Answer:
4.96 mol/dm³
Explanation:
From the question,
Mass of NaCl that dissolved in 0.5L of water = 500-346.8 = 153.2 g.
Therefore, 145.2(1/0.5)g of NaCl will dissolve in 1 L of water
mass of NaCl that will dissolve in 1 L of water = 290.4 g/dm³
Molar mass of NaCl = 58.5 g/mol.
Solubility is the amount of substance in mol that will dissolve in 1 L or 1 dm³ Solution.
solubility in (mol/dm³) = solubility in (g/dm³)/molar mass.
solubility in (mol/dm³) = 290.4/58.5
solubility in (mol/dm³) = 4.96 mol/dm³
Drag the description to the category
Answer:
ok
Explanation:
We are all familiar with the general principles of operation of an internal combustion engine: the combustion of fuel drives out the piston. It is possible to imagine engines that use reactions other than combustions, and we need to assess the work they can do. A chemical reaction takes place in a container of cross-sectional area 100.0 cm^2; the container has a piston at one end. As a result of the reaction, the piston is pushed out through 10 cm against a constant external pressure of 100 kPa. Calculate the work done by the system in Joules.
Answer:
The work done by the system is 100 J
Explanation:
Given details
The cross sectional area of the of the container is A = 100.0 cm^2 = 0.01m²
The total distance pushed by the piston is d = 10 cm = 0.10m
The total external pressure by which piston pushed is P = 100 kPa
From above data, the following relation can be used to determine the change in volume of the container
∆V = A * d
∆V = 0.01 * 0.10 = 0.001 m³
By using the following relation, the work done by the system is calculated as;
Work done W = P * ∆V
W = 100 * 0.001 = 0.1 kJ = 100 J
The work done by the system is 100 J
Need help asap!!! Can someone please help me?
Answer:
The answer is option C.
voltage (V) = Current( I ) × Resistance (R)
V = IR
I = V/ R
V = 10V R = 20Ω
I = 10/20 = 1/2
I = 0.50A
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Helium (He) is the lightest noble gas component of air, and xenon (Xe) is the heaviest. Perform the following calculations, using R = 8.314 J/(mol·K) and ℳ in kg/mol. (a) Find the rms speed of He in winter (0.°C) and in summer (30.°C). Enter your answers in scientific notation. × 10 m/s (winter) × 10 m/s (summer) (b) Find the ratio of the rms speed of He to that of Xe at 30.°C. (rate He)/(rate Xe) (c) Find the average kinetic energy per mole of He and of Xe at 30.°C. Enter your answers in scientific notation. × 10 J/mol for He × 10 J/mol for Xe (d) Find the average kinetic energy per molecule of He at 30.°C. Enter your answer in scientific notation. × 10 J/He atom
Answer:
Explanation:
Hello,
Data;
R = 8.314J/(mol.K)
Temp (winter) = 0°C = (0 + 273.15)K = 274.15K
Temp.(summer) = 30°C = (30 + 273.15)K = 303.15K
Molar mass of He = 4g/mol = 0.004kg/mol
Molar mass of Xe = 131.29g/mol = 0.131kg/mol
a) rms speed in winter and summer
Vrms = √(3RT/M)
R = gas constant
T = temperature of the gas
M = molar mass of the gas
In winter,
Vrms = √(3×8.314×273.15) / 0.004
Vrms = 1.30×10³m/s
In summer
Vrms = √(3×8.314×303.15) / 0.004
Vrms = 1.37×10³m/s
b) Vrms of Xe at 30°C
Vrms = √(3 × 8.314 × 303.15) / 0.131
Vrms of Xe = 240.24m/s = 2.40×10²m/s
Vrms of He = 1.37×10³m/s
Rate of He / rate of Xe = 1.37×10³ / 2.40×10²
Rate of He / rate of Xe = 5.7
c) K.E per mole
At 30°C
K.E of He = (3/2) × 8.314 × 303.15
K.E of He = 3.78×10³J/mol
K.E of Xe = (3/2) × 8.314 × 303.15
K.E of Xe = 3.78×10³J/mol
d) K.E per molecule = ½mv²
K.E of He molecule = ½ × 0.004 × 1.37×10³
K.E = 2.74J
The rms speed of He in winter and in summer are 1.30×10³m/s & 1.37×10³m/s respectively, ratio of the rms speed of He to that of Xe at 30 degree celsius is 5.7, average kinetic energy per mole of He and of Xe and average kinetic energy per molecule of He are discussed below.
