Aspirin is a monoprotic acid called acetylsalicylic acid. Its foula is HC9​H7​O4​. A certain pain reliever was analyzed for aspirin by dissolving 0.149 g of the drug in water and titrating it with 0.0201MKOH solution. The titration required 15.06 mL of base. What is the percentage by weight of aspirin in the drug? % aspirin in the sample eTextbook and Media

Answers

Answer 1

The percentage by weight of aspirin in the drug is 73.86%.

To solve this question, we will use the formula: Percentage of aspirin in the sample = (molar mass of aspirin × equivalent mass of KOH × volume of KOH required × 100) / weight of the sample Firstly, let's calculate the molar mass of aspirin: C = 9 × 12.01 = 108.09H = 7 × 1.01 = 7.07O = 4 × 16.00 = 64.00Hence, the molar mass of aspirin = 108.09 + 7.07 + 64.00 = 179.16 g/mol

Now, let's calculate the equivalent mass of KOH:KOH reacts with 1 mole of aspirin, so its equivalent weight is equal to its molecular weight. The molecular weight of KOH = 39.10 + 16.00 + 1.01 = 56.11 g/mol Now, let's find the amount of KOH used in the reaction: Concentration of KOH = 0.0201 M Volume of KOH = 15.06 mL = 15.06 / 1000 = 0.01506 Ln(KOH) = C × V = 0.0201 M × 0.01506 L = 0.000302206 mol of KOH

Now, let's find the amount of aspirin in the sample: Number of moles of aspirin = (mass of aspirin) / (molar mass of aspirin) = 0.149 g / 179.16 g/mol = 8.32 × 10^-4 mol Finally, we can calculate the percentage by weight of aspirin in the drug: Percentage of aspirin in the sample = (molar mass of aspirin × equivalent mass of KOH × volume of KOH required × 100) / weight of the sample= (179.16 g/mol × 56.11 g/equiv × 0.000302206 equiv × 100) / 0.149 g= 73.86 %.

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Related Questions

4) 2NaCl+CaO−CaCl2​+Na2​O What is the theoretical yield of sodium oxide if 20.0 grams of calcium oxide was initially reacted with sodium chloride?

Answers

When 20.0 grams of calcium oxide is reacted with sodium chloride, the theoretical yield of sodium oxide can be calculated using the following method:

Step 1: Write the balanced chemical equation2NaCl + CaO → CaCl2 + Na2OStep 2: Determine the limiting reactantTo determine the limiting reactant, we need to convert the given mass of calcium oxide into moles. The molar mass of calcium oxide (CaO) is 56.08 g/mol. Therefore, the number of moles of CaO present in 20.0 g of CaO can be calculated as follows:

Number of moles of CaO = Mass of CaO / Molar mass of CaO= 20.0 g / 56.08 g/mol= 0.356 molesSimilarly, the number of moles of NaCl can be calculated using its molar mass, which is 58.44 g/mol.Moles of NaCl = Mass of NaCl / Molar mass of NaCl= Theoretically, the reaction will take place in a 1:1 mole ratio of CaO to Na2O.

Therefore, 0.356 moles of CaO will react completely with 0.356 moles of NaCl to produce 0.356 moles of Na2O.The molar mass of Na2O is 61.98 g/mol.

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Decide which method of data collection you would use to gather data for each study. Explain your reasoning. (a) A study on the effect of low dietary intake of vitamin C and iron on lead levels in adults (b) The ages of people living within 500 miles of your home

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(a) A study on the effect of low dietary intake of vitamin C and iron on lead levels in adults: The method of data collection that I would use to gather data for this study is through an experimental study.
(b) The ages of people living within 500 miles of your home: The method of data collection that I would use to gather data for this study is through a survey.

The method of data collection allows the researcher to observe the effects of independent variables on the dependent variables under strictly controlled conditions. In this case, the independent variables would be the low dietary intake of vitamin C and iron, and the dependent variable would be the lead levels in adults. To determine the causal relationship between the two, the researcher would need to manipulate the independent variables and measure the changes in the dependent variable.

Surveys allow researchers to collect data from a large number of people quickly and efficiently. In this case, the researcher would design a questionnaire and distribute it to a sample of people living within 500 miles of their home. The questionnaire would ask about the ages of the respondents and other demographic information. This method of data collection would allow the researcher to gather data from a large and diverse population, which would increase the generalizability of the findings.

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6. What is meant by a "black box" and why is this an appropriate analogy for the study of atomic structure?

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A "black box" is a term used in scientific analysis to describe a system whose internal workings are unknown. It's an appropriate analogy for the study of atomic structure because even though we may not know exactly how atoms are structured or what they look like on the inside, we can still observe their behavior and use that information to make predictions and draw conclusions. In other words, the behavior of atoms can be analyzed without fully understanding their inner workings.

When scientists are unsure of the inner workings of a system, they will often refer to it as a "black box." A black box is a system that has inputs and outputs, but whose internal workings are unknown or not understood. In other words, we know what goes in and what comes out, but we don't know how it works.A similar approach is taken in the study of atomic structure. Even though scientists do not know what atoms look like on the inside, they can still observe their behavior and use that information to make predictions and draw conclusions. By looking at how atoms interact with each other and with their environment, scientists can deduce certain properties about their internal structure. This is similar to analyzing the behavior of a black box to make predictions about its internal workings.So, this is why a black box is an appropriate analogy for the study of atomic structure.

