Answer:
Δ [tex]G_{rxn}[/tex] = −51. 4 kJ/mol
However, since Δ [tex]G_{rxn}[/tex] is negative. The hydrolysis of ATP for this reaction is said to be spontaneous
Explanation:
From the question; The equation for this reaction can be represented as :
[tex]ATP_{(aq)} + H_2O_{(l)} \to ADP_{(aq)}+ HPO_4^{2-}} _{(aq)}[/tex]
where:
[tex]\Delta G ^0 _{rxn} =[/tex]-30.5 kJ/mol
= -30.5 kJ/mol × 1000 J/ 1 kJ
= -30.5 × 10 ⁻³ J/mol
Temperature T = 37 ° C
= (37+273)
= 310 K
pH = 7.0
[ATP] = 5.0 mM
= 5.0mM × 1M/1000mM
= 0.005 M
[ADP] = 0.30 mM
= 0.30 mM × 1M/1000mM
= 0.0003 M
[tex][HPO_4^{2-}}][/tex] = 5.0 mM
= 5.0mM × 1M/1000mM
= 0.005 M
The objective is to calculate the value for Δ [tex]G_{rxn}[/tex] in the biological cell and to determine if the hydrolysis of ATP is spontaneous under these conditions.
Now;
From the equation given; the equilibrium constant [tex]K_{eq}[/tex] can be expressed as:
[tex]K_{eq} = \dfrac{[ADP][ HPO_4^{2-}]} {[ATP]}[/tex]
[tex]K_{eq} = \dfrac{(0.0003 \ M)(0.005 \ M)} {(0.005 \ M)}[/tex]
[tex]K_{eq} = 3*10^{-4}[/tex]
The Δ [tex]G_{rxn}[/tex] in the biological cell can now be calculated as:
Δ [tex]G_{rxn}[/tex] = [tex](-30.5 * 10 ^3 \ J/mol) + (8.314 \ J/mol.K)(310 K ) In ( 3*10^{-4})[/tex]
Δ [tex]G_{rxn}[/tex] = [tex](-30.5 * 10 ^3 \ J/mol) + (-20906.68126)[/tex]
Δ [tex]G_{rxn}[/tex] = −51406.68 J/mol
Δ [tex]G_{rxn}[/tex] = −51. 4 × 10³ J/mol
Δ [tex]G_{rxn}[/tex] = −51. 4 kJ/mol
Thus since Δ [tex]G_{rxn}[/tex] is negative. The hydrolysis for this reaction is said to be spontaneous
A cylindrical rod of length 1 m and radius 1 cm is submerged in water. The rod has a non-uniform mass distribution such that one half of the rod is much more massive than the other half. At which point in the rod can the buoyant force be considered to be acting?
A) at the rod's geometrical center
B) two of the given choices are correct
C) none of these
D) at the rod's center of mass
E) at the rod's center of gravity
Answer:
A) at the rod's geometrical center
Explanation:
Let us assume that the rod is replaced by water. And now this water volume is in translational and in rotational equilibrium.
Therefore, a net upward force must have been exerted by the surrounding liquid which acts at the center of mass of the water volume.
This force determines through the geometric center of the column of the cylindrical water
Moreover, the force is also independent of submerged body into it
Hence, the first option is correct
A gas particle of mass 5.31 × 10^-23 kg has a velocity of 1.00 102 m/s. What is the kinetic energy of the molecule
Answer:
Kinetic energy = 1/2mv²
where m is the mass
v = velocity
m = 5.31 × 10^-23 kg
v = 1.00 × 10^2 m/s
Kinetic energy = 1/2 × 5.31 × 10^-23 × ( 1.00 × 10^2)²
= 2.655 × 10^-19 Joules
Hope this helps
Which element has the largest atomic radius
Answer:
Francium
Explanation:
The atomic radius increases from top to bottom in a group, and decreases from left to right across a period.
so francium (Fr) is the largest atom or has highest radii.
Hope this helps & please mark as brainiest!
Answer:
Francium has the largest atomic radius.