How do we calculate the root mean square velocity?Root mean square velocity of the gases will be calculated as:
Vrms = √(3RT/M), where
R = universal gas constant = 8.314J/(mol.K)
M = molar mass of gas in kg/mol
T = temperature in K
Root mean square velocity of Helium at 0°C or 273.15K and 30°C or 303.15K will be calculated as:At 273.15K-
Vrms = √(3×8.314×273.15) / 0.004 = 1.30×10³m/s
At 303.15K-
Vrms = √(3×8.314×303.15) / 0.004 = 1.37×10³m/s
Vrms (winter×summer) = 1.30×10³m/s × 1.37×10³m/s = 1.78×10⁶m/s
Vrms of Xe at 303.15KVrms = √(3 × 8.314 × 303.15) / 0.131
Vrms of Xe = 240.24m/s = 2.40×10²m/s
Vrms of He = 1.37×10³m/s
Rate of He / rate of Xe = 1.37×10³ / 2.40×10²
Rate of He / rate of Xe = 5.7
Average kinetic energy will be calculated as:K.E = 3RT / 2N, where
N = avgadros number = 6.022×10²³ atoms/mole
Average kinetic energy per mole of He & Xe at 303.15K is same as:
K.E = 3/2(1.38 × 10⁻²³J/K)(303.15K) = 6.2 × 10⁻²⁵J/mol
Average kinetic energy per molecule of He will be calculated as:K.E of He molecule = ½ × 0.004 × 1.37×10³
K.E = 2.74J
Hence, calculations for the given points are described above.
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There are five constitutional isomers with the molecular formula C6H14. When treated with chlorine at 300°C, isomer A gives a mixture of two monochlorination products. Under the same conditions, isomer B gives a mixture of five monochlorination products, isomer C gives four monochlorination products, and isomer D gives a mixture of three monochlorination products. From this information, draw the structural formula of isomer D.
Answer:
Pentane or 2,2-dimethylbutane
Explanation:
I've numbered the isomeric hexanes from 1 to 5 and labelled the sets of equivalent hydrogens.
The results are
Isomer 1— three sets of equivalent hydrogens
Isomer 2— five sets of equivalent hydrogens
Isomer 3— four sets of equivalent hydrogens
Isomer 4— two sets of equivalent hydrogens
Isomer 5— three sets of equivalent hydrogens
Each set will give one monochloro substitution product.
4 = A. Two monochloro isomers.
2 = B. Five monochloro isomers.
3 = C. Four monochloro isomers.
Isomers 1 and 5 each give three monochloro isomers.
Thus, we cannot assign Structure D definitively.
D is either pentane or 2,2-dimethylbutane.
Calculate the theoretical percentage of water for the following hydrates.
(a) manganese(II) monohydrate, MnSO4 H2O
(b) manganese(II) tetrahydrate, MnSO4 4H2O
Answer:
(a) [tex]\% H_2O=10.65\%[/tex]
(b) [tex]\% H_2O=32.2[/tex]
Explanation:
Hello.