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Consider the Lewis structure of the amino acid alanine, shown below: Then choose which option (A D) most correctly answers questions a, b, and c. A '0: H;c_N H H 0-~H Al What are the approximate bond angles around the two oxygen atoms? How many total 0 bonds are there in alanine? How many total Tr bonds are there in alanine? A. a = both 1208; b = 12; c = 1 B. a = ~1209 and ~109.58 b = 10; c = C.a = ~120" and ~109.5%; b = 9; c = D. a = ~120" and ~109.5%; b = 12; c = 1 E.a = both 109.59; b = 12; c = 1

Answers

The correct answer is D. a = ~120° and ~109.5°; b = 12; c = 1.

Step 1: The approximate bond angles around the two oxygen atoms in alanine are ~120° and ~109.5°. The first value represents the bond angle between the central carbon atom and one of the oxygen atoms, while the second value represents the bond angle between the central carbon atom and the other oxygen atom.

Step 2: There are a total of 12 oxygen (O) bonds in alanine. Each oxygen atom forms two bonds, one with the central carbon atom and another with a hydrogen atom.

Step 3: There is 1 nitrogen (N) bond in alanine. The nitrogen atom forms a single bond with the central carbon atom.

In summary, the approximate bond angles around the oxygen atoms are ~120° and ~109.5°, there are 12 oxygen (O) bonds, and there is 1 nitrogen (N) bond in alanine.

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Which is larger, 0. 45 mol of a material or 2. 75 x 10% of the same material? Justify your answer

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0.45 mol of a material is larger than 2.75 x 10% of the same material.

In order to determine which quantity is larger, we need to compare the two values provided.

0.45 mol is a measure of the amount of substance, specifically the number of particles (atoms, molecules, or ions) in a given sample. It represents a relatively large amount of the material.

On the other hand, 2.75 x 10% (or 0.275) represents a fraction of the same material. This value is obtained by multiplying the material's total quantity by 10% (or 0.1) and then by 2.75. So, it corresponds to a smaller fraction of the whole.

Comparing these two quantities, we can conclude that 0.45 mol is larger than 0.275 of the same material. The mol unit represents a greater quantity than a fraction of a material, even if the fraction is multiplied by a factor.

Therefore, based on the comparison of the two values provided, 0.45 mol of the material is larger than 2.75 x 10% of the same material.

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What product would you expect to obtain from catalytic
hydrogenation of this alkene?

Answers

The product that we should expect to obtain from the catalytic hydrogenation of the alkene depends on the reaction conditions and the alkene itself.

However, in general, catalytic hydrogenation of an alkene converts the double bond into a single bond by adding hydrogen gas (H₂) to each carbon atom in the double bond. In this process, the double bond is replaced with a single bond, and two hydrogen atoms are added to each carbon atom.


The result of this reaction is an alkane, which is a saturated hydrocarbon that contains only single bonds. This is because the hydrogenation of an alkene makes it more stable, and alkane is more stable than an alkene. The product from the hydrogenation of this alkene would be an alkane. Here is an example of the hydrogenation of ethene:
C₂H₄ + H₂ → C₂H₆


In this reaction, ethene (C₂H₄) reacts with hydrogen (H₂) gas to form ethane (C₂H₆). The double bond in ethene is replaced with a single bond, and two hydrogen atoms are added to each carbon atom.


Therefore, the product that we should expect to obtain from the catalytic hydrogenation of this alkene is an alkane, which would have one less degree of unsaturation than the starting alkene.

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Pure copper may be produced by the reaction of copper(t) sulfide with oxygen gas as follows: Cu 2 S( s)+O 2 ( g)→2Cu(s)+SO2

( g) What mass of copper(I) sulfide is required in order to prepare 0.100 kg of copper metal? 0.0752 kg 0.25 kg 0.1 kg 0.05 kg 0.125 kg

Answers

To determine the mass of copper(I) sulfide required to produce 0.100 kg of copper metal, we need to consider the stoichiometry of the reaction and perform some calculations.

The balanced chemical equation for the reaction is:

Cu2S(s) + O2(g) → 2Cu(s) + SO2(g)

From the equation, we can see that 1 mole of Cu2S reacts to produce 2 moles of Cu. We need to convert the given mass of copper metal (0.100 kg) into moles. The molar mass of copper is approximately 63.55 g/mol, so:

0.100 kg = 100 g

100 g Cu × (1 mol Cu/63.55 g Cu) = 1.572 mol Cu

Since 1 mole of Cu2S produces 2 moles of Cu, we need half the amount of moles of Cu2S:

1.572 mol Cu/2 = 0.786 mol Cu2S

Now, we can find the mass of Cu2S required using its molar mass. The molar mass of Cu2S is approximately 159.17 g/mol:

0.786 mol Cu2S × (159.17 g Cu2S/1 mol Cu2S) = 125 g

Therefore, the mass of copper(I) sulfide required to produce 0.100 kg of copper metal is 125 grams. Among the options provided, the closest answer is 0.125 kg, which is equivalent to 125 grams.

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What is the reducing agent in the redox reaction represented by the following cell notation? Cd(s) | Cd 2+(aq) || Ag+(aq) | Ag(s)
a) Ag+(aq)
b) Cd(s)
c) Ag(s)
d) Cd 2+(aq)
e) Pt

Answers

The reducing agent is Cd(s).