The general trend for atomic radii is increasing from top to bottom and decreasing from left to right so the one with the largest atomic radius will be in the bottom left of the periodic table.
What is the half-life for the first order decay of 14C according to the reaction, 146C — 147N +e- ?
The rate constant for the decay is 1.21 x10-4 year-1
Answer:
5727 years or 5730 (rounded to match 3 sig figs) whichever one your teacher prefers
Explanation:
First Order decay has a half life formula of Half Life = Ln (2) / k = 0.693/K
Half-life = 0.693/k = 0.693/1.21 x10-4 = 5727 years or 5730 (rounded to match 3 sig figs)
This should be correct because if you google the half-life of 14 C it is ~ 5700 years
How many moles of carbon atoms are there in 0.500 mol of C2H6?
The number of moles of carbon atoms in 0.500 mol of ethane (C₂H₆) is equal to one mole.
What is a mole?A mole can be defined as a scientific unit that is utilized to calculate the quantities such as atoms, molecules, ions, or other particular particles. The mass of one mole of a given chemical element is atomic mass and that of 1 mole of a chemical compound is molar mass.
The number of entities found in one mole is equal to 6.023 × 10 ²³ which is known as Avogadro’s constant.
Given, the number of moles of C₂H₆ = 0.500 mole
One molecule of ethane has carbons = 2
One mole of ethane has moles of carbons = 2 moles
0.500 mol of ethane has moles of carbon atoms = 0.500×2 = 1 mol
Therefore, one mole of carbon atoms is present in 0.500 mol of ethane C₂H₆.
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when dissolved in water, an acid or a base breaks down into a. a proton and an electron b. two negative ions c. a positive and a negative ion d. a positive ion and a proton
Answer:
C. A positive and a negative ion
Explanation:
Acids and bases are made up of charged particles known as ions. The ions present in acids are oppositely charged and are held together by strong electrostatic forces. When acids or bases are dissolved in water, the electrostatic forces holding their individual molecules together are weakened and these ions are free to move apart in a process known as dissociation. Dissociation occurs because of the attraction between the positive and negative ions in the acid and bases and the negative and positive polarity of water.
For example, when an acid like hydrochloric acid is dissolved in water it dissociates into positive and negative ions as follows:
HCl(aq) -----> H+ + Cl-
When a base like sodium hydroxide is dissolved in water, it dissociates into positive and negative ions as follows:
NaOH(aq) ----> Na+ + OH-
Answer:
yeah C is correct
Explanation:
1. Corrosion in metals is an example of what?
Answer:
In the most common use of the word, this means electrochemical oxidation of metal in reaction with an oxidant such as oxygen or sulfates. Rusting, the formation of iron oxides, is a well-known example of electrochemical corrosion.A chemist measures the energy change Delta H during the following
2Fe2O3(s)->4FeO(s)+O2(g).
1) this reactions is: Endothermic or exothermic.
2) suppose 94.2g of Fe2O3 react. will any heat be relased or absorbed. yes absorbed. yes releases. no.
3) If you said heat will be released or absorbed in the second part of the question. calculate how much heat will be absored or released. be sure your answer has correct number of significant digits.
Answer: 1) Endothermic
2) Yes, absorbed.
3) 166.86 kJ will be absorbed.
Explanation:
1) To determine if a reaction is endothermic (heat is absorbed by the system) or exothermic (heat is released by the system), first calculate its change in Enthalpy, which is given by:
ΔH = [tex]H_{products} - H_{reagents}[/tex]
For the reaction 2Fe₂O₃(s) ⇒ 4FeO(s) + O₂(g):
Enthalpy of Reagent (Fe₂O₃(s))
Enthalpy of formation for Fe₂O₃(s) is - 822.2 kJ/mol
The reaction needs 2 mols of the molecule, so:
H = 2(-822.2)
H = - 1644.4
Enthalpy of Products (4FeO(s) + O₂(g))
Enthalpy of formation of O₂ is 0, because it is in its standard state.
