product + Product
C. Reactant + Product → Reactant + Product
D. Product + Product Reactant + Reactant
Answer:
B. Reactant + Reactant -> Product + Product
Explanation:
Reactants are substances that- as the name suggests- reacts with other substances at the beginning of a reaction
Products are substances that are produced as a result of the reaction
Typically, when writing a chemical reaction, an arrow is used to show the direction the reaction is moving. In this case, the arrows in options B and C suggest that the reaction only moves in one direction- forwards
And as mentioned above, reactants are the substances at the start of the reaction, they're what mixes together to form a new product.
To keep things simple:
Products can't be at the beginning of a reaction since they weren't formed yet.
Similarly, reactants can't be part of the products since they already existed and didn't need to be made. In a lot cases, the reactants would be completely used up to make the products
As such, only one possible chemical reaction would follow that reasoning:
Reactant + Reactant -> Product + Product
Reactant + Reactant → Product + Product is the correctly written chemical reaction. Hence, option B is correct.
What is a chemical equation?A chemical equation is a mathematical expression of the chemical reaction which represents the product formation from the reactants.
In an equation, the reactants are written on the left-hand side and the products are written on the right-hand side demonstrated by one-headed or two-headed arrows.
Hence, option B is correct.
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Calculate the work (kJ) done during a reaction in which the internal volume expands from 28 L to 51 L against an outside pressure of 4.9 atm.
Answer:
W= -11KJ
Explanation:
Given:
volume expands from 28 L to 51 L
pressure =4.9 atm.
We will need to Convert the pressure to Pascal SI
But 1 atm = 101,325 Pa.
Then,
Pressure= (4.9*101323)/1atm = 5*10^5 pa
Then we need to Convert the volumes to cubic meters
But we know that1 m³ = 1,000 L.
V1= 28L * 1m^3/1000L = 0.028m^3
V2=51L × 1m^3 /1000L =0.051m^3
The work done during the expansion of a gas can be calculated as
W= -P(V2-V1)
W= - 5*10^5(0.051m^3 - 0.028m^3)
W= -1.1× 10^4J
Then we can Convert the work to kiloJoule
But1 kJ = 1,000 J.
W= -1.1× 10^4J× 1kj/1000J
= -11KJ
Why does the excess of base used in these eliminations favor the E2 over the E1 mechanism for elimination
Answer:
The base is involved in the rate determining step of an E2 reaction mechanism
Explanation:
Let us get back to the basics. Looking at an E1 reaction, the rate determining step is unimolecular, that is;
Rate = k [Carbocation] since the rate determining step is the formation of a carbonation.
For an E2 reaction however, the reaction is bimolecular hence for the rate determining step we can write;
Rate = k[alkyl halide] [base]
The implication of this is that an excess of either the alkyl halide or base will facilitate an E2 reaction.
Hence, when excess base is used, E2 reaction is favoured since the base is involved in its rate determining step. In an E1 reaction, the base is not involved in the rate determining step hence an excess of the base has no effect on an E1 reaction.
g A microwave oven heats by radiating food with microwave radiation, which is absorbed by the food and converted to heat. If the radiation wavelength is 12.5 cm, how many photons of this radiation would be required to heat a container with 0.250 L of water from a temperature of 20.0oC to a temperature of 99oC
Answer:
The total photons required = 5.19 × 10²⁸ photons
Explanation:
Given that:
the radiation wavelength λ= 12.5 cm = 0.125 m
Volume of the container = 0.250 L = 250 mL
The density of water = 1 g/mL
Density = mass /volume
Mass = Volume × Density
Thus; the mass of the water = 250 mL × 1 g/mL
the mass of the water = 250 g
the specific heat of water s = 4.18 J/g° C
the initial temperature [tex]T_1[/tex] = 20.0° C
the final temperature [tex]T_2[/tex] = 99° C
Change in temperature [tex]\Delta T[/tex] = (99-20)° C = 79 ° C
The heat q absorbed during the process = ms [tex]\Delta T[/tex]
The heat q absorbed during the process = 250 g × 4.18 J/g° C × 79° C
The heat q absorbed during the process = 82555 J
The energy of a photon can be represented by the equation :
= hc/λ
where;
h = planck's constant = [tex]6.626 \times 10^{-34} \ J.s[/tex]
c = velocity of light = [tex]3.0 \times 10^8 \ m/s[/tex]
= [tex]\dfrac{6.626 \times 10^{-34} \times 3.0 \times 10^8}{0.125}[/tex]
= [tex]1.59024 \times 10^{-24}[/tex] J
The total photons required = Total heat energy/ Energy of a photon
The total photons required = [tex]\dfrac{82555 J}{1.59024 \times 10^{-24}J}[/tex]
The total photons required = 5.19 × 10²⁸ photons
Calculate the height of a column of water at 25 °C that corresponds to normal atmospheric pressure. The density of water at this temperature is 1.0 g/
Answer:
10.328 m
Explanation:
normal atmospheric pressure = 101325 Pa
density of water at 25 °C = 1.0 g/cm^3 = 1000 kg/m^3
pressure = pgh
where p = density
g = acceleration due to gravity = 9.81 m/s^2
h = height of column
imputing values, we have
101325 = 1000 x 9.81 x h
height of column h = 101325/9810 = 10.328 m
Which of the following types of electromagnetic radiation have higher frequencies than visible light and which have shorter frequencies than visible light?
1. Gamma rays
2. Infrared radiation
3. Ultraviolet liht
4. X-rays
5. Microwaves
6. Radio waves
Answer:
3,4,1 and 6,5,2
Explanation:
In the electromagnetic spectrum the arrangement of the waves in increasing frequencies and decreasing wavelengths are as follows;
Radio waves
Microwaves
Infrared waves
Visible light rays
Ultraviolet rays
X-rays
Gamma rays
(a simple mnemonic is RMIVUXG)
If an electron has a principal quantum number (n) of 7 and an angular momentum quantum number (l) of 1, the subshell designation is ________
Answer:
7p
Explanation:
principal quantum number is 7
n=7( principle shell)
angular momentum quantum number gives sub shell
l = 1 means it is p orbital
so answer is 7p orbital