The reducing agent in the redox reaction represented by the following cell notation is Cd (s). The cell notation given can be separated into two half-reactions. An anode half-reaction occurs at the electrode where oxidation takes place while the cathode half-reaction occurs at the electrode where reduction takes place. The anode half-reaction is written first and the cathode half-reaction is written second. An oxidation reaction occurs at the anode while a reduction reaction occurs at the cathode.In the anode half-reaction, Cd (s) loses two electrons to form Cd2+ (aq), which is then dissolved in the solution. In the cathode half-reaction, Ag+ (aq) is reduced to Ag (s) by gaining one electron. Therefore, the reducing agent in this reaction is Cd (s).Explanation: The cell notation can be broken into two half reactions. An oxidation reaction takes place at the anode and a reduction reaction takes place at the cathode.

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what did you observe after adding the sodium carbonate to the hydrochloric acid?

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When sodium carbonate is added to hydrochloric acid, a chemical reaction occurs that produces salt, carbon dioxide, and water as products.

The reaction is represented by the equation:

Na₂CO₃ + 2HCl → 2NaCl + CO₂ + H₂O.

Sodium carbonate (Na₂CO₃) and hydrochloric acid (HCl) are both strong electrolytes, and their reaction is a type of double displacement reaction.

Upon adding sodium carbonate to hydrochloric acid, a fizzing sound and bubbling of gas will be observed. This indicates that carbon dioxide is being produced as one of the products. The salt produced as a product of the reaction is sodium chloride (NaCl), which is a white solid.

The reaction is highly exothermic, which means it releases heat. This can also be observed by touching the beaker or container holding the reaction mixture, which will feel warm or hot to the touch.

In conclusion, upon adding sodium carbonate to hydrochloric acid, the reaction produces salt, carbon dioxide, and water as products, accompanied by fizzing, bubbling of gas, and the release of heat.

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How many phosphorus atoms are present in a (2.57x10^1)g sample
of pure phosphorus?

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To find out the number of phosphorus atoms present in a sample of pure phosphorus, we need to use Avogadro's number.  there are 4.98 x [tex]10^{23}[/tex] phosphorus atoms present in a (2.57x[tex]10^{1}[/tex] )g sample of pure phosphorus.

Avogadro's number is 6.022 x [tex]10^{23}[/tex] and it represents the number of atoms or molecules in one mole of a substance.We can use the molar mass of phosphorus to calculate the number of moles present in the given sample. The molar mass of phosphorus is 30.97 g/mol.

Therefore, the number of moles present in the sample can be calculated as follows:Number of moles of phosphorus = mass of sample / molar mass= 2.57 x 10^1 g / 30.97 g/mol= 0.829 molNow that we know the number of moles of phosphorus present in the sample, we can calculate the number of atoms using Avogadro's number.

This can be done using the following formula:Number of atoms = Number of moles x Avogadro's number= 0.829 mol x 6.022 x [tex]10^{23}[/tex] atoms/mol= 4.98 x [tex]10^{23}[/tex]  atoms

Therefore, there are 4.98 x [tex]10^{23}[/tex] phosphorus atoms present in a (2.57x[tex]10^{1}[/tex] )g sample of pure phosphorus.

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What is the mass in grams of 1.50×10 12
lead ( Pb ) atoms? Round your answer to 3 significant digits.

Answers

The mass in grams of[tex]1.50 x 10^12[/tex] lead (Pb) atoms is `0.000516 g`. Given that the number of lead (Pb) atoms is [tex]1.50 x 10^12.[/tex]

We need to find the mass in grams of these atoms. The molar mass of lead (Pb) is 207.2 g/mol.

This means that 1 mole of lead (Pb) has a mass of 207.2 grams.

Hence, to find the mass of 1.50 x 10^12 lead (Pb) atoms, we need to find the number of moles and then multiply by the molar mass.

Number of moles of lead (Pb) atoms present is:

`number of atoms / Avogadro's number`

= [tex]`1.50 x 10^12 / 6.022 x 10^23`[/tex]

[tex]= 2.491 x 10^-12 mol[/tex]

Now, we can find the mass of lead (Pb) atoms by multiplying the number of moles with molar mass of lead (Pb) atoms.[tex]`mass of 1.50 x 10^12[/tex] lead (Pb) atoms`

[tex]= `2.491 x 10^-12 mol x 207.2 g/mol`[/tex]

=`0.000516 g`

Rounded to three significant figures, the mass in grams of [tex]1.50 x 10^12[/tex]lead (Pb) atoms is `0.000516 g`.

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6. Colifo bacteria are organisms that are present in the waste/feces of all wa-blooded animals and humans. Lack of sewage treatment prior to disposal is the main cause of infectious agents/pathoge

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Coliform bacteria are organisms that are present in the waste/feces of all warm-blooded animals and humans. Lack of sewage treatment prior to disposal is the main cause of infectious agents/pathogens.

According to the given information, coliform bacteria are organisms that are present in the waste/feces of all warm-blooded animals and humans. Additionally, the lack of sewage treatment before disposal is the primary reason for infectious agents/pathogens.So, more than 100 infectious agents/pathogens can be caused by coliform bacteria.

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Look up the structure of ibuprofen. Draw both stereoisomers of ibuprofen. Assign R and S configuration and indicate (circle) the active isomer.

Answers

Ibuprofen is a nonsteroidal anti-inflammatory drug that has a chemical structure composed of two main functional groups, an aromatic ring and a carboxylic acid. The molecular formula of ibuprofen is [tex]C13H18O2[/tex] and it has a molecular weight of 206.28 g/mol.

The structure of ibuprofen consists of a racemic mixture of two stereoisomers: (S)-ibuprofen and (R)-ibuprofen. These two stereoisomers are enantiomers, which means they are non-superimposable mirror images of each other.

