A gaseous mixture contains 441.0 Torr H2(g), 387.3 Torr N2(g), and 74.5 Torr Ar(g). Calculate the mole fraction, ????, of each of these gases.
????H2=
????N2=
????Ar=

Answers

Answer 1

Answer:

XH₂ = 0.4885

XN₂ = 0.4290

XAr = 0.0825

Explanation:

Step 1: Given data

Partial pressure of H₂ (pH₂): 441.0 TorrPartial pressure of N₂ (pN₂): 387.3 TorrPartial pressure of Ar (pAr): 74.5 Torr

Step 2: Calculate the total pressure (P)

The total pressure is equal to the sum of the partial pressures of all the gases.

P = pH₂ + pN₂ + pAr = 441.0 Torr + 387.3 Torr + 74.5 Torr = 902.8 Torr

Step 3: Calculate the mole fraction (X) of each gas

We will use the following expression.

Xi = pi / P

where,

Xi: mole fraction of the gas i

pi: partial pressure of the gas i

P: total pressure

XH₂ = pH₂ / P = 441.0 Torr / 902.8 Torr = 0.4885

XN₂ = pN₂ / P = 387.3 Torr / 902.8 Torr = 0.4290

XAr = pAr / P = 74.5 Torr / 902.8 Torr = 0.0825


Related Questions

Which element will gain three electrons to form an anion?
A. aluminum
B. chromium
C. iron
D. nitrogen

Answers

Answer:

D represents the element nitrogen which will gain three valence electrons forming a 3 ion.

Answer:

answer is

Explanation:

D

Which of the items below is a colloid?
a.fruit salad b.gelatin c.lacquer​

Answers

Answer:

b. gelatin

Explanation:

a homogeneous noncrystalline consisting of large molecules or ultramicroscopic particles of one substance.

Gases A and B are confined to a cylinder and piston and react to form product C. As the reaction occurs, the system loses 1189 J of heat to surroundings. The piston moves downward as the gases react to form a solid. As the volume of the gas decreases under the constant pressure of the atmosphere, the surroundings do 311 J of work on the system. What is the change in the internal energy of the system

Answers

Answer:

The change in the internal energy of the system -878 J

Explanation:

Given;

energy lost by the system due to heat, Q = -1189 J (negative because energy was lost by the system)

Work done on the system, W = -311 J (negative because work was done on the system)

change in internal energy of the system, Δ U = ?

First law of thermodynamics states that the change in internal energy of a system (ΔU) equals the net heat transfer into the system (Q) minus the net work done by the system (W).

ΔU = Q - W

ΔU = -1189 - (-311)

ΔU = -1189 + 311

ΔU = -878 J

Therefore, the change in the internal energy of the system -878 J

When you finish exercising, you are hot, tired, and sweating. After a bottle of juice, you feel a lot better. Which organ systems are working together in this scenario?

Answers

Answer:

Nervous and Excretory

Explanation:

The nervous system makes you thirsty. The integumentary system makes you sweat. the integumentary system is very similar to the Excretory system.

Nervous and Excretory systems are working together in this scenario.

The nervous system makes you thirsty. The integumentary system makes you sweat. the integumentary system is very similar to the Excretory system.

The blood flow increases, your brain is exposed to more oxygen and nutrients. Exercise also induces the release of beneficial proteins in the brain. Sweating cools the body when it becomes warm. When the body temperature rises, such as when exercising on a hot day, the dermal blood vessels dilate.The excretory system works with the endocrine system to help maintain homeostasis.

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What is the most highly populated rotational level of Cl2 (i) 25deg C and (ii) 100 deg C? Take B=0.244cm-1.This question should not be resubmitted, it is a textbook question from the Atkins physical chemistry txtbook. 10 e.