For this questions we must consider the ratio of the molar mass of water to hydrated compound molar mass as shown below:
(a) In this case, we can consider that inside the manganese (II) sulfate monohydrate, whose molar mass is 169.02 g/mol, there is one water molecule that has a molar mass of 18 g/mol, for which the theoretical percentage of water is:
[tex]\% H_2O=\frac{18g/mol}{169.0g/mol} *100\%\\\\\% H_2O=10.65\%[/tex]
(b) In this case, we can consider that inside the manganese (II) sulfate tetrahydrate, whose molar mass is 223.1 g/mol, there are four water molecules that have a molar mass of 4*18 g/mol, for which the theoretical percentage of water is:
[tex]\% H_2O=\frac{4*18g/mol}{223.1g/mol} *100\%\\\\\% H_2O=32.27\%[/tex]
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Aqueous calcium chloride reacts with aqueous potassium carbonate in a double-displacement reaction. Write a balanced equation to describe this reaction. Include states of matter in your answer. Click in the answer box to open the symbol palett
Answer: [tex]CaCl_2(aq)+K_2CO_3(aq)\rightarrow 2KCl(aq)+CaCO_3(s)[/tex]
Explanation:
A double displacement reaction is one in which exchange of ions take place. The salts which are soluble in water are designated by symbol (aq) and those which are insoluble in water and remain in solid form are represented by (s) after their chemical formulas.
The balanced reaction between aqueous calcium chloride reacts with aqueous potassium carbonate is shown as:
[tex]CaCl_2(aq)+K_2CO_3(aq)\rightarrow 2KCl(aq)+CaCO_3(s)[/tex]
How many moles of aqueous magnesium ions and chloride ions are formed when 0.240 mol of magnesium chloride dissolves in water
Answer:
1. 0.240 mole of magnesium ion, Mg^2+
2. 0.48 mole of chloride ion, Cl^-
Explanation:
We'll begin by writing the balanced dissociation equation for magnesium chloride. This is given below:
MgCl2(aq) —> Mg^2+(aq) +2Cl^-(aq)
1. Determination of the number of mole of magnesium ion, Mg^2+ obtained from the dissolution 0.240 mol of magnesium chloride, MgCl2 in water. This is illustrated below:
From the balanced equation above,
1 mole of MgCl2 produced 1 mole of Mg^2+.
Therefore, 0.240 mole of MgCl2 will also produce 0.240 mole of Mg^2+.
Therefore, 0.240 mole of magnesium ion, Mg^2+ is produced.
2. Determination of the number of mole of chloride ion, Cl^- obtained from the dissolution 0.240 mol of magnesium chloride, MgCl2 in water. This is illustrated below:
From the balanced equation above,
1 mole of MgCl2 produced 2 moles of Cl^-.
Therefore, 0.240 mole of MgCl2 will produce = (0.240 x 2) = 0.48 mole of Cl^-.
Therefore, 0.48 mole of chloride ion, Cl^- is produced.
The two reactions above, show routes for conversion of an alkene into an oxirane. If the starting alkene is cis-3-hexene the configurations of the oxirane products, A and B are Product A: _______ Product B: _______ Will either of these two oxirane products rotate the plane of polarization of plane polarized light? _____
Answer:
Product A: cis; no
Product B: cis: no
Explanation:
Two common methods of forming oxiranes from alkenes are:
Reaction with peroxyacids Formation of a halohydrin followed by reaction with base
1. Reaction with peroxyacids
(a) Stereochemistry
The reaction with a peroxyacid is a syn addition, so the product has the same stereochemistry as the alkene.
The starting alkene is cis, so the product is cis-2,3-diethyloxirane.
(b) Configuration
The product is optically inactive because it has an internal plane of symmetry.
It will not rotate the plane of polarized light.
2. Halohydrin formation
(a) Stereochemistry
The halogenation of the alkene proceeds via a cyclic halonium ion.
The backside displacement of halide ion by alkoxide is also stereospecific, so a cis alkene gives a cis epoxide.
The product is cis-2,3-diethyloxirane.
(b) Configuration
The cyclic halonium ion has an internal plane of symmetry, as does the product (meso).
The oxirane will not rotate the plane of polarized light.
What is the rate constant of a reaction if rate = 1.5 (mol/L)/s, [A] is 1 M, [B] is
3 M, m = 2, and n = 1?
k=
rate
[A]" [B]"
A. 0.17
B. 13.5
C. 0.5
D. 4.5
[tex]\mathfrak{\huge{\pink{\underline{\underline{AnSwEr:-}}}}}[/tex]
Actually Welcome to the Concept of the Rate Constant.
Here, the "K" is the Rate Constant.
so the ANSWER IS C.) 0.5
The rate of constant is 0.5.