To draw the stereoisomers of ibuprofen, we need to assign the R and S configurations to the chiral centers. The chiral center in ibuprofen is the carbon atom next to the carboxylic acid group, denoted as [tex]C2[/tex]. The other chiral center is the carbon atom at position 1 of the isobutyl group.

(S)-ibuprofen has the (S) configuration at both chiral centers, while (R)-ibuprofen has the (R) configuration at both chiral centers. The (S)-ibuprofen is the active isomer of ibuprofen and is responsible for the anti-inflammatory and analgesic effects.

In summary, the structure of ibuprofen is composed of an aromatic ring and a carboxylic acid. It exists as a racemic mixture of (S)-ibuprofen and (R)-ibuprofen stereoisomers. The active isomer is (S)-ibuprofen, which has the (S) configuration at both chiral centers.

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QUESTION 8 Classify each of the following reactions as ANABOLIC, CATABOL.IC or EXCHANGE: 1. C6​H12​O6​+O2​BCOCO2​+H2​O+ ATP 2. CO2​+H2​OCC6​H12​O6​+O2​ 14. What are the reactants in the chemical reaction in question 3 ?

Answers

1. The reaction C₆H₁₂O₆ + O₂ → CO₂ + H₂O + ATP is an example of CATABOLIC reaction.

2. The reaction CO₂ + H₂O → C₆H₁₂O₆ + O₂ is an example of ANABOLIC reaction.

3. The reactants in the chemical reaction mentioned in question 3 are not provided in the given question.

1. The reaction C₆H₁₂O₆ + O₂ → CO₂ + H₂O + ATP involves the breakdown of glucose (C₆H₁₂O₆) and oxygen (O₂) to produce carbon dioxide (CO₂), water (H₂O), and ATP. This process is known as cellular respiration and occurs in living organisms to generate energy. Since it involves the breakdown of complex molecules into simpler ones, it is classified as a catabolic reaction.

2. The reaction CO₂ + H₂O → C₆H₁₂O₆ + O₂ represents photosynthesis, where carbon dioxide (CO₂) and water (H₂O) are converted into glucose (C₆H₁₂O₆) and oxygen (O₂) in the presence of sunlight. This process is anabolic in nature as it involves the synthesis of complex molecules (glucose) from simpler ones (carbon dioxide and water).

3. The reactants in question 3 are not provided in the given question, so it is not possible to determine the reactants or classify the reaction.

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The change in entropy associated with the expansion or compression of an ideal gas is given by
ΔS = nCV ln T2
T1
+ nR ln V2
V1
where n is the number of moles of gas, CV is the molar heat capacity of the gas at constant volume, V is the volume of
the gas, and T is the absolute temperature. The subscripts indicate the initial (1) and final (2) states. In the expansion of
1.00 mole of an ideal gas from 1.00 liter to 3.00 liters, the temperature falls from 300K to 284K. Deteine the change in
entropy, ΔS, for the ideal gas in this process. Take CV = 32 R and R = 8.314 J/mol K.

Answers

The change in entropy of the ideal gas is -3.33 J/K. The given equation is ΔS = nCV ln T2/T1 + nR ln V2/V1 Where n is the number of moles of gas, CV is the molar heat capacity of the gas at constant volume, V is the volume of the gas, and T is the absolute temperature.

The subscripts indicate the initial (1) and final (2) states. In this problem, the initial volume of the gas is 1.00 L, and the final volume is 3.00 L.

Therefore, V2/V1 = 3.00/1.00

= 3.00

Also, the initial temperature of the gas is 300 K, and the final temperature is 284 K. Therefore,

T2/T1 = 284/300

= 0.947. We are given that CV = 32 R and R = 8.314 J/mol K.

Therefore, CV = 32 × 8.314

= 265.408 J/mol K. Now we can calculate the change in entropy.

ΔS = nCV ln T2/T1 + nR ln V2/V1

ΔS = (1 mol) × (265.408 J/mol K) ln (0.947) + (1 mol) × (8.314 J/mol K) ln (3.00)

ΔS = -3.33 J/K

Therefore, the change in entropy of the ideal gas is -3.33 J/K.

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A teacher wants to find the average score for a student in his class. The teacher's sample set has seven different test scores: 78,89,93,95,88,78,95. He adds all the scores together and gets a sum of 616 . Use the given dataset to calculate the sample standard deviation.

Answers

To calculate the sample standard deviation, we need to follow these steps using the given dataset:

Step 1: Find the mean (average) of the dataset.
Step 2: Subtract the mean from each data point and square the result.
Step 3: Find the sum of all the squared differences.
Step 4: Divide the sum of squared differences by (n-1), where n is the number of data points.
Step 5: Take the square root of the result from step 4.

Now let's calculate the sample standard deviation for the given dataset:

Dataset: 78, 89, 93, 95, 88, 78, 95

Step 1: Find the mean
Mean = (78 + 89 + 93 + 95 + 88 + 78 + 95) / 7
Mean = 616 / 7
Mean ≈ 88

Step 2: Subtract the mean from each data point and square the result
(78 - 88)^2 = 100
(89 - 88)^2 = 1
(93 - 88)^2 = 25
(95 - 88)^2 = 49
(88 - 88)^2 = 0
(78 - 88)^2 = 100
(95 - 88)^2 = 49

Step 3: Find the sum of all the squared differences
Sum = 100 + 1 + 25 + 49 + 0 + 100 + 49
Sum = 324

Step 4: Divide the sum of squared differences by (n-1)
Sample variance = Sum / (n-1)
Sample variance = 324 / (7-1)
Sample variance = 324 / 6
Sample variance = 54

Step 5: Take the square root of the sample variance
Sample standard deviation ≈ √54
Sample standard deviation ≈ 7.35

Therefore, the sample standard deviation for the given dataset is approximately 7.35.