Answers

Answer:

i

[tex]J_{m} = 20 [/tex]

ii

[tex]J_{m} = 22.5 [/tex]

Explanation:

From the question we are told that

  The first temperatures is [tex]T_1 =  25^oC =  25 +273 =298 \ K[/tex]

   The second temperature is  [tex]T_2 =  100^oC =  100 +273 = 373 \ K[/tex]

Generally the equation for  the most highly populated rotational energy level is mathematically represented as

     [tex]J_{m} = [ \frac{RT}{2B}]  ^{\frac{1}{2} } - \frac{1}{2}[/tex]

Here R is the gas constant with value [tex]R =8.314 \ J\cdot K^{-1} \cdot mol^{-1}[/tex]

Also  

      B is given as [tex]B=\ 0.244 \ cm^{-1}[/tex]

   Generally the energy require per mole to move 1 cm is  12 J /mole

So   [tex]0.244 \ cm^{-1}[/tex]  will require x J/mole

           [tex]x =  0.244 *  12[/tex]

=>          [tex]x =  2.928 \ J/mol [/tex]

So at the first temperature

     [tex]J_{m} = [ \frac{8.314 * 298  }{2*  2.928 }]  ^{\frac{1}{2} } - 0.5 [/tex]

=>  [tex]J_{m} = 20 [/tex]

So at the second temperature

           [tex]J_{m} = [ \frac{8.314 * 373  }{2*  2.928 }]  ^{\frac{1}{2} } - 0.5 [/tex]

=>  [tex]J_{m} = 22.5 [/tex]

If you collect 5.74 mL of O 2 at 298 K and 1.00 atm over 60.0 seconds from a reaction solution of 5.08 mL, what is the initial rate of the reaction

Answers

Answer:

7.71 × 10⁻⁴ M/s

Explanation:

The initial rate of the reaction can be expressed by using the formula:

[tex]\dfrac{\Delta [O_2]}{\Delta t}[/tex]

where the number of moles of O₂ = [tex]\dfrac{PV}{RT}[/tex]

where;

Pressue P = 1.00 atm

Volume V =5.74mL =  (5.74 /1000) L

Rate R = 0.082 L atm/mol.K

Temperature = 298 K

[tex]= \dfrac{1.00 \ atm \times \dfrac{5.74 }{1000}L}{0.082 \ L \ atm/mol.K \times 298 K}[/tex]

= 2.35 × 10⁻⁴ mol

Δ[O₂] = [tex]\dfrac{moles \ produced - initial \ mole}{\dfrac{5.08 }{1000}L }[/tex]

Δ[O₂] = [tex]\dfrac{2.35 \times 10^{-4} M - 0 M}{\dfrac{5.08 }{1000}}[/tex]

Δ[O₂]  = 0.04626 M

The initial rate = [tex]\dfrac{\Delta [O_2]}{\Delta t}[/tex]

= [tex]\dfrac{0.04626}{60}[/tex]

= 7.71 × 10⁻⁴ M/s

On the graph, which shows the potential energy curve of two N atoms, carefully sketch a curve that corresponds to the potential energy of two O atoms versus the distance between their nuclei.

Answers

Answer:

Explanation:

We are to carefully sketch a curve that relates to the potential energy of two O atoms versus the distance between their nuclei.

From the diagram, O2 have higher potential energy than the N2 molecule. Because on the periodic table, the atomic size increases from left to right on across the period, thus O2 posses a larger atomic size than N2 atom.

Therefore, the bond length formation between the two O atoms will be larger compared to that of the two N atoms.

pencil has a density of 14.5 g/mL and a volume of 5 mL. Calculate the mass in grams.

Answers

Answer:

The answer is 72.5 g

Explanation:

The mass of a substance when given the density and volume can be found by using the formula

mass = Density × volume

From the question we have

mass = 14.5 × 5

We have the final answer as

72.5 g

Hope this helps you

1. In general, what is meant by the term chemical bond? Name and
describe the 3 principle types of chemical bonds.

Answers

Answer: The simplest and most common type is a single bond in which two atoms share two electrons. Other types include the double bond, the triple bond, one- and three-electron bonds, the three-center two-electron bond and three-center four-electron bond. ... Bonds within most organic compounds are described as covalent.

Explanation:

An increase in temperature results in A) a decrease in the required activation energy while the reaction rate remains constant. B) an increase in reaction rate due to a decrease in the kinetic energy of the reactants. C) an increase in the rate of reaction because reactant molecules collide with greater energy. D) an increase in both the reaction rate and activation energy due to increased kinetic energy.

Answers

Answer:

C) an increase in rate of reaction because reactant molecules collide with greater energy

Explanation:

Temperature is one of the factors that affect the rate of a reaction. The rate of a reaction increases with an increase in temperature and vice versa. When the temperature of a reaction increases, the kinetic energy of the reactant molecules increases causing them to react at a faster rate.