The answer is option C.
How do find the rate of constant?To determine the fee regulation from a desk, you have to mathematically calculate how differences in molar concentrations of reactants affect the response charge to parent out the order of every reactant. Then, plug in values of the response charge and reactant concentrations to discover the particular rate constant.
What's the rate of constant?The particular rate constant is the proportionality steady touching on the rate of the reaction to the concentrations of reactants. The fee regulation and the unique charge constant for any chemical response need to be decided experimentally. The price of the fee regular is temperature-established.
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How many grams of material is lost in the aqueous phase if two extractions are carried out on 100 mL of a 5% (m/v) aqueous solution using 100 mL of ethyl acetate per extraction if the partition coefficient is 8
Answer:
4.94g of material
Explanation:
Partition coefficient (Kp) of a substance is defined as the ratio between concentration of organic solution and aqueous solution, that is:
Kp = 8 = Concentration in Ethyl acetate / Concentration in water
100mL of a 5% solution contains 5g of material in 100mL of water. Thus:
8 = X / 100mL / (5g-X) / 100mL
Where X is the amount of material in grams that comes to the organic phase.
8 = X / 100mL / (5g-X) / 100mL
8 = 100X / (500-100X)
4000 - 800X = 100X
4000 = 900X
4.44g = X
Thus, in the first extraction you will lost 4.44g of material from the aqueous phase.
And will remain 5g-4.44g = 0.56g.
In the second extraction:
8 = X / 100mL / (0.56g-X) / 100mL
8 = 100X / (56-100X)
448 - 800X = 100X
448 = 900X
0.50g = X
In the second extraction, you will extract 0.50g of material
Thus, after the two extraction you will lost:
4.44g + 0.50g = 4.94g of material
Question 4
2 pts
A careless chemistry student performed a chemical reaction where his theoretical yield of
Magnesium oxide was 57.82 grams, but he actually produced 12.89 grams. What is his percent yield
for this experiment? (include the number with 4 significant figures but no units)
Answer:
22.29%
Explanation:
Percent yield = experimental yield / theoretical yield * 100
= 12.89 / 57.82 * 100 = 22.29%
Lewis structure of methyl metcaptain
Answer:
The lewis structure of the compounds can be drawn by making the skeleton of the molecule first. Then the different atoms are arranged and the electrons are arranged in their bonding pattern. The lone pair of the atoms, which are not involved in the bonding are represented by the dots.
So the lewis structures of both the compound methyl mercaptan has been in the attached image:
Spelling of methyl metcaptain is wrong, the correct spelling is methyl mercaptan.
Answer:
Methyl mercaptan is also known as Methanethiol with the chemical formula CH3SH and it is an organosulfur compound.
For lewis structure of methyl mercaptan (CH3SH), there are total 14 valence electrons. Four hydrogen atoms has one valence electron each, carbon has four valence electrons and sulfur has six valence electrons. Carbon form one bond with three hydrogen atoms by sharing one electron with each, carbon form one single bond with sulfur atom by sharing one electron with it and sulfur form one single bond with hydrogen. Sulfur left with four unpair electrons.
Consider the three statements below. Which numbered response contains all the statements that are true and no false statements?
I. Hydration is a special case of solvation in which the solvent is water.
II. The oxygen end of water molecules is attracted toward Ca2+ ions.
III. The hydrogen end of water molecules is attracted toward Cl- ions.
a) I, II, and III
b) I and II
c) III
d) I
e) II
Answer:
a) I, II, and III
Explanation:
For the first statement;
Solvation, is the process of attraction and association of molecules of a solvent with molecules or ions of a solute. if the solvent is water, we call this process hydration.
This means the statement is TRUE.
For the second statement;
The negatively-charged side of the water molecules are attracted to positively-charged ions. In the case of water, the oxygen end is the negatively charged side of water. This means the statement is TRUE.
For the third statement;
The positively-charged side of the water molecules are attracted to the negatively-charged chloride ions. In the case of water, the hydrogen end is the positively charged side of water. This means the statement is TRUE.
Going through the options, we can tell that the correct option is option A.