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A compound exists in two fos having two different colors – pink and red. At 1.0 bar, the
density of the pink fo is 2.71 g/cm3 and the density of red fo is 2.93 g/cm3. What is the
difference between enthalpy change and internal energy change for the process when 1.0 mol of
the compound converted from the pink to red fo? The molar mass of the compound is 100
g/mol. Calculate the difference between the change in enthalpy and the change in internal energy
for this process.

Answers

The internal energy, enthalpy change, and entropy change of a chemical reaction all aid in determining if a reaction is spontaneous or not. Difference between the change in enthalpy and the change in internal energy for this process is +0.0042 kJ/mol.

For the conversion of 1 mole of a compound from the pink fo to the red fo, the difference between the enthalpy change and the internal energy change is to be calculated.  It can be done by using the formula: ∆H = ∆U + p∆Vwhere∆H = Enthalpy change∆U = Internal energy change p = Pressure ∆V = Change in volume

Molar mass of the compound, M = 100g/mol Density of pink fo, ρ1 = 2.71g/cm³ Density of red fo, ρ2 = 2.93g/cm³Volume of 1 mole of pink fo, V1 = (100g/2.71g/cm³) = 36.90 cm³ Volume of 1 mole of red fo, V2 = (100g/2.93g/cm³) = 34.12 cm³Thus, the difference in volume when 1 mole of the compound is converted from the pink fo to the red fo, ∆V = V2 – V1 = (34.12 – 36.90) cm³ = -2.78 cm³

However, the concept that pressure is directly proportional to density can be used. As density and volume are known, pressure can be calculated. Pressure of the pink fo, P1 = ρ1/M = 2.71/100 = 0.0271 barPressure of the red fo, P2 = ρ2/M = 2.93/100 = 0.0293 bar ∆P = P2 – P1 = (0.0293 – 0.0271) bar = 0.0022 barThus, pressure change ∆P = 0.0022 bar

Substituting the known values into the formula ∆H = ∆U + p∆V∆H = (1 mol)(-0.0022 bar)(-2.78 cm³) = +0.0061 kJ/molAs ∆U = q + wwhereq = Heat exchanged w = Work done Since the reaction is carried out at constant pressure, ∆H = q.

Hence, ∆U = ∆H – p∆V∆U = (0.0061 kJ/mol) – [(1 bar)(-2.78 cm³)]/1000 = +0.0019 kJ/mol Difference between the change in enthalpy and the change in internal energy for this process, ∆H – ∆U= (0.0061 kJ/mol) – (0.0019 kJ/mol) = +0.0042 kJ/mol.

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It is difficult to limit the chlorination of higher alkanes to _____ products. Mixtures of monochlorinated products are obtained for alkanes containing _____ that are not equivalent.

Answers

It is difficult to limit the chlorination of higher alkanes to specific products. Mixtures of monochlorinated products are obtained for alkanes containing non-equivalent hydrogen atoms.

Chlorination is a chemical reaction that involves the substitution of hydrogen atoms in an organic compound with chlorine atoms. When chlorinating higher alkanes, which are hydrocarbons with multiple carbon atoms, it becomes challenging to control the reaction to produce only one specific product.

The difficulty arises from the fact that higher alkanes contain non-equivalent hydrogen atoms. Non-equivalent hydrogen atoms refer to hydrogen atoms that have different chemical environments or are bonded to different carbon atoms within the molecule. These non-equivalent hydrogen atoms have varying reactivity towards chlorination.

As a result, when chlorinating higher alkanes, the chlorine atoms tend to react with different non-equivalent hydrogen atoms, leading to the formation of mixtures of monochlorinated products. These products differ in the positions where the chlorine atoms have replaced hydrogen atoms.

The formation of mixtures of monochlorinated products is a consequence of the reactivity differences among the non-equivalent hydrogen atoms present in higher alkanes.

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Which of the following names is correct according to IUPAC? A. 1,1-dimethylhexane B. 1,2-dimethylcyclohexane C. 1,2-dimethylhexane D.2,3-dimethylcyclohexane

Answers

The correct name according to IUPAC nomenclature is A. 1,1-dimethylhexane.

In IUPAC nomenclature, the naming of organic compounds follows specific rules to provide a systematic and unambiguous way to identify and describe chemical structures.

Option A, 1,1-dimethylhexane, is the correct name according to IUPAC rules. Let's break down the name to understand its structure: "1,1-dimethyl" indicates that there are two methyl (CH₃) groups attached to the first carbon atom of the hexane chain. "Hexane" indicates a six-carbon chain.

Option B, 1,2-dimethylcyclohexane, contains the term "cyclohexane," which implies a cyclic structure. However, the rest of the name suggests two methyl groups attached to the first and second carbon atoms of the cyclohexane ring, which is not accurate based on the given options.

Option C, 1,2-dimethylhexane, implies two methyl groups attached to the first and second carbon atoms of a linear hexane chain, which is different from the provided structure.

Option D, 2,3-dimethylcyclohexane, suggests two methyl groups attached to the second and third carbon atoms of a cyclohexane ring, which is again different from the given structure.

Based on the IUPAC nomenclature rules and the given options, option A, 1,1-dimethylhexane, is the correct name that accurately describes the structure of the compound.