The reactant molecules respond to an increase in temperature by colliding at a faster rate due to an increased kinetic energy between the reactant molecules.

which material should you use so that the area is cool in terms of temperture O asphalt O red bricks O concrete O soil O

Answers

Answer:

red bricks

Explanation:

right on edg 2020

Red bricks should you use so that the area is cool in terms of temperture. Therefore, option B is correct.

What are red bricks used for?

Red bricks can be used in the construction of structures such as buildings, foundations, arches, pavement, and bridges. These can also be used for aesthetic purposes such as landscaping, face work, and a variety of other architectural purposes.

Traditional red bricks are saw to be more robust, and structures constructed with them are stronger than hollow block structures.Red brick can be warm, with rust or terracotta undertones. They could also be cool and more burgundy.

Thus, Red bricks should you use so that the area is cool in terms of temperture, option B is correct.

To learn more about the red bricks, follow the link;

https://brainly.com/question/14893671

#SPJ6

A piece of metal has a mass of 0.650 kilograms, has a width of 0.136 meters, and has a length of 0.0451 meters.Part A: If the metal’s volume is 291 cm3, what is the height of the metal in centimeters? (The width & length values given above are in a different unit!)

Part B: What is the density of this piece of metal?

Answers

Answer:

height = 4.74 cm

density = 2.23 g/ cm³

Explanation:

Mass of metal = 0.650 kg (650 g)

Width = 0.136 m    

Length = 0.0451 m  

Volume of metal = 291 cm³

Height in cm = ?

density of metal =?

Solution:

Width = 0.136 m    (0.136 m×100 cm/1m = 13.6 cm)

Length = 0.0451 m  (0.0451 m×100 cm/1m = 4.51 cm)

First of all we will calculate the height:

Volume = height× width× length

291 cm³ =      h     × 13.6 cm × 4.51 cm

291 cm³ =      h     × 61.34 cm²

h = 291 cm³ / 61.34 cm²

h = 4.74 cm

Density:

d = m/v

d = 650 g/291 cm³

d = 2.23 g/ cm³

HELP FAST PLZ!!!!! Which phase change allows a substance to transform from a liquid to a
gas?
melting
Ofreezing
O ionization
condensation
deionization
O
evaporation
sublimation

Answers

Answer:evaporation

Explanation:

Answer:

Pretty sure its evaporation, if its not I'm very sorry.

Solid diarsenic trioxide reacts with fluorine gas (F2) to produce liquid arsenic pentafluoride and oxygen gas (O2). Write the Qc for this reaction.

Answers

Answer:

QC= [O2]^3/[F2]^10

Explanation:

2) (3 pts) Convert 85 oF to oC.

Answers

Answer:

The answer will be 29.4˚C.

Explanation:

Using the formula 5(˚F-32)/9, plug in the numbers and you'll get 29.4˚C.

Which statements about mixture is FALSE?
A. The ingredients ofvthe mixture keep their physical properties
B. Mixture components can be separated
C. All mixtures are food or drink only
D. A mixture contains more than one ingredients

Answers

It’s b I took the test

In the laboratory you dissolve 18.7 g of copper(II) bromide in a volumetric flask and add water to a total volume of 375mL.

Required:
a. What is the molarity of the solution?
b. What is the concentration of the copper(II) cation?
c. What is the concentration of the acetate anion?

Answers

Answer:

a) - 0.2 M

b) - 0.2 M

c)- 0

Explanation:

The chemical formula of copper (II) bromide is CuBr₂. Its molar mass (MM) is calculated as follows:

MM(CuBr₂)= MM(Cu) + (2 x MM(Br) = 63.5 g/mol + (2 x 80 g/mol)= 223.5 g/mol

a). Molarity = moles CuBr₂/1 L solution

moles CuBr₂ = mass/MM = 18.7 g x 1 mol/223.5 g = 0.084 mol

Volume in L = 375 mL x 1 L/1000 mL = 0.375 L

M = 0.084 mol/(0.375 L) = 0.223 M ≅ 0.2 M

b). When is added to water, CuBr₂ dissociates into ions as follows:

CuBr₂ ⇒ Cu²⁺ + 2 Br⁻

We have 1 mol Cu²⁺ (copper (II) cation) per mol of CuBr₂. Thus, the concentration of copper (II) cation is:

0.2 mol CuBr₂ x 1 mol Cu²⁺/mol CuBr₂ = 0.2 M

c). The concentration of acetate anion is 0. There is no acetate anion in the solution (the anion from CuBr₂ is bromide Br⁻).