You've just synthesized a new molecule and need to purify it by recrystallization. You find that it is poorly soluble in water and highly soluble in ethanol, even when cooled in ice. What solvent should work in this situation
Answer:
Water is used as a solvent.
Explanation:
In order to purify the new molecule, recrystallization occurs in which the new molecule should be added in water and heated the water in order to increase the solubility of the solution. The new molecule dissolve in water while the impurity remains undissolved which can be removed from the solution and then remain the solution to be cold down and the new molecule will again undissolved and the molecule can be extracted without any impurities. We use water instead of ethanol due to lower solubility.
What is science?
O A. Attempting to solve ethical problems through research
O B. Learning about the physical world through observation
O C. Determining a body of knowledge that never changes
O D. Using rules and patterns to predict what humans will do
SUBMIT
Answer:
The answer is B
Explanation:
Answer:
B. Learning about the physical world through observation
Explanation:
A p e x 2021 :) Trust me!
what is the modification of the Dalton's atomic theory
Answer:
Dalton's theory had to be modified after mass spectrometry experiments demonstrated that atoms of the same element can have different masses because the number of neutrons can vary for different isotopes of the same element
. Explain with examples following characteristics of chemical reactions:
a. Change of colour b. Evolution of gas c. Change of smell d. Change of state
Answer:
See explanation.
Explanation:
Hello,
a. In this case, the change of color is evident for instance when copper reacts with nitric acid to form hydrogen and copper (II) nitrate since copper orange-like and nitric acid is colorless, but copper (II) nitrate is green (dry) or blue (hydrated).
b. In this case, when we make react hydrochloric acid and magnesium, we notice a gas giving off while the magnesium chloride remains aqueous, due to the fact that magnesium displaces hydrogen which is given off as a gas.
c. In this case, we can consider an egg since when it is edible it has a tasty smell but when it decomposes to rotten egg, hydrogen sulfide is given off due to the action of specific bacteria, causing a change in smell to a quite stinky one.
d. In this case, a reaction by which a change of state is exhibited is for instance when aqueous lead (II) nitrate reacts with aqueous potassium iodide to yield potassium nitrate which remains aqueous whereas the lead (II) iodide precipitates out as a solid due to its tiny solubility as a yellow solid.
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Two stereoisomers are obtained from the reaction of HBr with (S)-4-bromo-1-pentene. One of the stereoisomers is optically active, and the other is not. Draw the structure of the optically active stereoisomer.
Answer:
See explanation
Explanation:
In this case, we have an addition reaction. Additionally, this is a marknovnikov addition, therefore the "Br" atom would be added in the most substituted carbon (in this case carbon a). And we are going to have 2 enantiomers (2S,4S)-2,4-dibromopentane and (2R,4S)-2,4-dibromopentane. In the case of (2R,4S)-2,4-dibromopentane we will have a symmetry plane (a point in the molecule in which we can divide the molecule into two equal parts). When this happens we will have a mesocompound and we will not have optical activity.
See figure 1
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What would have happened to your % Transmittance reading and to your calculations of Keq if the spectrophotometer had been set at 520 nm rather than 447nm
Answer:
On the off chance that the wavelength(λ) maximum worth has been changed to 520 nm from 470 nm on the spectrophotometer, less light would be absorbed and in this way %T would be higher than the one found at 470 nm. The wavelength utilized at 520 nm isn't adequate for the excitation and consequently lesser light is absorbed by the arrangement.
Explanation:
A spectrophotometer is an analytical equipment used to quantitatively gauge the transmission(passage) or impression of visible light, UV light or infrared light through a medium.
Transmittance (τ) is the ratio of the brilliant or luminous flux at a given wavelength that is transmitted to that of the incident radiation.
where, Keq is the equilibrium constant.
On the off chance that the wavelength(λ) has been changed to 520 nm from 470 nm on the spectrophotometer, less light would be absorbed and in this way %T would be higher than the one found at 470 nm.
