An empty steel container is filled with 2.0 atm of H₂ and 1.0 atm of F₂. The system is allowed to reach equilibrium according to the reaction below. If Kp = 0.45 for this reaction, what is the equilibrium partial pressure of HF?
The equilibrium partial pressure of HF is 0.55 atm.
The equation of the reaction is;
H2(g) + F2(g) ⇄ 2HF
I 2 1 0
C -x -x +x
E 2 - x 1 - x x
We know that;
pH2 = 2.0 atm
PF2 = 1.0 atm
pHF = ??
Kp = 0.45
So;
Kp = (pHF)^2/pH2. pF2
0.45 = x^2/(2 - x) (1 - x)
0.45 = x^2/x^2 - 3x + 2
0.45(x^2 - 3x + 2) = x^2
0.45x^2 - 1.35x + 0.9 = x^2
0.55 x^2 + 1.35x - 0.9 = 0
x = 0.55 atm
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Calculate the pH of each of the following aqueous solutions. (Enter your answers to two decimal places.) (a) 10.0 mL deionized water WebAssign will check your answer for the correct number of significant figures. 2.72 Incorrect: Your answer is incorrect. (b) 10.0 mL deionized water plus 5.0 mL of 0.10 M NaOH WebAssign will check your answer for the correct number of significant figures. (c) 10.0 mL deionized water plus 10.0 mL of 0.10 M NaOH WebAssign will check your answer for the correct number of significant figures. (d) 10.0 mL deionized water plus 15.0 mL of 0.10 M NaOH WebAssign will check your answer for the correct number of significant figures.
Answer:
a. pH = 7.0
b. pH = 12.52
c. pH = 12.70
d. pH = 12.78
Explanation:
a. Deionized water has the [H⁺] of pure water = 1x10⁻⁷ (Kw = 1x10⁻¹⁴ = [H⁺][OH⁻] - [H⁺] = [OH⁻ -)
pH = -log[H⁺] = 7
b. Moles NaOH = 5x10⁻³L * (0.10mol / L) = 5x10⁻⁴moles OH⁻ / 0.015L = 0.0333M = [OH⁻]
-Total volume = 10mL+5mL = 15mL = 0.015L
pOH = -log[OH⁻] = 1.48
pH = 14-pOH
pH = 12.52
c. Moles NaOH = 0.010L * (0.10mol / L) = 1x10⁻³moles OH⁻ / 0.020L = 0.0500M = [OH⁻]
-Total volume = 10mL+10mL = 20mL = 0.020L
pOH = -log[OH⁻] = 1.30
pH = 14-pOH
pH = 12.70
d. Moles NaOH = 0.015L * (0.10mol / L) = 1.5x10⁻³moles OH⁻ / 0.025L = 0.060M = [OH⁻]
-Total volume = 10mL+15mL = 25mL = 0.025L
pOH = -log[OH⁻] = 1.22
pH = 14-pOH
pH = 12.78
How many atoms are in 90.43 moles of copper
Mole measure the number of elementary entities of a given substance that are present in a given sample. Therefore, 8.12×10²³ atoms are in 90.43 mole of copper.
What is mole?
The SI unit of amount of substance in chemistry is mole. The mole is used to measure the quantity of amount of substance. It measure the number of elementary entities of a given substance that are present in a given sample. There are so many formula for calculating mole.
we know one mole of any element contains 6.022×10²³ atoms which is also called Avogadro number
number of atoms/molecules=number of moles × 6.022×10²³(Avogadro number)
number of moles of copper=90.43 moles
Substituting all the given values in the above equation, we get
number of atoms/molecules= 90.43 × 6.022×10²³
number of atoms/molecules=8.12×10²³ molecules
Therefore, 8.12×10²³ atoms are in 90.43 mole of copper.
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Which change represents an oxidation reaction?