Enthalpy of formation of FeO is - 272.04 kJ/mol
The reaction produces 4 mols of iron oxide, so:
H = 4(-272.04)
H = -1088.16
Change in Enthalpy:
ΔH = [tex]H_{products} - H_{reagents}[/tex]
ΔH = - 1088.16 - (-1644.4)
ΔH = + 556.2 kJ/mol
The change in enthalpy is positive, which means that the reaction is absorving heat. Then, the chemical reaction is Endothermic.
2) When Fe₂O₃(s) reacts, heat is absorbed because it is an endothermic reaction.
3) Calculate how many mols there is in 94.2 g of Fe₂O₃(s):
n = [tex]\frac{mass}{molar mass}[/tex]
n = [tex]\frac{94.2}{160}[/tex]
n = 0.6 mols
In the reaction, for 2 mols of Fe₂O₃(s), 556.2 kJ are absorbed. Then:
2 mols --------------- 556.2 kJ
0.6 mols ------------- x
x = [tex]\frac{0.6*556.2}{2}[/tex]
x = 167 kJ
It will be absorbed 167 kJ of energy, when 94.2 g of Fe₂O₃(s) reacts.
A student wants to prepare a salt starting with H2SO4. Select all of the compound types that can react with H2SO4 to form a salt.
1. salt
2. acid
3. acid salt
4. basic oxide
5. base
6. metal
7. acidic oxide
Answer:
4 and 6 would work for this
what is the molarity of a solution that contains 49.8 grams of nai and is dissolved in enough water to make 1.50 liters
Answer: The molarity of solution is 0.221 M
Explanation:
Molarity of a solution is defined as the number of moles of solute dissolved per liter of the solution.
[tex]Molarity=\frac{n}{V_s}[/tex]
where,
n = moles of solute
[tex]V_s[/tex] = volume of solution in L
moles of [tex]NaI[/tex] = [tex]\frac{\text {given mass}}{\text {Molar mass}}=\frac{49.8g}{149.89g/mol}=0.332mol[/tex]
Now put all the given values in the formula of molality, we get
[tex]Molarity=\frac{0.332mol}{1.50L}[/tex]
[tex]Molarity=0.221mol/L[/tex]
Therefore, the molarity of solution is 0.221 M
Why Graphite is Diamagnetic?
Answer: Through years of studying and research ;
Graphite has shown that in weak and quantizing magnetic fields it is material is a highly anisotropie diamagnetic substance whose non-oscillating part of the magnetic suscepti- bility weakly depends on magnetic field.
Explanation:
Diamagnetism is a (very) weak form of magnetism which is caused (induced) by a change in the orbital motion of electrons mostly due to an applied magnetic field.
Identify which of the following are carbohydrates.
Check oh that apply
Answer:
3d and 4th
Explanation:
Carbohydrates general formula (CH2O)n.
Not 1st one because it has NH2-group.
2nd - C3H6O4, also it is acid.
3d - C3H6O3
4th - C6H12O6
Among the given compounds only compound present in 3rd option is a carbohydrate.
What are carbohydrates?Carbohydrates are the organic molecules which are made up of oxygen atom, carbon atom and hydrogen atom and general molecular formula of carbohydrates is CₙH₂ₙOₙ, where n is the number of atoms.
In the carbohydrate molecule, alcoholic group and aldehyde groups may present.
First given compound is not a carbohydrates as in that NH₃ group is present.Second given compound is also not a carbohydrate as in that carboxylic (-COOH) group is present.Third compound is a carbohydrate as in that compound same number of carbon and oxygen atoms are present and number of hydrogen atom is double to C & O atom.Fourth compound is also not a carbohydrate, as in that molecule number of carbon and oxygen atom is same but number of hydrogen is not double with respect to C & O.Hence compound C is carbohydrate.
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What are the three types of combustion reactions
Answer:
Slow combustion
Spontaneous combustion
Explosive combustion
Explanation:
-Slow combustion reactions: Occurs at low temperatures. Cellular respiration is an example.
-Spontaneous combustion reactions: Occurs suddenly without an outside heat source. The heat source is the result of oxidation.