What happens to Transmittance?A spectrophotometer is an analytical equipment used to quantitatively gauge the transmission(passage) or impression of visible light, UV light or infrared light through a medium. Transmittance (τ) is the ratio of the brilliant or luminous flux at a given wavelength that is transmitted to that of the incident radiation. The wavelength utilized at 520 nm isn't adequate for the excitation and consequently lesser light is absorbed by the arrangement. As the concentration goes up, more radiation is absorbed and the absorbance goes up. Therefore, the absorbance is directly proportional to the concentration.
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g Which statement is incorrect regarding oxidation? Oxidation is a "gain" of electrons. Oxidation is the combination with O atoms. Oxidation is an increase in oxidation state. Oxidation is always accompanied by reduction. none of these
Answer:
The incorrect statement from the options is OXIDATION IS A "GAIN" OF ELECTRONS
Explanation:
Oxidation in a redox reaction is the loss of electrons. It is also the increase in the oxidation states of an atom or ion or atoms in a molecule. A redox reaction is a type of chemical reaction in which there is a transfer of electrons from an atom or ion to another resulting in a change in oxidation states of the substances involved. The reducing agent in the reaction is undergoes oxidation by losing electrons while the oxidating agent is reduced that is it gains electrons at the end of the reaction. The atom or ion from which electron is lost is said to be oxidized while the other atom or ion involved in the reaction is reduced.
Oxidation is also the combination with O atoms and it is always accompanied by reduction because oxidation forms a half of the whole redox reaction. A substance cannot be oxidized except it has reduced another substance by losing electrons to it.
A chemist dissolves 867. mg of pure barium hydroxide in enough water to make up 170. mL of solution. Calculate the pH of the solution. (The temperature of the solution is 25 degree C.) Be sure your answer has the correct number of significant digits.
Answer: The pH of the solution is 11.2
Explanation:
Molarity of a solution is defined as the number of moles of solute dissolved per liter of the solution.
[tex]Molarity=\frac{n\times 1000}{V_s}[/tex]
where,
n = moles of solute
[tex]V_s[/tex] = volume of solution in ml
moles of [tex]Ba(OH)_2[/tex] = [tex]\frac{\text {given mass}}{\text {Molar mass}}=\frac{0.867g}{171g/mol}=0.00507mol[/tex] (1g=1000mg)
Now put all the given values in the formula of molality, we get
[tex]Molarity=\frac{0.00507\times 1000}{170}[/tex]
[tex]Molarity=0.0298[/tex]
pH or pOH is the measure of acidity or alkalinity of a solution.
pH is calculated by taking negative logarithm of hydrogen ion concentration.
[tex]pOH=-\log [OH^-][/tex]
[tex]Ba(OH)_2\rightarrow Ba^{2+}+2OH^{-}[/tex]
According to stoichiometry,
1 mole of [tex]Ba(OH)_2[/tex] gives 2 mole of [tex]OH^-[/tex]
Thus 0.0298 moles of [tex]Ba(OH)_2[/tex] gives =[tex]\frac{2}{1}\times 0.0298=0.0596[/tex] moles of [tex]OH^-[/tex]
Putting in the values:
[tex]pOH=-\log[0.0596]=2.82[/tex]
[tex]pH+pOH=14[/tex]
[tex]pH=14-2.82[/tex]
[tex]pH=11.2[/tex]
Thus the pH of the solution is 11.2
How many carbon atoms are represented by the model below
A) 0
B) 3
C) 2
D) 1
Answer:
Option (B) 3.
Explanation:
In the model represented above, the two extreme represent carbon atoms since no other group are attached to it. The joint at the middle also represent carbon atom.
Thus, we can write a more simplify illustration for the model above as
C—C—C
From the above illustration, we can see that the model contains 3 carbon atom.
Identify the type of solid for AgCl. Identify the type of solid for AgCl. metallic atomic solid nonbonding atomic solid molecular solid ionic solid networking atomic solid
Silver chloride (AgCl) is a crystalline solid substance that is composed of silver and chloride ions. AgCl is an ionic solid. Thus, option D is correct.
What are ionic solids?Ionic solids are substances that show the properties of solid matter and have ionic, positive, and negative charges in them. They are linked together by the attraction of the opposite charges.
