The pH of the buffer will decrease after adding 0.10 mol of HCl to 1.00 liter of the buffer.
To determine the pH after adding 0.10 mol of HCl, we need to understand the chemistry of the buffer system. The buffer consists of a weak acid (CH3COOH) and its conjugate base (CH3COONa), which can resist changes in pH by undergoing the following equilibrium reaction:
CH3COOH ⇌ CH3COO- + H+
The acetic acid (CH3COOH) donates protons (H+) while the acetate ion (CH3COO-) accepts protons, maintaining the buffer's pH. The pH of the buffer is given as 4.74, indicating that the concentration of H+ ions is 10^(-4.74) M.
When 0.10 mol of HCl is added, it reacts with the acetate ion (CH3COO-) in the buffer. The reaction can be represented as:
CH3COO- + HCl → CH3COOH + Cl-
Since the HCl is a strong acid, it completely dissociates in water, providing a high concentration of H+ ions. As a result, some of the acetate ions will be converted into acetic acid, reducing the concentration of acetate ions and increasing the concentration of H+ ions in the buffer.
To calculate the new pH, we need to determine the new concentrations of CH3COOH and CH3COO-. Initially, both concentrations are 0.50 M. After adding 0.10 mol of HCl, the concentration of CH3COOH will increase by 0.10 M, while the concentration of CH3COO- will decrease by the same amount.
Considering the volume of the buffer is 1.00 liter, the final concentration of CH3COOH will be 0.50 M + 0.10 M = 0.60 M. The concentration of CH3COO- will be 0.50 M - 0.10 M = 0.40 M.
Next, we need to calculate the new concentration of H+ ions. Since the initial pH is 4.74, the concentration of H+ ions is 10^(-4.74) M = 1.79 x 10^(-5) M.
With the addition of HCl, the concentration of H+ ions will increase by 0.10 M. Thus, the new concentration of H+ ions will be 1.79 x 10^(-5) M + 0.10 M = 0.1000179 M (approximately).
Finally, we can calculate the new pH using the equation:
pH = -log[H+]
pH = -log(0.1000179) ≈ 1.00
Therefore, the pH of the buffer after adding 0.10 mol of HCl is approximately 1.00.
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The standard molar enthalpy change for this reaction is -1.3 MJ. What is the enthalpy change when 6 moles of octane are combusted
The enthalpy change when 6 moles of octane are combusted is -7.8 MJ. This value is obtained by multiplying the standard molar enthalpy change (-1.3 MJ/mol) by the number of moles of octane combusted.
The balanced combustion equation for octane (C8H18) is:
C8H18 + 12.5O2 → 8CO2 + 9H2O
According to the balanced equation, the stoichiometric coefficient of octane is 1, which means that the enthalpy change for the combustion of 1 mole of octane is -1.3 MJ.
To find the enthalpy change when 6 moles of octane are combusted, we can multiply the standard molar enthalpy change by the number of moles of octane:
Enthalpy change = -1.3 MJ/mol * 6 mol
Enthalpy change = -7.8 MJ
Therefore, when 6 moles of octane are combusted, the enthalpy change is -7.8 MJ.
The enthalpy change when 6 moles of octane are combusted is -7.8 MJ. This value is obtained by multiplying the standard molar enthalpy change (-1.3 MJ/mol) by the number of moles of octane combusted. The negative sign indicates that the combustion process is exothermic, releasing energy in the form of heat.
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If the uncertainty associated with the position of an electron is 3.3×10−11 m, what is the uncertainty associated with its momentum?
The uncertainty associated with the momentum of an electron is given by the Heisenberg uncertainty principle as approximately 5.5×10^(-21) kg·m/s, which is calculated by the uncertainty in position.
According to the Heisenberg uncertainty principle, the product of the uncertainty in position (Δx) and the uncertainty in momentum (Δp) of a particle is always greater than or equal to a constant value, Planck's constant (h), divided by 4π:
Δx * Δp ≥ h / (4π)
In this case, the uncertainty in position (Δx) of the electron is given as 3.3 × 10^(-11) m. To find the uncertainty in momentum (Δp), we rearrange the equation:
Δp ≥ h / (4π * Δx)
Plugging in the values, we have:
Δp ≥ (6.626 × 10^(-34) J*s) / (4π * 3.3 × 10^(-11) m)
Simplifying the expression:
Δp ≥ 5.03 × 10^(-24) kg*m/s
Therefore, the uncertainty associated with the momentum of the electron is 5.03 × 10^(-24) kg*m/s.
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What are the limitations of litmus paper and phenolphthalein indicators? name two other indicators that can be used that do not have such limitations. source stylesnormal
Litmus paper and phenolphthalein indicators have pH range limitations and lack precision. Universal indicator and bromothymol blue are alternative indicators that offer a broader range and greater accuracy.
Litmus paper is a pH indicator that changes color in the presence of an acid or a base. However, it can only indicate whether a substance is acidic (turns red) or basic (turns blue), without providing an accurate pH value. Phenolphthalein, on the other hand, is colorless in acidic solutions and pink in basic solutions, but it has a limited pH range of 8.2 to 10.0.