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A sallor on a trans-Pacific solo voyage notices one day that if he puts 694.mL of fresh water into a plastic cup weighing 25.0 g, the cup floats in the seawater around his boat with the fresh water inside the cup at exactly the same level as the seawater outside the cup (see sketch at right), Calculate the amount of salt dissolved in each liter of seawater. Be sure your answer has a unit symbol, if needed, and round it to 2 significant digits. You'll need to know that the density of fresh water at the temperature of the sea around the sailor is 0.999 g remember Archimedes' Principle, that objects float when they displace a mass of water equal to their own ma

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The amount of salt dissolved in each liter of seawater is 36.7 g/L.

Archimedes' Principle states that the buoyant force on an object immersed in a fluid is equivalent to the weight of the displaced fluid and is aimed upward.

This principle is named after the ancient Greek scientist Archimedes, who discovered that the volume of an object submerged in water could be determined using this principle. This principle is used to evaluate the relative density of objects immersed in a fluid in the modern era.

Sailors on a trans-Pacific solo voyage observe one day that if they place 694 ml of fresh water into a 25.0 g plastic cup, the cup floats in the seawater around their boat with the fresh water inside the cup at the same level as the seawater outside the cup.

We must calculate the amount of salt dissolved in each liter of seawater.To solve the problem, we can use the following steps: We'll start by calculating the mass of water displaced by the cup using Archimedes' principle.Buoyant force = Weight of displaced water, Fb = W Water displaced = mWater * g Buoyant force = mCup * g, where mCup is the mass of the cupWe may express the density of seawater, ρSw, in terms of the salt dissolved in it using the following formula:ρSw = ρfw + Δρ, where Δρ is the increase in density due to salt.[tex]Δρ = ρSw - ρfw[/tex].

The volume of water displaced by the cup is equal to the volume of fresh water it contains. Thus: [tex]ρCup * Vfw = (mCup + mWater) / ρSw[/tex], where Vfw is the volume of fresh water, mWater is the mass of the water, and ρCup is the density of the cup.

Rearranging the formula gives:[tex]ρSw = (mCup + mWater) / (ρCup * Vfw) + ρfw[/tex]. Substituting the given values into the formula yields: [tex]ρSw = (25.0 g + 694.0 g) / (ρCup * 694.0 mL) + 0.999 g/mLρSw = (719.0 g) / (ρCup * 0.6940 L) + 0.999 g/mLρSw = (719.0 g) / (ρCup * 694.0 mL) + 0.999 g/mLρSw = (719.0 g) / (ρCup * 6.940 × 10-4 L) + 0.999 g/mLρSw = (719.0 g) / (ρCup * 0.0006940 L) + 0.999 g/mLρSw = 1.0358 g/mL.[/tex].

The mass of salt in each liter of seawater, mSalt, can be calculated using the formula:m [tex]Salt = Δρ / ρSw * 1000 g/LmSalt = (1.0358 - 0.9990) / 1.0358 * 1000 g/LmSalt = 36.7 g/L[/tex]. Therefore, the amount of salt dissolved in each liter of seawater is 36.7 g/L.

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he half-life of a radioactive substance is 21 years. If we begin with a sam substance, calculate the value of b to complete the model belo which gi sample remaining after t years. f(t)=85⋅(b) t
Enter your answer for b in the box below, rounded to three decimals.

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The value of b in the equation [tex]\( f(t) = 85 \cdot b^t \)[/tex] represents the decay factor of the radioactive substance. To determine the value of \( b \), we can use the information that the half-life of the substance is 21 years.

The half-life of a radioactive substance is the time it takes for half of the substance to decay. In this case, the half-life is 21 years, which means that after 21 years, the amount of the substance remaining will be half of the initial amount.

We can use this information to set up an equation:

[tex]\(\frac{1}{2} = b^{21}\)[/tex]

To solve for b, we need to take the 21st root of both sides of the equation:

[tex]\(b = \left(\frac{1}{2}\right)^{\frac{1}{21}}\)[/tex]

Using a calculator, we can evaluate this expression:

[tex]\(b \approx 0.965\)[/tex]

Therefore, the value of b in the equation [tex]\( f(t) = 85 \cdot b^t \)[/tex] is approximately 0.965.

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How many formula units are in a mole?; What is the formula mass of Fe NO3 2?; How do you find the formula units in a mol sample?; How many total atoms are represented Fe NO3 2?

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A mole contains 6.022 × 10^23 formula units. The total number of atoms in Fe(NO3)2 is 9.

In a mole of any substance, there are always 6.022 × 10^23 formula units. This value is known as Avogadro's number and is a fundamental constant in chemistry. A formula unit refers to the smallest whole number ratio of ions or atoms in an ionic or covalent compound.

To calculate the formula mass of Fe(NO3)2, you need to determine the atomic masses of each element and multiply them by their respective subscripts.

The atomic mass of iron (Fe) is approximately 55.85 g/mol, the atomic mass of nitrogen (N) is about 14.01 g/mol, and the atomic mass of oxygen (O) is roughly 16.00 g/mol. The subscript 2 indicates that there are two nitrate (NO3) groups. Thus, the formula mass can be calculated as follows:

Fe(NO3)2 = (1 × 55.85 g/mol) + (2 × (14.01 g/mol + 3 × 16.00 g/mol))

= 55.85 g/mol + 2 × (14.01 g/mol + 48.00 g/mol)

= 55.85 g/mol + 2 × (14.01 g/mol + 48.00 g/mol)

= 55.85 g/mol + 2 × (14.01 g/mol + 48.00 g/mol)

= 55.85 g/mol + 2 × 62.01 g/mol

= 55.85 g/mol + 124.02 g/mol

= 179.87 g/mol

To determine the number of formula units in a given amount of a substance, you need to know the mass of the sample and the formula mass of the compound. Then, you can use the following formula:

Number of formula units = (mass of sample)/(formula mass of compound)

To find the total number of atoms represented by Fe(NO3)2, you need to consider the subscripts in the formula.

