Chemistry College

At 25 ∘C
, the equilibrium partial pressures for the reaction

A(g)+2B(g)↽−−⇀C(g)+D(g)

were found to be A=5.63
atm, B=5.00
atm, C=5.47
atm, and D=5.63
atm.

What is the standard change in Gibbs free energy of this reaction at 25 ∘C
?

At 25 C , The Equilibrium Partial Pressures For The ReactionA(g)+2B(g)C(g)+D(g)were Found To Be A=5.63

Answers

Answer 1

The standard change in Gibbs free energy of the reaction at 25 ∘C is -1.69 kJ/mol.

What is standard change?

To find the standard change in Gibbs free energy of the reaction, we need to use the following equation:

ΔG° = -RT ln(K)

where ΔG° is the standard change in Gibbs free energy, R is the gas constant (8.314 J/mol·K), T is the temperature in Kelvin (25 °C = 298 K), and K is the equilibrium constant.

To find K, we need to use the equilibrium partial pressures:

K = (PC × PD) / (PA × PB²)

where PA, PB, PC, and PD are the equilibrium partial pressures of A, B, C, and D, respectively.

Substituting the values, we get:

K = (5.47 atm × 5.63 atm) / (5.63 atm × (5.00 atm)²)

K = 0.6176

Now we can calculate the standard change in Gibbs free energy:

ΔG° = -RT ln(K)

ΔG° = -(8.314 J/mol·K) × (298 K) × ln(0.6176)

ΔG° = -1,690 J/mol or -1.69 kJ/mol

Therefore, the standard change in Gibbs free energy of the reaction at 25 ∘C is -1.69 kJ/mol.

What is free energy?

Free energy, also known as Gibbs free energy, is a thermodynamic quantity that represents the amount of energy in a system that is available to do work at a constant temperature and pressure. It is denoted by the symbol G and is expressed in units of joules (J) or calories (cal).

In simple terms, free energy is the energy that can be used to do work. It is defined by the equation:

ΔG = ΔH - TΔS

where ΔH is the change in enthalpy (heat content) of the system, ΔS is the change in entropy (disorder) of the system, and T is the absolute temperature in Kelvin.

If ΔG is negative, the reaction is spontaneous and can proceed without the input of external energy. If ΔG is positive, the reaction is non-spontaneous and requires energy input to proceed. If ΔG is zero, the system is at equilibrium.

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Related Questions

Question 5(Multiple Choice Worth 3 points)
(07.02 LC)

The substances below are listed by increasing specific heat capacity value. Starting at 30.0 °C, they each absorb 100 kJ of thermal energy. Which one do you expect to increase in temperature the least?

a) Cadmium, 0.230 J/(g °C)
b) Sodium, 1.21 J/(g °C)
c) Water, 4.184 J/(g °C)
d) Hydrogen, 14.267 J/(g °C)

Answers

Component form of the vector v is as follows: 4 3 1.5 1 Using the standard basis vectors I and j), express the vector w as follows: 3 two 1 4 pp . 1 3 w 3.5 C. V plus w= d. Determine the vector v's magnitude

What does "vector" mean?

Latin word for "carrier" is "vector." Point A is transported to point B by vectors. The orientation of the vectors AB is the direction in which point A is moved in relation to point B, and the amplitude of the vector is the width of the line connecting the two locations A and B. The terms Euclidean vectors and spatial vectors are also used to refer to vectors.

A vector space is what?

A vector space, also known as a linear space, is a collection of things called vectors that can be added to and multiplied ("scaled") by figures called scalars in the fields of mathematics, physics, and engineering.

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The two possible units of molarity are

Answers

Answer: The units for molarity are moles/liter.

Similarly, the equation to find molarity is moles divided by liters.

Explanation:  

mol / L is a unit of molar concentration. These are the number of moles of dissolved material per liter of solution. 1 mol / L is also called 1M or 1molar. Mol / m3 is also a unit of molar concentration.

Molarity is expressed in units of moles per liter (mol / L). This is a very common unit, so it has its own symbol, which is the uppercase M. A solution with a concentration of 5 mmol / l is called a 5 M solution or has a concentration value of 5 mol.

The molar concentration of the solution is equal to the number of moles of the solute divided by the mass of the solvent (kilogram), and the molar concentration of the solution is equal to the number of moles of the solute divided by the volume of the solution (liter). increase.

What happens when a solid is dissolved into a liquid?
.

Answers

The solid has broken down into pieces so small that its particles spread all throughout the new mixture

In the Periodic Table below, shade all the elements for which the neutral atom has an outer electron configuration of ms2nd2, where n and m are integers, and =m+n1.

Answers

The elements that have an outer electron configuration of ms2nd2 are located in the d-block of the periodic table and include some of the transition metals and lanthanides.

What is the periodic table?

To determine which elements in the periodic table have this outer electron configuration, you can look at the position of the d-block elements in the table. The d-block elements are located in the middle of the table and include the transition metals. These elements have partially filled d orbitals, which can accommodate up to 10 electrons.

Elements in the d-block with an atomic number of 21 through 30 (scandium through zinc) have an outer electron configuration of d10s2 and do not fit the ms2nd2 configuration. However, elements in the d-block with an atomic number of 39 through 48 (yttrium through cadmium) have an outer electron configuration of d10s2p1 and can have the ms2nd2 configuration by removing the single electron in the p orbital. Elements in the d-block with an atomic number of 57 through 80 (lanthanum through mercury) also have the possibility of having an outer electron configuration of ms2nd2.

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