-Explosive combustion reactions: Involves an oxidizing agent.
hopefully this helped :3
Answer:
Three types are: Rapid Combustion, Complete Combustion, and Spontaneous Combustion.
Explanation:
Note: there are more types! This is just three random ones I picked to list. Hope this helps! :)
Which element's neutral atoms will have the electron configuration
1s22s22p3s23p'?
a. boron
b. carbon
c. silicon
d. aluminum
Answer:
Alumunium
Explanation:
Alumunium = [Ne] 3s² 3p¹
Ne = [He]2s²2p⁶
He = 1s
Alumunium = 1s 2s²2p⁶3s² 3p¹
Answer:
D
Explanation:
Write the empirical formula
Answer:
[tex]1) NH_{4}IO_{3}\\2) Pb(IO_{3})_{4} \\3) NH_{4}(C_{2}H_{3}O_{2})\\4) Pb(C_{2}H_{3}O_{2})_{4}[/tex]
Explanation:
[tex]1) NH_{4}^{+}IO_{3}^{-} ---> NH_{4}IO_{3}\\2) Pb^{4+}(IO_{3}^{-})_{4} --->Pb(IO_{3})_{4} \\3) NH_{4}^{+}(C_{2}H_{3}O_{2})^{-} ---> NH_{4}(C_{2}H_{3}O_{2})\\4) Pb^{4+}(C_{2}H_{3}O_{2})^{-} _{4} --->Pb(C_{2}H_{3}O_{2})_{4}[/tex]
Vitamin c is known chemically by the name ascorbic acid determine the empirical formula of ascorbic acid if it is composed of 40.92% carbon, 4.58% hydrogen, and 54.50% oxygen.
Answer:
[tex]=C_3H_4O_3[/tex]
Explanation:
When percentage composition is given, and asked for the empirical formula, it is simplest to assume 100 g of material. Thus,
Mass C = 40.92 g. Moles C = 40.92 g x 1 mole/12 g = 3.41 moles C
Mass H = 4.58 g. Moles H = 4.58 g x 1 mole/1.0 g = 4.58 moles H
Mass O = 54.50 g. Moles O = 54.50 g x 1 mole/16 g = 3.41 moles O
Now, we want to get the moles into whole numbers, so we begin by dividing all by the smallest, i.e. divide all values by 3.41.
Moles C = 3.41/3.41 = 1
Moles H = 4.58/3.41 = 1.34
Moles O = 3.41/3.41 = 1
Now, in order to get 1.34 to be a whole number we multiply it (and all others) by 3
Moles C = 1x3 = 3
Moles H = 1.34x3 = 4
Moles O = 1x3 = 3
Empirical Formula [tex]=C_3H_4O_3[/tex]
A naturally occurring oil co-distills with water to produce an oil/water distillate that is 20% oil by weight. If the molecular weight of the oil 100 g/mol, what was the partial pressure of the oil during distillation assuming atmospheric pressure is 760 mm Hg
Answer:
Explanation:
Partial pressure of oil = mole fraction of oil x total pressure
mole fraction of oil = mole of oil / mole of water + mole of oil
= mole of oil = mass of oil / molecular weight of oil
= 20 / 100 = .2
mole of water = 80 / 18
= 4.444
mole fraction of oil = .2 / .2 + 4.444
= .2 / 4.644
Partial pressure of oil = mole fraction of oil x total pressure
= (.2 / 4.644 ) x 760 mm
= 32.73 mm Hg .
Dinitrogen tetraoxide, a colorless gas, exists in equilibrium with nitrogen dioxide, a reddish brown gas.
One way to represent this equilibrium is:
N2O4(g)----------> 2NO2(g)
<----------
Indicate whether each of the following statements is true or false
At equilibrium at a fixed temperature, we can say that:
1. The concentration of NO2 is equal to the concentration of N2O4.
2. The rate of dissociation of N2O4 is equal to the rate of formation of N2O4.
3. The rate constant for the forward reaction is equal to the rate constant of the reverse reaction.
4. The concentration of NO2 divided by the concentration of N2O4 is equal to the same constant (regardless of initial concentrations)
Explanation:
N2O4(g) <----------> 2NO2(g)
Before proceeding,
A chemical equilibrium can be defined as a condition in the course of a reversible chemical reaction in which no net change in the amounts of reactants and products occurs.