To overcome these limitations, the universal indicator is commonly used. It is a mixture of several indicators that produces a wide range of colors depending on the pH of the solution. The resulting color can be compared to a color chart to determine the approximate pH value of the substance being tested. This allows for a more precise measurement of pH compared to litmus paper or phenolphthalein.
Another alternative indicator is bromothymol blue. It changes color depending on the pH of the solution, from yellow in acidic solutions to blue in basic solutions. Bromothymol blue has a pH range of 6.0 to 7.6, which makes it suitable for a broader range of pH measurements compared to phenolphthalein.
These alternative indicators, universal indicator and bromothymol blue, provide a wider pH range and more precise measurements compared to litmus paper and phenolphthalein. They offer greater versatility and accuracy in determining the acidity or basicity of a solution.
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The atoms of elements in the same group or family have similar properties because.
The atoms of elements in the same group or family have similar properties because they have the same number of valence electrons.
Valence electrons are the electrons in the outermost energy level of an atom. They are responsible for the chemical behavior of an element. Elements in the same group or family have the same number of valence electrons, which means they have similar chemical behavior.
For example, elements in Group 1, also known as the alkali metals, all have 1 valence electron. This gives them similar properties such as being highly reactive and having a tendency to lose that electron to form a positive ion.
In contrast, elements in Group 18, also known as the noble gases, all have 8 valence electrons (except for helium, which has 2). This makes them stable and unreactive because their valence shell is already filled.
So, the similar properties of elements in the same group or family can be attributed to their similar number of valence electrons.
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The gold foil experiment performed in Rutherford's lab ________. Group of answer choices proved the law of multiple proportions
The gold foil experiment performed in Rutherford's lab did not prove the law of multiple proportions.
The gold foil experiment, also known as the Rutherford scattering experiment, was conducted by Ernest Rutherford in 1911 to investigate the structure of the atom. In this experiment, alpha particles were directed at a thin gold foil, and their scattering patterns were observed.
The main conclusion drawn from the gold foil experiment was the discovery of the atomic nucleus. Rutherford observed that most of the alpha particles passed through the gold foil with minimal deflection, indicating that atoms are mostly empty space. However, a small fraction of alpha particles were deflected at large angles, suggesting the presence of a concentrated positive charge in the center of the atom, which he called the nucleus.
The law of multiple proportions, on the other hand, is a principle in chemistry that states that when two elements combine to form multiple compounds, the ratio of masses of one element that combine with a fixed mass of the other element can be expressed in small whole numbers. This law was formulated by John Dalton and is unrelated to Rutherford's gold foil experiment.
The gold foil experiment performed in Rutherford's lab did not prove the law of multiple proportions. Its main contribution was the discovery of the atomic nucleus and the proposal of a new atomic model, known as the Rutherford model or planetary model.
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Consider the reaction H3PO4 + 3 NaOH â Na3PO4 + 3 H2O How much Na3PO4 can be prepared by the reaction of 3.92 g of H3PO4 with an excess of NaOH? Answer in units of g.
The reaction H₃PO₄ + 3 NaOH → Na₃PO₄ + 3 H₂O . 6.46 grams of Na₃PO₄ can be prepared by the reaction of 3.92 grams of H₃PO₄ with an excess of NaOH.
To determine the amount of Na₃PO₄ that can be prepared, we need to consider the balanced chemical equation and the stoichiometric ratio between H₃PO₄ and Na₃PO₄.
The balanced equation is:
H₃PO₄ + 3 NaOH → Na₃PO₄ + 3 H₂O
From the equation, we can see that 1 mole of H₃PO₄ reacts to produce 1 mole of Na₃PO₄. Therefore, the stoichiometric ratio is 1:1.
First, let's calculate the number of moles of H₃PO₄ given its mass:
Mass of H₃PO₄ = 3.92 g
Molar mass of H₃PO₄ = 97.994 g/mol
Moles of H₃PO₄ = Mass / Molar mass = 3.92 g / 97.994 g/mol
Since the stoichiometric ratio is 1:1, the moles of Na₃PO₄ produced will be equal to the moles of H₃PO₄.
Moles of Na₃PO₄ = Moles of H₃PO₄ = 3.92 g / 97.994 g/mol
Now, let's calculate the mass of Na₃PO₄ using the molar mass of Na₃PO₄:
Molar mass of Na₃PO₄ = 163.94 g/mol
Mass of Na₃PO₄ = Moles of Na₃PO₄ * Molar mass of Na₃PO₄
By substituting the calculated values into the equation, we can find the mass of Na₃PO₄ that can be prepared:
Mass of Na₃PO₄ = (3.92 g / 97.994 g/mol) * 163.94 g/mol
Calculating the result:
Mass of Na₃PO₄ ≈ 6.46 g
Therefore, approximately 6.46 grams of Na₃PO₄ can be prepared by the reaction of 3.92 grams of H₃PO₄ with an excess of NaOH.
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