When 2.16g of H2 reacts with excess O2 by the following equation, 258 kJ of heat are released. What is the change of enthalpy associated with the reaction of 1.00 mol of hydrogen gas? 2H2+O2⟶2H2O

Answers

Answer:

-241 kJ/mol

Explanation:

Let's consider the reaction of hydrogen with excess oxygen to form water.

2 H₂ + O₂ ⟶ 2 H₂O

When 2.16g of hydrogen reacts with excess oxygen, 258 kJ of heat are released, that is, Q = -258 kJ. Considering that the molar mass of hydrogen is 2.02 g/mol, the change of enthalpy associated with the reaction of 1.00 mol of hydrogen gas is:

ΔH° = -258 kJ/2.16 g × (2.02 g/1.00 mol) = -241 kJ/mol

9th grade science need help ASAP

Answers

Answer:

D

Explanation:

It is a solid everything that is a solid is heavier

help pls
Which process of sedimentary rock formation occurs last?

cementation
compaction
deposition
erosion

Answers

Erosion is the answer

Answer:

Compaction.

Explanation:

All the others are before this.

If the earth was a guava fruit, the space where the seeds are would be the core/mantle​

Answers

Right on ! I need to answer a question to get mine answered so here I am :)

When aqueous solutions of AgNO3 and KI are mixed, AgI precipitates. The balanced net ionic equation is ________. When aqueous solutions of AgNO3 and KI are mixed, AgI precipitates. The balanced net ionic equation is ________. AgNO3 (aq) + KI (aq) → AgI (s) + KNO3 (aq) Ag+ (aq) + I- (aq) → AgI (s) AgNO3 (aq) + KI (aq) → AgI (aq) + KNO3 (s) Ag+ (aq) + NO3 - (aq) → AgNO3 (aq) Ag+ (aq) + NO3 - (aq) → AgNO3 (s)

Answers

Answer:

Ag⁺ (aq) + I¯ (aq) —> AgI (s)

Explanation:

We'll begin by writing the dissociation equation for aqueous AgNO₃ and KI.

Aqueous AgNO₃ and KI will dissociate in solution as follow:

AgNO₃ (aq) —> Ag⁺(aq) + NO₃¯ (aq)

KI (aq) —> K⁺(aq) + I¯(aq)

Aqueous AgNO₃ and KI will react as follow:

AgNO₃ (aq) + KI (aq) —>

Ag⁺(aq) + NO₃¯ (aq) + K⁺ (aq) + I¯(aq) —> AgI (s) + K⁺ (aq) + NO₃¯ (aq)

Cancel out the spectator ions (i.e ions that appears on both sides of the equation) to obtain the net ionic equation. The spectator ions are K⁺ and NO₃¯.

Thus, the net ionic equation is:

Ag⁺ (aq) + I¯ (aq) —> AgI (s)

The net ionic equation of aqueous solutions of [tex]AgNO_3[/tex] and [tex]KI[/tex] to form [tex]AgI[/tex] precipitates is: B. [tex]Ag^{+}_{(aq)} + I^{-}_{(aq)}[/tex] -----> [tex]AgI_{(s)}[/tex]

A balanced chemical equation can be defined as a chemical equation wherein the number of atoms on the reactant (left) side is equal to the number of atoms on the product (right) side.

This ultimately implies that, both the charge on each atom and sum of the masses of the chemical compounds or elements in a chemical equation are properly balanced.

An ion can be defined as an atom or molecules (group of atoms) that has lost or gained one or more of its valence electrons, thereby, making it have a net positive or negative electrical charge.

First of all, we would write the dissociation equation for aqueous solutions of [tex]AgNO_3[/tex] and [tex]KI[/tex]:

For [tex]AgNO_3[/tex]:

[tex]AgNO_3_{(aq)}[/tex] -----> [tex]Ag^{+}_{(aq)} + NO_{3}^{-}_{(aq)}[/tex]

For [tex]KI[/tex]:

[tex]KI_{(aq)}[/tex] -----> [tex]K^{+}_{(aq)} + I^{-}_{(aq)}[/tex]

Next, we would write a chemical equation for the reaction of aqueous solutions of [tex]AgNO_3[/tex] and [tex]KI[/tex]:

[tex]AgNO_3_{(aq)} + KI_{(aq)}[/tex]  -----> [tex]Ag^{+}_{(aq)} + NO_{3}^{-}_{(aq)}[/tex] [tex]+ \;K^{+}_{(aq)} + I^{-}_{(aq)}[/tex] ----->[tex]AgI_{(s)} + K^{+}_{(aq)} + NO_{3}^{-}_{(aq)}[/tex]

Note: Spectator ions refers to the ions that exist as a reactant and a product in a chemical equation because they are unchanged by the chemical reaction.