The subscript 2 after NO3 indicates that there are two nitrate groups. Each nitrate group consists of one nitrogen atom and three oxygen atoms. Additionally, there is one iron atom in the formula. Therefore, the total number of atoms in Fe(NO3)2 is:

1 iron atom + (2 nitrate groups × (1 nitrogen atom + 3 oxygen atoms))

= 1 + (2 × (1 + 3))

= 1 + (2 × 4)

= 1 + 8

= 9 atoms

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You have 150.0 {~mL} of a 0.565 {M} solution of {Ce}({NO}_{3})_{4} . What is the concentration of the nitrate ions in the solution?

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The molecular weight of cerium(IV) nitrate hexahydrate is 446.24 g/mol. Therefore, one mole of cerium(IV) nitrate hexahydrate contains one mole of cerium(IV) ions, which will combine with four moles of nitrate ions to form one mole of cerium(IV) nitrate hexahydrate.

The formula for the concentration of ions in a solution is C = n/V where C is the concentration of ions, n is the number of moles of ions, and V is the volume of the solution in liters. The first step in solving this problem is to calculate the number of moles of cerium(IV) nitrate hexahydrate in 150.0 mL of a 0.565 M solution. This can be done using the following formula:n = M x V n = 0.565 mol/L x 0.150 L= 0.08475 mol of cerium(IV) nitrate hexahydrate This amount contains four times as many moles of nitrate ions as cerium(IV) ions.

Therefore, the number of moles of nitrate ions is: nitrate ions = 4 x 0.08475 militate ions = 0.339 molThe volume of the solution is 150.0 mL, which is equal to 0.150 L. Using the formula given above, we can calculate the concentration of nitrate ions :C = n/V= 0.339 mol/0.150 LC = 2.26 M Therefore, the concentration of nitrate ions in the solution is 2.26 M.

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name the following compound. there is a structure of a cc double bond. the first (from left to right) carbon has a ch3 group attached above and an h atom attached below the plane of the bond. the other carbon has a ch2ch3 group attached above and an h atom attached below the plane of the bond. name the following compound. there is a structure of a cc double bond. the first (from left to right) carbon has a ch3 group attached above and an h atom attached below the plane of the bond. the other carbon has a ch2ch3 group attached above and an h atom attached below the plane of the bond. cis-2-butane cis-2-pentene trans-2-pentene 2-butane trans-2-butene

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The compound described consists of a CC double bond, where the first carbon has a CH3 group above and an H atom below the plane of the bond, and the other carbon has a CH2CH3 group above and an H atom below the plane of the bond hence the name of the compound is cis-2-butene.

To name this compound, we need to consider the positions of the substituents and the configuration of the double bond. Since the CH3 and CH2CH3 groups are on the same side of the double bond, this is an example of cis configuration. To name the compound, we start by identifying the longest carbon chain containing the double bond, which in this case is a 2-carbon chain.

Next, we assign a locator number to each carbon in the chain. The carbon with the CH3 group is carbon 1, and the carbon with the CH2CH3 group is carbon 2. Finally, we combine the locator numbers with the prefix for the substituents. In this case, the CH3 group is a methyl group and the CH2CH3 group is an ethyl group. Putting it all together, the name of the compound is cis-2-butene.

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Which of these is the function of a poly (A) signal sequence?
-It adds the poly (A) tail to the 3' end of the mRNA.
-It codes for a sequence in eukaryotic transcripts that signals enzymatic cleavage~10 35 nucleotides away.
-It allows the 3' end of the mRNA to attach to the ribosome.
-It is a sequence that codes for the hydrolysis of the RNA polymerase.
-It adds a 7-methylguanosine cap to the 3' end of the mRNA.

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Poly (A) signal sequence is an RNA element that regulates the post-transcriptional processing of most eukaryotic genes. The Poly (A) signal sequence is responsible for adding the poly (A) tail to the 3' end of the mRNA.

It is a sequence that codes for enzymatic cleavage of the newly transcribed pre-mRNA. This signal marks the end of the coding region and the beginning of the 3′-untranslated region (3′-UTR) of the pre-mRNA.

The 3' end of the mRNA then attaches to the ribosome so that the mRNA can be translated into a protein. The 5' cap, which consists of a 7-methylguanosine structure, is added to the 5' end of the mRNA. The Poly (A) signal sequence is one of the key post-transcriptional mechanisms that regulate the timing and efficiency of mRNA translation. The length of the poly (A) tail is often a critical determinant of mRNA stability and translation efficiency.

Typically, the longer the poly (A) tail, the more stable and efficiently translated the mRNA. This is because the poly (A) tail binds to specific proteins that protect the mRNA from degradation and help the mRNA bind to ribosomes. The Poly (A) signal sequence is, therefore, a critical element in controlling gene expression.

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what kinds of attractive forces may exist between particles in molecular crystals? check all that apply. what kinds of attractive forces may exist between particles in molecular crystals?check all that apply. ionic bonds dipole-dipole interactions hydrogen bonding london dispersion forces

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All the listed options (ionic bonds, dipole-dipole interactions, hydrogen bonding, and London dispersion forces) may exist between particles in molecular crystals.