Statement 1.
This statement is false. Equilibrium is not about equal concentrations but rather zero change in concentration of the reactants and products.
Statement 2.
This statement is True in chemical equilibrium; the forward and reverse reactions occur at equal rates.
Statement 3.
This statement is False. The rate constant for the forward reaction is not equal to the rate constant of the reverse reaction.
Statement 4.
The concentration of NO2 divided by the concentration of N2O4 is NOT equal to a constant. To obtain a constant value irregardless of the concentrations, the concentration of NO2 must be squared. This comes from the stoichiometry of the reaction
Kc= [NO2]2 / [N2O4]
This statement is false.
1-chloro-4-methyl-2-pentene undergoes hydrolysis in warm water to give a mixture of 4-methyl-2-penten-1-ol and 4-methyl-1-penten-3-ol. Draw the structure of the intermediate's resonance contributor leading to the formation of 4-methyl-1-penten-3-ol.
Answer:
Explanation:
attached here is the diagram representing the structure
At what geographical location would the boiling point of water be lowest?
A. Boston, Massachusetts
B. The coast of the Atlantic Ocean
C. The Dead Sea
D. The top of Mount Everest
Answer:
I think it would be the Dead Sea
Explanation:
Because the dead sea is already usually in the warmer temperatures, the boiling point of the water would be lower than the rest.
which factor is most responsible for the fact that water is a liquid rather than a gas at room temperature
The answer is Hydrogyn bonding. It keeps the water molocules bonded together and in a liquid state, without it it'd be in a gashious state.
Answer:Hydrogen bonds keep them together in room temperature, hope this helps!
Explanation:
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How many formula units make up 36.0 g of magnesium chloride (MgCl2)?
Express the number of formula units numerically.
Answer: There are [tex]2.29\times 10^{23}[/tex] formula units
Explanation:
According to avogadro's law, 1 mole of every substance occupies 22.4 L at STP and contains avogadro's number [tex]6.023\times 10^{23}[/tex] of particles.
To calculate the moles, we use the equation:
[tex]\text{Number of moles}=\frac{\text{Given mass}}{\text {Molar mass}}=\frac{36.0g}{95g/mol}=0.38moles[/tex]
1 mole of [tex]MgCl_2[/tex] contains = [tex]6.023\times 10^{23}[/tex] formula units
Thus 0.38 moles of [tex]MgCl_2[/tex] contains = [tex]\frac{6.023\times 10^{23}}{1}\times 0.38=2.29\times 10^{23}[/tex] formula units
Thus there are [tex]2.29\times 10^{23}[/tex] formula units
What is the specific heat of a 85.01 g piece of an unknown metal that exhibits a 45.2°C temperature change upon absorbing 1870 J of heat?
Answer:
[tex]0.48~\frac{J}{g~^{\circ}C}[/tex]
Explanation:
In this question, we have to remember the relationship between Q (heat) and the specific heat (Cp) the change in temperature (ΔT), and the mass (m).
[tex]Q=m*Cp*ΔT[/tex]
The next step is to identify what values we have:
[tex]Q~=~1870~J[/tex]
[tex]m~=~85.01~g[/tex]
[tex]ΔT~=~45.2~^{\circ}C[/tex]
[tex]Cp~=~X[/tex]
Now, we can plug the values and solve for "Cp":
[tex]1870~J=~85.01~g~*Cp*45.2~^{\circ}C[/tex]
[tex]Cp=\frac{1870~J}{85.01~g~*45.2~^{\circ}C}[/tex]
[tex]Cp=0.48~\frac{J}{g~^{\circ}C}[/tex]
The unknow metal it has a specific value of [tex]0.48~\frac{J}{g~^{\circ}C}[/tex]
I hope it helps!
Describe the formation of an aqueous libr solution when solid libr dissolves in water
Fill in the blanks with words given below.