The silver metal in the molecule has a positive charge and the chloride ions are negative in charge making them establish an ionic bond.
The solid molecule is held together by ionic bonds and not the covalent or other metallic bonds. The cations and anions of AgCl are linked together by the electrostatic forces that make their structure appear strong and brittle.
Therefore, AgCl has been known as an ionic solid.
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oxidation number of Se in Se8
Answer:
0.
Explanation:
All elements existing on their own in their free states has an oxidation number of 0.
The oxidation number of Se in Se8 is 0. The element Se in its elemental state has an oxidation number of 0.
Chemistry uses the idea of oxidation number, also known as oxidation state, to describe the charge that an atom seems to have when it forms a compound or ion. It is a notion that aids in our comprehension of how electrons are distributed within a molecule or ion. Oxidation numbers can be used to balance chemical equations and identify the many kinds of chemical reactions that may take place. For a better understanding of the reactivity and bonding of various elements in compounds, they offer insights into the transfer or sharing of electrons between atoms. Se in Se8 has an oxidation number of 0. Se has an oxidation number of 0 when it is in its purest form.
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MnBr2 molecular or ionic:
name:
molecular or ionic
Answer: Manganese(II)bromide
Explanation:
Because it is a chemical compound composed of manganese and bromine
The speed of a car is 32.0 miles/hr . What is it's speed in m/s ? ( given 1 mile = 1609m )
Answer:14.3 m/s
Explanation:
32 x 1609 = 51488
51488 / 60 / 60 = 14.3
(60 minutes and 60 seconds so you can get unit of 1 second)
What is T2, if T1= 500 k, v1=10L, V2=8L,P1=600 torr,P2=200 torr?
Answer:
T2 = 133.333°K
Explanation:
Using Combined Gas Laws:
(600 torr)(10L)/500°K = (200 torr)(8L)/x°K
[tex]\frac{600 torr(10L)}{500K} =\frac{200 torr(8L)}{xK}[/tex]
Cross multiply:
x°K (600 torr)(10L) = 500°K(200 torr)(8L)
Divide:
x°K = (500°K(200 torr)(8L))/(600 torr)(10L)
[tex]xK = \frac{500K(200 torr)(8L)}{600 torr(10L)}[/tex]
x = 400/3°K or 133.333°K
(a) How many stereoisomers are possible for 4-methyl-1,2-cyclohexanediol? ___ (b) Name the stereoisomers formed by oxidation of (S)-4-methylcyclohexene with osmium tetroxide. If there is only one stereoisomer formed, leave the second space blank. Isomer #1: Isomer #2: (c) Is the product formed in step (b) optically active? _____
Answer:
See explanation
Explanation:
For the first part of the question, we have to check the chiral carbons in 4-methyl-1,2-cyclohexanediol. In this case carbons, 1 and 2 are chiral, if we have 2 chiral carbons we will have 4 isomers. We have to remember that formula 2^n in which "n" is the number of chiral carbons, so:
2^n = 2^2 = 4 isomers
And the isomers that we can have are:
1) (1R,2S)-4-methylcyclohexane-1,2-diol
2) (1S,2S)-4-methylcyclohexane-1,2-diol
3) (1S,2S)-4-methylcyclohexane-1,2-diol
4) (1S,2R)-4-methylcyclohexane-1,2-diol
See figure 1
For the second part of the question, we have to remember that the oxidation with [tex]OsO_4[/tex] is a syn addition. In other words, the "OHs" are added in the same plane. In this case, we have the methyl group with a wedge bond, so the "OH" groups will have a dashed bond due to the steric hindrance. Due to this we only can have 1 isomer ((1S,2R,4S)-4-methylcyclohexane-1,2-diol). Finally, on this molecule, we dont have any symmetry planes (this characteristic will cancel out the optical activity), so the product of this reaction has optical activity.
See figure 2
I hope it helps!
How many grams of LiNO3 must be added to 25.0 g of water to prepare a 5.00% (m/m) solution of LiNO3?
Answer:
1.25 g.
Explanation:
5% or 25 g
= 0.05 * 25
= 1.25 g (answer).