In this chemical reaction, the spectator ions are:

[tex]K^+[/tex][tex]NO_{3}^{-}[/tex]

Finally, in order to obtain the net ionic equation, we would cancel out the two (2) spectator ions:

[tex]Ag^{+}_{(aq)} + I^{-}_{(aq)}[/tex] -----> [tex]AgI_{(s)}[/tex]

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PLEASE HELP! WILL DO BRAINLIEST! What do scientists call all of the compounds that contain carbon and are found in living things?
organic

inorganic

acidic

nonacidic

Answers

Answer:

acidic because of electrical issues and the body of electrical equipment

Which of the following elements has the largest atomic radius? Bromine, Barium, Magnsium, Zinc

Answers

Answer:

Atomic radii vary in a predictable way across the periodic table. As can be seen in the figures below, the atomic radius increases from top to bottom in a group, and decreases from left to right across a period. Thus, helium is the smallest element, and francium is the largest.

Explanation:

How long would it take a bus traveling 52 km/h to travel 130 km

Answers

Answer:

2 and a half hours

Explanation:

Time is equal to distance over speed

The wood in my house is crumbling. *

Problem

Hypothesis

Law

Theory

Answers

Answer:

Problem

Explanation:

The given statement is a problem. It states the problem that the house of the speaker has been undergoing with. This problem gives rise to the Hypothesis in which the 'why' question is asked. The reason of the crumbling of the wood is stated in the hypothesis. Any reason placed of the happening of the event is stated to be hypothesis.

Which of the following best describes the structure of a nucleic acid?


a. Carbon ring(s)
b. Globular or fibrous
c. Single or double helix
d. Hydrocarbon(s)

Answers

It’s A. Carbon Rings

which angles are right

Answers

Right angle acute angle obtuse angle

Answer:

a right is 90 degrees

If 25.98 mL of 0.1180 M KOH reacts with 52.50 mL of CH3COOH solution, what is the molarity of the acid solution?

Answers

Answer:

Explanation:

We shall use the formula S₁V₁ = S₂V₂

S₁ = .1180 M , V₁ = 25.98 mL

S₂ = ? , V₂ = 52.50 mL

.1180 M  x 25.98 = 52.50 x S₂

S₂ = .0584 M

Molarity of the acid solution = .0584 M .

The concentration of the acid solution is 0.058 M.

The equation of the reaction is;

CH3COOH(aq) + KOH(aq) ----->  CH3COOK(aq) + H2O(l)

The following are known;

Concentration of base CB = 0.1180 M

Volume of base VB =  25.98 mL

Concentration of acid CA = ?

Volume of acid VA = 52.50 mL

Number of moles of acid NA = 1

Number of moles of base NB = 1

Using;

CAVA/CBVB =NA/NB

CAVANB = CBVBNA

CA=  CBVBNA/VANB

CA = 0.1180 M × 25.98 mL × 1/52.50 mL × 1

CA = 0.058 M

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4. What reagent would you predict to be in excess for reacting 7.50 mL of a 0.10M BaCl2 solution with 7.50 mL of 0.10M KIO3 solution

Answers

Answer : [tex]BaCl_2[/tex] reagent predict to be in excess.

Explanation : Given,

Concentration of [tex]BaCl_2[/tex] = 0.10 M

Volume of [tex]BaCl_2[/tex] = 7.50 mL = 0.0075 L       (1 L = 1000 mL)

Concentration of [tex]KIO_3[/tex] = 0.10 M

Volume of [tex]KIO_3[/tex] = 7.50 mL = 0.0075 L

First we have to calculate the moles of [tex]BaCl_2[/tex]  and [tex]KIO_3[/tex].