K and I atoms
K and IF ions
dissociation
atoms
KI molecules
polar dilution
hydration
molecules ions
nonpolar
At the_______ surface of the solid _____________are pulled into solution by___________ the water molecules, where the______________ process surrounds separate with water molecules.
Answer and Explanation:
The water is a polar solvent which dissolves into the LiBr molecules and converts into [tex]Li^+[/tex] and [tex]Br^-[/tex] ions far from the solid also into the solution, when they are hydrated.
Now, the complete words are as given below:-
The [tex]K^+[/tex] and [tex]I^-[/tex] ions at the surface of the solid are pulled into the solution by the polar water molecules, where the hydration process surrounds separate ions with water molecules.
LiBr has been the ionic compound and has been dissociated in the water by the force of the polar water molecules. The water molecules that have been polar in nature exert the force onto the ionic compounds and help in the dissociation.
At the dissociation surface of the solid KI molecules, are pulled into the solution by the polar water molecules, where the hydration process surrounds ions and separates them with water molecules.
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What is the mass of 3.45 moles
NO2?
(N = 14.01 g/mol, O = 16.00 g/mol)
Answer:
158.7 g
Its the right answer
Which pair of factors affects the force of gravity between objects
Answer:
The Answer is B. Mass and distance
Explanation:
Trust me lol
Answer:mass and distance
Explanation:
How many oxygen molecules are needed to make 10 carbon dioxide molecules according to the following balanced chemical equation? 2 CO + O2 → 2 CO2
five oxygen molecules
step by step explanation.
according to the equation,one molecule of oxygen is enough to react with two carbon molecules thus 10 carbon molecules need 5oxygen molecules
if 2.22 moles of ammonia (NH3) decomposes according to the reaction shown how many moles of hydrogen (H2) are formed?
Answer:
five(5) hydrogen are formed
A small amount of red paint is mixed with water. When a laser pointer shines through the mixture, the beam is clearly visible in the mixture. This mixture is a .
Answer: Heterogeneous (Colloid)
Explanation: This is because your solution is a colloid. A colloidal solution has particles between 40 and 900 nm and as the laser light shines through the paint and Water mixture, the paint particles scatter the light because of the Tyndall Effect (Named after the physicist John Tyndall). A Colloidal Solution is a heterogeneous solution that looks like its homogeneous but is a mixture of very small particles that don't really become a solution.
A small amount of red paint is mixed with water. When a laser pointer shines through the mixture, the beam is clearly visible in the mixture. This mixture is a Heterogeneous.
What is mixture?A mixture is a substance made by combining two or more dissimilar chemical compounds that are not chemically linked in chemistry. When two or more substances are physically combined, their identities are maintained, and the mixture takes the shape of solutions, suspensions, or colloids.
Chemical elements and compounds, among others, can be mechanically blended or mixed to create mixtures without causing any chemical bonding and other chemical change, preserving the chemical characteristics and makeup of each ingredient. A small amount of red paint is mixed with water. When a laser pointer shines through the mixture, the beam is clearly visible in the mixture. This mixture is a Heterogeneous.
Therefore, the mixture is Heterogeneous mixture.
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(-)-Cholesterol has a specific rotation of -32o. A mixture of ( )- and (-)-cholesterol was analyzed by polarimetry, and the observed rotation was 14o. What is the percent composition of the ( ) isomer in this mixture
Answer:
(+)-cholesterol = 71.88%
(-)-cholesterol = 28.12%
Explanation:
Asuming 1 gram of sample is dissolved in 1mL of water and the sample cell was 1dm long.
Enantiomeric excess is defined as the amount of pure enantiomer in a sample. The formula is:
ee = [α]mixture / [α]pure enantiomer.
Replacing:
ee = 14° / 32°×100 = 43.75%
As the sample is 14°, There is an excess of (+)-cholesterol and 56.25% is a 1:1 mixture of enantiomers.
That means percent composition of enantiomers is:
(+)-cholesterol = 43.75% + 56.25%/2 = 71.88%(-)-cholesterol = 56.25%/2 = 28.12%