The attractive forces that may exist between particles in molecular crystals include:

Ionic bonds: Ionic compounds, consisting of positively and negatively charged ions, can form crystal structures held together by strong electrostatic attractions.

Dipole-dipole interactions: Molecules with permanent dipole moments can interact with each other through the attraction of their positive and negative ends.

Hydrogen bonding: Hydrogen bonding occurs when a hydrogen atom is bonded to an electronegative atom (such as oxygen, nitrogen, or fluorine) and forms a weak bond with another electronegative atom in a neighboring molecule.

London dispersion forces: Also known as van der Waals forces, these forces arise from temporary fluctuations in electron density, resulting in the creation of temporary dipoles that induce dipole moments in neighboring molecules.

Hence, all of the listed options (ionic bonds, dipole-dipole interactions, hydrogen bonding, and London dispersion forces) may exist between particles in molecular crystals.

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km a. is the concentration of substrate where the enzyme achieves 1/2 vmax. b. is equal to ks. c. measures the stability of the product. d. is high if the enzyme has high affinity for the substrate. e. all of the above are correct.

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Km, also known as the Michaelis constant, is a measure of the affinity between an enzyme and its substrate. The correct answer is: a. Km is the concentration of substrate where the enzyme achieves 1/2 vmax.

It represents the concentration of substrate at which the enzyme achieves half of its maximum reaction velocity (vmax). In other words, Km indicates the substrate concentration required for the enzyme to be half-saturated.

b. Ks, or substrate dissociation constant, is a term used in the context of enzyme-substrate binding. It represents the equilibrium constant for the dissociation of the enzyme-substrate complex into the enzyme and substrate. Ks is different from Km, which specifically measures the substrate concentration needed for the enzyme to achieve 1/2 vmax.

c. Km does not measure the stability of the product. Km is not related to the stability of the product. It is solely focused on the relationship between the enzyme and substrate, specifically the affinity of the enzyme for the substrate.

d. This statement is incorrect. In fact, Km is low if the enzyme has a high affinity for the substrate. A low Km value indicates that the enzyme requires a low concentration of the substrate to achieve 1/2 vmax, meaning it has a high affinity for the substrate. Conversely, a high Km value indicates that the enzyme has a low affinity for the substrate and requires a higher concentration of the substrate to achieve 1/2 vmax.

Hence, e is the correct option.

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If 45 g of NaCl are dissolved in H2O to prepare 500 mL of
solution, determine its concentration in % W/V.

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The concentration of NaCl in the solution is 9% W/V, indicating that there are 9 grams of NaCl dissolved per 100 mL of solution

To determine the concentration of a solution in % W/V (weight/volume), we need to calculate the mass of solute (NaCl) dissolved in a given volume of solvent (H₂O) and express it as a percentage.

Mass of NaCl = 45 g

Volume of solution (H₂O) = 500 mL = 0.5 L

Concentration in % W/V = (Mass of NaCl / Volume of solution) × 100

Substituting the given values:

Concentration in % W/V = (45 g / 0.5 L) × 100 = 90 g/L × 100 = 9,000 g/L

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Calculate the effective nuclear charge of a 5 s electron of Rb. C. 1.00 D. 2.57 1.85 2.20 Question 19 Calculate the effective nuclear charge of a 3 d electron of Cu. 13.02 17.05 7.85 8.20

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Effective Nuclear Charge:The effective nuclear charge (Zeff) is the net positive charge experienced by valence electrons of an atom. It is equivalent to the atomic number minus the number of inner-shell electrons in an atom.

The screening impact of internal electrons decreases the attraction between the positively charged nucleus and the negatively charged valence electrons. As a result, the valence electrons experience a lower effective nuclear charge. The effective nuclear charge can be calculated by the formula Zeff = Z – S where Z is the atomic number and S is the screening constant.

a. The electron configuration of Rb is [Kr] 5s1. Rb has 37 electrons in total and has a Kr noble gas core. The screening constant is S=0.35. Therefore, Zeff = Z – S = 37 – 0.35 = 36.65.
b. The electron configuration of Cu is [Ar] 3d10 4s1. The Cu+ ion, which lacks one electron, is the ion most frequently encountered in Cu compounds. Since the question is about a 3d electron, let's first fill the 3d orbitals: [Ar] 3d10. The 4s electron comes before the 3d electron because 4s has a lower energy level. S=0.78 for 3d electrons. Therefore, Zeff = Z – S = 29 – 0.78 = 28.22.

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a solution is made by dissolving 4.50 g of nacl in enough water to make 70.0 ml of solution. what is the concentration of sodium chloride in units of weight/volume percent?

Answers

To calculate the weight/volume percent concentration of sodium chloride in the solution, we need to determine the mass of sodium chloride and the volume of the solution.

Given to us is:

Mass of sodium chloride (NaCl) = 4.50 g

Volume of solution = 70.0 ml

First, we need to convert the volume of the solution from milliliters to liters:

Volume of solution = 70.0 ml = 70.0 ml × (1 L / 1000 ml)

Volume of solution  = 0.070 L

Next, we can calculate the weight/volume percent concentration using the formula:

Weight/volume percent = (Mass of solute / Volume of solution) × 100

Plugging in the values:

Weight/volume percent = (4.50 g / 0.070 L) × 100

Weight/volume percent = 64.29%

Therefore, the concentration of sodium chloride in units of weight/volume percent is approximately 64.29%.

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