[tex]\text{Moles of }BaCl_2=\text{Concentration of }BaCl_2\times \text{Volume of }BaCl_2[/tex]

[tex]\text{Moles of }BaCl_2=0.10M\times 0.0075L=0.00075mol[/tex]

and,

[tex]\text{Moles of }KIO_3=\text{Concentration of }KIO_3\times \text{Volume of }KIO_3[/tex]

[tex]\text{Moles of }KIO_3=0.10M\times 0.0075L=0.00075mol[/tex]

Now we have to calculate the excess and limiting reagent.

The balanced equilibrium reaction will be:

[tex]BaCl_2+2KIO_3\rightleftharpoons Ba(IO_3)_2+2KCl [/tex]

From the balanced reaction we conclude that

As, 2 mole of [tex]KIO_3[/tex] react with 1 mole of [tex]BaCl_2[/tex]

So, 0.00075 moles of [tex]KIO_3[/tex] react with [tex]\frac{0.00075}{2}=0.000375[/tex] moles of [tex]BaCl_2[/tex]

From this we conclude that, [tex]BaCl_2[/tex] is an excess reagent because the given moles are greater than the required moles and [tex]KIO_3[/tex] is a limiting reagent and it limits the formation of product.

Hence, [tex]BaCl_2[/tex] reagent predict to be in excess.

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9. What did the Olive Branch Petition ask the King to do? For what values of m does the graph of y = 3x2 + 7x + m have two x-intercepts?m greater-than StartFraction 25 Over 3 EndFractionm less-than StartFraction 25 Over 3 EndFractionm less-than StartFraction 49 Over 12 EndFractionm greater-than StartFraction 49 Over 12 EndFraction What is 8S8 In need for a quick answer Troy, a cash basis taxpayer, owns an office building. His records reflect the following for 20X1. On March 1, 20X1, office B was leased for twelve months for $12,000. A $900 security deposit was received which will be used as the last month's rent. On September 30, 20X1, the tenant in office A paid Troy $3,600 to cancel the lease expiring on March 31, 20X1. The lease of the tenant in office C expired on December 31, 20X1, and the tenant left improvements valued at $1,400. The improvements were not in lieu of any required rent. Considering just these four amounts, what amount must Troy include in rental income on his income tax return for 20X1? a. $17,900 b. $17,000 c. $16,500 d. $13,800 Solve: 3(2x + 4) = 5x - 2 What is the best definition of the word pall as used in this sentence?Her audience's attention began to pall as Catherine's speech kept going and going.dwindleculminatewaxheighten is this correct? say something if it's wrong lol Which words from the passage are a good example of direct characterization?I lazily flipped through the pages of my textbookToo bad I cant be more like my brotherHe is very studious and a bit of a perfectionistI am much more likely to spend my time daydreaming Differentiate between the homes of the poor and the homes of the wealthy. Where are most of Europe's agricultural fields are located?A) Northern European PlainB) None of these answers is correctC) Along the Mediterranean SeaD) In the coastal Nordic regions Identify the slope and y- intercept of the linear equation.y = -2x + 5Slope: y-intercept: What is the solution to the linear equation?4b + 6 = 2 b + 4 A record store was selling 3 used CD's for $12.51.Online youcould buy 5 used CD's for $20.70.Which place has a lower unit price?Answer: which sentence best rewrites the following line so that that it includes hyperbole?Jackson lived for a long period of time in a small Brainliest will be given to the correct answer!The formula for the area of a trapezoid is A = 1/2h (b1 + b2), where h is the height of the trapezoid, and b1 and b2 are the lengths of the bases.Part A: Solve the formula for h. What is the height of a trapezoid that has an area of 91 cm2 and bases of 12 cm and 16 cm?Part B: What method would you use to solve the formula for b1? What is the formula when solved for b1?Part C: What is the length of the other base if one base of a trapezoid is 30 cm, the height of the trapezoid is 8.6 cm, and the area is 215 cm2?Part D: If both bases of a trapezoid have the same length, can you find their lengths given the area and height of the trapezoid? Explain. What does the bill of rights limit A Puritan seeking religious freedom would have most likely settled in which British colony?GANAVAMA i need a well-written summary about the Greek god Apollo. and pls hurry! Whats the difference from the first and second law of thermodynamics At the end of the article, Kathleen Hall Jamieson says, "Elections in times of national crisis place challenges in front of whoever is president. When a president steps up in one of those moments, you get Lincoln in the Civil War, you get Roosevelt in World War II. This is one of those moments." What does she mean by that?